CN105820669A - Tearable spray film and preparation method thereof - Google Patents

Tearable spray film and preparation method thereof Download PDF

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Publication number
CN105820669A
CN105820669A CN201610398661.3A CN201610398661A CN105820669A CN 105820669 A CN105820669 A CN 105820669A CN 201610398661 A CN201610398661 A CN 201610398661A CN 105820669 A CN105820669 A CN 105820669A
Authority
CN
China
Prior art keywords
spray film
mill base
film
spray
dimethyl ether
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610398661.3A
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Chinese (zh)
Inventor
梁伟明
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GUANGDONG LAYA CHEMICAL CO Ltd
Original Assignee
GUANGDONG LAYA CHEMICAL CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by GUANGDONG LAYA CHEMICAL CO Ltd filed Critical GUANGDONG LAYA CHEMICAL CO Ltd
Priority to CN201610398661.3A priority Critical patent/CN105820669A/en
Publication of CN105820669A publication Critical patent/CN105820669A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D121/00Coating compositions based on unspecified rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/36Silica
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/20Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for coatings strippable as coherent films, e.g. temporary coatings strippable as coherent films
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/20Diluents or solvents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Paints Or Removers (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

The invention provides a tearable spray film and a preparation method thereof. The spray film is prepared from 5-10% of synthetic rubber, 5-15% of n-heptane, 20-40% of a naphtha solvent, 5-10% of xylene, 1-5% of butanone, 2-9% of heptanon, 0.5-1.5% of pigment, 0.1-0.5% of fumed silica and 30-50% of dimethyl ether. The spray film has proper adhesive force and good flexibility and can be torn off and stripped from an object in flake; besides, bubbles and pits are not likely to be formed due to coloring uniformity and smoothness, and a substrate or an original color is not corroded or damaged due to the mild formula.

Description

A kind of tearable spray film and preparation method thereof
Technical field
The present invention relates to a kind of membranous type being easily peeled spray paint.
Background technology
Modern people follow the fashion changeable life, decoration of liking changing colour automobile, furniture or electrical equipment.
Particularly, along with the raising of people's living standard, automobile is the most no longer luxury goods, and car detailing has been the hottest The industry of door, vehicle body changes colour a big focus especially.Aerosol paint, because of the feature that it is easy and simple to handle, color variety is various, forms Carry out the first-selection that vehicle body changes colour, especially wheel hub for numerous automobile players to change colour.
But mostly traditional spraying paint is to be attached to change colour on object by chemistry bond energy, strong to substrate adhesion, molding of typically painting The most just being difficult to clean off changing, the man-hour that colour changing is consumed is very large, troublesome.And the solvent of tradition paint is to ground or former paint all There is stronger corrosiveness.
Existing market is popular changes colour with tearable spraying paint of spray membranous type, but such spray film generally exists following defect:
1, spray paint uneven, bubble, pit too much;
2, paint film is peeled off and is removed inconvenience, is difficult to larger area in blocks and peels off, retains the more mottle being difficult to and peeling off, still Need by solvent clean.
3, ground or former paint there is stronger corrosiveness.
Summary of the invention
For overcoming disadvantages described above, the invention provides a kind of tearable spray film being easily peeled and preparation method thereof, this spray film has suitable When adhesive force and preferable pliability, stripping object can be torn in flakes.
Described spray film is made up of following component by mass percentage: synthetic rubber 5-10%, normal heptane 5-15%, solvent stone Cerebrol 20-40%, dimethylbenzene 5-10%, butanone 1-5%, two heptanone 2-9%, pigment 0.5-1.5%, aerosil 0.1-0.5%, dimethyl ether 30-50%.
Optimum ratio is: synthetic rubber 5.5%, normal heptane 10%, solvent naphtha 25%, dimethylbenzene 6%, butanone 3%, two Heptanone 9%, pigment 1%, aerosil 0.5%, dimethyl ether 40%.
The preparation method of spray film, it is characterised in that comprise the following steps:
(1) dispersion: normal heptane, dimethylbenzene are put into scuffing of cylinder bore, stirs with dispersion machine, put into synthetic rubber while stirring, extremely Solution clear;Then, aerosil and pigment are put into while stirring;Disperse with the rotating speed of 2000 turns/min again Within 30 minutes, obtain thick mill base;
(2) grind: thick mill base grinder grinds suitable fineness repeatedly, and grinding temperature is 50-60 DEG C, obtains thin mill base;
(3) dilution: put into remaining component in thin mill base and be diluted, stir with dispersion machine, adjusts viscosity, mistake Filter mechanical admixture, must spray coating materials liquid;
(4) it is filled into tank, filling dimethyl ether, obtain target product.
The present invention is sprayed film and is had the advantage that relative to prior art
1, inventive formulation uses synthetic rubber to be main film forming material, ground can be produced elastic absorption but be formed without real Chemical bond attachment;And the principle being dependent on elastic absorption forms " false attachment ", the pulling force of appropriateness only need to be imposed, Complete stripping, has suitable adhesive force and pliability, and adhesive force is stable, is difficult to depainting, it is possible to tear overburden in flakes Body.
2, the present invention spray film can by spraying film forming, it is not necessary to by other instruments, easy construction is simple.
3, the granules of pigments of this spray film is fine and smooth, and uniform coloring is smooth, is difficult to bubble or pit.
4, this spray film uses substantial amounts of low polarity Weak solvent, and formula is gentle, does not corrodes or damage ground or primary colors, after stripping The primary colors color and luster of object is still kept intact.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described further.
One, the preparation method of product of the present invention, comprises the following steps:
1, dispersion: normal heptane, dimethylbenzene are put into scuffing of cylinder bore, stirs with dispersion machine, put into synthetic rubber while stirring, directly To solution clear;Continue to put into while stirring aerosil and pigment, improve dispersing speed, with 2000 turns / min moves to milling zone and grinds after disperseing 30 minutes.
2, grind: with grinder master grind several times, until fineness is qualified.In process of lapping, mill base temperature controls 50-60 DEG C, do not allow >=75 DEG C.
3, dilution: the mill base after grinding puts into the dilution of remaining component solvent, then is uniformly dispersed with dispersion machine, adjusts material Fluid viscosity, to qualified, removes mechanical admixture with strainer filtering.
4, quality inspection is carried out, filling fill, add valve, compacting seals, and fills liquefied dimethyl ether, and check weighing leaks hunting, and adds Dress button lid.
Two, prepare embodiment sample by the formula in table 1, test this using the spray film that certain factory in the market produces as comparison The performance of embodiment sample, performance using spray film outward appearance, be easily peeled degree, damage to ground and primary colors refers to as test Mark.
Method of testing: spray film and the comparison of each embodiment are sprayed film and be sprayed at nave boss and the front cover of same material condition respectively On, only spraying 1/2nd areas, another 1/2nd areas do not process, and after peeling off spray film, two parts carry out contrast inspection Survey spray film to ground and the damage of primary colors.
Result of the test is shown in Table 2.
Table 1
Table 2

Claims (3)

1. a tearable spray film, it is characterised in that described spray film is made up of following component by mass percentage: synthesis rubber Glue 5-10%, normal heptane 5-15%, solvent naphtha 20-40%, dimethylbenzene 5-10%, butanone 1-5%, two heptanone 2-9%, face Material 0.5-1.5%, aerosil 0.1-0.5%, dimethyl ether 30-50%.
Spray film the most as claimed in claim 1, it is characterised in that described spray film is by mass percentage by following component system Become: synthetic rubber 5.5%, normal heptane 10%, solvent naphtha 25%, dimethylbenzene 6%, butanone 3%, two heptanone 9%, pigment 1%, aerosil 0.5%, dimethyl ether 40%.
3. spray the preparation method of film as claimed in claim 1 or 2, it is characterised in that comprise the following steps:
(1) dispersion: normal heptane, dimethylbenzene are put into scuffing of cylinder bore, stirs with dispersion machine, put into synthetic rubber while stirring, extremely Solution clear;Put into aerosil and pigment while stirring;30 points are disperseed again with the rotating speed of 2000 turns/min Clock obtains thick mill base;
(2) grind: thick mill base grinder is ground to suitable fineness repeatedly, and grinding temperature is 50-60 DEG C, obtains thin mill base;
(3) dilution: put into remaining component in thin mill base and be diluted, stir with dispersion machine, adjusts viscosity, mistake Filter mechanical admixture, must spray coating materials liquid;
(4) it is packed into tank, fills dimethyl ether, obtain target product.
CN201610398661.3A 2016-06-06 2016-06-06 Tearable spray film and preparation method thereof Pending CN105820669A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610398661.3A CN105820669A (en) 2016-06-06 2016-06-06 Tearable spray film and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610398661.3A CN105820669A (en) 2016-06-06 2016-06-06 Tearable spray film and preparation method thereof

Publications (1)

Publication Number Publication Date
CN105820669A true CN105820669A (en) 2016-08-03

Family

ID=56531938

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610398661.3A Pending CN105820669A (en) 2016-06-06 2016-06-06 Tearable spray film and preparation method thereof

Country Status (1)

Country Link
CN (1) CN105820669A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106675139A (en) * 2016-12-06 2017-05-17 钦州市高新技术产业服务中心 Peelable spray membrane and preparation method thereof
CN115815079A (en) * 2022-11-23 2023-03-21 维沃移动通信有限公司 Frame processing method, frame and electronic equipment

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102432953A (en) * 2011-09-22 2012-05-02 中国航天科工集团第二研究院二一〇所 Sand blasted surface protective film and protective method for engine metal shell
CN103305077A (en) * 2013-05-28 2013-09-18 济宁恒泰机械有限公司 Coating with protection and color alteration functions
CN103923537A (en) * 2014-04-28 2014-07-16 东莞市海鲸实业投资有限公司 Spraying agent capable of stripping protective coating film and production process of spraying agent
CN104292925A (en) * 2014-10-17 2015-01-21 广东三和化工科技有限公司 Strippable spray lacquer and preparation method thereof
US9273214B1 (en) * 2013-03-04 2016-03-01 Mark Figliozzi Removable spray coating and application method

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102432953A (en) * 2011-09-22 2012-05-02 中国航天科工集团第二研究院二一〇所 Sand blasted surface protective film and protective method for engine metal shell
US9273214B1 (en) * 2013-03-04 2016-03-01 Mark Figliozzi Removable spray coating and application method
CN103305077A (en) * 2013-05-28 2013-09-18 济宁恒泰机械有限公司 Coating with protection and color alteration functions
CN103923537A (en) * 2014-04-28 2014-07-16 东莞市海鲸实业投资有限公司 Spraying agent capable of stripping protective coating film and production process of spraying agent
CN104292925A (en) * 2014-10-17 2015-01-21 广东三和化工科技有限公司 Strippable spray lacquer and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106675139A (en) * 2016-12-06 2017-05-17 钦州市高新技术产业服务中心 Peelable spray membrane and preparation method thereof
CN115815079A (en) * 2022-11-23 2023-03-21 维沃移动通信有限公司 Frame processing method, frame and electronic equipment
CN115815079B (en) * 2022-11-23 2023-11-17 维沃移动通信有限公司 Frame processing method, frame and electronic equipment

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Application publication date: 20160803

RJ01 Rejection of invention patent application after publication