CN101074345A - Color SBS modified waterproof asphalt material - Google Patents

Color SBS modified waterproof asphalt material Download PDF

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Publication number
CN101074345A
CN101074345A CN 200710054646 CN200710054646A CN101074345A CN 101074345 A CN101074345 A CN 101074345A CN 200710054646 CN200710054646 CN 200710054646 CN 200710054646 A CN200710054646 A CN 200710054646A CN 101074345 A CN101074345 A CN 101074345A
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CN
China
Prior art keywords
sbs
asphalt material
waterproof asphalt
modified waterproof
sbs modified
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN 200710054646
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Chinese (zh)
Inventor
翟广玉
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Zhengzhou University
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Zhengzhou University
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Filing date
Publication date
Application filed by Zhengzhou University filed Critical Zhengzhou University
Priority to CN 200710054646 priority Critical patent/CN101074345A/en
Publication of CN101074345A publication Critical patent/CN101074345A/en
Pending legal-status Critical Current

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Abstract

A color SBS modified asphalt waterproof coating with colorless asphalt as main filming substance is cheap and convenient. It adopts diamylene resin and petroleum resin as viscosity increaser and acetic ether as solvent. It saves resources, It's non-toxic, has no environmental pollution and excellent heat, freezing, ageing, water and weather resistances, has better extensibility and adhesive strength. It can be used for roof of architectures, toilet, gain depot, dam, oil depot, pipeline, swimming pool and tunnel.

Description

Color SBS modified waterproof asphalt material
Technical field
The invention belongs to the coating class in the chemical industry.Just be to use the waterproof paint on buildings specifically.
Background technology
The SBS modified waterproof asphalt material has overcome pitch heat and has dropped down cold short shortcoming, and tension set is big, and good weatherability is applied widely, is widely used in the water proof anti-seepage engineering of various buildings.But also there are some significant disadvantages in the SBS modified waterproof asphalt material: 1. color is single.At present, the SBS modified waterproof asphalt material of domestic use all is a black, and this is because the pitch that uses when producing is that black causes.Because pitch is black, can only produce the SBS modified waterproof asphalt material of black, color is single.Use the SBS modified waterproof asphalt material of black, because the heat-absorbing action of black, when using on building roofing, the top layer room temp of buildings will have rising slightly in summer, brings extra burden with regard to the reducing temperature of heatstroke prevention of giving the user; 2. bonding strength is poor.Because the polarity of SBS is less, and is relatively poor with the bonding strength of other materials.The bonding strength of the modified waterproof asphalt material of use SBS preparation is also poor, and the sticking power on buildings is relatively poor; 3. environmental pollution is big.The SBS modified waterproof asphalt material mainly contains two kinds of production methods at present.A kind of is hot melt process, and another kind is the normal temperature method.Hot melt process needs heating, and temperature controlling is very crucial.Temperature height, pitch produce blue or green cigarette, emit a large amount of poisonous smogs, and be very big to operator's healthy effect, serious environment pollution; Temperature is low, and pitch and SBS can not well dissolve mutually, poor storage stability, and the bituminous modified effect is not obvious, the poor-performing of coating.Normal temperature is produced the SBS modified waterproof asphalt material, is that pitch and SBS are dissolved in benzene, or toluene, or cold mixing forms in the dimethylbenzene equal solvent.Because benzene kind solvent toxicity is bigger, and the production operation workers'health is had a strong impact on, environmental pollution is serious.In sum, special the present invention---the color SBS modified waterproof asphalt material that proposes.
Summary of the invention
Color SBS modified waterproof asphalt material, use be colourless pitch.Because pitch is colourless, the SBS modified waterproof asphalt material of producing also is colourless, can add different pigment according to user's needs, makes various color SBS modified waterproof asphalt materials.For example, add titanium dioxide or zinc sulfide white, can make white SBS modified waterproof asphalt material.Add red iron oxide, can make red SBS modified waterproof asphalt material.Add chromoxide green, can make green SBS modified waterproof asphalt material etc.
Color SBS modified waterproof asphalt material, owing to used the SBS modifying asphalt, modified effect is good.SBS is vinylbenzene (Styrene) and divinyl (Butadiene) polymeric segmented copolymer, and its molecular composition is formed by this three pitch chains section phase embedding of vinylbenzene segment (S)-polyhutadiene (B)-vinylbenzene segment (S).The snappiness that has rubber under the normal temperature can show the plasticity-of thermoplastics again during high temperature, have the fundamental characteristics of rubber and plastics concurrently.Use the pitch of SBS modification, tension set is big, and the UV resistant irradiation is anti-aging, Pei Zhi waterproof paint thus, and water proof anti-seepage is effective, excellent property, good weatherability; Because the polarity of SBS is less, and is relatively poor with the bonding strength of other materials.The present invention uses terpine resin and petroleum resin to do tackifier, and SBS has been carried out modification, has improved the bonding strength of SBS to other materials, has improved the sticking power to buildings, and adhesive effect is good.
Color SBS modified waterproof asphalt material is produced at normal temperatures, saves the energy, and is easy and simple to handle.
Color SBS modified waterproof asphalt material uses nontoxic organic solvent to replace the bigger benzene kind solvent of toxicity, has improved production operation workman's Working environment, has reduced environmental pollution.On the solvent of color SBS modified waterproof asphalt material was selected, the present invention abides by can make SBS, pitch, tackifying resin be dissolved as criterion, according to the similar principle that mixes, chose Yi Rong, low toxicity, inexpensive solvent.Through after a large amount of experiments, the present invention has selected petroleum naphtha, acetoneand ethyl acetate to use as mixed solvent, and this mixed solvent is to SBS, pitch, good, nontoxic, the non-environmental-pollution of tackifying resin solubility property.
Color SBS modified waterproof asphalt material adds mica powder and talcum powder as filler, the hole in can the filling waterproof paint filming, increase the density of filming, stop uviolizing, anti-aging, improve flowability, the levelling property of coating, improve the fullness ratio of coating.Mica powder is flakey, and it uses in waterproof paint, can improve the toughness of filming, and can stop penetrating of ultraviolet ray and moisture, prevents be full of cracks and efflorescence, can improve the weather resistance and the water-repellancy of filming.
Color SBS modified waterproof asphalt material, heat-resisting freeze proof, good extending performance; It is a solvent-borne type, has avoided the aqueous waterproofing paint waterproof effect bad, shortcomings such as loss of properties on aging; It can make shades of colour as required, has overcome the single shortcoming of other waterproof paint color; Its tension set is big, and bonding strength is good; Its water proof anti-seepage, anti-aging, good weatherability; Its cold construction, directly brushing is easy and simple to handle; It is applicable to the new old roof of various buildingss, waterproof, antiseepage, the protection against the tide of all kinds of buildings such as vault, toilet, grain depot, water conservancy dykes and dams, oil depot, pipeline, swimming pool, tunnel, construction joint, expansion joint, road and bridge.
The prescription of color SBS modified waterproof asphalt material is as follows:
Material name mass percent (%)
SBS 4-15
Colourless pitch 10-30
Terpine resin 5-10
Petroleum resin 1-6
Petroleum naphtha 5-20
Acetone 5-15
Ethyl acetate 5-18
Mica powder 1-9
Talcum powder 1-10
Pigment 2-15
Above-mentioned all components sum equals 100%.
The technological process of production:
Technological process:
1.SBS the preparation of solution: get petroleum naphtha, acetoneand ethyl acetate, add SBS, terpine resin and petroleum resin, stirring is dissolved it fully, and is standby.
2. the preparation of bituminous solution: get petroleum naphtha, acetoneand ethyl acetate, add colourless pitch, stirring is dissolved it fully, and is standby.
3. the preparation of color SBS modified waterproof asphalt material: SBS solution and bituminous solution are mixed, add mica powder, talcum powder and pigment, mix.Detect, filter, promptly get product of the present invention.
Embodiment
Embodiment one
White SBS modified waterproof asphalt material
Prescription:
Material name mass percent (%)
SBS 12
Colourless pitch 21
Terpine resin 5
Petroleum resin 6
Petroleum naphtha 20
Acetone 10
Ethyl acetate 15
Mica powder 2
Talcum powder 2
Titanium dioxide 7
Technological process:
1.SBS the preparation of solution: get 10kg petroleum naphtha, 5kg acetone and 10kg ethyl acetate, add 12kgSBS, 5kg terpine resin and 6kg petroleum resin, stirring is dissolved it fully, and is standby.
2. the preparation of bituminous solution: get 10kg petroleum naphtha, 5kg acetone and 5kg ethyl acetate, add the colourless pitch of 21kg, stirring is dissolved it fully, and is standby.
3. the preparation of color SBS modified waterproof asphalt material: SBS solution and bituminous solution are mixed, add 2kg mica powder, 2kg talcum powder and 7kg titanium dioxide, mix.Detect, filter, promptly get product of the present invention.
Embodiment two
Green SBS modified waterproof asphalt material
Prescription:
Material name mass percent (%)
SBS 12
Colourless pitch 21
Terpine resin 5
Petroleum resin 6
Petroleum naphtha 20
Acetone 10
Ethyl acetate 15
Mica powder 2
Talcum powder 2
Chromoxide green 7
Technological process:
1.SBS the preparation of solution: get 10kg petroleum naphtha, 5kg acetone and 10kg ethyl acetate, add 12kgSBS, 5kg terpine resin and 6kg petroleum resin, stirring is dissolved it fully, and is standby.
2. the preparation of bituminous solution: get 10kg petroleum naphtha, 5kg acetone and 5kg ethyl acetate, add the colourless pitch of 21kg, stirring is dissolved it fully, and is standby.
3. the preparation of color SBS modified waterproof asphalt material: SBS solution and bituminous solution are mixed, add 2kg mica powder, 2kg talcum powder and 7kg chromoxide green, mix.Detect, filter, promptly get product of the present invention.
Embodiment three
Red SBS modified waterproof asphalt material
Prescription:
Material name mass percent (%)
SBS 12
Colourless pitch 21
Terpine resin 5
Petroleum resin 6
Petroleum naphtha 20
Acetone 10
Ethyl acetate 15
Mica powder 2
Talcum powder 2
Red iron oxide 7
Technological process:
1.SBS the preparation of solution: get 10kg petroleum naphtha, 5kg acetone and 10kg ethyl acetate, add 1kgSBS, 5kg terpine resin and 6kg petroleum resin, stirring is dissolved it fully, and is standby.
2. the preparation of bituminous solution: get 10kg petroleum naphtha, 5kg acetone and 5kg ethyl acetate, add the colourless pitch of 21kg, stirring is dissolved it fully, and is standby.
3. the preparation of color SBS modified waterproof asphalt material: SBS solution and bituminous solution are mixed, add 2kg mica powder, 2kg talcum powder and 7kg red iron oxide, mix.Detect, filter, promptly get product of the present invention.
Reference:
1. natural latex rubber modified waterproof asphalt material of the wide friendly Zhu Qing in Pu grace timely rain Shandong and preparation method thereof CN 1072436
2. Liu state heat-clearing plastic rubber roofing waterproof paint and preparation method CN 1478838
3. high woods duckweed poplar ancestor literary composition multifunctional colour water-proof paint CN 1109902
4. Cui Ke increases the method for making CN 1096527 of the outstanding uniform thickness matter of Zhang Jingyi Zhao Ju modified waterproof asphalt material.

Claims (1)

1. color SBS modified waterproof asphalt material is characterized in that the mass percent that raw material is formed is:
Material name mass percent (%)
SBS 4-15
Colourless pitch 10-30
Terpine resin 5-10
Petroleum resin 1-6
Petroleum naphtha 5-20
Acetone 5-15
Ethyl acetate 5-18
Mica powder 1-9
Talcum powder 1-10
Pigment 2-15
Above-mentioned all components sum equals 100%.
The addition sequence of each feed composition and working method are:
1. the preparation of .SBS solution: get petroleum naphtha, acetoneand ethyl acetate, add SBS, terpine resin and petroleum resin, stirring is dissolved it fully, and is standby.
2.. the preparation of bituminous solution: get petroleum naphtha, acetoneand ethyl acetate, add colourless pitch, stirring is dissolved it fully, and is standby.
3.. the preparation of color SBS modified waterproof asphalt material: SBS solution and bituminous solution are mixed, add mica powder, talcum powder and pigment, mix.Detect, filter, promptly get product of the present invention.
CN 200710054646 2007-06-22 2007-06-22 Color SBS modified waterproof asphalt material Pending CN101074345A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 200710054646 CN101074345A (en) 2007-06-22 2007-06-22 Color SBS modified waterproof asphalt material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 200710054646 CN101074345A (en) 2007-06-22 2007-06-22 Color SBS modified waterproof asphalt material

Publications (1)

Publication Number Publication Date
CN101074345A true CN101074345A (en) 2007-11-21

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
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Country Status (1)

Country Link
CN (1) CN101074345A (en)

Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101921545A (en) * 2010-09-27 2010-12-22 杭州中富彩新材料科技有限公司 Asphalt waterproof paint for building and preparation method thereof
CN101935488A (en) * 2010-09-30 2011-01-05 北京立高科技股份有限公司 Plant root resistant waterproof coating and preparation method thereof
CN102108234A (en) * 2010-12-22 2011-06-29 白铁林 Colourful environmental-friendly synthesized polymer waterproof paint
CN102120916A (en) * 2011-01-18 2011-07-13 白晓斌 Macromolecular colored road surface anti-skid coating
CN102199397A (en) * 2010-03-23 2011-09-28 陈磊 Self-healing elastic waterproof paint and its preparation technology
CN102408829A (en) * 2011-10-27 2012-04-11 北京东方雨虹防水技术股份有限公司 Hot melt type modified asphalt waterproof paint and preparation method thereof
CN102443322A (en) * 2010-10-12 2012-05-09 3M创新有限公司 Paint composition and coating product prepared from same
CN103421428A (en) * 2013-08-19 2013-12-04 南通市通州区俊朗建筑工程有限公司 Waterproof asphalt cement coating
CN103468140A (en) * 2013-08-16 2013-12-25 安徽快来防水防腐有限公司 Rubber-asphalt waterproof coating
CN103468142A (en) * 2013-08-16 2013-12-25 安徽快来防水防腐有限公司 Solvent type petroleum asphalt waterproof coating
CN103554933A (en) * 2013-10-21 2014-02-05 长安大学 High adhesion prime coat oil for cement stabilized macadam base and preparation method of high adhesion prime coat oil
CN103602266A (en) * 2013-11-18 2014-02-26 三友(天津)高分子技术有限公司 Normal-temperature stone-impact-resistant paint and preparation method thereof
CN103666260A (en) * 2013-09-12 2014-03-26 宁波镭纳涂层技术有限公司 Color polymer modified emulsion asphalt-base waterproof paint and preparation method thereof
CN104109479A (en) * 2014-06-18 2014-10-22 安徽先锋门业科技有限公司 Preparation method of thermoplastic rubber modified asphalt waterproof paint
CN105482703A (en) * 2015-12-14 2016-04-13 广东鑫大公路材料有限公司 Application of polymer-colorful modified emulsified asphalt in road marking
CN107100380A (en) * 2017-05-15 2017-08-29 江阴正邦化学品有限公司 Old roof waterproof renovation method and exposed conveying appliance weather resisting colorful water-repellent paint used
CN109135669A (en) * 2018-08-16 2019-01-04 肇庆欧迪斯实业有限公司 For bonding plastics and the bonding agent of concrete and preparation method thereof
CN110028904A (en) * 2019-04-02 2019-07-19 中铁四局集团有限公司 A kind of modified waterproof asphalt material and preparation method thereof
CN111138977A (en) * 2019-12-30 2020-05-12 上海浦东路桥沥青材料有限公司 Asphalt paint and preparation method thereof

Cited By (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102199397A (en) * 2010-03-23 2011-09-28 陈磊 Self-healing elastic waterproof paint and its preparation technology
CN102199397B (en) * 2010-03-23 2015-05-20 陈磊 Self-healing elastic waterproof paint and its preparation technology
CN101921545A (en) * 2010-09-27 2010-12-22 杭州中富彩新材料科技有限公司 Asphalt waterproof paint for building and preparation method thereof
CN101935488A (en) * 2010-09-30 2011-01-05 北京立高科技股份有限公司 Plant root resistant waterproof coating and preparation method thereof
CN102443322B (en) * 2010-10-12 2014-06-18 3M创新有限公司 Paint composition and coating product prepared from same
CN102443322A (en) * 2010-10-12 2012-05-09 3M创新有限公司 Paint composition and coating product prepared from same
CN102108234A (en) * 2010-12-22 2011-06-29 白铁林 Colourful environmental-friendly synthesized polymer waterproof paint
CN102120916B (en) * 2011-01-18 2013-07-31 白晓斌 Macromolecular colored road surface anti-skid coating
CN102120916A (en) * 2011-01-18 2011-07-13 白晓斌 Macromolecular colored road surface anti-skid coating
CN102408829A (en) * 2011-10-27 2012-04-11 北京东方雨虹防水技术股份有限公司 Hot melt type modified asphalt waterproof paint and preparation method thereof
CN103468140A (en) * 2013-08-16 2013-12-25 安徽快来防水防腐有限公司 Rubber-asphalt waterproof coating
CN103468142A (en) * 2013-08-16 2013-12-25 安徽快来防水防腐有限公司 Solvent type petroleum asphalt waterproof coating
CN103421428A (en) * 2013-08-19 2013-12-04 南通市通州区俊朗建筑工程有限公司 Waterproof asphalt cement coating
CN103666260A (en) * 2013-09-12 2014-03-26 宁波镭纳涂层技术有限公司 Color polymer modified emulsion asphalt-base waterproof paint and preparation method thereof
CN103666260B (en) * 2013-09-12 2016-05-11 宁波镭纳涂层技术有限公司 Colored modified-high polymer emulsion type asphaltic base water-repellent paint and preparation method thereof
CN103554933A (en) * 2013-10-21 2014-02-05 长安大学 High adhesion prime coat oil for cement stabilized macadam base and preparation method of high adhesion prime coat oil
CN103554933B (en) * 2013-10-21 2015-09-23 长安大学 For the high-adhesion priming oil and preparation method thereof of cement stabilized macadam base
CN103602266A (en) * 2013-11-18 2014-02-26 三友(天津)高分子技术有限公司 Normal-temperature stone-impact-resistant paint and preparation method thereof
CN103602266B (en) * 2013-11-18 2016-01-20 三友(天津)高分子技术有限公司 A kind of Normal-temperature stone-impact-resistapaint paint and preparation method thereof
CN104109479A (en) * 2014-06-18 2014-10-22 安徽先锋门业科技有限公司 Preparation method of thermoplastic rubber modified asphalt waterproof paint
CN105482703A (en) * 2015-12-14 2016-04-13 广东鑫大公路材料有限公司 Application of polymer-colorful modified emulsified asphalt in road marking
CN107100380A (en) * 2017-05-15 2017-08-29 江阴正邦化学品有限公司 Old roof waterproof renovation method and exposed conveying appliance weather resisting colorful water-repellent paint used
CN107100380B (en) * 2017-05-15 2019-06-18 江阴正邦化学品有限公司 Old roof waterproof renovation method and exposed conveying appliance weather resisting colorful water-repellent paint used
CN109135669A (en) * 2018-08-16 2019-01-04 肇庆欧迪斯实业有限公司 For bonding plastics and the bonding agent of concrete and preparation method thereof
CN110028904A (en) * 2019-04-02 2019-07-19 中铁四局集团有限公司 A kind of modified waterproof asphalt material and preparation method thereof
CN111138977A (en) * 2019-12-30 2020-05-12 上海浦东路桥沥青材料有限公司 Asphalt paint and preparation method thereof

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Inventor after: Di Guangyu

Inventor after: Zhang Yinpeng

Inventor after: Chen Jianwei

Inventor before: Di Guangyu

COR Change of bibliographic data

Free format text: CORRECT: INVENTOR; FROM: ZHAI GUANGYU TO: ZHAI GUANGYU ZHANG YINPENG CHEN JIANWEI

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Open date: 20071121