CN105820669A - Tearable spray film and preparation method thereof - Google Patents
Tearable spray film and preparation method thereof Download PDFInfo
- Publication number
- CN105820669A CN105820669A CN201610398661.3A CN201610398661A CN105820669A CN 105820669 A CN105820669 A CN 105820669A CN 201610398661 A CN201610398661 A CN 201610398661A CN 105820669 A CN105820669 A CN 105820669A
- Authority
- CN
- China
- Prior art keywords
- spray film
- mill base
- film
- spray
- dimethyl ether
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D121/00—Coating compositions based on unspecified rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/20—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for coatings strippable as coherent films, e.g. temporary coatings strippable as coherent films
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention provides a tearable spray film and a preparation method thereof. The spray film is prepared from 5-10% of synthetic rubber, 5-15% of n-heptane, 20-40% of a naphtha solvent, 5-10% of xylene, 1-5% of butanone, 2-9% of heptanon, 0.5-1.5% of pigment, 0.1-0.5% of fumed silica and 30-50% of dimethyl ether. The spray film has proper adhesive force and good flexibility and can be torn off and stripped from an object in flake; besides, bubbles and pits are not likely to be formed due to coloring uniformity and smoothness, and a substrate or an original color is not corroded or damaged due to the mild formula.
Description
Technical field
The present invention relates to a kind of membranous type being easily peeled spray paint.
Background technology
Modern people follow the fashion changeable life, decoration of liking changing colour automobile, furniture or electrical equipment.
Particularly, along with the raising of people's living standard, automobile is the most no longer luxury goods, and car detailing has been the hottest
The industry of door, vehicle body changes colour a big focus especially.Aerosol paint, because of the feature that it is easy and simple to handle, color variety is various, forms
Carry out the first-selection that vehicle body changes colour, especially wheel hub for numerous automobile players to change colour.
But mostly traditional spraying paint is to be attached to change colour on object by chemistry bond energy, strong to substrate adhesion, molding of typically painting
The most just being difficult to clean off changing, the man-hour that colour changing is consumed is very large, troublesome.And the solvent of tradition paint is to ground or former paint all
There is stronger corrosiveness.
Existing market is popular changes colour with tearable spraying paint of spray membranous type, but such spray film generally exists following defect:
1, spray paint uneven, bubble, pit too much;
2, paint film is peeled off and is removed inconvenience, is difficult to larger area in blocks and peels off, retains the more mottle being difficult to and peeling off, still
Need by solvent clean.
3, ground or former paint there is stronger corrosiveness.
Summary of the invention
For overcoming disadvantages described above, the invention provides a kind of tearable spray film being easily peeled and preparation method thereof, this spray film has suitable
When adhesive force and preferable pliability, stripping object can be torn in flakes.
Described spray film is made up of following component by mass percentage: synthetic rubber 5-10%, normal heptane 5-15%, solvent stone
Cerebrol 20-40%, dimethylbenzene 5-10%, butanone 1-5%, two heptanone 2-9%, pigment 0.5-1.5%, aerosil
0.1-0.5%, dimethyl ether 30-50%.
Optimum ratio is: synthetic rubber 5.5%, normal heptane 10%, solvent naphtha 25%, dimethylbenzene 6%, butanone 3%, two
Heptanone 9%, pigment 1%, aerosil 0.5%, dimethyl ether 40%.
The preparation method of spray film, it is characterised in that comprise the following steps:
(1) dispersion: normal heptane, dimethylbenzene are put into scuffing of cylinder bore, stirs with dispersion machine, put into synthetic rubber while stirring, extremely
Solution clear;Then, aerosil and pigment are put into while stirring;Disperse with the rotating speed of 2000 turns/min again
Within 30 minutes, obtain thick mill base;
(2) grind: thick mill base grinder grinds suitable fineness repeatedly, and grinding temperature is 50-60 DEG C, obtains thin mill base;
(3) dilution: put into remaining component in thin mill base and be diluted, stir with dispersion machine, adjusts viscosity, mistake
Filter mechanical admixture, must spray coating materials liquid;
(4) it is filled into tank, filling dimethyl ether, obtain target product.
The present invention is sprayed film and is had the advantage that relative to prior art
1, inventive formulation uses synthetic rubber to be main film forming material, ground can be produced elastic absorption but be formed without real
Chemical bond attachment;And the principle being dependent on elastic absorption forms " false attachment ", the pulling force of appropriateness only need to be imposed,
Complete stripping, has suitable adhesive force and pliability, and adhesive force is stable, is difficult to depainting, it is possible to tear overburden in flakes
Body.
2, the present invention spray film can by spraying film forming, it is not necessary to by other instruments, easy construction is simple.
3, the granules of pigments of this spray film is fine and smooth, and uniform coloring is smooth, is difficult to bubble or pit.
4, this spray film uses substantial amounts of low polarity Weak solvent, and formula is gentle, does not corrodes or damage ground or primary colors, after stripping
The primary colors color and luster of object is still kept intact.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described further.
One, the preparation method of product of the present invention, comprises the following steps:
1, dispersion: normal heptane, dimethylbenzene are put into scuffing of cylinder bore, stirs with dispersion machine, put into synthetic rubber while stirring, directly
To solution clear;Continue to put into while stirring aerosil and pigment, improve dispersing speed, with 2000 turns
/ min moves to milling zone and grinds after disperseing 30 minutes.
2, grind: with grinder master grind several times, until fineness is qualified.In process of lapping, mill base temperature controls
50-60 DEG C, do not allow >=75 DEG C.
3, dilution: the mill base after grinding puts into the dilution of remaining component solvent, then is uniformly dispersed with dispersion machine, adjusts material
Fluid viscosity, to qualified, removes mechanical admixture with strainer filtering.
4, quality inspection is carried out, filling fill, add valve, compacting seals, and fills liquefied dimethyl ether, and check weighing leaks hunting, and adds
Dress button lid.
Two, prepare embodiment sample by the formula in table 1, test this using the spray film that certain factory in the market produces as comparison
The performance of embodiment sample, performance using spray film outward appearance, be easily peeled degree, damage to ground and primary colors refers to as test
Mark.
Method of testing: spray film and the comparison of each embodiment are sprayed film and be sprayed at nave boss and the front cover of same material condition respectively
On, only spraying 1/2nd areas, another 1/2nd areas do not process, and after peeling off spray film, two parts carry out contrast inspection
Survey spray film to ground and the damage of primary colors.
Result of the test is shown in Table 2.
Table 1
Table 2
Claims (3)
1. a tearable spray film, it is characterised in that described spray film is made up of following component by mass percentage: synthesis rubber
Glue 5-10%, normal heptane 5-15%, solvent naphtha 20-40%, dimethylbenzene 5-10%, butanone 1-5%, two heptanone 2-9%, face
Material 0.5-1.5%, aerosil 0.1-0.5%, dimethyl ether 30-50%.
Spray film the most as claimed in claim 1, it is characterised in that described spray film is by mass percentage by following component system
Become: synthetic rubber 5.5%, normal heptane 10%, solvent naphtha 25%, dimethylbenzene 6%, butanone 3%, two heptanone 9%, pigment
1%, aerosil 0.5%, dimethyl ether 40%.
3. spray the preparation method of film as claimed in claim 1 or 2, it is characterised in that comprise the following steps:
(1) dispersion: normal heptane, dimethylbenzene are put into scuffing of cylinder bore, stirs with dispersion machine, put into synthetic rubber while stirring, extremely
Solution clear;Put into aerosil and pigment while stirring;30 points are disperseed again with the rotating speed of 2000 turns/min
Clock obtains thick mill base;
(2) grind: thick mill base grinder is ground to suitable fineness repeatedly, and grinding temperature is 50-60 DEG C, obtains thin mill base;
(3) dilution: put into remaining component in thin mill base and be diluted, stir with dispersion machine, adjusts viscosity, mistake
Filter mechanical admixture, must spray coating materials liquid;
(4) it is packed into tank, fills dimethyl ether, obtain target product.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610398661.3A CN105820669A (en) | 2016-06-06 | 2016-06-06 | Tearable spray film and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610398661.3A CN105820669A (en) | 2016-06-06 | 2016-06-06 | Tearable spray film and preparation method thereof |
Publications (1)
Publication Number | Publication Date |
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CN105820669A true CN105820669A (en) | 2016-08-03 |
Family
ID=56531938
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN201610398661.3A Pending CN105820669A (en) | 2016-06-06 | 2016-06-06 | Tearable spray film and preparation method thereof |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106675139A (en) * | 2016-12-06 | 2017-05-17 | 钦州市高新技术产业服务中心 | Peelable spray membrane and preparation method thereof |
CN115815079A (en) * | 2022-11-23 | 2023-03-21 | 维沃移动通信有限公司 | Frame processing method, frame and electronic equipment |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102432953A (en) * | 2011-09-22 | 2012-05-02 | 中国航天科工集团第二研究院二一〇所 | Sand blasted surface protective film and protective method for engine metal shell |
CN103305077A (en) * | 2013-05-28 | 2013-09-18 | 济宁恒泰机械有限公司 | Coating with protection and color alteration functions |
CN103923537A (en) * | 2014-04-28 | 2014-07-16 | 东莞市海鲸实业投资有限公司 | Spraying agent capable of stripping protective coating film and production process of spraying agent |
CN104292925A (en) * | 2014-10-17 | 2015-01-21 | 广东三和化工科技有限公司 | Strippable spray lacquer and preparation method thereof |
US9273214B1 (en) * | 2013-03-04 | 2016-03-01 | Mark Figliozzi | Removable spray coating and application method |
-
2016
- 2016-06-06 CN CN201610398661.3A patent/CN105820669A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102432953A (en) * | 2011-09-22 | 2012-05-02 | 中国航天科工集团第二研究院二一〇所 | Sand blasted surface protective film and protective method for engine metal shell |
US9273214B1 (en) * | 2013-03-04 | 2016-03-01 | Mark Figliozzi | Removable spray coating and application method |
CN103305077A (en) * | 2013-05-28 | 2013-09-18 | 济宁恒泰机械有限公司 | Coating with protection and color alteration functions |
CN103923537A (en) * | 2014-04-28 | 2014-07-16 | 东莞市海鲸实业投资有限公司 | Spraying agent capable of stripping protective coating film and production process of spraying agent |
CN104292925A (en) * | 2014-10-17 | 2015-01-21 | 广东三和化工科技有限公司 | Strippable spray lacquer and preparation method thereof |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106675139A (en) * | 2016-12-06 | 2017-05-17 | 钦州市高新技术产业服务中心 | Peelable spray membrane and preparation method thereof |
CN115815079A (en) * | 2022-11-23 | 2023-03-21 | 维沃移动通信有限公司 | Frame processing method, frame and electronic equipment |
CN115815079B (en) * | 2022-11-23 | 2023-11-17 | 维沃移动通信有限公司 | Frame processing method, frame and electronic equipment |
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Application publication date: 20160803 |
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