CN106147451A - Fire resistant water-based aluminizing transfer paint compositions and preparation method thereof - Google Patents
Fire resistant water-based aluminizing transfer paint compositions and preparation method thereof Download PDFInfo
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- CN106147451A CN106147451A CN201610605819.XA CN201610605819A CN106147451A CN 106147451 A CN106147451 A CN 106147451A CN 201610605819 A CN201610605819 A CN 201610605819A CN 106147451 A CN106147451 A CN 106147451A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D129/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Coating compositions based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Coating compositions based on derivatives of such polymers
- C09D129/02—Homopolymers or copolymers of unsaturated alcohols
- C09D129/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
The invention provides a kind of fire resistant water-based aluminizing transfer paint compositions and preparation method thereof；Described coating composition includes each component of following parts by weight: water-base resin 60 85 parts, high-temperature-resistant silicon resin 10 35 parts, cosolvent 12 parts；Deionized water 14 parts；Wetting agent 0.02 part；Levelling agent 0.01 part；Defoamer 0.05 part.Present invention can apply to the lifting of the water paint heat resistance of many body system, by adding appropriate modified silicone resin, the resistance to temperature value of die pressing test is compared the coating heatproof not added and is obviously improved 10 30 DEG C, and this addition will not cause consistency problem.
Description
Technical field
The invention belongs to technical field of composite materials, relate to a kind of fire resistant water-based aluminizing transfer paint compositions and system thereof
Preparation Method.
Background technology
Current high temperature resistant aluminizing transfer paint major part is solvent-based system and least a portion of water-based system, wherein solvent-borne type
System uses organic solvent, on the one hand volatile organic matter (VOCs) the severe contamination production environment of high-load, the opposing party in a large number
Face is the solvent tax starting to increase income association area, forces people that water paint produces more keen interest.And existing small part
The heat resistance of water-based system is also unable to reach the level of solvent based coating, therefore needs badly and improves aqueous and aluminize transfer coated resistance to
Warm nature energy, thus meet the market demand.
The aluminize means versatility of transfer coated heat resistance of existing raising aqueous is poor.A kind of conventional method is to adopt
With the higher raw material resin of heat resistance, PEPA as higher in Tg, but there is the shortcoming of synthesising stability difference in it, very
It is difficult to ensure card large-scale use.Another kind of method is the resin raising heat resistance high by being mixed into heat resistance, but this type of tree
The general levelling of fat and transfer performance are poor, even cause insoluble consistency problem.Lack a kind of general and can the most at present
Control improves the means of heat resistance.
Summary of the invention
For defect of the prior art, it is an object of the invention to provide the combination of a kind of fire resistant water-based aluminizing transfer paint
Thing and preparation method thereof.
It is an object of the invention to be achieved through the following technical solutions:
The invention provides a kind of aqueous high-temperature-resistant aluminizing transfer paint compositions, described coating composition includes following
Each component of parts by weight:
Preferably, described water-base resin includes aqueous acrylic emulsion, aqueous polyurethane emulsion, acrylic acid modified poly-ammonia
The combination of one or more in ester emulsion, water-dispersible nitrocotton, watersoluble polyvinyl alcohol emulsion.
Preferably, in described water-base resin, solid content is 20-40wt%.Described water-base resin solid content is too high, can cause
The coating flow leveling of coating is poor；Solid content is too low, and coating can be caused to shift.
Preferably, described high-temperature-resistant silicon resin is the aqueous solution of organically-modified silicones.
Preferably, in the aqueous solution of described organically-modified silicones, silicones solid content is 30-40wt%.Described modification
Silicones solid content too high, coating moulding property can be caused poor；Content is too low, causes heatproof to promote the most notable.
It is highly preferred that described organically-modified silicones includes methyl phenyl silicone resin, epoxide modified silicones, organosilicon
One or more in polyurethane resin.
Preferably, described cosolvent includes at least one in isopropanol, ethanol.
Preferably, described wetting agent includes dodecylbenzene sodium sulfonate.
Preferably, described levelling agent includes Siloxane-Oxyalkylene Copolymers；Described defoamer includes modified organic silicon breast
Liquid.
Present invention also offers the preparation method of a kind of aqueous high-temperature-resistant aluminizing transfer paint compositions, described method bag
Include following steps:
A1, weigh each component according to weight/mass percentage composition；
A2, water-base resin and high-temperature-resistant silicon resin are placed in reactor, stirring at low speed 5-10min；
A3, in reactor, add cosolvent and deionized water, stirring at low speed 5min；
A4, in reactor, it is sequentially added into wetting agent, levelling agent and defoamer, high-speed stirred 20-30min, then through filtering,
Obtain described coating composition.
Prior art is compared, and the present invention has a following beneficial effect:
(1) suitability is wide: this method can be applicable to water paint (water soluble acrylic acid, aqueous polyurethane, the aqueous of many body system
Polyvinyl alcohol etc.) lifting of heat resistance, by adding appropriate modified silicone resin, the resistance to temperature value of die pressing test is compared
The coating heatproof not added is obviously improved 10-30 DEG C, and this addition will not cause consistency problem；
(2) environment-friendly advantage: the high-temperature-resistant silicon resin solvent that this method introduces is deionized water, safety non-toxic；
(3) raw material is stable: this fire resistant resin is widely used in fiber, rubber and coating industry, has stable supply
Ensure；
(4) controllability is high: according to the heatproof requirement of different coating, can design the different amounts of fire resistant resin of addition, reach
Heatproof requirement.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in detail.Following example will assist in the technology of this area
Personnel are further appreciated by the present invention, but limit the present invention the most in any form.It should be pointed out that, the ordinary skill to this area
For personnel, without departing from the inventive concept of the premise, it is also possible to make some deformation and improvement.These broadly fall into the present invention
Protection domain.
Embodiment 1
Present embodiments provide a kind of aqueous high-temperature-resistant aluminizing transfer paint compositions and preparation method thereof, described coating
Compositions includes each component of following weight: 83Kg water-base resin, 14Kg high-temperature-resistant silicon resin, 2Kg cosolvent, 1Kg deionization
Water, 0.02Kg wetting agent, 0.01Kg levelling agent and 0.05Kg defoamer.Wherein water-base resin is aqueous acrylic emulsion, admittedly contain
Amount is 0-30 DEG C for 20wt%, Tg, molecular weight >=200,000；High-temperature-resistant silicon resin is methyl phenyl silicone resin, in weakly alkaline the moon
Ion-type aqueous solution, solid content 40wt%；Cosolvent is isopropanol；Wetting agent is dodecylbenzene sodium sulfonate；Levelling agent is poly-
Ether modified polyorganosiloxane；Defoamer is modified organic silicon emulsion.
Described preparation method comprises the following steps that:
(1) get the raw materials ready according to said components and content；
(2) water-base resin and high-temperature-resistant silicon resin are placed in reactor, stirring at low speed 5-10min；
(3) in reactor, add cosolvent and deionized water, continue stirring at low speed 5min；
(4) in reactor, wetting agent, levelling agent and defoamer it are sequentially added into, high-speed stirred 20-30min, then through filtering,
Obtain product.
Embodiment 2
Present embodiments provide a kind of aqueous high-temperature-resistant aluminizing transfer paint compositions and preparation method thereof, described coating
Compositions includes each component of following weight: 80Kg water-base resin, 15Kg high-temperature-resistant silicon resin, 1Kg cosolvent, 4Kg deionization
Water, 0.02Kg wetting agent, 0.01Kg levelling agent and 0.05Kg defoamer, wherein water-base resin is aqueous polyurethane emulsion, admittedly contain
Amount is 0-30 DEG C for 23wt%, Tg, molecular weight >=200,000；High-temperature-resistant silicon resin is organic silicon polyurethane resin, in weakly alkaline
Anionic aqueous solution, solid content is 35wt%；Cosolvent is isopropanol；Wetting agent is dodecylbenzene sodium sulfonate；Levelling agent
For Siloxane-Oxyalkylene Copolymers；Defoamer is modified organic silicon emulsion.
Described preparation method comprises the following steps that:
(1) get the raw materials ready according to following components and content:
(2) water-base resin and high-temperature-resistant silicon resin are placed in reactor, stirring at low speed 5-10min；
(3) in reactor, add cosolvent and deionized water, continue stirring at low speed 5min；
(4) in reactor, wetting agent, levelling agent and defoamer it are sequentially added into, high-speed stirred 20-30min, then through filtering,
Obtain product.
Embodiment 3
Present embodiments provide a kind of aqueous high-temperature-resistant aluminizing transfer paint compositions and preparation method thereof, described coating
Compositions includes each component of following weight: 70Kg water-base resin, 25Kg high-temperature-resistant silicon resin, 1Kg cosolvent, 4Kg deionization
Water, 0.02Kg wetting agent, 0.01Kg levelling agent and 0.05Kg defoamer, wherein water-base resin is acrylic acid modified polyurethane,
Solid content is that 30wt%, Tg are 0-30 DEG C, molecular weight >=200,000；High-temperature-resistant silicon resin is epoxide modified silicones, in alkalescence
Anionic aqueous solution, solid content is 40wt%；Cosolvent is ethanol；Wetting agent is dodecylbenzene sodium sulfonate；Levelling agent
For Siloxane-Oxyalkylene Copolymers；Defoamer is modified organic silicon emulsion.
Described preparation method comprises the following steps that:
(1) get the raw materials ready according to following components and content:
(2) water-base resin and high-temperature-resistant silicon resin are placed in reactor, stirring at low speed 5-10min；
(3) in reactor, add cosolvent and deionized water, continue stirring at low speed 5min；
(4) in reactor, wetting agent, levelling agent and defoamer it are sequentially added into, high-speed stirred 20-30min, then through filtering,
Obtain product.
Embodiment 4
Present embodiments provide a kind of aqueous high-temperature-resistant aluminizing transfer paint compositions and preparation method thereof, described coating
Compositions includes each component of following weight: 60Kg water-base resin, 35Kg high-temperature-resistant silicon resin, 2Kg cosolvent, 3Kg deionization
Water, 0.02Kg wetting agent, 0.01Kg levelling agent and 0.05Kg defoamer, wherein water-base resin is watersoluble polyvinyl alcohol emulsion, Gu
Content is that 30wt%, Tg are 0-30 DEG C, molecular weight >=200,000；High-temperature-resistant silicon resin is methyl phenyl silicone resin, in weakly alkaline
Anionic aqueous solution, solid content is 30wt%；Cosolvent is ethanol；Wetting agent is dodecylbenzene sodium sulfonate；Levelling agent is
Siloxane-Oxyalkylene Copolymers；Defoamer is modified organic silicon emulsion.
Described preparation method comprises the following steps that:
(1) get the raw materials ready according to following components and content:
(2) water-base resin and high-temperature-resistant silicon resin are placed in reactor, stirring at low speed 5-10min；
(3) in reactor, add cosolvent and deionized water, continue stirring at low speed 5min；
(4) in reactor, wetting agent, levelling agent and defoamer it are sequentially added into, high-speed stirred 20-30min, then through filtering,
Obtain product.
Comparative example 1
This comparative example provides a kind of aqueous high-temperature-resistant aluminizing transfer paint compositions and preparation method thereof, described coating
Component and the weight of compositions are same as in Example 1, the difference is that only: the high-temperature-resistant silicon resin that the present invention uses is poly-first
Base silicones.
The preparation method of this comparative example is same as in Example 1.
Comparative example 2
This comparative example provides a kind of aqueous high-temperature-resistant aluminizing transfer paint compositions and preparation method thereof, described coating
Component and the weight of compositions are same as in Example 1, the difference is that only: the cosolvent that the present invention uses is n-butyl alcohol.
The preparation method of this comparative example is same as in Example 1.
Compliance test result
Coating composition embodiment 1-4 and comparative example 1-2 prepared, uses tobacco bale to aluminize transfer coated mold pressing heatproof
Testing standard (pressure is 130KPa, and the testing time is 4s) measures.Result is as follows:
| Embodiment | Heatproof test DEG C |
| Embodiment 1 | 150 |
| Embodiment 2 | 145 |
| Embodiment 3 | 155 |
| Embodiment 4 | 160 |
| Comparative example 1 | 120 |
| Comparative example 2 | 130 |
In sum, coating composition prepared by the present invention is by adding appropriate modified silicone resin, and die pressing is tested
Resistance to temperature value is compared the coating heatproof not added and is obviously improved 10-30 DEG C, and this addition will not cause consistency problem；This method
The high-temperature-resistant silicon resin solvent introduced is deionized water, safety non-toxic；The fire resistant resin that the present invention uses is widely used in fibre
Dimension, rubber and coating industry, have stable supply guarantee；The present invention, according to the heatproof requirement of different coating, can design addition not
Commensurability fire resistant resin, reaches heatproof requirement.
The concrete application approach of the present invention is a lot, and the above is only the preferred embodiment of the present invention.It should be pointed out that, above
Embodiment is merely to illustrate the present invention, and is not limited to protection scope of the present invention.Common skill for the art
For art personnel, under the premise without departing from the principles of the invention, it is also possible to make some improvement, these improvement also should be regarded as this
Bright protection domain.
Claims (10)
1. a fire resistant water-based aluminizing transfer paint compositions, it is characterised in that described coating composition includes following weight
Each component of number:
Fire resistant water-based aluminizing transfer paint compositions the most according to claim 1, it is characterised in that described water-base resin
Gather including aqueous acrylic emulsion, aqueous polyurethane emulsion, acrylic acid modified polyaminoester emulsion, water-dispersible nitrocotton, aqueous
The combination of one or more in vinyl alcohol emulsion.
Fire resistant water-based aluminizing transfer paint compositions the most according to claim 2, it is characterised in that described water-base resin
In, solid content is 20-40wt%.
Fire resistant water-based aluminizing transfer paint compositions the most according to claim 1, it is characterised in that described high temperature resistant silicon
Resin is the aqueous solution of organically-modified silicones.
Fire resistant water-based aluminizing transfer paint compositions the most according to claim 4, it is characterised in that described organically-modified
Silicones aqueous solution in, organically-modified silicones solid content is 30-40wt%.
6. according to the fire resistant water-based aluminizing transfer paint compositions described in claim 4 or 5, it is characterised in that described organic
Modified silicones includes one or more in methyl phenyl silicone resin, epoxide modified silicones, organic silicon polyurethane resin.
Fire resistant water-based aluminizing transfer paint compositions the most according to claim 1, it is characterised in that described cosolvent
Including at least one in isopropanol, ethanol.
Fire resistant water-based aluminizing transfer paint compositions the most according to claim 1, it is characterised in that described wetting agent
Including dodecylbenzene sodium sulfonate.
Fire resistant water-based aluminizing transfer paint compositions the most according to claim 1, it is characterised in that described levelling agent
Including Siloxane-Oxyalkylene Copolymers；Described defoamer includes modified organic silicon emulsion.
10. a preparation method for the fire resistant water-based aluminizing transfer paint compositions described in any one of claim 1-9, it is special
Levy and be, said method comprising the steps of:
A1, weigh each component according to weight/mass percentage composition；
A2, water-base resin and high-temperature-resistant silicon resin are placed in reactor, stirring at low speed；
A3, in reactor, add cosolvent and deionized water, stirring at low speed；
A4, in reactor, it is sequentially added into wetting agent, levelling agent and defoamer, high-speed stirred, then through filtering, obtain described coating
Compositions.
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Cited By (6)
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| CN106752822A (en) * | 2016-12-13 | 2017-05-31 | 西安大天新材料有限公司 | A kind of aqueous high-temperature-resistant matt transferring aluminum-plating paint and preparation method thereof |
| CN110256919A (en) * | 2019-05-28 | 2019-09-20 | 广东梵竹水性涂料有限公司 | A kind of fire resistant water-based transfer coatings and preparation method thereof |
| CN110305577A (en) * | 2019-06-12 | 2019-10-08 | 黄琳 | A kind of preparation method of folding aqueous transfer coating |
| CN111087879A (en) * | 2019-12-31 | 2020-05-01 | 彭磊 | Graphene paint preparation process |
| CN113480903A (en) * | 2021-07-15 | 2021-10-08 | 云南恩典科技产业发展有限公司 | High-temperature-resistant water-based transfer coating and preparation method thereof |
| CN114656868A (en) * | 2020-12-23 | 2022-06-24 | 汕头市紫光光电科技有限公司 | Waterborne polyurethane high-temperature transfer resistant coating and preparation process thereof |
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| CN101768398A (en) * | 2009-12-16 | 2010-07-07 | 上海维凯化学品有限公司 | Water-based temperature resistant single-coating transfer laser aluminizing paint and preparation method thereof |
| CN103555180A (en) * | 2013-11-19 | 2014-02-05 | 三友（天津）高分子技术有限公司 | Water-based laser transfer coating for wine bottle glass baking paper, and preparation method thereof |
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| CN106752822A (en) * | 2016-12-13 | 2017-05-31 | 西安大天新材料有限公司 | A kind of aqueous high-temperature-resistant matt transferring aluminum-plating paint and preparation method thereof |
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| CN110305577A (en) * | 2019-06-12 | 2019-10-08 | 黄琳 | A kind of preparation method of folding aqueous transfer coating |
| CN111087879A (en) * | 2019-12-31 | 2020-05-01 | 彭磊 | Graphene paint preparation process |
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