CN101570667B - Radioresistant, high temperature resistant and waterproof sealing rubber belt material and preparation method thereof - Google Patents
Radioresistant, high temperature resistant and waterproof sealing rubber belt material and preparation method thereof Download PDFInfo
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- CN101570667B CN101570667B CN 200910067089 CN200910067089A CN101570667B CN 101570667 B CN101570667 B CN 101570667B CN 200910067089 CN200910067089 CN 200910067089 CN 200910067089 A CN200910067089 A CN 200910067089A CN 101570667 B CN101570667 B CN 101570667B
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Abstract
The invention provides a radioresistant, high temperature resistant and waterproof sealing rubber belt. Rubber is degraded by a basal body of an open mill through mastication, and is additionally provided with viscosity increaser, reinforcing filler, age resistor and radioresistant rubber; the operation of milling is carried out repeatedly until the materials are uniformly mixed; and the well mixed materials are cut into stripe-shaped standard sample stripes, and the radioresistant, high temperature resistant and waterproof sealing rubber belt can be obtained. The invention adopts the mixture of butyl rubber and ethylene propylene terpolymer rubber; under high irradiation dose, the cross bonding and the degrading parts of the two rubbers are counteracted and combined with each other to maintain the properties of the sealing rubber belt; and the compatibility of the radioresistant silicon rubber and the basal body is good, and the dose of the age inhibitor is slightly higher than the dose in a normal rubber system so as to enhance the high temperature property and the radioresistant property of the sealing rubber belt.
Description
Technical field
The present invention relates to a kind of anti-irradiation, high temperature resistant, water-proof seal adhesive tape, the preparation technology of sealing adhesive tape also is provided simultaneously, belong to cable accessory manufacturing technology field.
Background technology
Along with developing rapidly of nation-building cause, rubber plastic cable is used widely in all trades and professions, and the docking of moulding the cable splice place for rafter requires also more and more higher, should convenient construction, again firm and durable.Develop insulation, waterproof, self-adhesion sealant tape take isoprene-isobutylene rubber as main base material for this reason, and used it for the joint of rubber plastic cable, obtained good effect.
The isoprene-isobutylene rubber water-proof seal adhesive tape is the elastoplasticity sealing tape of making take saturated polyisobutylene rubber, isoprene-isobutylene rubber etc. as main raw material.This series products has excellent resistance to air loss, watertightness, good autohension, extensibility, weathering resistance, lower temperature resistance and water tolerance, solvent-free pollution, the i.e. characteristics such as sticking i.e. usefulness, construction safety convenience.But saturated polyisobutylene rubber, isoprene-isobutylene rubber are typical irradiation to crack polymkeric substance.The tensile strength at yield of this type of water-proof seal adhesive tape, flexibility, recovery of elasticity and elongation at break all increase with irradiation dose and obviously descend, when it is used for high radiation field institute (such as Nuclear power plants, aerospace etc.), will lose the effects such as its original insulation, waterproof, self-adhesion.
Summary of the invention
Main purpose of the present invention is by selecting suitable base rubber, and adds anti-irradiation composition and prepare a kind of anti-irradiation, resistant to elevated temperatures insulation water-proof seal adhesive tape.
The present invention also provides the preparation method of above-mentioned sealant tape, is applicable to suitability for industrialized production.
The anti-irradiation of the present invention, resistant to elevated temperatures insulation water-proof seal adhesive tape are comprised of by mass parts following material:
The water proof rubber matrix of 15-30 part, the tackifier of 20-30 part, the reinforcing filler of 15-30 part, the anti-aging agent of 0.5-5 part, the rubber of anti-irradiation of 1-10 part.
The rubber matrix that the present invention adopts is the mixture of terpolymer EP rubber and isoprene-isobutylene rubber, and its blending ratio is: (1~2): (1~2).
It is tackifier that the present invention adopts terpine resin and polyisobutene, and its blending ratio is: (1~1.5): 1.
It is reinforcing filler that the present invention adopts aluminium hydroxide.
The anti-aging agent that the present invention adopts is antioxidant MB or anti-aging agent RD or both mixtures.
The rubber of anti-irradiation that the present invention adopts is silicon rubber.
The concrete preparation method of the anti-irradiation of the present invention, resistant to elevated temperatures insulation water-proof seal adhesive tape is as follows:
The rubber of 15-30 part is degraded with mill matrix mastication, add the tackifier of 20-30 part, the reinforcing filler of 15-30 part, the anti-aging agent of 0.5-5 part, the rubber of anti-irradiation of 1-10 part, repeatedly mixing, until material is mixing evenly.The material that mixes is cut into strip, is strip with extruder for shaping, adopts automatic cutting means, is cut into the standard batten of 350 * 25 * 1.8mm, just obtains anti-irradiation, resistant to elevated temperatures insulation water-proof seal adhesive tape.
Positively effect of the present invention is: the anti-irradiation that obtains, resistant to elevated temperatures insulation water-proof seal adhesive tape, adopt the mixture of isoprene-isobutylene rubber and terpolymer EP rubber: wherein isoprene-isobutylene rubber is the irradiation-induced degradation type, and terpolymer EP rubber is irradiation crosslinking type, under high irradiation dose, two kinds of rubber crosslinked and degraded partial offset interosculate to keep the performance of sealant tape; The consistency of selected anti-irradiation silicon rubber and matrix is better in addition, and the amount of anti-aging agent is larger than the amount in the normal rubbery system, strengthens its high-temperature behavior and radiation-resistant property.
Embodiment:
Respectively with isoprene-isobutylene rubber 120,268, terpolymer EP rubber 4045, the degraded of 4725 mastications are until the rubber color is turned white or can when shoaling.Be used for following examples.
Embodiment 1
Get 2kg open 120 isoprene-isobutylene rubbers after the refining and 2.5Kg4045 terpolymer EP rubber mixing evenly after, add 1Kg silicon rubber, and 0.1Kg hexichol dihydroxy expanding material, after mixing, add 3.75Kg aluminium hydroxide, 0.4kg antioxidant MB, 0.6Kg anti-aging agent RD, after powder is infiltrated fully, add the 2.5Kg terpine resin, the 2.2Kg polyisobutene is adjusted roll spacing repeatedly, material is fully mixed, the discharging when time reaches about 20 minutes.
The glue that refining is good cuts into strip about 10 * 100mm with cutter.
Under 120 ℃ of temperature, being pressed into the sheet glue of 1.8mm with oil press, it is cut into the adhesive tape of 350 * 25 * 1.8mm, is 1
#Sample.
Embodiment 2
To open refining roller roller temperature and transfer to 120 ℃, get 2.3kg open 120 isoprene-isobutylene rubbers after the refining and 2.4Kg4725 terpolymer EP rubber mixing evenly after, add 1.3Kg silicon rubber, and 0.1Kg hexichol dihydroxy expanding material, after mixing, add 3.75Kg aluminium hydroxide, 0.8kg antioxidant MB, 1.2Kg anti-aging agent RD after powder is infiltrated fully, adds the 2.8Kg terpine resin, the 2Kg polyisobutene, repeatedly adjust roll spacing, material is fully mixed, the discharging when time reaches about 15 minutes.
The glue that refining is good cuts into strip about 10 * 100mm with cutter.
Under 120 ℃ of temperature, being pressed into the sheet glue of 1.8mm with oil press, it is cut into the adhesive tape of 350 * 25 * 1.8mm, is 2
#Sample.
Embodiment 3
Get 2.8kg open 268 isoprene-isobutylene rubbers after the refining and 2.2Kg4725 terpolymer EP rubber mixing evenly after, add 1Kg silicon rubber, and 0.1Kg hexichol dihydroxy expanding material, after mixing, add 4Kg aluminium hydroxide, 0.6kg antioxidant MB, 0.8Kg anti-aging agent RD, after powder is infiltrated fully, add the 2.5Kg terpine resin, the 2.0Kg polyisobutene is adjusted roll spacing repeatedly, material is fully mixed, the discharging when time reaches about 25 minutes.
The glue that refining is good cuts into strip about 10 * 100mm with cutter.
Under 120 ℃ of temperature, being pressed into the sheet glue of 1.8mm with oil press, it is cut into the adhesive tape of 350 * 25 * 1.8mm, is 3
#Sample.
The performance index of gained sample and the contrast of common self-adhesive tape see Table 1
The anti-irradiation of table 1, resistant to elevated temperatures insulation water-proof seal adhesive tape performance index
Can obviously be found out by table 1, the resulting anti-irradiation of above-mentioned three embodiment of the present invention, its radiation-resistant property of resistant to elevated temperatures insulation water-proof seal adhesive tape are compared with common self-adhesive tape, its radiation-resistant property obviously improves, behind the dosage of irradiation 750KGy, still can use, can be applicable to high temperature resistant and anti-irradiation place.
Claims (1)
1. an anti-irradiation, resistant to elevated temperatures insulation water-proof seal adhesive tape it is characterized in that being comprised of by mass parts following material:
15-30 part water proof rubber matrix, 20-30 part tackifier, the reinforcing filler of 15-30 part, 0.5-5 part anti-aging agent, 1-10 part rubber of anti-irradiation;
Rubber matrix is the mixture of terpolymer EP rubber and isoprene-isobutylene rubber, and its blending ratio is: (1-2): (1-2);
Terpine resin and polyisobutene are tackifier, and its blending ratio is: (1-1.5): 1;
Reinforcing filler is aluminium hydroxide;
Anti-aging agent is MB or RD or both mixtures;
The rubber of anti-irradiation is silicon rubber.
Priority Applications (1)
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CN 200910067089 CN101570667B (en) | 2009-06-10 | 2009-06-10 | Radioresistant, high temperature resistant and waterproof sealing rubber belt material and preparation method thereof |
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CN 200910067089 CN101570667B (en) | 2009-06-10 | 2009-06-10 | Radioresistant, high temperature resistant and waterproof sealing rubber belt material and preparation method thereof |
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CN101570667A CN101570667A (en) | 2009-11-04 |
CN101570667B true CN101570667B (en) | 2013-03-06 |
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Families Citing this family (12)
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CN101818031B (en) * | 2010-03-25 | 2011-12-07 | 同济大学 | Method for preparing rubber-based adhesive for communication product |
CN102153966B (en) * | 2011-02-24 | 2015-06-03 | 中科英华湖州工程技术研究中心有限公司 | Special hot melt adhesive for mating 1E-grade K1-type cable accessories for nuclear power station |
CN102115648A (en) * | 2011-03-02 | 2011-07-06 | 常州市江永化工有限公司 | Hot melt adhesive for car light and manufacturing method thereof |
CN103232824B (en) * | 2013-04-15 | 2015-11-04 | 中国核电工程有限公司 | A kind of Irradiation-resistanhot hot melt adhesive and preparation method thereof |
CN103254847B (en) * | 2013-05-08 | 2015-11-25 | 安徽艳阳电气集团有限公司 | Butyl rubber sealant and preparation method thereof |
CN104231975A (en) * | 2014-08-21 | 2014-12-24 | 江苏华侃核电器材科技有限公司 | Sealing adhesive tape material for third-generation nuclear power plant and preparation method of sealing adhesive tape material |
CN104212382A (en) * | 2014-08-21 | 2014-12-17 | 江苏华侃核电器材科技有限公司 | Hot-melt adhesive for third-generation nuclear power plant cable accessories and preparation method of hot-melt adhesive |
CN106928883B (en) * | 2015-12-31 | 2019-02-26 | 比亚迪股份有限公司 | A kind of sealant tape composition and sealant tape and its application |
CN105504832A (en) * | 2016-01-07 | 2016-04-20 | 马兴华 | Silica gel heat-resistant covering glue for conveyor belt and manufacturing method of silica gel heat-resistant covering glue |
CN108384489B (en) * | 2018-03-28 | 2020-04-28 | 江苏嘉好热熔胶股份有限公司 | High-performance glass fiber adhesive tape adhesive and preparation method thereof |
CN112251154B (en) * | 2019-07-22 | 2022-12-20 | 深圳科创新源新材料股份有限公司 | Waterproof insulating adhesive tape with low-temperature operation performance and preparation method and application thereof |
CN110669341A (en) * | 2019-09-27 | 2020-01-10 | 深圳市沃尔核材股份有限公司 | Irradiation crosslinking self-adaptive permanent self-melting belt and preparation method thereof |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4404056A (en) * | 1981-02-25 | 1983-09-13 | Mitsuboshi Belting Ltd. | Method of joining waterproof vulcanized synthetic rubber sheets |
CN1618924A (en) * | 2003-10-22 | 2005-05-25 | 日东电工株式会社 | Waterproofing and airtight adhesive tape |
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2009
- 2009-06-10 CN CN 200910067089 patent/CN101570667B/en active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4404056A (en) * | 1981-02-25 | 1983-09-13 | Mitsuboshi Belting Ltd. | Method of joining waterproof vulcanized synthetic rubber sheets |
CN1618924A (en) * | 2003-10-22 | 2005-05-25 | 日东电工株式会社 | Waterproofing and airtight adhesive tape |
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Effective date of registration: 20161020 Address after: 130000 No. 1666 Air North Street, Gaoxin North Zone, Jilin, Changchun Patentee after: Zhongke Yinghua Changchun High-Tech Co.,Ltd. Address before: 130011 Torch Road 286, hi tech Zone, Jilin, Changchun Patentee before: China-Kinwa High Technology Co., Ltd. |