CN105273651A - Manufacturing method of self-adhesive butyl rubber waterproof coiled material - Google Patents
Manufacturing method of self-adhesive butyl rubber waterproof coiled material Download PDFInfo
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- CN105273651A CN105273651A CN201510849134.5A CN201510849134A CN105273651A CN 105273651 A CN105273651 A CN 105273651A CN 201510849134 A CN201510849134 A CN 201510849134A CN 105273651 A CN105273651 A CN 105273651A
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Abstract
The invention provides a manufacturing method of a self-adhesive butyl rubber waterproof coiled material. Solid waste butyl rubber is utilized, high-temperature desulfurization is not needed, a high shearing force is applied, the operating temperature is controlled below 100 DEG C, and a butyl rubber waterproof coiled material base course is prepared directly and is used as a main waterproof layer; a butyl rubber self-adhesive layer in the middle is a paste-shaped self adhesive which is also prepared from waste butyl rubber and is used as an auxiliary waterproof layer; and the lower surface can be isolated by using removable anti-adhesive paper. The waterproof coiled material provided by the invention has excellent water resistance and outstanding aging resistance, and is energy-saving and environment-friendly.
Description
Technical field
The present invention relates to a kind of manufacture method of selfadhesive butyl-rubber waterproof coil materials.
Background technology
Waterproof roll is material conventional in building operation, is mainly used in the waterproof construction of building roof, underground works etc., and to resisting rainwater, the seepage of underground water plays vital effect.Now, owing to being polluted in air and underground, waterproof roll not only will possess excellent weathering resistance, also will possess erosion resistance and chemical stability.
Selfadhesive butyl-rubber waterproof coil materials, comprises main water barrier, butyl rubber adhesive layer and antiadhesion barrier, and wherein, main water barrier and butyl rubber adhesive layer are combined with each other, and antiadhesion barrier is arranged on described butyl rubber adhesive layer lower surface.The main water barrier of selfadhesive butyl-rubber waterproof coil materials is in the market scarcely make with isoprene-isobutylene rubber, but uses the materials such as TPO, PVC, PET, Ethylene Propylene Terpolymer, aluminium foil to make, and just self-adhesive layer isoprene-isobutylene rubber manufactures.The waterproof roll of these kinds because of main water barrier different with the material that self-adhesive layer uses, not there are resistance to air loss, watertightness, erosion resistance and insulating property that isoprene-isobutylene rubber is generally acknowledged in the use of reality, and there will be the problem of intermiscibility difference due to the non-bulk material bonding of seam.Therefore result of use and the work-ing life of waterproof roll can be affected.
Such as, application for a patent for invention CN201310042498.3 discloses the reactive butyl rubber adhesive waterproof roll of a kind of thermoplastic elastomer, comprise thermoplastic elastomer coiled material, butyl rubber adhesive layer and antiadhesion barrier, wherein, self-adhesive layer employs isoprene-isobutylene rubber, and thermoplastic elastomer coiled material uses thermoplastic polyolefin elastomer coiled material or thermoplastic polyvinyl chloride's elastomer coiled material.Main water barrier due to the waterproof roll of said structure is not use isoprene-isobutylene rubber to be raw material manufacture, not only lack resistance to air loss, watertightness, erosion resistance and insulating property that isoprene-isobutylene rubber is generally acknowledged, and there will be the problem of intermiscibility difference aspect due to the non-bulk material bonding of seam, therefore, seam crossing need adopt mechanical thermal to weld, add working procedure and difficulty of construction, affect actual waterproof effect.
Application for a patent for invention CN200610013679.3 discloses a kind of waste rubber-rubber powder modified and prepares the method for compounded rubber waterproof roll with it.Be on drum vulcanizer carry out drum-type sulfuration compound through the film of modified preparation with the unvulcanized film prepared with isoprene-isobutylene rubber, petroleum resin etc. with shoddy, obtain compounded rubber waterproof roll.Whole manufacture method is with traditional high temperature desulfurizing, vulcanization process, and consume energy and contaminate environment, production efficiency is low.Shoddy is that the waterproof roll ageing-resistant performance that raw material manufactures is low, not corrosion-resistant, can not expose life-time service.
Be all raw material manufacture with isoprene-isobutylene rubber by the main water barrier of waterproof roll and self-adhesive layer, effectively can solve the non-bulk material Binder Phase dissolubility difference that exists in prior art and the poor problem of weathering resistance.But main water barrier, self-adhesive layer all use isoprene-isobutylene rubber to be main raw material(s) manufacture, complex manufacturing can be there is and the problem of production cost costliness.
Therefore, need the manufacture method developing a kind of new selfadhesive butyl-rubber waterproof coil materials, main water barrier and self-adhesive layer all adopt isoprene-isobutylene rubber to be main raw material(s) manufacture, while raising waterproof effect, can save production cost again.
Summary of the invention
In order to solve the problem, the object of this invention is to provide a kind of manufacture method of selfadhesive butyl-rubber waterproof coil materials.
The invention provides a kind of method that waste butyl rubber manufactures selfadhesive butyl-rubber waterproof coil materials.The selfadhesive butyl-rubber waterproof coil materials that method according to the present invention is made comprises butyl-rubber waterproof coil materials basic unit, self-adhesive layer and antiseized sealing coat from top to bottom successively, wherein, butyl-rubber waterproof coil materials basic unit and self-adhesive layer all adopt isoprene-isobutylene rubber to do main raw and make, and achieve body self-adhesion.Its distinguishing feature is: utilize solid waste butyl rubber, do not need high temperature desulfurizing, heating of not consuming energy, and uses high shear force, processing temperature is controlled below 100 DEG C, directly make butyl-rubber waterproof coil materials basic unit, as main water barrier; Middle self-adhesive layer is also the paste self-adhesive made with waste butyl rubber, as auxiliary waterproof layer; The lower surface separate paper isolation that can remove.
According to the manufacture method of selfadhesive butyl-rubber waterproof coil materials of the present invention, comprising:
A, prepare the thick rubber unvulcanizate of isoprene-isobutylene rubber
Be cut into small pieces by the waste butyl rubber of 40-60 weight part, join in pressure initial refining machine, temperature controls between 80-100 DEG C, carries out thick mixing 5-8 minute; Then the carbon black adding 5-15 weight part in 6-10 minute continues mixing, obtains the thick rubber unvulcanizate of isoprene-isobutylene rubber;
B, prepare butyl-rubber waterproof coil materials basic unit
(1) isoprene-isobutylene rubber steps A prepared thick rubber unvulcanizate 90-110 weight part, light calcium carbonate 70-90 weight part, paraffin 0.1-0.5 weight part, stearic acid 0.1-0.5 weight part join in high speed mill, blended at 60-80 DEG C of temperature, obtain isoprene-isobutylene rubber thin slice I;
(2) by tri-roll press machine, the isoprene-isobutylene rubber thin slice I obtained is rolled into butyl-rubber waterproof coil materials basic unit;
C, prepare butyl rubber adhesive glue
(1) isoprene-isobutylene rubber thick rubber unvulcanizate 90-110 weight part, rubber accelerator 1-3 weight part, the paraffin 2-5 weight part prepared of steps A, joins in high speed mill, blended between 60-80 DEG C of temperature, is refined into isoprene-isobutylene rubber thin slice II;
(2) isoprene-isobutylene rubber thin slice II18-22 weight part, polyisobutene 8-12 weight part, halogenated butyl rubber 1-5 weight part, talcum powder 10-15 weight part, other auxiliary agents 0.2-0.6 weight part, join in rubber kneading machine and mix, make paste butyl rubber adhesive glue;
D, compound
By the paste butyl rubber adhesive glue that obtains and butyl-rubber waterproof coil materials basic unit compound, the self-adhesive layer then formed at paste butyl rubber adhesive glue being arranged interleaving paper, to carry out isolation curling, obtains selfadhesive butyl-rubber waterproof coil materials.
Preferably, the manufacture method of described selfadhesive butyl-rubber waterproof coil materials, comprising:
A, prepare the thick rubber unvulcanizate of isoprene-isobutylene rubber
Be cut into small pieces by the waste butyl rubber of 50 weight parts, join in pressure initial refining machine, temperature controls between 80-100 DEG C, carries out slightly mixing 6 minutes; Then the carbon black adding 10 weight parts in 8 minutes continues mixing, obtains the thick rubber unvulcanizate of isoprene-isobutylene rubber;
B, prepare butyl-rubber waterproof coil materials basic unit
(1) isoprene-isobutylene rubber steps A prepared thick rubber unvulcanizate 100 weight part, light calcium carbonate 80 weight part, paraffin 0.3 weight part, stearic acid 0.3 weight part join in high speed mill, blended at 60-80 DEG C of temperature, obtain isoprene-isobutylene rubber thin slice I;
(2) by tri-roll press machine, the isoprene-isobutylene rubber thin slice I obtained is rolled into butyl-rubber waterproof coil materials basic unit;
C, prepare butyl rubber adhesive glue
(1) isoprene-isobutylene rubber steps A prepared thick rubber unvulcanizate 100 weight part, rubber accelerator 2 weight part, paraffin 3 weight part join in high speed mill, blended between 60-80 DEG C of temperature, are refined into isoprene-isobutylene rubber thin slice II;
(2) isoprene-isobutylene rubber thin slice II20 weight part, polyisobutene 10 weight part, halogenated butyl rubber 3 weight part, talcum powder 12 weight part, other auxiliary agent 0.2 weight parts, join in rubber kneading machine and mix, and make paste butyl rubber adhesive glue;
D, compound
By the paste butyl rubber adhesive glue that obtains and butyl-rubber waterproof coil materials basic unit compound, the self-adhesive layer then formed at paste butyl rubber adhesive glue being arranged interleaving paper, to carry out isolation curling, obtains selfadhesive butyl-rubber waterproof coil materials.
Wherein, light calcium carbonate is more than 300 orders; Talcum powder is more than 400 orders.
Described rubber accelerator can be RV rubber regeneration reductive agent etc., and such as, RDS-IIR, for waste butyl rubber regeneration reducing.
Other auxiliary agents described be selected from stearic acid, protective agent one or more.
Described protective agent can be, such as, and antioxidant D etc.
In step B and step C, the speed ratio controlling high speed mill is more than 1:1.575, and use high shear force, temperature controls below 100 DEG C, high efficient production sheet of butyl rubber.
The linear velocity 17-28m/min of tri-roll press machine, slice temperature 90-100 DEG C.
Preferably, by the butyl-rubber waterproof coil materials basic unit that obtained by tri-roll press machine further across cooler, and normal temperature was cooled in 1 minute.
Barrier film can use silicon oil membrane.
Waste butyl rubber is mainly derived from isoprene-isobutylene rubber capsule, curing bag, the inner tube of a tyre etc., belongs to solid waste.Because isoprene-isobutylene rubber viscosity is large, be not easily processed into rubber powder recycling under normal temperature, traditional treating method manufactures butyl reclaimed rubber by high temperature desulfurizing method (butyl rubber desulfurization temperature 160 DEG C-280 DEG C), not only consumes energy, and contaminate environment.
The present invention proposes a kind of method utilizing waste butyl rubber to manufacture selfadhesive butyl-rubber waterproof coil materials, be characterised in that, waste butyl rubber does not need high temperature desulfurizing, use high shear force, processing temperature controls below 100 DEG C, high efficient production sheet of butyl rubber, heating of not consuming energy, free from environmental pollution.
Selfadhesive butyl-rubber waterproof coil materials of the present invention has following beneficial effect:
1, main and auxiliary waterproof layer all adopts isoprene-isobutylene rubber to do main raw manufacture, achieves body self-adhesion.Waterproof roll of the present invention has outstanding ageing resistance, low temperature resistant-40 DEG C, high temperature resistant 120 DEG C, can be exposed in sunlight and air not easily aging for a long time.
2, the completely sticky not channeling water with basal plane, auxiliary waterproof layer is the not solid type damping material of paste, " skin-type " is adsorbed in substrate surface, there is pressure-sensitive, hold viscosity, creep properties and self-healing property, various stress from basic unit can not only be offset to the destruction of main water barrier, and there is body self-repairing capability and damping effect.
3, chemical stability is good, and isoprene-isobutylene rubber is the best rubber of the resistance to air loss of generally acknowledging in the world at present and watertightness, corrosion-resistant and insulating property are superior, can resist from the various corrosive deposit of air or underground the impact of waterproof effect.
4, environmentfriendly products are belonged to, not containing any solvent and pitch, pollution-free, nonflammable.
5, cold self-adhesion construction, operative technique is simple, safety, and self-service maintenance, still can construct for-10 DEG C.
6, because using waste butyl rubber to make main raw material(s), finished product do not need sulfuration, and comprehensive production cost is low, are applicable to China's actual conditions and Vehicles Collected from Market, are specially adapted to the old roof waterproof repairment engineerings such as Lightweight Steel Construction colored steel roof.
Embodiment
Below by embodiment, the present invention is described in detail.
Embodiment 1
1, the thick rubber unvulcanizate of isoprene-isobutylene rubber is prepared
Waste butyl rubber removes impurity, is cut into small pieces, for subsequent use.
The waste butyl rubber be cut into small pieces by 50kg joins in 55 liter pressure initial refining machines, and temperature controls at about 90 DEG C, carries out slightly mixing about 6 minutes; Then in 8 minutes, add 10kg carbon black continues mixing, obtains the thick rubber unvulcanizate of isoprene-isobutylene rubber.
2, butyl-rubber waterproof coil materials basic unit is prepared
Thick for isoprene-isobutylene rubber rubber unvulcanizate 15kg, 325 order light calcium carbonate 12kg, paraffin 0.045kg, stearic acid 0.045kg are added in the high speed mill with automatic charging device, the speed ratio of high speed mill is more than 1:1.575, and temperature is blended into the isoprene-isobutylene rubber thin slice I of thick about 0.5mm at about 70 DEG C.
Tri-roll press machine is used isoprene-isobutylene rubber thin slice I to be made the butyl-rubber waterproof coil materials basic unit of different thickness, linear velocity 17-28m/min, slice temperature about 95 DEG C.As required, the thickness of butyl-rubber waterproof coil materials basic unit can be 1.5mm, 1.8mm etc.
3, butyl rubber adhesive glue is prepared
Thick for isoprene-isobutylene rubber rubber unvulcanizate 30kg, rubber regeneration reductive agent RDS-IIR0.6kg, paraffin 0.9kg are joined in the high speed mill with automatic charging device, the speed ratio of high speed mill is 1:1.575, temperature is blended at about 70 DEG C, is refined into the isoprene-isobutylene rubber thin slice II of thick about 0.5mm.
Isoprene-isobutylene rubber thin slice II20kg, polyisobutene 10kg, halogenated butyl rubber 3kg, 500 order talcum powder 12kg, stearic acid 0.2kg, be mixed and made into paste butyl rubber adhesive glue in rubber kneading machine by said components.
4, compound
By the paste butyl rubber adhesive glue that obtains and butyl-rubber waterproof coil materials basic unit compound, the self-adhesive layer then formed at paste butyl rubber adhesive glue being arranged interleaving paper, to carry out isolation curling, obtains selfadhesive butyl-rubber waterproof coil materials.
Embodiment 2
1, the thick rubber unvulcanizate of isoprene-isobutylene rubber is prepared
Waste butyl rubber removes impurity, is cut into small pieces, for subsequent use.
The waste butyl rubber be cut into small pieces by 45kg joins in 55 liter pressure initial refining machines, and temperature controls at about 90 DEG C, carries out slightly mixing about 6 minutes; Then in 8 minutes, add 8kg carbon black continues mixing, obtains the thick rubber unvulcanizate of isoprene-isobutylene rubber.
2, butyl-rubber waterproof coil materials basic unit is prepared
Thick for isoprene-isobutylene rubber rubber unvulcanizate 19kg, 325 order light calcium carbonate 17kg, paraffin 0.04kg, stearic acid 0.06kg are added in the high speed mill with automatic charging device, the speed ratio of high speed mill is more than 1:1.575, and temperature is blended into isoprene-isobutylene rubber thin slice I at about 75 DEG C.
Tri-roll press machine is used isoprene-isobutylene rubber thin slice I to be made the butyl-rubber waterproof coil materials basic unit of different thickness, linear velocity 17-28m/min, slice temperature about 95 DEG C.
By the butyl-rubber waterproof coil materials basic unit that obtained by tri-roll press machine further across cooler, and be cooled to normal temperature in one minute.
3, butyl rubber adhesive glue is prepared
Thick for isoprene-isobutylene rubber rubber unvulcanizate 27.5kg, rubber regeneration reductive agent RDS-IIR0.75kg, paraffin 0.75kg are joined in the high speed mill with automatic charging device, the speed ratio of high speed mill is more than 1:1.575, temperature is blended at about 70 DEG C, is refined into the isoprene-isobutylene rubber thin slice II of thick about 0.5mm.
Isoprene-isobutylene rubber thin slice II22kg, polyisobutene 11kg, halogenated butyl rubber 3kg, 500 order talcum powder 12kg, antioxidant D 0.3kg, be mixed and made into paste butyl rubber adhesive glue in rubber kneading machine by said components.
4, compound
By the paste butyl rubber adhesive glue that obtains and butyl-rubber waterproof coil materials basic unit compound, the self-adhesive layer then formed at paste butyl rubber adhesive glue being arranged interleaving paper, to carry out isolation curling, obtains selfadhesive butyl-rubber waterproof coil materials.
All adopt isoprene-isobutylene rubber to do main raw manufacture according to the main and auxiliary waterproof layer of waterproof roll of the present invention, achieve body self-adhesion, efficiently solve the problem that non-bulk material Binder Phase dissolubility is poor and weathering resistance is poor existed in prior art.
The present invention utilizes waste butyl rubber to manufacture selfadhesive butyl-rubber waterproof coil materials, does not need high temperature desulfurizing, uses high shear force, processing temperature controls below 100 DEG C, and high efficient production sheet of butyl rubber, does not consume energy, free from environmental pollution, and significantly can reduce production cost.
Test-results shows, and waterproof roll of the present invention has outstanding chemical stability, can low temperature resistant-40 DEG C, high temperature resistant 120 DEG C, can be exposed in sunlight and air not easily aging for a long time.
Waterproof roll according to the present invention is applicable to the roofing of industry under various weather condition and covil construction, underground, exterior wall, toilet warterproof, and subway, high ferro water-tight corrosion-proof.
Claims (7)
1. a manufacture method for selfadhesive butyl-rubber waterproof coil materials, comprising:
A, prepare the thick rubber unvulcanizate of isoprene-isobutylene rubber
Be cut into small pieces by the waste butyl rubber of 40-60 weight part, join in pressure initial refining machine, temperature controls between 80-100 DEG C, carries out thick mixing 5-8 minute; Then the carbon black adding 5-15 weight part in 6-10 minute continues mixing, obtains the thick rubber unvulcanizate of isoprene-isobutylene rubber;
B, prepare butyl-rubber waterproof coil materials basic unit
(1) isoprene-isobutylene rubber thick rubber unvulcanizate 90-110 weight part, light calcium carbonate 70-90 weight part, paraffin 0.1-0.5 weight part, the stearic acid 0.1-0.5 weight part prepared of steps A, said components is joined in high speed mill, blended at 60-80 DEG C of temperature, obtain isoprene-isobutylene rubber thin slice I;
(2) by tri-roll press machine, the isoprene-isobutylene rubber thin slice I obtained is rolled into butyl-rubber waterproof coil materials basic unit;
C, prepare butyl rubber adhesive glue
(1) isoprene-isobutylene rubber thick rubber unvulcanizate 90-110 weight part, rubber accelerator 1-3 weight part, the paraffin 2-5 weight part prepared of steps A, joins in high speed mill by said components, blended between 60-80 DEG C of temperature, is refined into isoprene-isobutylene rubber thin slice II;
(2) isoprene-isobutylene rubber thin slice II18-22 weight part, polyisobutene 8-12 weight part, halogenated butyl rubber 1-5 weight part, talcum powder 10-15 weight part, other auxiliary agents 0.2-0.6 weight part, said components is joined in rubber kneading machine and mixes, make paste butyl rubber adhesive glue;
D, compound
By the paste butyl rubber adhesive glue that obtains and butyl-rubber waterproof coil materials basic unit compound, the self-adhesive layer then formed at paste butyl rubber adhesive glue being arranged interleaving paper, to carry out isolation curling, obtains selfadhesive butyl-rubber waterproof coil materials.
2. the manufacture method of selfadhesive butyl-rubber waterproof coil materials according to claim 1, comprising:
A, prepare the thick rubber unvulcanizate of isoprene-isobutylene rubber
Be cut into small pieces by the waste butyl rubber of 50 weight parts, join in pressure initial refining machine, temperature controls between 80-100 DEG C, carries out slightly mixing 6 minutes; Then the carbon black adding 10 weight parts in 8 minutes continues mixing, obtains the thick rubber unvulcanizate of isoprene-isobutylene rubber;
B, prepare butyl-rubber waterproof coil materials basic unit
(1) isoprene-isobutylene rubber thick rubber unvulcanizate 100 weight part, light calcium carbonate 80 weight part, paraffin 0.3 weight part, stearic acid 0.3 weight part prepared of steps A, said components is joined in high speed mill, blended at 60-80 DEG C of temperature, obtain isoprene-isobutylene rubber thin slice I;
(2) by tri-roll press machine, the isoprene-isobutylene rubber thin slice I obtained is rolled into butyl-rubber waterproof coil materials basic unit;
C, prepare butyl rubber adhesive glue
(1) isoprene-isobutylene rubber thick rubber unvulcanizate 100 weight part, rubber accelerator 2 weight part, paraffin 3 weight part prepared of steps A, joins in high speed mill by said components, blended between 60-80 DEG C of temperature, is refined into isoprene-isobutylene rubber thin slice II;
(2) isoprene-isobutylene rubber thin slice II20 weight part, polyisobutene 10 weight part, halogenated butyl rubber 3 weight part, talcum powder 12 weight part, other auxiliary agent 0.2 weight parts, said components is joined in rubber kneading machine and mixes, make paste butyl rubber adhesive glue;
D, compound
By the paste butyl rubber adhesive glue that obtains and butyl-rubber waterproof coil materials basic unit compound, the self-adhesive layer then formed at paste butyl rubber adhesive glue being arranged interleaving paper, to carry out isolation curling, obtains selfadhesive butyl-rubber waterproof coil materials.
3. the manufacture method of selfadhesive butyl-rubber waterproof coil materials according to claim 1 and 2, wherein,
Other auxiliary agents described be selected from stearic acid, protective agent one or more.
4. the manufacture method of selfadhesive butyl-rubber waterproof coil materials according to claim 1 and 2, wherein,
In step B and step C, the speed ratio of high speed mill is respectively more than 1:1.575.
5. the manufacture method of selfadhesive butyl-rubber waterproof coil materials according to claim 1 and 2, wherein,
In stepb, the linear velocity of tri-roll press machine is 17-28m/min, the slice temperature 90-100 DEG C of butyl-rubber waterproof coil materials basic unit.
6. the manufacture method of selfadhesive butyl-rubber waterproof coil materials according to claim 5, wherein,
The butyl-rubber waterproof coil materials basic unit obtained by tri-roll press machine further across cooler, and was cooled to normal temperature in one minute.
7. the selfadhesive butyl-rubber waterproof coil materials prepared by manufacture method of the selfadhesive butyl-rubber waterproof coil materials according to any one of claim 1-6.
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105585978A (en) * | 2016-03-14 | 2016-05-18 | 王辉 | Waterproof self-adhesive coiled material prepared from butyl rubber and preparation method of coiled material |
| CN105925214A (en) * | 2016-03-17 | 2016-09-07 | 北京博瑞众诚科技有限公司 | Pressure-sensitive type self-adhesive waterproof adhesive |
| CN107459942A (en) * | 2017-09-14 | 2017-12-12 | 杨志武 | A kind of self-adhering-type EPDM waterproof rolled sheet |
| CN109370068A (en) * | 2018-09-25 | 2019-02-22 | 青岛东方雨虹建筑材料有限公司 | A kind of low temperature resistant TPO self-adhesive layer and preparation method thereof and low temperature resistant TPO waterproof roll |
| CN111269668A (en) * | 2020-03-27 | 2020-06-12 | 山东双圆密封科技有限公司 | Exposed flexible flashing sealing repairing adhesive tape and preparation method thereof |
| CN112375504A (en) * | 2020-10-23 | 2021-02-19 | 四川鑫桂湖防水保温节能科技有限公司 | Waterproof roll for color steel roof maintenance and use method thereof |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07216322A (en) * | 1994-02-07 | 1995-08-15 | Sekaicho Rubber Co Ltd | Self-adhesive unvulcanized water-proofing rubber sheet or tape developing no rumple during winding and storage and production thereof |
| CN101545285A (en) * | 2009-04-30 | 2009-09-30 | 北京立高科技有限公司 | Self-adhering rubber water-proof coiled material and method for preparing same |
| CN103088846A (en) * | 2013-02-04 | 2013-05-08 | 常熟市三恒建材有限责任公司 | Rubber reactive butyl rubber self-adhesion water-proof roll |
| CN103102843A (en) * | 2013-02-04 | 2013-05-15 | 常熟市三恒建材有限责任公司 | Reactive butyl rubber self-adhesive layer for waterproof roll and processing technology thereof |
| KR101343990B1 (en) * | 2013-05-14 | 2013-12-24 | 이현일 | A roof sheet of self viscosity type and preparing method thereof |
| CN104723630A (en) * | 2015-03-31 | 2015-06-24 | 解忠深 | Self-adhered reactive ethylene-propylene-diene monomer rubber composite waterproof roll and production method thereof |
| CN105034495A (en) * | 2015-08-21 | 2015-11-11 | 湖北永阳材料股份有限公司 | Ultra-weatherability self-adhered waterproof coiled material and preparation method thereof |
| JP2015206224A (en) * | 2014-04-22 | 2015-11-19 | 多摩防水技研株式会社 | Waterproof sheet and manufacturing method thereof |
-
2015
- 2015-11-26 CN CN201510849134.5A patent/CN105273651B/en active Active
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07216322A (en) * | 1994-02-07 | 1995-08-15 | Sekaicho Rubber Co Ltd | Self-adhesive unvulcanized water-proofing rubber sheet or tape developing no rumple during winding and storage and production thereof |
| CN101545285A (en) * | 2009-04-30 | 2009-09-30 | 北京立高科技有限公司 | Self-adhering rubber water-proof coiled material and method for preparing same |
| CN103088846A (en) * | 2013-02-04 | 2013-05-08 | 常熟市三恒建材有限责任公司 | Rubber reactive butyl rubber self-adhesion water-proof roll |
| CN103102843A (en) * | 2013-02-04 | 2013-05-15 | 常熟市三恒建材有限责任公司 | Reactive butyl rubber self-adhesive layer for waterproof roll and processing technology thereof |
| KR101343990B1 (en) * | 2013-05-14 | 2013-12-24 | 이현일 | A roof sheet of self viscosity type and preparing method thereof |
| JP2015206224A (en) * | 2014-04-22 | 2015-11-19 | 多摩防水技研株式会社 | Waterproof sheet and manufacturing method thereof |
| CN104723630A (en) * | 2015-03-31 | 2015-06-24 | 解忠深 | Self-adhered reactive ethylene-propylene-diene monomer rubber composite waterproof roll and production method thereof |
| CN105034495A (en) * | 2015-08-21 | 2015-11-11 | 湖北永阳材料股份有限公司 | Ultra-weatherability self-adhered waterproof coiled material and preparation method thereof |
Non-Patent Citations (3)
| Title |
|---|
| 冯新德等: "《高分子辞典》", 30 June 1998 * |
| 吴建明等: "EPB反应性丁基橡胶自粘防水卷材及其在地下防水工程中的应用", 《中国建筑防水》 * |
| 塑料技术与装备: "橡胶类反应性丁基橡胶自粘防水卷材", 《塑料技术与装备》 * |
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