CN100390240C - Nano modified anti-rust special primer - Google Patents
Nano modified anti-rust special primer Download PDFInfo
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- CN100390240C CN100390240C CNB2006100604702A CN200610060470A CN100390240C CN 100390240 C CN100390240 C CN 100390240C CN B2006100604702 A CNB2006100604702 A CN B2006100604702A CN 200610060470 A CN200610060470 A CN 200610060470A CN 100390240 C CN100390240 C CN 100390240C
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Abstract
The present invention relates to the special nanometer modified antirust primer, which is characterized in that the special nanometer modified antirust primer comprises (by weight percentage) 29.0 to 60.0 percent of antirust paint host crystal, 1.0 to 10.0 percent of nanometer oxide additive, 5.0 to 15.0 percent of curing agent and 30.0 to 65 percent of diluent, wherein the antirust paint host crystal is composed of antirust raw materials, coloring pigments, compounding resin and auxiliary agent; the curing agent is compounded by 75 percent of aromatic isocyanate and dimethylbenzene, butyl acetate, propanol and 2-butanol; the diluent is the combination of alcohol solvent and ester solvent. The components and the proportion of the present invention are thoroughly optimized and combined. The presention invention reduces the contents of toxic matter and harmful matter in total weight of products greatly, guarantees excellent cryogenic film forming property of the products, reduces the degree of pollution to environments and ensures the health of producers, users and people in ambient environments of the products effectively. The present invention accords with the requirements of green environmental protection and further enhances the quality of antirust primer simultaneously.
Description
Technical field
The present invention relates to the metallic paint technical field, be specifically related to a kind of metal rust preventing priming paint of special use, be mainly used in the corrosion rust protection application that use on mechanical means, hardware surface, be particularly useful for the protection and the decorative painting of equipment such as mechanical means, injection moulding machine, pressure die-casting machine, spark machine, CNC machining center, air compressor, elevator, motor and production thereof etc.
Background technology
Existing antiseptic and rustproof paint belongs to solvent based coating mostly at present, and its solvent generally all is that with the thinner as pigment, paint etc., content is higher based on benzene class organic solvents such as dimethylbenzene.Dimethylbenzene is a kind of colourless transparent liquid, and is water insoluble, is dissolved in ethanol and ether, toxic, volatile, but polluted air and contaminate environment, serious harm human body health.Simultaneously, this class coating products overwhelming majority contains plumbous system and chromate pigments, also can cause environmental pollution and harm humans health to environment.In recent years, occurred the anti-corrosive antirusting paint of some water-baseds on the market, mainly be divided into two major types: be i.e. latex type and water-soluble type.But because the former poor stability, rustless property is undesirable, from the requirement of the actual expectation of people bigger gap is arranged still; The latter is the antiseptic and rustproof paint of drying-type, its drying condition generally all 140 ℃ * more than 30 minutes, energy consumption is higher, also needs special-purpose drying plant, its rust-proof effect is also undesirable.Therefore, now on the market, still be main flow with traditional rust-inhibiting paint product, poor-performing, price are also cheaper, and environmental pollution is also serious, though product innovation in recent years reduces and has improved the pollution to environment relatively, but owing to technical reason, the stability and the performances such as salt spray resistance, corrosion resistance of its product are still unsatisfactory, do not meet at present in the world the development trend to antiseptic and rustproof product requirement environmental protection and health performance excellence.
Summary of the invention
Technical problem to be solved by this invention is to have many defectives such as toxic substance content height, not environmental protection, energy consumption height, quality instability, rustless property be not good at existing antiseptic and rustproof lacquer, a kind of nano modified anti-rust special primer has been proposed, effectively reduce content of harmful, can significantly reduce the pollution level of product to environment, also improved the quality scale of product simultaneously, favorable rust preventing effect makes antiseptic and rustproof lacquer quality level rise to a brand-new height.
The present invention is directed to the technical scheme that above-mentioned prior art defective proposed is:
A kind of nano modification rust-proofing primer is characterized in that comprising the component of following weight per-cent: rust-inhibiting paint host 29.0-60.0%, nano-oxide additive 1.0-10.0%, solidifying agent 5.0-15.0%, thinner 30.0-65%.
Described rust-inhibiting paint host comprises the component of following weight per-cent: antirust raw material 5.0-30.0%, tinting pigment 5.0-30.0%, composite resin 20.0-50%, auxiliary agent 1.0-20.0%, wherein antirust raw material is selected at least a in composite zinc phosphate, zinc phosphate, phosphide aluminium, tripolyphosphate zinc, aluminium triphosphate, zinc iron phosphate, barium metaborate, titanium-iron powder, red iron oxide, the iron oxide yellow or more than one for use, and iron oxide black is or/and the iron mica powder; Tinting pigment selects that green red, the titanium nickel yellow of Rutile type Titanium Dioxide, carbon black, coating molybdenum, coating are lemon yellow for use, any one and iron oxide black and/or iron mica powder in the titanium-iron powder, red iron oxide, iron oxide yellow; Composite resin be by the synthetic fat acid resin, Hydroxylated acrylic resin is composite forms; Described auxiliary agent comprises coupling agent, solubility promoter, flow agent, defoamer, dispersion agent, softening agent and inhibiter, wherein coupling agent is selected titante coupling agent for use, and it is a tetrabutyl titanate, titanate coupling agent TC-F, titanate coupling agent TC-2, titanate coupling agent TC-3, titanate coupling agent TC-27, titanate coupling agent TC-114, titanate coupling agent TC-Wt, titanate coupling agent G-2, titanate coupling agent G-6, titanate coupling agent TA-9-2, titanate coupling agent TA-13, among titanate coupling agent TA-361 or the titanate coupling agent TD-5-1 any one or more than one; Softening agent is the combination of any one or both in dibutyl phthalate, the dioctyl phthalate (DOP); Inhibiter is at least a in picric acid, five times of acid, gallic acid, Weibull, polyhydroxy phenol, barium mahogany sulfonate, sad dicyclohexyl amine, phenylformic acid monoethanolamine or the benzotriazoles or more than one; Solubility promoter is ethylene glycol ether acetate, propylene glycol ethers, Virahol, isopropylcarbinol or propyl carbinol.
Described nano-oxide additive is the combination of any two or more component in nano zine oxide, nanometer iron oxide red, nano iron oxide yellow, nano-sized black iron oxide, nano-aluminium oxide, nano silicon or the nano titanium oxide.
Described solidifying agent is that at least a above solvent complex forms in 75% aromatic isocyanate and dimethylbenzene, N-BUTYL ACETATE, propyl alcohol, the 2-butanols.
Described thinner is the combination of alcoholic solvent and esters solvent, wherein alcoholic solvent comprises by two or more the alcoholic solvent in the polyvalent alcohol of dibasic alcohol, three hydroxyls, select n-propyl alcohol, Virahol, 1-butanols, 2-butanols, 1-amylalcohol for use, 2-amylalcohol, 3-amylalcohol and contain 6 carbon atoms above monohydroxy-alcohol, ethylene glycol, esters solvent is ethylene glycol ether acetate, N-BUTYL ACETATE, isoamyl acetate, vinyl acetic monomer, acetone, the mixture more than at least three kinds or three kinds in toluene, dimethyl benzene or the propylene carbonate.
In the technical scheme proposed by the invention, component and its proportioning to rust-proofing primer have been carried out fully preferred and combination, at first, added have certain proportioning nano-oxide as additive because nano particle is minimum, specific surface area is big, its compactness extent is quite high, both increase the sticking power and the bonding force of its paint, improved salt spray resistance, protection against corrosion and the antirust ability of product again greatly, further improved the quality of rust-proofing primer.Secondly, the thinner that is added can adopt the lower alcoholic solvent of volatility fully, do not contain any toxic ingredient, or the corresponding content in thinner that has increased the lower alcoholic solvent of volatility, greatly reduce the ratio of the poisonous and hazardous organic solvent of aromatics in thinner and product gross weight such as toluene, dimethylbenzene of high volatility, both guaranteed that product has excellent film formation at low temp performance, had reduced the pollution level to environment again; Selected tinting pigment and color stuffing have also been abandoned deleterious leadedly or contain the compound of chromium on content and proportioning are selected, and have more effectively ensured the people's of products production person, user and surrounding environment health, meet environment protection requirement.
Embodiment
The present invention be directed to leaded that existing antiseptic and rustproof lacquer exists, contain poisonous and hazardous antiseptic and rustproof raw materials such as chromium and use dimethylbenzene in a large number, toluene etc. are volatile and leaded or contain the compound of chromium, the harmful improvement technical scheme that many shortcomings proposed, its major ingredient comprises rust-inhibiting paint host, the nano-oxide additive, solidifying agent and thinner, described rust-inhibiting paint host is main ingredient of the present invention, shared per-cent is 29.0～60.0% in the product gross weight, can form sealing coat in the metallic surface, the metallic surface is protected, prevent to combine the generation corrosion, damage the metallic surface with airborne oxygen.Rust-inhibiting paint host comprises antirust raw material 5.0-30.0%, tinting pigment 5.0-30.0%, composite resin 20.0-50.0%, auxiliary agent 1.0-20.0%, described antirust raw material selects for use any one and iron oxide black in composite zinc phosphate, phosphide aluminium, zinc phosphate, tripolyphosphate zinc, zinc iron phosphate, barium metaborate, titanium-iron powder, red iron oxide, the iron oxide yellow or/and iron mica powder, preferably composite zinc phosphate, phosphide zinc, phosphide aluminium, tripolyphosphate zinc, zinc iron phosphate, red iron oxide, iron oxide yellow.
Tinting pigment selects generally that green red, the titanium nickel yellow of Rutile type Titanium Dioxide, carbon black, coating molybdenum, coating are lemon yellow for use, any one and iron oxide black and/or iron mica powder in the titanium-iron powder, red iron oxide, iron oxide yellow; Above-mentioned enumerate do not exist any leaded, contain poisonous and hazardous compounds such as chromium.
Hydroxylated acrylic resin and synthetic fat acid resin all are products that market can directly buy.The acid number of Hydroxylated acrylic resin is less than 10mgKOH/g, and from German BYK company, Aksu company and domestic resin company buy and obtain; Described synthetic fat acid resin is the fatty acid modified urethane that a kind of medium-oil-length unsaturated fatty acids modified polyurethane and Acrylic Acid Monomer prepare through graft copolymerization, its acid number is less than 10mgKOH/g, China's Zibo City's Boshan is made lacquer factory, the Shandong southern Shandong is made lacquer factory, sino-america joint-venture Shanghai Ai Lijin coating company limited, the precious chemical plant of Yixing City China, Sanmu Group Corp, Jiangsu, German BYK company, all there is sale in Aksu company etc.With two kinds of above-mentioned resins in 4～6: 6～4 ratio is mixed and suitably add a small amount of solubility promoter, and stirring can obtain composite resin.
Auxiliary agent of the present invention plays important effect to the performance and the quality of rust-inhibiting paint, it comprises coupling agent, defoamer, flow agent, solubility promoter, softening agent, inhibiter and dispersion agent, described coupling agent can make product have good penetration wetting property, coupling, and dispersive ability is strong, can improve product and organic consistency and water resistance, simultaneously in cross-linking process, resistance of oxidation significantly strengthens, and long-term the placement also can not caused the base-material xanthochromia, and excellent bounding force and weather resistance can be provided.Coupling agent is generally silane coupling agent and titanate coupling agent at present, the present invention can select titante coupling agent for use, as selects for use any one or two kinds among tetrabutyl titanate, titanate coupling agent TC-F, titanate coupling agent TC-2, titanate coupling agent TC-3, titanate coupling agent TC-27, titanate coupling agent TC-114, titanate coupling agent TC-Wt, titanate coupling agent G-2, titanate coupling agent G-6, titanate coupling agent TA-9-2, titanate coupling agent TA-13, titanate coupling agent TA-361 or the titanate coupling agent TD-5-1 to form through composite.
But described defoamer can help paint and coating exhaust, froth breaking, prevents that bubble and foamy produce in the Paint Production, plays the bubble effect.The adding of defoamer can help to improve coating surface smooth finish, and its intermiscibility, dispersiveness and over-all properties are very outstanding.The present invention preferentially selects silicone antifoam agent for use, it is that polysiloxane with modification is a main component, the biologically inert defoamer that adopts special warfare to make has very strong press down bubble ability and good broken bubble effect, and antifoaming speed is fast, suds suppressing properties is excellent, the efficient height, consumption is low, and is nontoxic, do not have corrosion, do not have bad side effect, but also can be used as auxiliary agent or subsidiary material and other material shared or improve other materials processing performance.
Flow agent is a kind of coatings additive(s), it can impel coating in the drying and forming-film process, form one smooth, smooth, film uniformly, after can avoiding the paint brushing, owing to tension gradient, wrinkle and shrinkage cavity phenomenon appear in solvent evaporation, the different paint films that cause with the wetness degree of metallic surface of polymkeric substance, influence the rustless property of coating.The present invention selects the organosilicon flow agent for use, as phenylbenzene polysiloxane, methyl phenyl silicone, organic radical modified siloxane, fluorinated siloxane etc.
Above-mentioned defoamer and flow agent generally can be selected from the product that German BYK, Dutch EFKA, Aksu company and some domestic manufacturers produce.
Softening agent can improve the elasticity and the toughness of coating induration, and makes product and bounding force is preferably arranged between the paint metals surface.Softening agent of the present invention is selected the combination of any one or both in dibutyl phthalate, the dioctyl phthalate (DOP) for use, and wherein phthalic ester plasticizer is consumption maximum, a purposes raw material the most widely in the volatility paint.
The adding of described inhibiter can make coating form oxide film or indissoluble material in the metallic surface, has hindered oxygenant and has got electronics, with the corrosion speed of the metallic surface of slowing down.Inhibiter of the present invention can be at least a in picric acid, five times of acid, gallic acid, Weibull, polyhydroxy phenol, barium mahogany sulfonate, sad dicyclohexyl amine, phenylformic acid monoethanolamine or the 124 Triazoles or more than one.
Described solubility promoter can be alcoholic solvents such as ethylene glycol ether acetate, propylene glycol ethers, Virahol, isopropylcarbinol or propyl carbinol.
Also adding in the auxiliary agent of the present invention has color stuffing, as talcum powder etc.
The present invention also can add siccative in auxiliary agent, can improve the aerial rate of drying of coating, and siccative is generally selected aqueous dispersion type cobalt naphthenate or cobalt iso-octoate etc. for use.
The nano-oxide additive is an important component of the present invention, it is the nano-oxide powder particle, its particle diameter is that nano level, specific surface area are big, the surfactivity height, compare with conventional micropowder, have the excellent properties of aspects such as a series of optics, electricity, magnetics, mechanics, chemistry, can improve product quality greatly.Nano-oxide additive of the present invention shared per-cent in the product gross weight is 1.0～10.0%, can be selected from the combination of any two or more component in nano zine oxide, nanometer iron oxide red, nano iron oxide yellow, nano-sized black iron oxide, mica powder, nano-aluminium oxide, nano silicon or the nano titanium oxide.Ordinary priority is selected nano zine oxide, nanometer iron oxide red, nano-aluminium oxide, nano silicon or nano titanium oxide for use.
Because the nano-oxide powder particle diameter is little, be very easy to reunite, directly add and be difficult in the coating scatter, thereby influence the performance of performance.Therefore, add certain amount of dispersant in the auxiliary agent of the present invention, can make agglomerating powder separate reunion, obtained monodispersed primary particle again, improved the use properties of coating.Described dispersion agent can adopt HK-03 organic dispersing agent, CH series hyper-dispersant, SN5040 dispersion agent or polyacrylic acid hydramine salt dispersion agent.
Described solidifying agent is selected must be suitable with other components, if the solidifying agent proportioning is higher, then paint film is easily crisp, easily produce bubble during construction, low cross-linking density, the hardness of paint, the scratch resistance that then can influence paint of solidifying agent add-on, even make paint film be not easy to do, influence the anti-corrosion performance of coating.The present invention selected and thinner between reasonable proportioning, shared per-cent is 5.0～15.0% in the product gross weight, and its component is made up of in 75% aromatic isocyanate, dimethylbenzene, N-BUTYL ACETATE, propyl alcohol, 2-butanols or the cobalt naphthenate one or more.
Described thinner can reduce the pin bubble of coating surface or increase the surperficial levelling of coating, be used to regulate dope viscosity and thickness, under the thinner effect, can make product form transparent hydration gel matrix, also have styling simultaneously, can guarantee that coating is uniformly distributed in the metallic surface.Thinner of the present invention shared per-cent in the product gross weight is 30.0～65%, adopt the combination of alcoholic solvent and esters solvent, wherein alcoholic solvent is by n-propyl alcohol, Virahol, the 1-butanols, the 2-butanols, the 1-amylalcohol, the 2-amylalcohol, 3-amylalcohol and contain the above monohydroxy-alcohol of 6 carbon atoms, dibasic alcohol such as ethylene glycol, two kinds or multiple above alcoholic solvent composition in the polyvalent alcohol of three hydroxyls, esters solvent is an ethylene glycol ether acetate, N-BUTYL ACETATE, toluene, dimethyl benzene, components such as NSC 11801, can forgo fully toxic compounds or choose the combination of lower ratio reduces the content of toxic ingredient.Wherein better with effects such as ethylene glycol ether acetate, N-BUTYL ACETATE, toluene, dimethyl benzene, 2-butanols, Virahol, 3-amylalcohols.
Embodiment one:
A, preparation rust-inhibiting paint host and additive, selected raw material and proportioning are:
Sequence number material name %
1 Hydroxylated acrylic resin 10.0
2 synthetic fat acid resins 8.5
3 nanometer iron oxide red 2.5
4 iron oxide yellow 12.0
5 talcum powder 12.0
6 nano zine oxides 1.5
7 nano silicons 2.0
8 titanium-iron powders 3.0
9 zinc iron phosphate 2.0
10 tripolyphosphate zinc 6.5
11 CH series hyper-dispersant 2.0
12 composite zinc phosphates 1.0
13 ethylene glycol ether acetates 10.0
14 organosilicon flow agents 5.0
15 silicone antifoam agents 5.0
16 Virahols 1.5
17 barium mahogany sulfonates 0.6
18 titanic acid ester TC-F 0.2
19 dibutyl phthalates 0.2
20 Hydroxylated acrylic resins 14.5
Add up to: 100.0
Production technique and preparation method: with above-mentioned sequence number is that the raw material of 1-13 is inserted the agitation vat high speed and disperseed 30-60 minute, grind 2-3 all over qualified through three roll machine again to fineness, adding sequence number again is the 14-20 raw material, mixes evenly and checks, filtration, weighing, encapsulates, labels, puts in storage.
B, the agent of preparation rust-inhibiting paint solidifying priming paint, selected raw material and proportioning are:
Sequence number material name %
1 75% aromatic isocyanate 55.0
2 dimethylbenzene 10.0
3 N-BUTYL ACETATEs 15.0
4 acetone 10.0
5 2-butanols 10.0
Add up to: 100.0
Production technique and preparation method: above-mentioned raw materials is added in the agitation vat homodisperse check, filter, encapsulate, label, put in storage about 30 minutes.
C, preparation rust-inhibiting paint priming paint thinner, selected raw material and proportioning are:
Sequence number material name %
1 dimethyl benzene 20.0
2 N-BUTYL ACETATEs 30.0
3 acetone 15.0
4 2-butanols 15.0
5 n-propyl alcohols 20.0
Add up to: 100.0
Production technique and preparation method: above-mentioned raw materials is added homodisperse in the agitation vat, check, encapsulate, label, put in storage.
Above-mentioned A, B, C prepare for three kinds finish after, after preparing, when concrete construction, implement by following execution conditions and mode.
Execution conditions:
(1) substrate surface is handled oil removing, cleaning, drying.As process phosphatization, polishing, sandblast, its sticking power can be better;
(2) construction proportioning: press rust-proofing primer host: the rust-proofing primer solidifying agent: the mixed of thinner=4: 1: 5 is even, leaves standstill 5～10 minutes still backs and constructs;
(3) working viscosity: 14～18 seconds (being coated with-4 glasss).
Constructional method: spraying.
Drying conditions:
(1) surface drying time: 5 minutes/60 ℃ or 15 minutes/25 ℃;
(2) do solid work the time: placed 18 hours behind the surface drying;
(3) chemical property test: 7 days/25 ℃;
(4) topcoating is dry requires: after general 3～4 hours or complete drying;
Particular requirement: after host, solidifying agent mix, use up in 4 hours.
Embodiment two:
A, preparation rust-inhibiting paint host and additive, selected raw material and proportioning are:
Sequence number material name %
1 Hydroxylated acrylic resin 10.0
2 synthetic fat acid resins 15.0
3 nano iron oxide yellows 1.0
4 red iron oxides 5.5
5 talcum powder 8.0
6 nano iron oxide yellows 1.5
7 nano silicons 1.0
8 Rutile type Titanium Dioxides 3.0
9 zinc phosphates 2.0
10 aluminium triphosphates 7.0
11 HK-03 organic dispersing agents 3.0
12 composite zinc phosphates 1.0
13 propylene glycols 10.0
14 organosilicon flow agents 5.0
15 silicone antifoam agents 5.0
16 Virahols 1.5
17 sad dicyclohexyl amines 0.5
18 titanate coupling agent TC-2 0.25
19 dioctyl phthalate (DOP)s 0.25
20 Hydroxylated acrylic resins 19.5
Add up to: 100.0
Production technique and preparation method: with embodiment together.
B, the agent of preparation rust-inhibiting paint solidifying priming paint, selected raw material and proportioning are:
Sequence number material name %
1 75% aromatic isocyanate solidifying agent 60.0
2 dimethylbenzene 10.0
3 N-BUTYL ACETATEs 10.0
4 acetone 10.0
5 2-butanols 10.0
Add up to: 100.0
Production technique and preparation method: with embodiment together.
C, preparation rust-inhibiting paint priming paint thinner, selected raw material and proportioning are:
Sequence number material name %
1 Virahol 20.0
2 vinyl acetic monomers 15.0
3 2-amylalcohols 13.0
4 1-butanols 20.0
5 ethylene glycol ether acetates 15.0
6 N-BUTYL ACETATEs 17.0
Add up to: 100.0
Production technique and preparation method: with embodiment together.
After above-mentioned A, B, C prepared, the mixed by 3: 0.5: 6.5 was even respectively, and all the other are implemented by embodiment 1 execution conditions and mode.
Embodiment three:
A, preparation rust-inhibiting paint host and additive, selected raw material and proportioning are:
Sequence number material name %
1 Hydroxylated acrylic resin 8.0
2 synthetic fat acid resins 11.0
3 nano-sized black iron oxides 1.5
4 iron oxide blacks 10.5
5 talcum powder 8.0
6 nano titanium oxides 2.5
7 mica powders 1.0
8 carbon blacks 3.0
9 titanium-iron powders 5.5
10 phosphide aluminium 6.5
11 SN5040 dispersion agents 3.0
12 zinc phosphates 1.0
13 ethylene glycol ether acetates 10.0
14 organosilicon flow agents 4.0
15 silicone antifoam agents 4.0
16 polyhydroxy phenols 0.5
17 titanate coupling agent G-2 0.25
18 dibutyl phthalates 0.25
19 Hydroxylated acrylic resins 19.5
Add up to: 100.0
Production technique and preparation method: with above-mentioned sequence number is that the raw material of 1-13 is inserted the agitation vat high speed and disperseed 30-60 minute, grind 2-3 all over qualified through three roll machine again to fineness, adding sequence number again is the 14-19 raw material, mixes evenly and checks, filtration, weighing, encapsulates, labels, puts in storage.
B, the agent of preparation rust-inhibiting paint solidifying priming paint, selected raw material and proportioning are:
Sequence number material name %
1 75% aromatic isocyanate solidifying agent 66.0
2 dimethylbenzene 12.0
3 N-BUTYL ACETATEs 15.0
4 2-butanols 5.0
5 cobalt naphthenates 2.0
Add up to: 100.0
Production technique and preparation method: with embodiment together.
C, preparation rust-inhibiting paint priming paint thinner, selected raw material and proportioning are:
Sequence number material name %
1 toluene 15.0
2 propylene carbonates 30.0
3 N-BUTYL ACETATEs 15.0
4 ethylene glycol 15.0
5 Virahols 25.0
Add up to: 100.0
Production technique and preparation method: with embodiment together.
After above-mentioned A, B, C prepared, the mixed by 6: 1: 3 was even respectively, and all the other are implemented by embodiment 1 execution conditions and mode.
Embodiment four:
A, preparation rust-inhibiting paint host and additive, selected raw material and proportioning are:
Sequence number material name %
1 Hydroxylated acrylic resin 15.0
2 synthetic fat acid resins 20.0
3 nano-aluminium oxides 3.0
4 iron oxide blacks 6.0
5 iron mica powder 5.0
6 talcum powder 6.0
7 nano titanium oxides 2.0
8 titanium-iron powders 5.5
9 barium metaborates 4.5
10 SN5040 dispersion agents 3.0
11 zinc phosphates 0.5
12 ethylene glycol ether acetates 9.0
13 organosilicon flow agents 4.0
14 silicone antifoam agents 4.0
15 124 Triazoles 0.2
16 titanate coupling agent TA-13 0.15
17 dibutyl phthalates 0.15
18 Hydroxylated acrylic resins 12.0
Add up to: 100.0
Production technique and preparation method: with above-mentioned sequence number is that the raw material of 1-12 is inserted the agitation vat high speed and disperseed 30-60 minute, grind 2-3 all over qualified through three roll machine again to fineness, adding sequence number again is the 13-18 raw material, mixes evenly and checks, filtration, weighing, encapsulates, labels, puts in storage.
B, the agent of preparation rust-inhibiting paint solidifying priming paint, selected raw material and proportioning are:
Sequence number material name %
1 75% aromatic isocyanate solidifying agent 65.0
2 dimethylbenzene 9.0
3 N-BUTYL ACETATEs 16.0
4 2-butanols 6.0
5 cobalt iso-octoates 4.0
Add up to: 100.0
Production technique and preparation method: with embodiment together.
C, preparation rust-inhibiting paint priming paint thinner, selected raw material and proportioning are:
Sequence number material name %
1 isoamyl acetate 15.0
2 propylene carbonates 20.0
3 ethylene glycol ether acetates 20.0
4 1-amylalcohols 20.0
5 Virahols 25.0
Add up to: 100.0
Production technique and preparation method: with embodiment together.
After above-mentioned A, B, C prepared, the mixed by 5: 1.5: 3.5 was even respectively, and all the other are implemented by embodiment 1 execution conditions and mode.
The present invention both can use spraying method in practice, can use dip coating construction again, and easily dry, the condition of surface drying is: under 60 ℃ only dry 5 minutes, under 25 ℃ only dry 15 minutes, when doing solid work, only need to place behind the surface drying and got final product in 18 hours.
In order to prove superperformance of the present invention, the applicant detects product and the coating that obtains with the present invention, and its performance test results is as follows:
The sequence number Interventions Requested set quota measured result method of inspection
1 flash-point＞23 ℃ ASTMD3278
2 solid part 65-80% ISO3251
3 viscosity (Stormer) 90-100KU SS/2800
The 4 snappiness diameter 4mm BS3900:E1 that do not ftracture
5 sticking power 0-1 level BS3900:E6
6 pencil hardnesss 〉=1H ASTMD3363
7 fineness≤50 GB1724
8 shock strengths, kg.cm 〉=50 50 GB/T1732-93
9 opacifying power g.m
-2≤ 80 (greater than 250) 60 GB/T1726
10 anti-gasoline (120
#, 24) and immerse all no abnormal SS/2800 in the 92# gasoline
11 anti-machine oil immerse all no abnormal SS/2800 in the standard machine oil
12 time of drying, 120 ℃, min 15 GB/T1728-79
13 gloss, % 60-80 76 GB/T1743-79
(168h) is non-foaming for 14 salt water resistances, and be wrinkle resistant non-foaming, wrinkle resistant GB/T1763-79
15 alkali resistances (0.1NNaOH, 24h) non-foaming, wrinkle resistant non-foaming, wrinkle resistant GB/T1763-79
16 acid resistance (0.1NH
2SO
4, 48h) non-foaming, wrinkle resistant non-foaming, wrinkle resistant GB/T1763-79
This product is mainly used in the protection against corrosion rust protection application that use on mechanical means, hardware surface, is particularly useful for the protection of equipment such as mechanical means, injection moulding machine, pressure die-casting machine, spark machine, CNC machining center, air compressor, elevator, motor and production thereof etc. and the novel nano modified anti-rust special primer of decorative painting.
Claims (9)
1. nano modification rust-proofing primer, it is characterized in that comprising the component of following weight per-cent: rust-inhibiting paint host 29.0-60.0%, nano-oxide additive 1.0-10.0%, solidifying agent 5.0-15.0%, thinner 30.0-65%, wherein said rust-inhibiting paint host comprises the component of following weight per-cent: rush-resisting material 5.0-30.0%, tinting pigment 5.0-30.0%, composite resin 20.0-50%, auxiliary agent 1.0-20.0%, described composite resin is by the synthetic fat acid resin and Hydroxylated acrylic resin is composite forms, and wherein the synthetic fat acid resin is a kind of medium-oil-length unsaturated fatty acids modified polyurethane and the Acrylic Acid Monomer fatty acid modified urethane through the graft copolymerization preparation.
2. nano modification rust-proofing primer according to claim 1 is characterized in that: described nano-oxide additive is the combination of any two or more component in nano zine oxide, nanometer iron oxide red, nano iron oxide yellow, nano-sized black iron oxide, nano-aluminium oxide, nano silicon or the nano titanium oxide.
3. nano modification rust-proofing primer according to claim 1 is characterized in that: described solidifying agent is that at least a above solvent complex forms in 75% aromatic isocyanate and dimethylbenzene, N-BUTYL ACETATE, propyl alcohol, the 2-butanols.
4. nano modification rust-proofing primer according to claim 1, it is characterized in that: described thinner is the combination of alcoholic solvent and ester solvent, wherein alcoholic solvent comprises two or more in the polyvalent alcohol of dibasic alcohol, three hydroxyls, and contain the above monohydroxy-alcohol of 6 carbon atoms, ester solvent is ethylene glycol ether acetate, N-BUTYL ACETATE, isoamyl acetate, vinyl acetic monomer, acetone, the mixture more than at least three kinds or three kinds in toluene, dimethyl benzene or the propylene carbonate.
5. nano modification rust-proofing primer according to claim 1, it is characterized in that: described thinner is two or more alcoholic solvent at least, with any at least three kinds of combining or the mixture more than three kinds in ester solvent and acetone, toluene, the dimethyl benzene, wherein alcoholic solvent comprises the polyvalent alcohol of dibasic alcohol, three hydroxyls and contains the above monohydroxy-alcohol of 6 carbon atoms, ester solvent is ethylene glycol ether acetate, N-BUTYL ACETATE, isoamyl acetate, vinyl acetic monomer.
6. nano modification rust-proofing primer according to claim 5 is characterized in that: described dibasic alcohol is selected ethylene glycol for use, and the polyvalent alcohol of three hydroxyls is selected n-propyl alcohol, Virahol, 1-butanols, 2-butanols, 1-amylalcohol for use, 2-amylalcohol, 3-amylalcohol.
7. nano modification rust-proofing primer according to claim 1 is characterized in that: described tinting pigment selects that green red, the titanium nickel yellow of Rutile type Titanium Dioxide, carbon black, coating molybdenum, coating are lemon yellow for use, the combination of any one and iron oxide black or iron mica powder in titanium-iron powder, red iron oxide, iron oxide yellow, iron oxide black or the iron mica powder.
8. nano modification rust-proofing primer according to claim 1 is characterized in that: described auxiliary agent comprises coupling agent, solubility promoter, flow agent, defoamer, dispersion agent, softening agent and inhibiter.
9. nano modification rust-proofing primer according to claim 8, it is characterized in that: described coupling agent is selected titanate coupling agent for use, its be among tetrabutyl titanate, titanate coupling agent TC-F, titanate coupling agent TC-2, titanate coupling agent TC-3, titanate coupling agent TC-27, titanate coupling agent TC-114, titanate coupling agent TC-Wt, titanate coupling agent G-2, titanate coupling agent G-6, titanate coupling agent TA-9-2, titanate coupling agent TA-13, titanate coupling agent TA-361 or the titanate coupling agent TD-5-1 any one or more than one; Described softening agent is the combination of any one or both in dibutyl phthalate, the dioctyl phthalate (DOP); Described inhibiter is at least a in picric acid, five times of acid, gallic acid, Weibull, polyhydroxy phenol, barium mahogany sulfonate, sad dicyclohexyl amine, phenylformic acid monoethanolamine or the benzotriazoles or more than one; Described solubility promoter is ethylene glycol ether acetate, propylene glycol, Virahol, isopropylcarbinol or propyl carbinol.
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| CNB2006100604702A CN100390240C (en) | 2006-04-28 | 2006-04-28 | Nano modified anti-rust special primer |
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| CNB2006100604702A CN100390240C (en) | 2006-04-28 | 2006-04-28 | Nano modified anti-rust special primer |
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| CN100390240C true CN100390240C (en) | 2008-05-28 |
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| WO2020099916A1 (en) * | 2018-11-18 | 2020-05-22 | Rahmani Mahdi | Rust converter |
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