CN103923516B - The semi-transparent grey plasticising ink of silk screen printing - Google Patents
The semi-transparent grey plasticising ink of silk screen printing Download PDFInfo
- Publication number
- CN103923516B CN103923516B CN201410181726.XA CN201410181726A CN103923516B CN 103923516 B CN103923516 B CN 103923516B CN 201410181726 A CN201410181726 A CN 201410181726A CN 103923516 B CN103923516 B CN 103923516B
- Authority
- CN
- China
- Prior art keywords
- weight parts
- ink
- semi
- plasticising
- mixed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000007650 screen-printing Methods 0.000 title claims abstract description 10
- 239000011347 resin Substances 0.000 claims abstract description 15
- 229920005989 resin Polymers 0.000 claims abstract description 15
- 239000012046 mixed solvent Substances 0.000 claims abstract description 13
- 229920000083 poly(allylamine) Polymers 0.000 claims abstract description 9
- DOOTYTYQINUNNV-UHFFFAOYSA-N Triethyl citrate Chemical compound CCOC(=O)CC(O)(C(=O)OCC)CC(=O)OCC DOOTYTYQINUNNV-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000049 pigment Substances 0.000 claims abstract description 8
- VMYFZRTXGLUXMZ-UHFFFAOYSA-N triethyl citrate Natural products CCOC(=O)C(O)(C(=O)OCC)C(=O)OCC VMYFZRTXGLUXMZ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 235000013769 triethyl citrate Nutrition 0.000 claims abstract description 8
- 239000001069 triethyl citrate Substances 0.000 claims abstract description 8
- 239000002253 acid Substances 0.000 claims abstract description 7
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000012463 white pigment Substances 0.000 claims abstract description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 17
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims description 12
- 239000011259 mixed solution Substances 0.000 claims description 12
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 6
- 239000006185 dispersion Substances 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 3
- 239000004576 sand Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 abstract description 8
- 239000011521 glass Substances 0.000 abstract description 5
- 229920003229 poly(methyl methacrylate) Polymers 0.000 abstract description 5
- 239000004926 polymethyl methacrylate Substances 0.000 abstract description 5
- 239000004800 polyvinyl chloride Substances 0.000 abstract description 5
- 150000002148 esters Chemical class 0.000 abstract description 3
- 229920000915 polyvinyl chloride Polymers 0.000 abstract description 3
- 239000004014 plasticizer Substances 0.000 abstract description 2
- 238000004321 preservation Methods 0.000 abstract description 2
- 230000000052 comparative effect Effects 0.000 description 11
- 229920001944 Plastisol Polymers 0.000 description 7
- 239000004999 plastisol Substances 0.000 description 7
- 239000000523 sample Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 238000007639 printing Methods 0.000 description 5
- 239000000654 additive Substances 0.000 description 4
- 230000000996 additive effect Effects 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 239000002390 adhesive tape Substances 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 238000005282 brightening Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 239000013530 defoamer Substances 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 210000000795 conjunctiva Anatomy 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000009998 heat setting Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The present invention relates to the semi-transparent grey plasticising ink of a kind of silk screen printing, described ink contains the Seiko 1000-800 gloss oil of 28.0 ~ 32.0 weight parts, the black pigment of 1.3 ~ 1.5 weight parts, the white pigment of 8.5 ~ 8.7 weight parts, the organosilicon modified crylic acid resin of 25.0 ~ 28.0 weight parts, the glycidyl methacrylate of 15.0 ~ 25.0 weight parts, the triethyl citrate of 8.0 ~ 10.0 weight parts, the polyallylamine of 2.0 ~ 2.5 weight parts, the mixed solvent of 50 ~ 60 weight parts.In ink of the present invention, not containing phthalic ester and polyvinyl chloride resin plasticiser; But its flowing property is suitable with prior art, there is good preservation stability, and excellent to the tack of glass or PMMA base material.
Description
Technical field
The invention belongs to the technical field of printing-ink, in particular, the present invention relates to the semi-transparent grey plasticising ink of a kind of silk screen printing.
Background technology
Ink is the important materials for wrapping material printing, and pattern, the present stock curing ink of literal table are comprised main component and ancillary component by printing by it, and they mix equably and form the gluey fluid of a kind of viscosity through repeat-rolling.Printing-ink is by the pulpous state colloid of colorant, low-melting ink vehicle and the homogenize material such as auxiliary agent and solvent dispersing and mixing.The binder of solvent type ink is made up of solid resin and a large amount of volatile organic solvent.Solid resin is dissolved in after in solvent, is dispersed in by colorant in binder, and ink is printed to printed medium, the rapid volatile dry conjunctiva of solvent.
For ink, general expectation uses the aesthetic effect and the permanent printing characteristic kept that can produce on printed medium and show pleasant simultaneously.The example of these printing characteristics comprises press quality, as optical density (OD), colourity etc.; And weather resistance, as water tolerance, fade resistance, persistence, acidproof and alkaline-resisting etc.Plastisol ink composite is often referred to as plastisol ink, because the mode applied utilizes plastisol fluid properties before heating, causes the base resin in plastisol to be solidified into solid by baking or thermofixation.In prior art, most plastisol is dispersed in the softening agent based on phthalic ester and is occurred in the composition of swelling polyvinyl chloride (PVC) RESINS by it.Polyvinyl chloride (PVC) RESINS plastisol ink is widely used for screen printing operation.But due to the consideration of environment, health and safety, the use of these ink is subject to strict restriction just day by day.Therefore, under the prerequisite ensureing ink quality, develop performance identical with PVC plastisol, and the ink with less health and environmental risk and high tack becomes the R&D direction of those skilled in the art.
Summary of the invention
In order to solve above-mentioned technical problem of the prior art, the object of the present invention is to provide the semi-transparent grey plasticising ink of a kind of silk screen printing.
In order to realize foregoing invention object, present invention employs following technical scheme:
The semi-transparent grey plasticising ink of silk screen printing of the present invention, it is characterized in that: described ink contains the Seiko 1000-800 gloss oil of 28.0 ~ 32.0 weight parts, the black pigment of 1.3 ~ 1.5 weight parts, the white pigment of 8.5 ~ 8.7 weight parts, the organosilicon modified crylic acid resin of 25.0 ~ 28.0 weight parts, the glycidyl methacrylate of 15.0 ~ 25.0 weight parts, the triethyl citrate of 8.0 ~ 10.0 weight parts, the polyallylamine of 2.0 ~ 2.5 weight parts, the mixed solvent of 50 ~ 60 weight parts.
Wherein, the number-average molecular weight of described polyallylamine is 1000 ~ 3000.
Wherein, described mixed solvent is made up of propyl carbinol, n-butyl acetate and acetone; And described propyl carbinol is 25 ~ 30 weight parts, n-butyl acetate is 12 ~ 15 weight parts, and acetone is 13 ~ 15 weight parts.
Wherein, described plasticising ink also comprises additive.And as preferably, described additive is selected from least one in wetting agent, brightening agent, oxidation inhibitor, stablizer or defoamer.
Wherein, the viscosity of described plasticising ink is about 20,000 ~ 200,000 centipoises.
Wherein, described plasticising ink adopts the preparation method comprised the following steps to obtain:
(1) by the glycidyl methacrylate of 15.0 ~ 25.0 weight parts, the mixed solvent of 10.0 ~ 15.0 weight parts fully mixes with alr mode and dissolves, obtained dispersion soln;
(2) by the black pigment of 1.3 ~ 1.5 weight parts, the dispersion soln that the white pigment of 8.5 ~ 8.7 weight parts and step (1) prepare, fully mixes with alr mode and soaks, obtained first mixed solution;
(3) by the organosilicon modified crylic acid resin of 25.0 ~ 28.0 weight parts, the mixed solvent of 40.0 ~ 45.0 weight parts fully mixes with alr mode and dissolves, obtained second mixed solution;
(4) the Seiko 1000-800 gloss oil of the first mixed solution step (2) obtained, the second mixed solution that step (3) obtains, 28.0 ~ 32.0 weight parts, the triethyl citrate of 8.0 ~ 10.0 weight parts and the polyallylamine of 2.0 ~ 2.5 weight parts are fully mixed to get mixed liquor with alr mode;
(5) mixed liquor that step (4) obtained adopts sand mill to grind, and obtains the ink that fineness is less than 5 μm.
Compared with prior art, semi-transparent grey plasticising ink of the present invention has following beneficial effect:
(1) in ink of the present invention, not containing phthalic ester and polyvinyl chloride resin plasticiser; But its flowing property is suitable with prior art, there is good preservation stability, and excellent to the tack of glass or PMMA base material.
(2) adopt dispersing method of the present invention, the surface tension of pigment and interlaminar resin can be reduced, improve their wettability, the grinding effect of ink can be strengthened, reduce jitter time, and make described ink have good brightness effect, and suitable viscosity.
Embodiment
Below with reference to specific embodiment, semi-transparent grey plasticising ink of the present invention and preparation method thereof is described further, has more complete, accurate and deep understanding to help those skilled in the art to inventive concept of the present invention, technical scheme.What applicant needed to declare is the description of related materials in embodiment, performance and technique etc. is all exemplary, and does not refer to the restriction to invention protection domain.
Semi-transparent grey plasticising ink of the present invention, Seiko 1000-800 gloss oil containing 28.0 ~ 32.0 weight parts, the black pigment of 1.3 ~ 1.5 weight parts, the white pigment of 8.5 ~ 8.7 weight parts, the organosilicon modified crylic acid resin of 25.0 ~ 28.0 weight parts, the glycidyl methacrylate of 15.0 ~ 25.0 weight parts, the triethyl citrate of 8.0 ~ 10.0 weight parts, the mixed solvent of 50 ~ 60 weight parts; Wherein, described mixed solvent is made up of propyl carbinol, n-butyl acetate and acetone; And described propyl carbinol is 25 ~ 30 weight parts, n-butyl acetate is 12 ~ 15 weight parts, and acetone is 13 ~ 15 weight parts.Described plasticising ink as required, also comprises additive, and described additive is selected from least one in wetting agent, brightening agent, antioxidant, stablizer or defoamer.
Following embodiment adopts the method comprised the following steps to obtain, and difference is only that the content of component is different:
(1) by the glycidyl methacrylate of 15.0 ~ 25.0 weight parts, the mixed solvent of 10.0 ~ 15.0 weight parts fully mixes with alr mode and dissolves, obtained dispersion soln;
(2) by the black pigment of 1.3 ~ 1.5 weight parts, the dispersion soln that the white pigment of 8.5 ~ 8.7 weight parts and step (1) prepare, fully mixes with alr mode and soaks, obtained first mixed solution;
(3) by the organosilicon modified crylic acid resin of 25.0 ~ 28.0 weight parts, the mixed solvent of 40.0 ~ 45.0 weight parts fully mixes with alr mode and dissolves, obtained second mixed solution;
(4) the Seiko 1000-800 gloss oil of the first mixed solution step (2) obtained, the second mixed solution that step (3) obtains, 28.0 ~ 32.0 weight parts, the triethyl citrate of 8.0 ~ 10.0 weight parts and the polyallylamine of 2.0 ~ 2.5 weight parts are fully mixed to get mixed liquor with alr mode;
(5) mixed liquor that step (4) obtained adopts sand mill to grind, and obtains the ink that fineness is less than 5 μm.
In step (4), employ different fluidizers in comparative example 1 and 2, and all do not add polyallylamine.In comparative example 3, in step (4), employ dibutyl phthalate instead of triethyl citrate.
Embodiment 1
Semi-transparent grey plasticising ink described in the present embodiment, the viscosity of described ink is about 80,000 ~ 150,000 centipoises, and it contains the component of following parts by weight:
Embodiment 2
Semi-transparent grey plasticising ink described in the present embodiment, the viscosity of described ink is about 30,000 ~ 50,000 centipoises, and it contains the component of following parts by weight:
Comparative example 1
Semi-transparent grey plasticising ink described in the present embodiment, the viscosity of described ink is about 50,000 ~ 100,000 centipoises, and it contains following heavy
Comparative example 2
Described semi-transparent grey plasticising ink, it contains the component of following parts by weight:
Comparative example 3
Described semi-transparent grey plasticising ink, it contains the component of following parts by weight:
Conventional method for printing screen is adopted to be printed on glass and PMMA base material by the ink described in embodiment 1 ~ 2 and comparative example 1 ~ 3; Then at the temperature of 120 ± 1 DEG C, first baking is carried out; Then at the temperature of 150 ± 1 DEG C, second baking is carried out; After ink complete drying, adopt following methods to carry out tack experiment.Silk screen printing rete (base material is respectively glass and PMMA) after adopting the wide 3M adhesive tape (3MScotchTMTape) of 20mm to paste oven dry, takes off with minimum angles, the attached power of described ink is divided into 0 ~ 6 grade.Wherein 0 grade is greater than 95% for the layer of ink be attached on adhesive tape, 1 grade is 50 ~ 95%, 2 grades be 30 ~ 50%, 3 grades be 20 ~ 30%, 4 grades to be 10 ~ 20%, 5 grades be 2 ~ 10%, 6 grades for being less than 2%.Test result is as shown in table 1.
Table 1 sticking power grade
| Embodiment 1 | Embodiment 2 | Comparative example 1 | Comparative example 2 | Comparative example 3 | |
| Glass | 6 | 6 | 5 | 5 | 4 |
| PMMA | 6 | 6 | 5 | 5 | 4 |
The each 20g of ink sample of Example 1-2 and comparative example 1-3 is placed in the thermostat container of 40 DEG C, detects ink sample stability in storage at elevated temperatures; Utilized probe to detect sample at interval of 12 hours, the time of silk screen printing cannot be carried out to determine sample to become enough thick, characterize the time of stability in storage.Result shows: the ink sample storage stability at an elevated temperature of embodiment of the present invention can reach 30-40 days, suitable with comparative example.
In the present invention; for the ordinary skill in the art described; specific embodiment is just to invention has been exemplary description; obvious specific implementation of the present invention is not subject to the restrictions described above; as long as have employed the improvement of the various unsubstantialities that method of the present invention is conceived and technical scheme is carried out; or design of the present invention and technical scheme directly applied to other occasion, all within protection scope of the present invention without to improve.
Claims (4)
1. the semi-transparent grey plasticising ink of silk screen printing, it is characterized in that: described ink contains the Seiko 1000-800 gloss oil of 28.0 ~ 32.0 weight parts, the black pigment of 1.3 ~ 1.5 weight parts, the white pigment of 8.5 ~ 8.7 weight parts, the organosilicon modified crylic acid resin of 25.0 ~ 28.0 weight parts, the glycidyl methacrylate of 15.0 ~ 25.0 weight parts, the triethyl citrate of 8.0 ~ 10.0 weight parts, the polyallylamine of 2.0 ~ 2.5 weight parts, the mixed solvent of 50 ~ 60 weight parts; Described plasticising ink adopts the preparation method comprised the following steps to obtain:
(1) by the glycidyl methacrylate of 15.0 ~ 25.0 weight parts, the mixed solvent of 10.0 ~ 15.0 weight parts fully mixes with alr mode and dissolves, obtained dispersion soln;
(2) by the black pigment of 1.3 ~ 1.5 weight parts, the dispersion soln that the white pigment of 8.5 ~ 8.7 weight parts and step (1) prepare, fully mixes with alr mode and soaks, obtained first mixed solution;
(3) by the organosilicon modified crylic acid resin of 25.0 ~ 28.0 weight parts, the mixed solvent of 40.0 ~ 45.0 weight parts fully mixes with alr mode and dissolves, obtained second mixed solution;
(4) the Seiko 1000-800 gloss oil of the first mixed solution step (2) obtained, the second mixed solution that step (3) obtains, 28.0 ~ 32.0 weight parts, the triethyl citrate of 8.0 ~ 10.0 weight parts and the polyallylamine of 2.0 ~ 2.5 weight parts are fully mixed to get mixed liquor with alr mode;
(5) mixed liquor that step (4) obtained adopts sand mill to grind, and obtains the ink that fineness is less than 5 μm.
2. semi-transparent grey plasticising ink according to claim 1, is characterized in that: the number-average molecular weight of described polyallylamine is 1000 ~ 3000.
3. semi-transparent grey plasticising ink according to claim 1, is characterized in that: described mixed solvent is made up of propyl carbinol, n-butyl acetate and acetone; And described propyl carbinol is 25 ~ 30 weight parts, n-butyl acetate is 12 ~ 15 weight parts, and acetone is 13 ~ 15 weight parts.
4. semi-transparent grey plasticising ink according to claim 1, is characterized in that: the viscosity of described plasticising ink is 20,000 ~ 200,000 centipoises.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410181726.XA CN103923516B (en) | 2014-04-30 | 2014-04-30 | The semi-transparent grey plasticising ink of silk screen printing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410181726.XA CN103923516B (en) | 2014-04-30 | 2014-04-30 | The semi-transparent grey plasticising ink of silk screen printing |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103923516A CN103923516A (en) | 2014-07-16 |
| CN103923516B true CN103923516B (en) | 2015-08-26 |
Family
ID=51141923
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410181726.XA Expired - Fee Related CN103923516B (en) | 2014-04-30 | 2014-04-30 | The semi-transparent grey plasticising ink of silk screen printing |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103923516B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106497231A (en) * | 2016-10-31 | 2017-03-15 | 秦晴晴 | A kind of temperature sensitive ink for containing 1,2 biphenoxyl ethanes and preparation method thereof |
| EP3916060A1 (en) * | 2020-05-29 | 2021-12-01 | Dover Europe Sàrl | Opaque grey ink jet ink composition |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5254632B2 (en) * | 2008-02-07 | 2013-08-07 | 富士フイルム株式会社 | Ink composition, inkjet recording method, printed matter, and molded printed matter |
| CN101760073B (en) * | 2010-01-29 | 2013-05-15 | 蓝思科技股份有限公司 | Colored translucent printing ink |
| CN102863849A (en) * | 2012-09-29 | 2013-01-09 | 苏州安洁科技股份有限公司 | IR (infrared) purple ink |
| CN103013225B (en) * | 2012-12-25 | 2014-12-17 | 广州慧谷工程材料有限公司 | IML gloss oil and IML printing ink and preparation method and application thereof |
| CN103666098A (en) * | 2013-12-05 | 2014-03-26 | 湖南互力达涂料科技有限公司 | Aqueous UV gravure varnish |
-
2014
- 2014-04-30 CN CN201410181726.XA patent/CN103923516B/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN103923516A (en) | 2014-07-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105419475B (en) | It is a kind of to exempt from gluing thermal transfer ink with release function | |
| CN102408826B (en) | American type water-based coating finish paint and preparation method thereof | |
| CN103602143A (en) | Transfer printing ink with release function | |
| CN103911037B (en) | The mute black ink of silk screen printing | |
| CN110229574A (en) | Aqueous flash of light colored paint of one kind and preparation method thereof | |
| CN103911036B (en) | Silk screen printing bright black ink | |
| CN103923516B (en) | The semi-transparent grey plasticising ink of silk screen printing | |
| CN103254686A (en) | High-covering property glass lens ink and preparation method thereof | |
| CN103923526B (en) | Semi-transparent grey environment-friendly ink | |
| CN103923525B (en) | The silk screen printing preparation method of bright black ink | |
| CN106700727A (en) | Gluing-free thermal transfer printing ink with release function | |
| CN103589226B (en) | High-adhesion pearized silver printing ink and preparation method thereof | |
| CN101490185B (en) | Crayon | |
| CN104804521A (en) | Toning process of ink for environment-friendly water-based paint | |
| CN103923521B (en) | The preparation method of semi-transparent grey environment-friendly ink | |
| CN103911035B (en) | Mute black environmental protection plasticising ink | |
| CN103923517B (en) | The preparation method of mute black plasticising ink | |
| CN103923518B (en) | Bright black plasticising ink | |
| CN103589228B (en) | High-adhesion, high-brilliant-silver and environment-friendly printing ink and preparation method thereof | |
| CN114196255B (en) | Water-based polyurethane ink for gravure printing | |
| CN103952033B (en) | A kind of general ink and preparation method thereof and using method | |
| CN104817885A (en) | Silver gray environment-friendly ink for screen printing | |
| CN104946005A (en) | Gray sparkle silver printing ink | |
| CN103589229B (en) | Brilliant black environment-friendly printing ink and preparation method thereof | |
| CN104927480A (en) | Preparation method of grey flash silver ink |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150826 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |