CN104774502A - Plastic printing ink with acid-base resistance property and preparation method thereof - Google Patents
Plastic printing ink with acid-base resistance property and preparation method thereof Download PDFInfo
- Publication number
- CN104774502A CN104774502A CN201510210850.9A CN201510210850A CN104774502A CN 104774502 A CN104774502 A CN 104774502A CN 201510210850 A CN201510210850 A CN 201510210850A CN 104774502 A CN104774502 A CN 104774502A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/108—Hydrocarbon resins
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention belongs to the technical field of printing ink, and particularly relates to plastic printing ink with the acid-base resistance property and a preparation method thereof. The plastic printing ink comprises, by weight, 30-50 parts of chlorinated polypropylene resin, 15-35 parts of water-based acrylic resin, 12-22 parts of nanometer aluminum oxide, 6-15 parts of glycerin monostearate, 8-20 parts of ethyl alcohol, 1-5 parts of chitosan and graphene composite materials, 1-5 parts of auxiliaries, 1-5 parts of hollow glass beads and 1-2 parts of walnut shell flour. According to the plastic printing ink with the acid-base resistance property and the preparation method thereof, all the raw materials achieve the purpose of mutual capacitance, and the acid-base resistance property is good.
Description
Technical field
The present invention relates to technical field of ink, particularly relate to ink used for plastic of a kind of resistance to acids and bases and preparation method thereof.
Background technology
Existing ink used for plastic is the liquid ink adopting water soluble acrylic resin, senior pigment, pure water, auxiliary agent to refine; It is good that it not only has printing effect on plastics, film, and do not fire, not quick-fried, nontoxic, health that pressman can not be damaged, to air also non-environmental-pollution.
In daily use, the frequent contact acidity of plastics, film or alkaline matter, this just requires that the ink used for plastic be printed on it also must have certain acid resistance, alkalescence, otherwise be easy to phenomenons such as occurring layer of ink variable color, come off, along with the continuous progress of people's living standard, constantly promote the resistance to acids and bases performance requriements of ink used for plastic itself, therefore the performance need such as resistance to acids and bases of existing ink used for plastic improves.
Summary of the invention
The object of the invention is to provide for the deficiencies in the prior art the ink used for plastic that a kind of resistance to acids and bases performance is good.
Another object of the present invention is the preparation method of the ink used for plastic providing a kind of resistance to acids and bases for the deficiencies in the prior art.
The present invention is achieved through the following technical solutions.
An ink used for plastic for resistance to acids and bases, it comprises the raw material of following weight part: chlorinated polypropylene 30-50 part, water-borne acrylic resin 15-35 part, nano aluminium oxide 12-22 part, glyceryl monostearate 6-15 part, ethanol 8-20 part, chitosan-graphene composite material 1-5 part, auxiliary agent 1-5 part, hollow glass micropearl 1-5 part, walnut shell flour 1-2 part.
Particularly, it comprises the raw material of following weight part: chlorinated polypropylene 30-40 part, water-borne acrylic resin 26-35 part, nano aluminium oxide 12-17 part, glyceryl monostearate 11-15 part, ethanol 8-13 part, chitosan-graphene composite material 1-3 part, auxiliary agent 4-5 part, hollow glass micropearl 4-5 part, walnut shell flour 1-2 part.
Particularly, it comprises the raw material of following weight part: chlorinated polypropylene 41-50 part, water-borne acrylic resin 15-25 part, nano aluminium oxide 18-22 part, glyceryl monostearate 6-10 part, ethanol 14-20 part, chitosan-graphene composite material 4-5 part, auxiliary agent 1-3 part, hollow glass micropearl 1-3 part, walnut shell flour 1-2 part.
Particularly, it comprises the raw material of following weight part: chlorinated polypropylene 35-45 part, water-borne acrylic resin 20-30 part, nano aluminium oxide 15-20 part, glyceryl monostearate 9-12 part, ethanol 12-16 part, chitosan-graphene composite material 2-3 part, auxiliary agent 3-4 part, hollow glass micropearl 2-3 part, walnut shell flour 1-2 part.
Particularly, it also comprises dextrin 1-3 weight part.Dextrin has good mobility, stronger adhesive capacity and adsorptive power, can permeate, act synergistically with other raw material, improve the physicals of ink used for plastic in raw material, improves the stability of ink used for plastic.
Particularly, auxiliary agent comprises defoamer, tensio-active agent, silicon wax emulsion.Defoamer is silicone antifoam agent or natural fats and oils; Tensio-active agent is silicon system tensio-active agent or fluorine system tensio-active agent.
A kind of preparation method of ink used for plastic of resistance to acids and bases, preparation process is as follows: by above-mentioned weight part, first nano aluminium oxide is mixed with ethanol, add chlorinated polypropylene, water-borne acrylic resin under whipped state, after mixing, dispersion, grinding, add chitosan-graphene composite material, ultrasonic grinding 30-40 minute, add all the other raw materials, after stirring, obtain the ink used for plastic of resistance to acids and bases.
the present invention has following beneficial effect:the ink used for plastic of resistance to acids and bases of the present invention; have the following advantages: glycan-graphene composite material has larger specific surface area; there is between chitosan and Graphene the synergy of enhancing; chitosan-graphene composite material and the synergy such as walnut shell flour, nano aluminium oxide simultaneously; ink used for plastic is made to have the self-shield coating of acid resistance, alkalescence; effectively inhibit the diffusion in ink used for plastic of acidity, alkaline matter, there is good acid-proof alkaline.The each raw material of the present invention reaches the object of mutual tolerance, and resistance to acids and bases performance is good.
Embodiment
Below in conjunction with embodiment, the present invention is described in detail.
embodiment 1.
An ink used for plastic for resistance to acids and bases, it comprises the raw material of following weight part: chlorinated polypropylene 30 parts, water-borne acrylic resin 35 parts, nano aluminium oxide 12 parts, glyceryl monostearate 15 parts, ethanol 8 parts, chitosan-graphene composite material 3 parts, auxiliary agent 4 parts, hollow glass micropearl 5 parts, walnut shell flour 1 part.Auxiliary agent comprises defoamer 1 part, 1 part, tensio-active agent, silicon wax emulsion 2 parts.Defoamer is silicone antifoam agent (as organic silicon modified by polyether) or natural fats and oils; Tensio-active agent is silicon system tensio-active agent or fluorine system tensio-active agent.
A kind of preparation method of ink used for plastic of resistance to acids and bases, preparation process is as follows: by above-mentioned weight part, first nano aluminium oxide is mixed with ethanol, add chlorinated polypropylene, water-borne acrylic resin under whipped state, after mixing, dispersion, grinding, add chitosan-graphene composite material, ultrasonic grinding 40 minutes, adds all the other raw materials, after stirring, obtain the ink used for plastic of resistance to acids and bases.
embodiment 2.
The difference of the present embodiment and embodiment 1 is: a kind of ink used for plastic of resistance to acids and bases, and it comprises the raw material of following weight part: chlorinated polypropylene 40 parts, water-borne acrylic resin 26 parts, nano aluminium oxide 17 parts, glyceryl monostearate 11 parts, ethanol 13 parts, chitosan-graphene composite material 1 part, auxiliary agent 5 parts, hollow glass micropearl 4 parts, walnut shell flour 2 parts.Auxiliary agent comprises defoamer 2 parts, 1 part, tensio-active agent, silicon wax emulsion 2 parts.
A kind of preparation method of ink used for plastic of resistance to acids and bases, preparation process is as follows: by above-mentioned weight part, first nano aluminium oxide is mixed with ethanol, add chlorinated polypropylene, water-borne acrylic resin under whipped state, after mixing, dispersion, grinding, add chitosan-graphene composite material, ultrasonic grinding 38 minutes, adds all the other raw materials, after stirring, obtain the ink used for plastic of resistance to acids and bases.
embodiment 3.
The difference of the present embodiment and embodiment 1 is: a kind of ink used for plastic of resistance to acids and bases, and it comprises the raw material of following weight part: chlorinated polypropylene 41 parts, water-borne acrylic resin 25 parts, nano aluminium oxide 18 parts, glyceryl monostearate 10 parts, ethanol 14 parts, chitosan-graphene composite material 5 parts, auxiliary agent 1 part, hollow glass micropearl 3 parts, walnut shell flour 1 part.Auxiliary agent comprises defoamer 0.2 part, 0.3 part, tensio-active agent, silicon wax emulsion 0.5 part.
A kind of preparation method of ink used for plastic of resistance to acids and bases, preparation process is as follows: by above-mentioned weight part, first nano aluminium oxide is mixed with ethanol, add chlorinated polypropylene, water-borne acrylic resin under whipped state, after mixing, dispersion, grinding, add chitosan-graphene composite material, ultrasonic grinding 36 minutes, adds all the other raw materials, after stirring, obtain the ink used for plastic of resistance to acids and bases.
embodiment 4.
The difference of the present embodiment and embodiment 1 is: a kind of ink used for plastic of resistance to acids and bases, and it comprises the raw material of following weight part: chlorinated polypropylene 50 parts, water-borne acrylic resin 15 parts, nano aluminium oxide 22 parts, glyceryl monostearate 6 parts, ethanol 20 parts, chitosan-graphene composite material 4 parts, auxiliary agent 3 parts, hollow glass micropearl 1 part, walnut shell flour 2 parts.Auxiliary agent comprises defoamer 1 part, 1 part, tensio-active agent, silicon wax emulsion 1 part.
A kind of preparation method of ink used for plastic of resistance to acids and bases, preparation process is as follows: by above-mentioned weight part, first nano aluminium oxide is mixed with ethanol, add chlorinated polypropylene, water-borne acrylic resin under whipped state, after mixing, dispersion, grinding, add chitosan-graphene composite material, ultrasonic grinding 33 minutes, adds all the other raw materials, after stirring, obtain the ink used for plastic of resistance to acids and bases.
embodiment 5.
The difference of the present embodiment and embodiment 1 is: a kind of ink used for plastic of resistance to acids and bases, and it comprises the raw material of following weight part: chlorinated polypropylene 40 parts, water-borne acrylic resin 25 parts, nano aluminium oxide 18 parts, glyceryl monostearate 10 parts, ethanol 15 parts, chitosan-graphene composite material 2 parts, auxiliary agent 2 parts, hollow glass micropearl 3 parts, walnut shell flour 1 part, 2 parts, dextrin.Auxiliary agent comprises defoamer 0.5 part, 1 part, tensio-active agent, silicon wax emulsion 0.5 part.
A kind of preparation method of ink used for plastic of resistance to acids and bases, preparation process is as follows: by above-mentioned weight part, first nano aluminium oxide is mixed with ethanol, add chlorinated polypropylene, water-borne acrylic resin under whipped state, after mixing, dispersion, grinding, add chitosan-graphene composite material, ultrasonic grinding 30 minutes, adds all the other raw materials, after stirring, obtain the ink used for plastic of resistance to acids and bases.
The ink used for plastic of resistance to acids and bases prepared by Application Example 1-5 carries out performance measurement, as table 1.
Table 1
Finally should be noted that; above embodiment is only in order to illustrate technical scheme of the present invention; but not limiting the scope of the invention; although done to explain to the present invention with reference to preferred embodiment; those of ordinary skill in the art is to be understood that; can modify to technical scheme of the present invention or equivalent replacement, and not depart from essence and the scope of technical solution of the present invention.
Claims (7)
1. the ink used for plastic of a resistance to acids and bases, it is characterized in that, it comprises the raw material of following weight part: chlorinated polypropylene 30-50 part, water-borne acrylic resin 15-35 part, nano aluminium oxide 12-22 part, glyceryl monostearate 6-15 part, ethanol 8-20 part, chitosan-graphene composite material 1-5 part, auxiliary agent 1-5 part, hollow glass micropearl 1-5 part, walnut shell flour 1-2 part.
2. the ink used for plastic of resistance to acids and bases according to claim 1, it is characterized in that, it comprises the raw material of following weight part: chlorinated polypropylene 30-40 part, water-borne acrylic resin 26-35 part, nano aluminium oxide 12-17 part, glyceryl monostearate 11-15 part, ethanol 8-13 part, chitosan-graphene composite material 1-3 part, auxiliary agent 4-5 part, hollow glass micropearl 4-5 part, walnut shell flour 1-2 part.
3. the ink used for plastic of resistance to acids and bases according to claim 1, it is characterized in that, it comprises the raw material of following weight part: chlorinated polypropylene 41-50 part, water-borne acrylic resin 15-25 part, nano aluminium oxide 18-22 part, glyceryl monostearate 6-10 part, ethanol 14-20 part, chitosan-graphene composite material 4-5 part, auxiliary agent 1-3 part, hollow glass micropearl 1-3 part, walnut shell flour 1-2 part.
4. the ink used for plastic of resistance to acids and bases according to claim 1, it is characterized in that, it comprises the raw material of following weight part: chlorinated polypropylene 35-45 part, water-borne acrylic resin 20-30 part, nano aluminium oxide 15-20 part, glyceryl monostearate 9-12 part, ethanol 12-16 part, chitosan-graphene composite material 2-3 part, auxiliary agent 3-4 part, hollow glass micropearl 2-3 part, walnut shell flour 1-2 part.
5. the ink used for plastic of resistance to acids and bases according to claim 1, is characterized in that, it also comprises dextrin 1-3 weight part.
6. the ink used for plastic of resistance to acids and bases according to claim 1, is characterized in that, auxiliary agent comprises defoamer, tensio-active agent, silicon wax emulsion.
7. the preparation method of the ink used for plastic of the resistance to acids and bases of claim 1 to 6 any one, it is characterized in that, preparation process is as follows: by above-mentioned weight part, first mixed with ethanol by nano aluminium oxide, chlorinated polypropylene, water-borne acrylic resin is added under whipped state, after mixing, dispersion, grinding, add chitosan-graphene composite material, ultrasonic grinding 30-40 minute, add all the other raw materials, after stirring, obtain the ink used for plastic of resistance to acids and bases.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510210850.9A CN104774502A (en) | 2015-04-29 | 2015-04-29 | Plastic printing ink with acid-base resistance property and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510210850.9A CN104774502A (en) | 2015-04-29 | 2015-04-29 | Plastic printing ink with acid-base resistance property and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN104774502A true CN104774502A (en) | 2015-07-15 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510210850.9A Pending CN104774502A (en) | 2015-04-29 | 2015-04-29 | Plastic printing ink with acid-base resistance property and preparation method thereof |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1290728A (en) * | 2000-10-26 | 2001-04-11 | 中山大学 | Water ink for plastic film relief printing and its producing method |
| CN101020753A (en) * | 2007-03-19 | 2007-08-22 | 江苏柏鹤涂料有限公司 | Water-base resin for polyacrylate primer and water-base paint |
| CN101429359A (en) * | 2008-12-08 | 2009-05-13 | 山西鹰鲲科技有限公司 | Water-based plastic composite inner-printing ink |
| CN103342926A (en) * | 2013-07-25 | 2013-10-09 | 江苏足迹涂料有限公司 | Paint for polyolefin and preparation method thereof |
-
2015
- 2015-04-29 CN CN201510210850.9A patent/CN104774502A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1290728A (en) * | 2000-10-26 | 2001-04-11 | 中山大学 | Water ink for plastic film relief printing and its producing method |
| CN101020753A (en) * | 2007-03-19 | 2007-08-22 | 江苏柏鹤涂料有限公司 | Water-base resin for polyacrylate primer and water-base paint |
| CN101429359A (en) * | 2008-12-08 | 2009-05-13 | 山西鹰鲲科技有限公司 | Water-based plastic composite inner-printing ink |
| CN103342926A (en) * | 2013-07-25 | 2013-10-09 | 江苏足迹涂料有限公司 | Paint for polyolefin and preparation method thereof |
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Application publication date: 20150715 |
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