CN103254686A - High-covering property glass lens ink and preparation method thereof - Google Patents
High-covering property glass lens ink and preparation method thereof Download PDFInfo
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- CN103254686A CN103254686A CN2013101549469A CN201310154946A CN103254686A CN 103254686 A CN103254686 A CN 103254686A CN 2013101549469 A CN2013101549469 A CN 2013101549469A CN 201310154946 A CN201310154946 A CN 201310154946A CN 103254686 A CN103254686 A CN 103254686A
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- printing ink
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Abstract
The invention discloses high-covering property glass lens ink and a preparation method thereof. The high-covering property glass lens ink comprises components A and B, wherein the component A comprises the following ingredients in percentage by weight: 60-75% of epoxy resin solution, 0.1-3% of dispersing agent, 1-38.7% of toner, 0.1-5% of defoaming agent and 0.1-6% of filler; the viscosity of the component A is 10000-20000cps at the room temperature of 20 DEG C; and the component B is a curing agent and accounts for 10-20% of the weight of the component A. The two-component high-covering property glass lens ink formed by mixing the component A(the ink) and the component B (the curing agent) is capable of effectively solving the problems existing when conventional glass lens ink is printed on the toughened glass lenses, good in printing effect, easy in achieving high covering and high resistance value properties, excellent in adhesive force to the glass lenses and good in solvent resistance.
Description
Technical field
The present invention relates to printing ink, relate in particular to high covering glass eyeglass printing ink of a kind of compliance with environmental protection requirements and preparation method thereof.
Background technology
Mobile phone, navigating instrument, LCD TV etc. relate in the industry of chilled glass eyeglass, need to use specific glass mirror printing ink, the glass mirror printing ink of prior art is when the segment glass eyeglass prints, exist printing effect undesirable, the shortcoming that opacifying power is low, do not reach the performance of high covering and high resistance at glass mirror, OD(optical density particularly, when optical density(OD)) value is lower than 4, must improve the OD value by the pass that increases ink printing, but increase the increase that the ink printing pass can cause the fraction defective of product, can not satisfy the requirement of production capacity.
Therefore, prior art has yet to be improved and developed.
Summary of the invention
The technical problem to be solved in the present invention is, above-mentioned defective at prior art, a kind of high covering glass eyeglass printing ink and preparation method thereof is provided, is intended to solve traditional glass eyeglass printing ink and when the segment glass eyeglass prints, has the low and low problem of resistance value of opacifying power.
The technical scheme that technical solution problem of the present invention adopts is as follows:
A kind of high covering glass eyeglass printing ink, wherein, described high covering glass eyeglass printing ink comprises component A and B component;
By weight percentage, described component A comprises following component:
Resins, epoxy liquid 60-75;
Dispersion agent 0.1-3;
Toner 1-38.7;
Defoamer 0.1-5;
Filler 0.1-6;
Described B component is solidifying agent, accounts for the 10-20% of component A weight.
Described high covering glass eyeglass printing ink, wherein, by weight percentage, described component A comprises following component:
Resins, epoxy liquid 60.5;
Dispersion agent 0.5;
Toner 32;
Defoamer 1;
Filler 6.
Described high covering glass eyeglass printing ink, wherein, the solids content of described Resins, epoxy liquid is equal to or greater than 50%.
Described high covering glass eyeglass printing ink, wherein, described defoamer is silicone antifoam agent.
Described high covering glass eyeglass printing ink, wherein, described filler is nano-calcium carbonate.
Described high covering glass eyeglass printing ink, wherein, described toner is the pigment of halogen-containing organic or inorganic not.
Described high covering glass eyeglass printing ink, wherein, described dispersion agent is the amino acid ester copolymer solution.
Described high covering glass eyeglass printing ink, wherein, described solidifying agent is the aliphatic cyclic amine solidifying agent.
A kind of preparation method of described high covering glass eyeglass printing ink wherein, comprises step:
Extracting epoxy resin liquid adds dispersion agent, filler and toner, and stirs with 600 rpms rotating speed;
Grind and disperse;
Add defoamer, stir with 1200 rpms rotating speed then.
A kind of high covering glass eyeglass printing ink provided by the present invention and preparation method thereof, its beneficial effect is: effectively overcome the low and low problem of resistance value of existing glass mirror printing ink existing opacifying power when segment glass eyeglasses such as chilled glass eyeglass print.High covering glass eyeglass printing ink compliance with environmental protection requirements of the present invention, and its sticking power on glass mirror is good, has opacifying property height, and the characteristics that resistance value is big, the patience of each side are all quite excellent.Owing to need not repeatedly to print the OD value that just can reach higher, also improved yield and the working (machining) efficiency of product simultaneously.
Embodiment
A kind of high covering glass eyeglass printing ink provided by the invention and preparation method thereof, clearer, clear and definite for making purpose of the present invention, technical scheme and advantage, the present invention is described in more detail by the following examples.Should be appreciated that specific embodiment described herein only in order to explaining the present invention, and be not used in restriction the present invention.
In order to make printing ink when glass mirror prints, have opacifying property height, resistance value is big, need not repeatedly to print the characteristics of the OD value that just can reach higher, the invention provides a kind of high covering glass eyeglass printing ink, described high covering glass eyeglass printing ink comprises component A and B component;
By weight percentage, described component A comprises following component:
Resins, epoxy liquid 60-75;
Dispersion agent 0.1-3;
Toner 1-38.7;
Defoamer 0.1-5;
Filler 0.1-6;
Described B component is solidifying agent, accounts for the 10-20% of component A weight.
Wherein, described component A according to weight percent meter, is preferably and composed of the following componentsly is:
Resins, epoxy liquid 60.5;
Dispersion agent 0.5;
Toner 32;
Defoamer 1;
Filler 6.
Preferable, the solids content of described Resins, epoxy liquid is equal to or greater than 50%.Solvent for use is different Fu Er ketone in the described Resins, epoxy liquid.
Preferable, described defoamer is silicone antifoam agent, its effect is to reduce the bubble that produces in manufacturing and the use.
Preferable, described dispersion agent is the amino acid ester copolymer solution, its effect is evenly to disperse those solid particulates that is difficult to be dissolved in liquid, also can prevent sedimentation and the cohesion of solid particulate simultaneously.
Preferable, described filler is nano-calcium carbonate, it has extremely excellent printing performance, the sliding sense in excellent surface and anti scuffing performance.Will acting on of filler is the printing performance that increases printing ink.
Preferable, described toner is the pigment of halogen-containing organic or inorganic not, and described toner also makes printing ink have good opacifying power at glass mirror except the colour developing effect.The performances such as photostabilization, thermotolerance, solvent resistance, resistance to chemical reagents of printing ink are promoted.
Preferable, described solidifying agent is the aliphatic cyclic amine solidifying agent, its effect is solvent resistance and the scratch-resistant performance that improves the China ink layer.
Further, in the specific embodiment of the invention, the preparation method of described component A comprises step:
Extracting epoxy resin liquid adds dispersion agent, filler and toner, and stirs with 600 rpms rotating speed;
Grind and disperse;
Add defoamer, stir with 1200 rpms rotating speed then.
By following examples 1-3 the component A of high covering glass eyeglass printing ink of the present invention is described in further detail.
Embodiment 1:
The component A of a kind of high covering glass eyeglass printing ink of the present invention by weight percentage, comprises following component:
Resins, epoxy liquid 60.5;
Dispersion agent 0.5;
Toner 32;
Defoamer 1;
Filler 6.
Accordingly, its preparation method is:
60.5 parts of extracting epoxy resin liquid (weight), add dispersion agent 0.5 part of (weight), filler 6 parts of (weight) and 32 parts of toner carbon blacks (weight), 600 rpms rotating speed stirring at low speed 15 minutes, cross three-roller six times after stirring, add 1 part of (weight) defoamer again, stirred 20 minutes with 1200 rpms rotating speed then, get product after being uniformly dispersed.
Embodiment 2:
The component A of a kind of high covering glass eyeglass printing ink of the present invention by weight percentage, comprises following component:
Resins, epoxy liquid 65;
Dispersion agent 0.5;
Toner 30;
Defoamer 0.5;
Filler 4.
Accordingly, its preparation method is:
65 parts of extracting epoxy resin liquid (weight), add dispersion agent 0.5 part of (weight), filler 4 parts of (weight) and 30 parts of toner carbon blacks (weight), 600 rpms rotating speed stirring at low speed 15 minutes, cross three-roller six times after stirring, add 0.5 part of (weight) defoamer again, stirred 20 minutes with 1200 rpms rotating speed then, get product after being uniformly dispersed.
Embodiment 3:
The component A of a kind of high covering glass eyeglass printing ink of the present invention by weight percentage, comprises following component:
Resins, epoxy liquid 65;
Dispersion agent 0.5;
Toner 30;
Defoamer 1;
Filler 4.5.
Accordingly, its preparation method is:
65 parts of extracting epoxy resin liquid (weight), add dispersion agent 0.5 part of (weight), filler 4.5 parts of (weight) and 30 parts of toner carbon blacks (weight), 600 rpms rotating speed stirring at low speed 15 minutes, cross three-roller six times after stirring, add 1 part of (weight) defoamer again, stirred 20 minutes with 1200 rpms rotating speed then, get product after being uniformly dispersed.
The component A compliance with environmental protection requirements of the described high covering glass eyeglass printing ink that is obtained by above-described embodiment, they are under 20 ℃ of room temperatures, and its viscosity is 10000～30000cps, has opacifying property height, the characteristics that resistance value is big.
Component A by the above embodiment of the present invention obtains before the glass mirror printing, adds component B in described component A, described component B is solidifying agent, and the component B of adding accounts for the 10-20% of component A weight.Preferable, the B of component described in embodiment of the invention solidifying agent is the aliphatic cyclic amine solidifying agent, solid content is absolutely.The effect of described component B solidifying agent is solvent resistance and the scratch-resistant performance that improves the China ink layer.
Preferable, the component A of corresponding above-described embodiment 1-3 is described in further detail high covering glass eyeglass printing ink of the present invention by following examples 4-6.
Embodiment 4:
A kind of described high covering glass eyeglass printing ink, by the component A of above-described embodiment 1 gained, and component B aliphatic cyclic amine solidifying agent composition, wherein, the ratio of described component B is 10% of described component A weight.
Embodiment 5:
A kind of described high covering glass eyeglass printing ink, by the component A of above-described embodiment 2 gained, and component B aliphatic cyclic amine solidifying agent composition, wherein, the ratio of described component B is 20% of described component A weight.
Embodiment 6:
A kind of described high covering glass eyeglass printing ink, by the component A of above-described embodiment 3 gained, and component B aliphatic cyclic amine solidifying agent composition, wherein, the ratio of described component B is 20% of described component A weight.
Corresponding, the concrete preparation method of the described high covering glass eyeglass printing ink of above-described embodiment 4-6 is: get component A, add component B aliphatic cyclic amine solidifying agent.Can use after mixing.
The high covering glass eyeglass of two components printing ink with above-described embodiment 4-6 gained prints one time at glass mirror respectively, and its physics and chemistry China ink layer resistance value and OD value are referring to table 1.
Table 1
| ? | Resistance value (voltage=500 volt time) | The OD value |
| Embodiment 4 | ≥1GΩ | 4 |
| Embodiment 5 | +∞ | 4 |
| Embodiment 6 | ≥1GΩ | 4 |
In sum, a kind of high covering glass eyeglass printing ink that the above embodiment of the present invention provides and preparation method thereof, described high covering glass eyeglass printing ink comprises component A and B component; By weight percentage, described component A comprises following component: Resins, epoxy liquid 60-75, dispersion agent 0.1-3, toner 1-38.7, defoamer 0.1-5, filler 0.1-6, described component A are under 20 ℃ of room temperatures, and its viscosity is 10000～20000cps; Described B component is solidifying agent, accounts for the 10-20% of component A weight.By the high covering glass eyeglass of the two components printing ink that described component A and B component are mixed and made into, its sticking power on glass mirror is good, during 350-420 order printing-ink layer thickness≤6um, and OD value 〉=4; 500v voltage, 1cm distance, resistance value is greater than 1G Ω, and halogen is less than 1000ppm, and has solvent resistance preferably.And owing to contain appropriate amount of defoamer and filler, make it to have the superior printing characteristics energy, reach high easily and hide and the high resistance performance.Effectively overcome existing glass mirror printing ink existing problem when the chilled glass eyeglass prints, the patience of each side is all quite excellent.Owing to need not repeatedly to print the OD value that just can reach higher, also improved the yield of product simultaneously.
Should be understood that application of the present invention is not limited to above-mentioned giving an example, for those of ordinary skills, can be improved according to the above description or conversion that all these improvement and conversion all should belong to the protection domain of claims of the present invention.
Claims (9)
1. one kind high covering glass eyeglass printing ink is characterized in that, described high covering glass eyeglass printing ink comprises component A and B component;
By weight percentage, described component A comprises following component:
Resins, epoxy liquid 60-75;
Dispersion agent 0.1-3;
Toner 1-38.7;
Defoamer 0.1-5;
Filler 0.1-6;
Described B component is solidifying agent, accounts for the 10-20% of component A weight.
2. high covering glass eyeglass printing ink according to claim 1 is characterized in that by weight percentage, described component A comprises following component:
Resins, epoxy liquid 60.5;
Dispersion agent 0.5;
Toner 32;
Defoamer 1;
Filler 6.
3. high covering glass eyeglass printing ink according to claim 1 and 2 is characterized in that the solids content of described Resins, epoxy liquid is equal to or greater than 50%.
4. require 1 or 2 described high covering glass eyeglass printing ink according to aforesaid right, it is characterized in that described defoamer is silicone antifoam agent.
5. require 1 or 2 described high covering glass eyeglass printing ink according to aforesaid right, it is characterized in that described filler is nano-calcium carbonate.
6. require 1 or 2 described high covering glass eyeglass printing ink according to aforesaid right, it is characterized in that, described toner is the pigment of halogen-containing organic or inorganic not.
7. high covering glass eyeglass printing ink according to claim 1 and 2 is characterized in that described dispersion agent is the amino acid ester copolymer solution.
8. high covering glass eyeglass printing ink according to claim 1 and 2 is characterized in that described solidifying agent is the aliphatic cyclic amine solidifying agent.
9. the preparation method of a high covering glass eyeglass printing ink as claimed in claim 1 is characterized in that, comprises step:
Extracting epoxy resin liquid adds dispersion agent, filler and toner, and stirs with 600 rpms rotating speed;
Grind and disperse;
Add defoamer, stir with 1200 rpms rotating speed then.
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| CN201310154946.9A CN103254686B (en) | 2013-04-28 | 2013-04-28 | High-covering property glass lens ink and preparation method thereof |
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| CN201310154946.9A CN103254686B (en) | 2013-04-28 | 2013-04-28 | High-covering property glass lens ink and preparation method thereof |
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| CN103254686B CN103254686B (en) | 2014-09-10 |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105925067A (en) * | 2016-07-04 | 2016-09-07 | 湖北世安科技有限公司 | Color paste used for preparing whiteboard marker ink and preparation method thereof |
| CN106433300A (en) * | 2016-08-31 | 2017-02-22 | 金湖宇迪光学有限责任公司 | Mobile phone cover plate glass black ink formula |
| CN106883674A (en) * | 2017-04-21 | 2017-06-23 | 深圳市美丽华油墨涂料有限公司 | A kind of glass lens ink and preparation method thereof |
| CN108864812A (en) * | 2018-08-01 | 2018-11-23 | 佛山市高明绿色德化工有限公司 | A kind of doubling glass ink and preparation method thereof |
| CN110607093A (en) * | 2019-10-17 | 2019-12-24 | 嘉宝莉化工集团股份有限公司 | Solvent-free glass screen printing ink and preparation method thereof |
| CN113354978A (en) * | 2021-06-18 | 2021-09-07 | 重庆京东方电子科技有限公司 | Display device, ink composition and preparation method thereof, cover plate and preparation method thereof |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105925067A (en) * | 2016-07-04 | 2016-09-07 | 湖北世安科技有限公司 | Color paste used for preparing whiteboard marker ink and preparation method thereof |
| CN106433300A (en) * | 2016-08-31 | 2017-02-22 | 金湖宇迪光学有限责任公司 | Mobile phone cover plate glass black ink formula |
| CN106883674A (en) * | 2017-04-21 | 2017-06-23 | 深圳市美丽华油墨涂料有限公司 | A kind of glass lens ink and preparation method thereof |
| CN108864812A (en) * | 2018-08-01 | 2018-11-23 | 佛山市高明绿色德化工有限公司 | A kind of doubling glass ink and preparation method thereof |
| CN108864812B (en) * | 2018-08-01 | 2021-05-25 | 佛山市高明绿色德化工有限公司 | Laminated glass ink and preparation method thereof |
| CN110607093A (en) * | 2019-10-17 | 2019-12-24 | 嘉宝莉化工集团股份有限公司 | Solvent-free glass screen printing ink and preparation method thereof |
| CN110607093B (en) * | 2019-10-17 | 2022-04-12 | 广东嘉宝莉科技材料有限公司 | Solvent-free glass screen printing ink and preparation method thereof |
| CN113354978A (en) * | 2021-06-18 | 2021-09-07 | 重庆京东方电子科技有限公司 | Display device, ink composition and preparation method thereof, cover plate and preparation method thereof |
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| CN103254686B (en) | 2014-09-10 |
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Address after: Shenzhen, Guangdong, Baoan District province Fuyong street, Feng Tong Avenue and Yonghe Road intersection Patentee after: Shenzhen beautiful Polytron Technologies Inc Address before: 518103, Feng Tong Road 243, Fuyong Town, Shenzhen, Guangdong, Baoan District Patentee before: Shenzhen Meilihua Ink & Coating Co., Ltd. |
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