CN109054619A - A kind of water-repellent paint with the weather-proof wear-resisting anti-fouling and self-cleaning of environmentally friendly high adhesiveness - Google Patents
A kind of water-repellent paint with the weather-proof wear-resisting anti-fouling and self-cleaning of environmentally friendly high adhesiveness Download PDFInfo
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- CN109054619A CN109054619A CN201811052852.XA CN201811052852A CN109054619A CN 109054619 A CN109054619 A CN 109054619A CN 201811052852 A CN201811052852 A CN 201811052852A CN 109054619 A CN109054619 A CN 109054619A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/08—Polyurethanes from polyethers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/004—Reflecting paints; Signal paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
Abstract
The invention discloses a kind of water-repellent paints with the weather-proof wear-resisting anti-fouling and self-cleaning of environmentally friendly high adhesiveness, including amine terminated polyether, liquid amine chainextender, isocyanates, oligomer dihydric alcohol, acrylic resin, organic silicon modified polyurethane, powder and auxiliary reagent, the auxiliary reagent is filler, reinforcing agent, crosslinking agent, catalyst, plasticizer, chain extender, pigment, tackifier, stabilizer, fire retardant and heat-resistant agent;The powder is;Special cement and graded sand;The water-repellent paint has outstanding metal base adhesive force, good fracture elongation and tensile strength, is able to maintain excellent performance, excellent water resistance, excellent solar reflecting properties, excellent long-term stain resistance under circumstances;Excellent physicochemical property, high anti-tensile impact strength, wearability, prevent the performances such as wet and slippery, ageing-resistant, anticorrosion at flexibility;It can the spray mo(u)lding on any ground such as steel, timber, concrete.
Description
Technical field
The present invention relates to a kind of water-repellent paints, and in particular to a kind of with the weather-proof wear-resisting anti-fouling and self-cleaning of environmentally friendly high adhesiveness
Water-repellent paint.
Background technique
Water-repellent paint is to be based on pure acrylic polymer emulsion, and one-component water and milk prepared by other additives is added
Type water-repellent paint.The waterproofing membrane formed after water-repellent paint is cured has certain extensibility, elastoplasticity, crack resistance, impervious
Property and weatherability, waterproof can be played, anti-blend protective effect.Water-repellent paint has good thermal adaptability, easy to operate, is easy to
Maintenance and maintenance.Polyurethane water-proof paint is a kind of one pack system Environmental-protecwaterproof waterproof paint of liquid construction, is with imported polyurethane
Performed polymer is fundamental component, the additives such as no tar and pitch.It is in air moisture contact after solidify, in substrate surface shape
At one layer of firm tough and tensile seamless integral waterproofing film.But existing water-repellent paint does not have environmental-protecting performance, often goes out
Now pungent pernicious gas distributes outlet, pollutes environment, is difficult to decompose, contaminated soil, and adhesive property is poor, in marine use
Middle poor corrosion resistance, do not have it is weather-proof wear-resisting, anti-pollution self-cleaning function brings inconvenience.
Summary of the invention
The object of the invention is that provide a kind of weather-proof wear-resisting with environmentally friendly high adhesiveness to solve the above-mentioned problems
The water-repellent paint of anti-fouling and self-cleaning, to solve the above problems.
In order to solve the above-mentioned technical problems, the present invention provides the following technical solutions:
The present invention provides a kind of water-repellent paints with the weather-proof wear-resisting anti-fouling and self-cleaning of environmentally friendly high adhesiveness, including Amino End Group
Polyethers, liquid amine chainextender, isocyanates, oligomer dihydric alcohol, acrylic resin, organic silicon modified polyurethane, powder and auxiliary
Help reagent, described amine terminated polyether 10-15 parts;6-8 parts of liquid amine chainextender;The isocyanates is 6-10 parts;It is described oligomeric
7-12 parts of object dihydric alcohol;The acrylic resin is 6-8 parts;The organic silicon modified polyurethane is 7-9 parts;The powder is 4-
6 parts;Auxiliary reagent 15-32;The auxiliary reagent be filler, reinforcing agent, crosslinking agent, catalyst, plasticizer, chain extender,
Pigment, tackifier, stabilizer, fire retardant and heat-resistant agent;Its ingredient is 1-3 parts;The powder is;Special cement and gradation
The ratio of sand, the special cement and the graded sand is 1:1.
As a preferred technical solution of the present invention, method of preparation and use is as follows:
Step 1: by the amine terminated polyether, the liquid amine chainextender, the pigment, the filler and the chain
Growing agent is launched in double-planet stirred tank, is stirred 1 hour and is evacuated;And it is packed into A barrels and is sealed packaging;
Step 2: by the isocyanates, the oligomer dihydric alcohol, the catalyst, the plasticizer and the benefit
Strong agent is launched in double-planet stirred tank, is stirred 1 hour and is evacuated;And it is packed into B barrels and is sealed packaging;
Step 3: by the acrylic resin, organic silicon modified polyurethane, the powder, the crosslinking agent, described
Tackifier, the stabilizer, the fire retardant and the heat-resistant agent are launched in double-planet stirred tank, are stirred 20 minutes simultaneously
It is evacuated;And it is packed into C barrels and is sealed packaging;
Step 4: when use, the reagent in A, B and C barrels is launched and is stirred in a mixing bowl after five minutes, is led to
Spray gun is crossed to be sprayed.
As a preferred technical solution of the present invention, the amine terminated polyether, the liquid amine chainextender, the isocyanide
Acid esters and the oligomer dihydric alcohol react the polyureas of production under certain condition.
As a preferred technical solution of the present invention, the organic silicon modified polyurethane can be made by modified method
Standby coating out.
As a preferred technical solution of the present invention, the powder is compared by the special cement and the graded sand by one
One is combined, and cement is a kind of hydraulic cementing materials, and combines with the organic silicon modified polyurethane.
As a preferred technical solution of the present invention, spraying method in the step 4, directly upper spray mo(u)lding, construction
Temperature is that solidification is constructed or sprayed in ice face at -28 DEG C.
As a preferred technical solution of the present invention, the synthesis technology of the amine terminated polyether is continuous fixed bed work
Skill utilizes the metallic catalyst being supported on carrier.
As a preferred technical solution of the present invention, the isocyanates is the isocyanates of two functional groups or more;
It is industrial that isocyanates is mainly produced using primary amine phosgenation;The acrylic resin is thermosetting acrylic resin.
As a preferred technical solution of the present invention, the organic silicon modified polyurethane is silicone oligomer and poly- ammonia
A kind of modified resin made of ester resin is common;With the polyester resin component containing activity through base first and containing activity through base or alkoxy
Silicone oligomer reaction, the organosilicon modified polyester still rich in the light base of activity is generated, then with the isocyanate component
It is made as crosslinking agent.
The beneficial effects obtained by the present invention are as follows being: the present invention is a kind of with the weather-proof wear-resisting anti-fouling and self-cleaning of environmentally friendly high adhesiveness
Water-repellent paint, the water-repellent paint have outstanding metal base adhesive force, good fracture elongation and tensile strength, each
It is able to maintain excellent performance under kind of environment, excellent water resistance, excellent solar reflecting properties are excellent long-term resistance to be stained with
Dirt;Excellent physicochemical property, high anti-tensile impact strength, wearability, prevent wet and slippery, ageing-resistant, anticorrosion etc. at flexibility
Performance;It can the spray mo(u)lding on any ground such as steel, timber, concrete.
Specific embodiment
Hereinafter, preferred embodiments of the present invention will be described, it should be understood that preferred embodiment described herein is only used
In the description and interpretation present invention, it is not intended to limit the present invention.
The present invention provides a kind of water-repellent paint with the weather-proof wear-resisting anti-fouling and self-cleaning of environmentally friendly high adhesiveness, including Amino End Group gathers
Ether, liquid amine chainextender, isocyanates, oligomer dihydric alcohol, acrylic resin, organic silicon modified polyurethane, powder and auxiliary
Reagent, 10-15 parts of amine terminated polyether;6-8 parts of liquid amine chainextender;Isocyanates is 6-10 parts;7-12 parts of oligomer dihydric alcohol;
Acrylic resin is 6-8 parts;Organic silicon modified polyurethane is 7-9 parts;Powder is 4-6 parts;Auxiliary reagent 15-32;Auxiliary reagent
For filler, reinforcing agent, crosslinking agent, catalyst, plasticizer, chain extender, pigment, tackifier, stabilizer, fire retardant and heat-resisting
Agent;Its ingredient is 1-3 parts;Powder is;The ratio of special cement and graded sand, special cement and graded sand is 1:1.
Its method of preparation and use is as follows:
Step 1: amine terminated polyether, liquid amine chainextender, pigment, filler and chain extender are launched and is stirred into double-planet
It mixes in kettle, be stirred 1 hour and be evacuated;And it is packed into A barrels and is sealed packaging;
Step 2: isocyanates, oligomer dihydric alcohol, catalyst, plasticizer and reinforcing agent are launched and stirred into double-planet
In kettle, it is stirred 1 hour and is evacuated;And it is packed into B barrels and is sealed packaging;
Step 3: by acrylic resin, organic silicon modified polyurethane, powder, crosslinking agent, tackifier, stabilizer, fire retardant
It launches in double-planet stirred tank, be stirred 20 minutes and be evacuated with heat-resistant agent;And it is packed into C barrels and is sealed packet
Dress;
Step 4: when use, the reagent in A, B and C barrels is launched and is stirred in a mixing bowl after five minutes, is led to
Spray gun is crossed to be sprayed.
Amine terminated polyether, liquid amine chainextender, isocyanates and oligomer dihydric alcohol react production under certain condition
Polyureas has extremely strong weather-proof wear-and corrosion-resistant waterproof material.
Acrylic resin has excellent light resistance, outdoor exposure durability, acid-alkali-corrosive-resisting, and good film-forming property etc. is excellent
Point;And organic silicon modified polyurethane has good resistance to soiling, hydrophobicity;It can prepare to have by modified method and well prevent
The coating of dirty performance.
Powder is combined by special cement and graded sand by one to one, and cement is a kind of hydraulic cementing materials, with
The cohesive force of moisture substrate is strong, and moisture resistance is very good, and compression strength is high, and combines with organic silicon modified polyurethane, can make to have
Machine and inorganic combination have complementary advantages, temper toughness with gentleness, and anti-paint property improves, and pressure-resisting ratio improves, and comprehensive comparison is superior, reaches
Preferable waterproof effect.
Spraying method in step 4, directly upper spray mo(u)lding, does not generate sagging phenomenon, 5 seconds gels, 1 minute i.e. reachable
To walking intensity to moisture, temperature-insensitive, when construction, is not influenced by environment temperature, humidity, can be constructed at -28 DEG C;It can
Solidification is sprayed in ice face;It is environmentally friendly without any volatile organic matter, pollution-free construction, the harmless use of health construction.
The exothermic temperature of amine terminated polyether reduces, and product is colorless and transparent, high glaze, tough and tensile, heat shock resistance;It synthesizes work
Skill is continuous fixed-bed process, and using the metallic catalyst being supported on carrier, catalyst efficiency is high, and conversion rate of products is high,
Side reaction is few, and production cost is low and performance is stablized;Isocyanates is the isocyanates of two functional groups or more, and can be used for closing
At a series of polyurethane foam plastics of function admirables, rubber, elastic fibers, coating and adhesive;It is industrial main using primary
Amine phosgenation produces isocyanates;Acrylic resin is thermosetting acrylic resin, except the general performance with acrylic resin
In addition, also there is heat resistance, water resistance, solvent resistance and wear-resisting scratch-resistant performance;Organic silicon modified polyurethane is that organosilicon is low
Polymers and the common manufactured a kind of modified resin of polyurethane resin;It is first passed through with containing activity with the polyester resin component containing activity through base
The reaction of the silicone oligomer of base or alkoxy generates the organosilicon modified polyester still rich in the light base of activity, then with isocyanic acid
Ester component is made as crosslinking agent;It is chiefly used in preparing bicomponent polyurethane paint, its heat resistance and weather-proof can be improved in normal temperature cure
Property.
Embodiment 1
Formula and its ratio:
10 parts of amine terminated polyether;6 parts of liquid amine chainextender;Isocyanates is 6 parts;7 parts of oligomer dihydric alcohol;Acrylic acid tree
Rouge is 6 parts;Organic silicon modified polyurethane is 7 parts;Powder is 4 parts;Auxiliary reagent 15;Auxiliary reagent is filler, reinforcing agent, friendship
Join agent, catalyst, plasticizer, chain extender, pigment, tackifier, stabilizer, fire retardant and heat-resistant agent;Its ingredient is 1-3
Part;
Its method of preparation and use:
Step 1: the amine terminated polyether of metering, liquid amine chainextender, pigment, filler and chain extender are launched into double
In planet stirring kettle, it is stirred 1 hour and is evacuated;And it is packed into A barrels and is sealed packaging;
Step 2: the isocyanates of metering, oligomer dihydric alcohol, catalyst, plasticizer and reinforcing agent are launched into duplicate rows
In star stirred tank, it is stirred 1 hour and is evacuated;And it is packed into B barrels and is sealed packaging;
Step 3: the acrylic resin of metering, organic silicon modified polyurethane, powder, crosslinking agent, tackifier, stabilizer, resistance
Combustion agent and heat-resistant agent are launched in double-planet stirred tank, are stirred 20 minutes and are evacuated;And it is packed into C barrels and is sealed
Packaging;
Step 4: when use, the reagent in A, B and C barrels is launched and is stirred in a mixing bowl after five minutes, is led to
Spray gun is crossed respectively to spray stainless steel, galvanized sheet, aluminium sheet, concrete and timber.
Performance test:
The present invention is a kind of water-repellent paint with the weather-proof wear-resisting anti-fouling and self-cleaning of environmentally friendly high adhesiveness, which has
Outstanding metal base adhesive force, good fracture elongation and tensile strength are able to maintain excellent property under circumstances
Can, excellent water resistance, excellent solar reflecting properties, excellent long-term stain resistance;Excellent physicochemical property, it is high
Anti-tensile impact strength, flexibility, wearability, prevent the performances such as wet and slippery, ageing-resistant, anticorrosion;It can be in steel, timber, coagulation
Spray mo(u)lding can be widely used for the waterproof and anticorrosion engineering of various fields and type on any ground such as soil, be best suited for following engineering
Type: high-speed railway, tunnel, concrete surfacing bridge deck water-proof;The waterproof of various industry and civil building roof covering engineering;
The structures waterproof of industry and waterproof, moisture-proof and indoor swimming pool, the fire cistern of civil buildings underground engineering etc.;Subway,
The municipal works such as sewage farm, landfill waterproof;The water conservancy projects waterproof and anticorrosion such as water channel, pond;Sports ground, sport
Field, runway waterproof and anticorrosion;Industrial storage tank, large-scale component waterproof and anticorrosion;Bridge, airplane parking area, industry ground slab, parking lot etc. are wear-resisting anti-
Water layer.
Finally, it should be noted that the foregoing is only a preferred embodiment of the present invention, it is not intended to restrict the invention,
Although the present invention is described in detail referring to the foregoing embodiments, for those skilled in the art, still may be used
To modify the technical solutions described in the foregoing embodiments or equivalent replacement of some of the technical features.
All within the spirits and principles of the present invention, any modification, equivalent replacement, improvement and so on should be included in of the invention
Within protection scope.
Claims (9)
1. a kind of water-repellent paint with the weather-proof wear-resisting anti-fouling and self-cleaning of environmentally friendly high adhesiveness, including amine terminated polyether, liquid amine expand
Chain agent, isocyanates, oligomer dihydric alcohol, acrylic resin, organic silicon modified polyurethane, powder and auxiliary reagent, feature
It is, described amine terminated polyether 10-15 parts;6-8 parts of liquid amine chainextender;The isocyanates is 6-10 parts;The oligomer
7-12 parts of dihydric alcohol;The acrylic resin is 6-8 parts;The organic silicon modified polyurethane is 7-9 parts;The powder is 4-6
Part;Auxiliary reagent 15-32;The auxiliary reagent is filler, reinforcing agent, crosslinking agent, catalyst, plasticizer, chain extender, face
Material, tackifier, stabilizer, fire retardant and heat-resistant agent;Its ingredient is 1-3 parts;The powder is;Special cement and graded sand,
The ratio of the special cement and the graded sand is 1:1.
2. a kind of water-repellent paint with the weather-proof wear-resisting anti-fouling and self-cleaning of environmentally friendly high adhesiveness according to claim 1, special
Sign is that method of preparation and use is as follows:
Step 1: by the amine terminated polyether, the liquid amine chainextender, the pigment, the filler and the chain growth
Agent is launched in double-planet stirred tank, is stirred 1 hour and is evacuated;And it is packed into A barrels and is sealed packaging;
Step 2: by the isocyanates, the oligomer dihydric alcohol, the catalyst, the plasticizer and the reinforcing agent
It launches in double-planet stirred tank, be stirred 1 hour and be evacuated;And it is packed into B barrels and is sealed packaging;
Step 3: by the acrylic resin, the organic silicon modified polyurethane, the powder, the crosslinking agent, the thickening
Agent, the stabilizer, the fire retardant and the heat-resistant agent are launched in double-planet stirred tank, are stirred 20 minutes and are pumped into
Vacuum;And it is packed into C barrels and is sealed packaging;
Step 4: when use, the reagent in A, B and C barrels is launched and is stirred in a mixing bowl after five minutes, pass through spray
Rifle is sprayed.
3. a kind of water-repellent paint with the weather-proof wear-resisting anti-fouling and self-cleaning of environmentally friendly high adhesiveness according to claim 1, special
Sign is that the amine terminated polyether, the liquid amine chainextender, the isocyanates and the oligomer dihydric alcohol are in certain item
The polyureas of production is reacted under part.
4. a kind of water-repellent paint with the weather-proof wear-resisting anti-fouling and self-cleaning of environmentally friendly high adhesiveness according to claim 1, special
Sign is that the organic silicon modified polyurethane can prepare coating by modified method.
5. a kind of water-repellent paint with the weather-proof wear-resisting anti-fouling and self-cleaning of environmentally friendly high adhesiveness according to claim 1, special
Sign is that the powder is combined by the special cement and the graded sand by one to one, and cement is a kind of hydraulicity
Cementitious material, and combined with the organic silicon modified polyurethane.
6. a kind of water-repellent paint with the weather-proof wear-resisting anti-fouling and self-cleaning of environmentally friendly high adhesiveness according to claim 1, special
Sign is that the spraying method in the step 4, directly upper spray mo(u)lding, construction temperature is to construct at -28 DEG C or spray in ice face
Apply solidification.
7. a kind of water-repellent paint with the weather-proof wear-resisting anti-fouling and self-cleaning of environmentally friendly high adhesiveness according to claim 1, special
Sign is that the synthesis technology of the amine terminated polyether is continuous fixed-bed process, utilizes the metal catalytic being supported on carrier
Agent.
8. a kind of water-repellent paint with the weather-proof wear-resisting anti-fouling and self-cleaning of environmentally friendly high adhesiveness according to claim 1, special
Sign is that the isocyanates is the isocyanates of two functional groups or more;It is industrial mainly different using the production of primary amine phosgenation
Cyanate;The acrylic resin is thermosetting acrylic resin.
9. a kind of water-repellent paint with the weather-proof wear-resisting anti-fouling and self-cleaning of environmentally friendly high adhesiveness according to claim 1, special
Sign is that the organic silicon modified polyurethane is silicone oligomer and the common manufactured a kind of modified resin of polyurethane resin;
It is first reacted with containing activity through the silicone oligomer of base or alkoxy with the polyester resin component containing activity through base, generation is still rich in
The organosilicon modified polyester of active light base, is then made using the isocyanate component as crosslinking agent.
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CN109321055A (en) * | 2018-09-28 | 2019-02-12 | 江苏海田技术有限公司 | High adhesion force water-borne wood coating and its manufacturing method |
CN113072851A (en) * | 2021-03-30 | 2021-07-06 | 湖南盛天新材料有限公司 | Scratch-resistant self-cleaning silicon PU (polyurethane) finish paint and preparation method thereof |
CN114227924A (en) * | 2021-12-13 | 2022-03-25 | 温州天康新材料科技有限公司 | New material production facility |
CN115124916A (en) * | 2022-08-17 | 2022-09-30 | 河南永科智能电力设备有限公司 | Insulating moisture-proof durable paint, manufacturing method and using method |
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CN109321055A (en) * | 2018-09-28 | 2019-02-12 | 江苏海田技术有限公司 | High adhesion force water-borne wood coating and its manufacturing method |
CN113072851A (en) * | 2021-03-30 | 2021-07-06 | 湖南盛天新材料有限公司 | Scratch-resistant self-cleaning silicon PU (polyurethane) finish paint and preparation method thereof |
CN114227924A (en) * | 2021-12-13 | 2022-03-25 | 温州天康新材料科技有限公司 | New material production facility |
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Application publication date: 20181221 |