CN106433300A - Mobile phone cover plate glass black ink formula - Google Patents
Mobile phone cover plate glass black ink formula Download PDFInfo
- Publication number
- CN106433300A CN106433300A CN201610789029.1A CN201610789029A CN106433300A CN 106433300 A CN106433300 A CN 106433300A CN 201610789029 A CN201610789029 A CN 201610789029A CN 106433300 A CN106433300 A CN 106433300A
- Authority
- CN
- China
- Prior art keywords
- black ink
- hand
- ink formulations
- set lid
- lid glass
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000005357 flat glass Substances 0.000 title abstract description 5
- 239000002904 solvent Substances 0.000 claims abstract description 14
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 10
- 229920003180 amino resin Polymers 0.000 claims abstract description 7
- 239000006229 carbon black Substances 0.000 claims abstract description 7
- 239000000654 additive Substances 0.000 claims abstract description 5
- 230000000996 additive effect Effects 0.000 claims abstract description 5
- 239000002270 dispersing agent Substances 0.000 claims abstract description 5
- 239000011347 resin Substances 0.000 claims abstract description 5
- 229920005989 resin Polymers 0.000 claims abstract description 5
- 239000000203 mixture Substances 0.000 claims description 25
- 238000009472 formulation Methods 0.000 claims description 19
- 239000011521 glass Substances 0.000 claims description 17
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 8
- 239000004925 Acrylic resin Substances 0.000 claims description 7
- 229920000178 Acrylic resin Polymers 0.000 claims description 7
- 229920000570 polyether Polymers 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- PPQREHKVAOVYBT-UHFFFAOYSA-H dialuminum;tricarbonate Chemical compound [Al+3].[Al+3].[O-]C([O-])=O.[O-]C([O-])=O.[O-]C([O-])=O PPQREHKVAOVYBT-UHFFFAOYSA-H 0.000 claims description 6
- 229910052731 fluorine Inorganic materials 0.000 claims description 6
- 239000011737 fluorine Substances 0.000 claims description 6
- 239000013530 defoamer Substances 0.000 claims description 5
- -1 polyethylene Polymers 0.000 claims description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 4
- 235000012241 calcium silicate Nutrition 0.000 claims description 4
- 150000002148 esters Chemical group 0.000 claims description 4
- 239000000945 filler Substances 0.000 claims description 4
- 150000002576 ketones Chemical class 0.000 claims description 4
- 229910052710 silicon Inorganic materials 0.000 claims description 4
- 239000010703 silicon Substances 0.000 claims description 4
- 239000005995 Aluminium silicate Substances 0.000 claims description 3
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 claims description 3
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 3
- 235000012211 aluminium silicate Nutrition 0.000 claims description 3
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- 239000004698 Polyethylene Substances 0.000 claims 1
- CGZZMOTZOONQIA-UHFFFAOYSA-N cycloheptanone Chemical group O=C1CCCCCC1 CGZZMOTZOONQIA-UHFFFAOYSA-N 0.000 claims 1
- 125000001153 fluoro group Chemical group F* 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 229920000573 polyethylene Polymers 0.000 claims 1
- 239000002518 antifoaming agent Substances 0.000 abstract description 4
- 238000012856 packing Methods 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 6
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 5
- 239000004372 Polyvinyl alcohol Substances 0.000 description 5
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical group O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 5
- 229920002451 polyvinyl alcohol Polymers 0.000 description 5
- MWSKJDNQKGCKPA-UHFFFAOYSA-N 6-methyl-3a,4,5,7a-tetrahydro-2-benzofuran-1,3-dione Chemical group C1CC(C)=CC2C(=O)OC(=O)C12 MWSKJDNQKGCKPA-UHFFFAOYSA-N 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229910000502 Li-aluminosilicate Inorganic materials 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- 235000010216 calcium carbonate Nutrition 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/103—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds of aldehydes, e.g. phenol-formaldehyde resins
Abstract
The invention relates to a mobile phone cover plate glass black ink formula; with the total weight of the ink as a benchmark, the mobile phone cover plate glass black ink formula mainly includes the following components by the mass percentage: 20-55% of water-soluble resin, 3-15% of a solvent, 10-30% of waterborne amino resin, 1-2% of a dispersant, 0.5-2% of a defoaming agent, 0.5-2% of a leveling agent, 15-30% of carbon black, 5-10% of a packing, 5-10% of an additive, and 1-20% of a curing agent. The black ink prepared by the formula has the advantages of good adhesion power, uniform color, and good covering ability and chemical resistance.
Description
Technical field
The present invention relates to a kind of ink formulations are and in particular to a kind of hand-set lid glass black ink formulations.
Background technology
Abundant perfect, the smart mobile phone of black or flat board etc. with the electronic product color such as smart mobile phone, flat board, style
Become the new lover of user, become the object that most women pursue.But it is applied to the black of these products in the market
Color ink is opacifying property poor, and traditional method to meet preferable covering power using increasing print pass, and existing process typically prints 3
Secondary, or even can be only achieved more satisfactory covering power 4 times, so lead to complicated construction technique, ink film thickness management and control is difficult, defective products
Rate is higher.
In view of above-mentioned defect, the design people, actively research and innovation in addition is black to founding a kind of hand-set lid glass
Color ink formula is so as to more the value in industry.
Content of the invention
For solving above-mentioned technical problem, it is an object of the invention to provide a kind of hand-set lid glass black ink formulations.
Technical scheme is as follows：
A kind of hand-set lid glass black ink formulations, on the basis of the gross weight of described ink, it is mainly by following matter
The group of amount percentage composition is grouped into：
Water-soluble resin：20-55%；
Solvent：3-15%；
Water-compatible amino resin：10-30%；
Dispersant：1-2%；
Defoamer：0.5-2%；
Levelling agent：0.5-2%；
White carbon black：15%-30%；
Filler：5-10；
Additive：5%-10%；
Firming agent：1%-20%.
Further, described water-soluble resin is water soluble acrylic resin.
Further, described solvent is one of esters solvent or ketones solvent or two kinds.
Further, described filler is one or more of Calcium Carbonate, calcium silicates, aluminium silicate, aluminium carbonate.
Further, described dispersant is polyvinyl alcohol.
Further, described is Polyether Modified Polysiloxanes Defoaming Agent for defoamer.
Further, described levelling agent is the acrylate of fluorine richness.
Further, described additive is Ketohexamethylene.
Further, described firming agent is methyl tetrahydro phthalic anhydride.
By such scheme, the present invention at least has advantages below：
The black ink that inventive formulation makes has good adhesive force, and color even, has good covering energy
Power and endurance；Respectively being grouped of the black ink for cover-plate glass of the present invention point directly can be buied by commercial sources,
Material is easy to get, and preparation is simple, and safety and environmental protection.
Described above is only the general introduction of technical solution of the present invention, in order to better understand the technological means of the present invention,
And can be practiced according to the content of description, below with presently preferred embodiments of the present invention and coordinate detailed description as after.
Specific embodiment
With reference to embodiment, the specific embodiment of the present invention is described in further detail.Following examples are used for
The present invention is described, but is not limited to the scope of the present invention.
Embodiment 1
A kind of hand-set lid glass black ink formulations, on the basis of the gross weight of described ink, it is mainly by following matter
The group of amount percentage composition is grouped into：
Water soluble acrylic resin：20%；
Ketones solvent：15%；
Water-compatible amino resin：30%；
Polyvinyl alcohol：2%；
Organic silicon modified by polyether：2%；
The acrylate of fluorine richness：2%；
White carbon black：15%；
Calcium Carbonate, calcium silicates：6%；
Ketohexamethylene：7%；
Methyl tetrahydro phthalic anhydride：1%.
Embodiment 2
A kind of hand-set lid glass black ink formulations, on the basis of the gross weight of described ink, it is mainly by following matter
The group of amount percentage composition is grouped into：
Water soluble acrylic resin：55%；
Esters solvent：5%；
Water-compatible amino resin：10%；
Polyvinyl alcohol：2%；
Organic silicon modified by polyether：1%；
The acrylate of fluorine richness：1%；
White carbon black：15%；
Calcium Carbonate, calcium silicates 5%；
Ketohexamethylene：5%；
Methyl tetrahydro phthalic anhydride：1%.
Embodiment 3
A kind of hand-set lid glass black ink formulations, on the basis of the gross weight of described ink, it is mainly by following matter
The group of amount percentage composition is grouped into：
Water soluble acrylic resin：35%；
Esters solvent：15%；
Water-compatible amino resin：15%；
Polyvinyl alcohol：2%；
Organic silicon modified by polyether：1%；
The acrylate of fluorine richness：1%；
White carbon black：20%；
Aluminium silicate, aluminium carbonate：5%；
Ketohexamethylene：5%；
Methyl tetrahydro phthalic anhydride：1%.
The preparation method of the black ink of the present invention comprises the steps：
(1) add solvent under normal temperature and pressure, rotating speed is 300-500r/min, adds water-soluble acrylic tree while stirring
Fat, adjustment rotating speed is 3000-4000r/min, after stirring 120-180min, is filtrated to get water soluble acrylic resin's solution；
(2) under the rotating speed of 600-900r/min, in water soluble acrylic resin's solution of (1) gained, sequentially add ketone
Class solvent, water-compatible amino resin, polyvinyl alcohol, white carbon black, part Polyether Modified Polysiloxanes Defoaming Agent, lithium aluminium silicate, Ketohexamethylene, stirs
Mix uniformly；Then it is ground to less than 5 μm on three-roller, then add remaining Polyether Modified Polysiloxanes Defoaming Agent, methyl tetrahydrochysene
Phthalic anhydride and the acrylate of fluorine richness, then stir, get product.
The black ink that inventive formulation makes has good adhesive force, and color even, has good covering energy
Power and endurance；Respectively being grouped of the black ink for cover-plate glass of the present invention point directly can be buied by commercial sources,
Material is easy to get, and preparation is simple, and safety and environmental protection.
The above is only the preferred embodiment of the present invention, is not limited to the present invention it is noted that for this skill
For the those of ordinary skill in art field, on the premise of without departing from the technology of the present invention principle, can also make some improve and
Modification, these improve and modification also should be regarded as protection scope of the present invention.
Claims (9)
1. a kind of hand-set lid glass black ink formulations it is characterised in that：On the basis of the gross weight of described ink, including with
The component of lower weight/mass percentage composition：
Water-soluble resin：20-55%；
Solvent：3-15%；
Water-compatible amino resin：10-30%；
Dispersant：1-2%；
Defoamer：0.5-2%；
Levelling agent：0.5-2%；
White carbon black：15-30%；
Filler：5-10%；
Additive：5-10%；
Firming agent：1-20%.
2. according to claim 1 hand-set lid glass black ink formulations it is characterised in that：Described water-soluble resin is water
Soluble acrylic resin.
3. according to claim 1 hand-set lid glass black ink formulations it is characterised in that：Described solvent is esters solvent
Or one of ketones solvent or two kinds.
4. according to claim 1 hand-set lid glass black ink formulations it is characterised in that：Described filler be Calcium Carbonate,
One or more of calcium silicates, aluminium silicate, aluminium carbonate.
5. according to claim 1 hand-set lid glass black ink formulations it is characterised in that：Described dispersant is polyethylene
Alcohol.
6. according to claim 1 hand-set lid glass black ink formulations it is characterised in that：Described is polyethers for defoamer
Modified organic silicon defoamer.
7. according to claim 1 hand-set lid glass black ink formulations it is characterised in that：Described levelling agent is fluorine richness
Acrylate.
8. according to claim 1 hand-set lid glass black ink formulations it is characterised in that：Described additive is hexamethylene
Ketone.
9. according to claim 1 hand-set lid glass black ink formulations it is characterised in that：Described firming agent is methyl four
Hydrogen phthalic anhydride.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610789029.1A CN106433300A (en) | 2016-08-31 | 2016-08-31 | Mobile phone cover plate glass black ink formula |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610789029.1A CN106433300A (en) | 2016-08-31 | 2016-08-31 | Mobile phone cover plate glass black ink formula |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106433300A true CN106433300A (en) | 2017-02-22 |
Family
ID=58163742
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610789029.1A Pending CN106433300A (en) | 2016-08-31 | 2016-08-31 | Mobile phone cover plate glass black ink formula |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106433300A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106987174A (en) * | 2017-04-19 | 2017-07-28 | 广州大学 | A kind of water-soluble mobile phone faceplate glass protection ink |
| CN107556812A (en) * | 2017-09-27 | 2018-01-09 | 广东星弛光电科技有限公司 | A kind of hand-set lid glass black ink with covering and preparation method thereof |
| CN108944231A (en) * | 2017-05-19 | 2018-12-07 | 比亚迪股份有限公司 | The trailing and 3D ambetti of printing ink composition and 3D glass |
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|---|---|---|---|---|
| CN103160170A (en) * | 2011-12-13 | 2013-06-19 | 金甲化工企业(中山)有限公司 | Printing ink |
| CN103254686A (en) * | 2013-04-28 | 2013-08-21 | 深圳市美丽华油墨涂料有限公司 | High-covering property glass lens ink and preparation method thereof |
| CN103509406A (en) * | 2013-07-23 | 2014-01-15 | 王景泉 | Aqueous decorative ink for glass printing and preparation method thereof |
| CN103773108A (en) * | 2014-01-29 | 2014-05-07 | 苏州昭奇凯虹精细化工有限公司 | White ink for glass cover plates |
-
2016
- 2016-08-31 CN CN201610789029.1A patent/CN106433300A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103160170A (en) * | 2011-12-13 | 2013-06-19 | 金甲化工企业(中山)有限公司 | Printing ink |
| CN103254686A (en) * | 2013-04-28 | 2013-08-21 | 深圳市美丽华油墨涂料有限公司 | High-covering property glass lens ink and preparation method thereof |
| CN103509406A (en) * | 2013-07-23 | 2014-01-15 | 王景泉 | Aqueous decorative ink for glass printing and preparation method thereof |
| CN103773108A (en) * | 2014-01-29 | 2014-05-07 | 苏州昭奇凯虹精细化工有限公司 | White ink for glass cover plates |
Non-Patent Citations (1)
| Title |
|---|
| 韩长日: "《精细无机化学品制造技术》", 科学技术文献出版社 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106987174A (en) * | 2017-04-19 | 2017-07-28 | 广州大学 | A kind of water-soluble mobile phone faceplate glass protection ink |
| CN106987174B (en) * | 2017-04-19 | 2020-10-23 | 广州大学 | Water-soluble mobile phone panel glass protection ink |
| CN108944231A (en) * | 2017-05-19 | 2018-12-07 | 比亚迪股份有限公司 | The trailing and 3D ambetti of printing ink composition and 3D glass |
| CN107556812A (en) * | 2017-09-27 | 2018-01-09 | 广东星弛光电科技有限公司 | A kind of hand-set lid glass black ink with covering and preparation method thereof |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information |
Address after: 211600 Jiangsu Huaian Jinhu County Economic Development Zone Jinshui Hexi Applicant after: YUDI OPTICS CO.,LTD. Address before: 211600 Jiangsu Wuxi Jinhu County Economic Development Zone Jinshui Hexi Applicant before: YUDI OPTICS CO.,LTD. |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170222 |
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| RJ01 | Rejection of invention patent application after publication |