CN114045067A - Four-color ink for water-based gravure cigarette packet and preparation method thereof - Google Patents
Four-color ink for water-based gravure cigarette packet and preparation method thereof Download PDFInfo
- Publication number
- CN114045067A CN114045067A CN202111540455.9A CN202111540455A CN114045067A CN 114045067 A CN114045067 A CN 114045067A CN 202111540455 A CN202111540455 A CN 202111540455A CN 114045067 A CN114045067 A CN 114045067A
- Authority
- CN
- China
- Prior art keywords
- water
- based gravure
- agent
- ink
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 52
- 235000019504 cigarettes Nutrition 0.000 title claims abstract description 34
- 238000002360 preparation method Methods 0.000 title abstract description 8
- 239000000049 pigment Substances 0.000 claims abstract description 15
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 12
- 239000002270 dispersing agent Substances 0.000 claims abstract description 11
- 239000000839 emulsion Substances 0.000 claims abstract description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 8
- RWNUSVWFHDHRCJ-UHFFFAOYSA-N 1-butoxypropan-2-ol Chemical compound CCCCOCC(C)O RWNUSVWFHDHRCJ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000003381 stabilizer Substances 0.000 claims abstract description 7
- 238000003756 stirring Methods 0.000 claims description 9
- 239000002518 antifoaming agent Substances 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 239000002562 thickening agent Substances 0.000 claims description 6
- 239000006185 dispersion Substances 0.000 claims description 5
- 238000000227 grinding Methods 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- -1 polydimethylsiloxane Polymers 0.000 claims description 3
- 239000002994 raw material Substances 0.000 claims description 3
- OSNILPMOSNGHLC-UHFFFAOYSA-N 1-[4-methoxy-3-(piperidin-1-ylmethyl)phenyl]ethanone Chemical compound COC1=CC=C(C(C)=O)C=C1CN1CCCCC1 OSNILPMOSNGHLC-UHFFFAOYSA-N 0.000 claims description 2
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical group CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 claims description 2
- 150000001450 anions Chemical group 0.000 claims description 2
- 239000001055 blue pigment Substances 0.000 claims description 2
- 239000006229 carbon black Substances 0.000 claims description 2
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 claims description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 2
- 239000012948 isocyanate Substances 0.000 claims description 2
- 150000002513 isocyanates Chemical class 0.000 claims description 2
- 239000012860 organic pigment Substances 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 2
- 229920000728 polyester Polymers 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- 238000000034 method Methods 0.000 claims 1
- 238000001035 drying Methods 0.000 description 13
- 230000000694 effects Effects 0.000 description 10
- 238000007639 printing Methods 0.000 description 10
- 239000002904 solvent Substances 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000002253 acid Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000007645 offset printing Methods 0.000 description 1
- QMYDVDBERNLWKB-UHFFFAOYSA-N propane-1,2-diol;hydrate Chemical compound O.CC(O)CO QMYDVDBERNLWKB-UHFFFAOYSA-N 0.000 description 1
- 230000001603 reducing effect Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The application provides a four-color ink for a water-based gravure cigarette packet and a preparation method thereof, and the four-color ink comprises the following components in percentage by weight: 60-75 parts of modified acrylic emulsion, 3-8 parts of propylene glycol butyl ether, 10-15 parts of pigment, 10-20 parts of water, 2-6 parts of water-based curing agent, 0.5-1 part of water-based dispersant, 3-5 parts of pH stabilizer and 1.5-3.5 parts of auxiliary agent.
Description
Technical Field
The invention belongs to the technical field of water-based ink, and particularly relates to a four-color ink for a water-based gravure cigarette packet and a preparation method thereof.
Background
The traditional four-color ink for the gravure cigarette packet is solvent-based, and although the printed finished product has a good effect, the content of volatile matters is high, the pollution is large, while the four-color ink for the water-based gravure cigarette packet is difficult to popularize all the time, and the main problems are that the printing drying speed and the good printing effect are difficult to solve.
Therefore, further improvement of the existing four-color ink for water-based gravure cigarette packets is needed.
Disclosure of Invention
The invention aims to solve the technical problems of poor printing drying speed and poor printing effect of the existing water-based gravure ink, provides the four-color ink for the water-based gravure cigarette packet, which has high drying speed and good printing effect, can meet the cigarette packet brush requirement, and has high drying speed, bright color and good adhesive force and flexibility.
The invention also aims to provide a preparation method of the four-color ink for the water-based gravure cigarette packet.
The technical scheme is as follows:
the water-based gravure four-color ink for cigarette packets comprises the following components in percentage by weight: 60-75 parts of modified acrylic emulsion, 3-8 parts of propylene glycol butyl ether, 10-15 parts of pigment, 10-20 parts of water, 2-6 parts of water-based curing agent, 0.5-1 part of water-based dispersant, 3-5 parts of pH stabilizer and 1.5-3.5 parts of auxiliary agent.
Preferably, the modified acrylic emulsion has the viscosity of 1000-2000cps25 ℃, the pH value of 7-8, the solid content of 40 +/-1%, the particle diameter of 0.1-0.2 mu m and the Tg of 32 ℃, has good pigment dispersing performance, good color development performance, good water resistance, good anti-after-tack effect and good anti-scratch effect, has good compatibility with propylene glycol butyl ether and water, is set for gravure ink special for cigarette packets, and can improve the drying speed and the printing effect of ink products.
Preferably, the pigment comprises one or a mixture of more of pigment red PR122, organic phthalocyanine blue pigment 15:3, organic pigment benzidine yellow No. 12 yellow and pigment carbon black, and has bright color, proper tinting strength and hiding power and higher dispersity.
Preferably, the water-based curing agent is anion modified isocyanate, preferably Costa Bayhydur quick 306-70, comprises aromatic and aliphatic parts, has drying performance similar to that of a solvent-based system, but has less VOC discharge amount, is as effective and efficient as the same solvent-based system, and can improve the drying speed and the printing effect of an ink product when being used for the gravure ink special for the cigarette packet. .
Preferably, the aqueous dispersant is polyester multi-chain polymer dispersant, preferably lubon brand wetting dispersant 24000, is used for improving pigment dispersion, shows very excellent grinding dispersion effect on pigment filling, and has very good color developing and viscosity reducing effects.
Preferably, the pH stabilizer is dimethylacetamide buffer, and the pH value is controlled to be between 8.5 and 9.5, and if the pH stabilizer is out of the range, the pH stabilizer can be used for adjusting, so that the viscosity and the pH value are kept stable.
Preferably, the auxiliary agent comprises 0.2-0.5 part of defoaming agent, 0.3-1 part of flatting agent and 1-2 parts of thickening agent, preferably, the defoaming agent is defoaming agent 1488, the flatting agent is polydimethylsiloxane emulsion, and the thickening agent is thickening agent 9005.
The preparation method of the four-color ink for the water-based gravure cigarette packet comprises the following steps:
(1) taking the raw materials according to the parts by weight for standby, firstly adding water into a reaction kettle, then slowly and sequentially adding the modified acrylic emulsion, the propylene glycol butyl ether and the waterborne curing agent under the stirring condition, and uniformly mixing and stirring;
(2) adding a water-based dispersant and a pigment for high-speed dispersion, grinding and filtering;
(3) and adding an auxiliary agent, and stirring and mixing uniformly to prepare the four-color ink for the water-based gravure cigarette packet.
Compared with the prior art, the invention has the following advantages:
the application provides a four-color ink for a water-based gravure cigarette packet, which comprises the following components in percentage by weight: 60-75 parts of modified acrylic emulsion, 3-8 parts of propylene glycol butyl ether, 10-15 parts of pigment, 10-20 parts of water, 2-6 parts of water-based curing agent, 0.5-1 part of water-based dispersant, 3-5 parts of pH stabilizer and 1.5-3.5 parts of auxiliary agent.
The preparation method of the four-color ink for the water-based gravure cigarette packet has the advantages that the cost is low, the synthesis is easy, the performance of the existing water-based gravure ink is upgraded, the four-color ink for the water-based gravure cigarette packet with high drying speed and good printing performance is prepared, the technical problems of poor drying speed and poor printing effect of the existing water-based gravure ink in printing are solved, the cigarette packet brush requirement can be met, the drying speed is high, the color is bright, the adhesive force flexibility is good, and the application prospect is good.
Detailed Description
The following describes a specific embodiment of the present invention with reference to specific examples 1 to 3:
the preparation method of the four-color ink for the water-based gravure cigarette packet in the embodiments 1 to 3 comprises the following steps: preparing the raw materials for later use according to the weight part ratio in the table 1, firstly adding water into a reaction kettle, then slowly and sequentially adding the modified acrylic emulsion, the propylene glycol butyl ether and the water-based curing agent under the stirring condition, uniformly mixing and stirring, then adding the water-based dispersing agent and the pigment for 100r/min for high-speed dispersion, then grinding the mixture on a three-roller machine to the fineness of less than 4 mu m, filtering, adding the auxiliary agent, uniformly mixing and stirring to prepare the water-based gravure ink for cigarette packets.
Table 1: the offset printing ink in the embodiments 1-3 comprises the following components in parts by weight:
the four-color ink for the water-based gravure cigarette packet prepared in the examples 1 to 3 is used for product trial and detection, and the test results are as follows:
the test results show that the four-color ink for the water-based gravure cigarette packet prepared in the embodiments 1 to 3 has good drying speed, the obtained product has smooth lines, full images and good mark adhesion, the printed product has full color, clear lines, complete drying, good tensile resistance and flexibility, acid resistance and alkali resistance of 5 grades, can meet the requirements of cigarette packet brushing, and has high drying speed, bright color and good adhesion and flexibility.
The above description is only exemplary of the present application and should not be taken as limiting the present application, as any modification, equivalent replacement, or improvement made within the spirit and principle of the present application should be included in the protection scope of the present application.
Claims (9)
1. The four-color ink for the water-based gravure cigarette packet is characterized by comprising the following components in percentage by weight:
2. the water-based gravure ink for cigarette packets as claimed in claim 1, wherein: the viscosity of the modified acrylic emulsion is 1000-2000cps25 ℃, the pH is 7-8, the solid content is 40 +/-1%, the particle diameter is 0.1-0.2 mu m, and the Tg is 32 ℃.
3. The water-based gravure ink for cigarette packets as claimed in claim 1, wherein: the pigment comprises one or a mixture of a plurality of pigment red PR122, organic phthalocyanine blue pigment 15:3, organic pigment benzidine yellow No. 12 yellow and pigment carbon black.
4. The water-based gravure ink for cigarette packets as claimed in claim 1, wherein: the aqueous curing agent is anion modified isocyanate.
5. The water-based gravure ink for cigarette packets as claimed in claim 1, wherein: the water-based dispersant is a polyester multi-chain polymer dispersant.
6. The water-based gravure ink for cigarette packets as claimed in claim 1, wherein: the pH stabilizer is dimethylacetamide buffer.
7. The water-based gravure ink for cigarette packets as claimed in claim 1, wherein: the auxiliary agent comprises 0.2-0.5 part of defoaming agent, 0.3-1 part of flatting agent and 1-2 parts of thickening agent.
8. The water-based gravure ink for cigarette packets as claimed in claim 7, wherein said ink comprises: the defoaming agent is a defoaming agent 1488, the leveling agent is polydimethylsiloxane emulsion, and the thickening agent is a thickening agent 9005.
9. The method for preparing the four-color ink for the water-based gravure cigarette packet as claimed in any one of claims 1 to 8, characterized by comprising the steps of:
(1) taking the raw materials according to the parts by weight for standby, firstly adding water into a reaction kettle, then slowly and sequentially adding the modified acrylic emulsion, the propylene glycol butyl ether and the waterborne curing agent under the stirring condition, and uniformly mixing and stirring;
(2) adding a water-based dispersant and a pigment for high-speed dispersion, grinding and filtering;
(3) and adding an auxiliary agent, and stirring and mixing uniformly to prepare the four-color ink for the water-based gravure cigarette packet.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111540455.9A CN114045067A (en) | 2021-12-16 | 2021-12-16 | Four-color ink for water-based gravure cigarette packet and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111540455.9A CN114045067A (en) | 2021-12-16 | 2021-12-16 | Four-color ink for water-based gravure cigarette packet and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN114045067A true CN114045067A (en) | 2022-02-15 |
Family
ID=80213272
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202111540455.9A Pending CN114045067A (en) | 2021-12-16 | 2021-12-16 | Four-color ink for water-based gravure cigarette packet and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN114045067A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114958083A (en) * | 2022-06-17 | 2022-08-30 | 惠州佳景印刷制品有限公司 | Printing process of environment-friendly printing ink and printing ink |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102358810A (en) * | 2011-09-14 | 2012-02-22 | 哈尔滨大东方卷烟材料科技开发有限责任公司 | Environment-friendly type water-based intaglio ink used for package printing and preparation method thereof |
| CN108410264A (en) * | 2018-04-10 | 2018-08-17 | 辽宁蔚蓝科技有限公司 | A kind of environment-friendly type aqueous gravure ink and preparation method thereof |
| CN109021692A (en) * | 2018-10-17 | 2018-12-18 | 江苏扬中印刷有限公司 | A kind of advertising and printing water-based ink |
| CN109181411A (en) * | 2018-10-17 | 2019-01-11 | 江苏扬中印刷有限公司 | A kind of quick-dry type water-based ink |
-
2021
- 2021-12-16 CN CN202111540455.9A patent/CN114045067A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102358810A (en) * | 2011-09-14 | 2012-02-22 | 哈尔滨大东方卷烟材料科技开发有限责任公司 | Environment-friendly type water-based intaglio ink used for package printing and preparation method thereof |
| CN108410264A (en) * | 2018-04-10 | 2018-08-17 | 辽宁蔚蓝科技有限公司 | A kind of environment-friendly type aqueous gravure ink and preparation method thereof |
| CN109021692A (en) * | 2018-10-17 | 2018-12-18 | 江苏扬中印刷有限公司 | A kind of advertising and printing water-based ink |
| CN109181411A (en) * | 2018-10-17 | 2019-01-11 | 江苏扬中印刷有限公司 | A kind of quick-dry type water-based ink |
Non-Patent Citations (2)
| Title |
|---|
| 《聚氨酯工业》编辑部: "科思创推出水性聚氨酯涂料新型快干固化剂", 《聚氨酯工业》 * |
| 周春山: "《新功能精细化工品配方及生产》", 31 December 1998, 中南工业大学出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114958083A (en) * | 2022-06-17 | 2022-08-30 | 惠州佳景印刷制品有限公司 | Printing process of environment-friendly printing ink and printing ink |
| CN114958083B (en) * | 2022-06-17 | 2023-08-15 | 惠州佳景印刷制品有限公司 | Printing process of environment-friendly printing ink and printing ink |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101701128B (en) | Water-based two-pack polyurethane preservative coating and preparation method thereof | |
| CN106590162B (en) | Water-based gravure plastic film surface printing ink and preparation method thereof | |
| CN111253801A (en) | Environment-friendly water-based ink for shopping bag printing and preparation method thereof | |
| CN105062208A (en) | Flexographic plate water-based ink for high-speed printing and preparation method thereof | |
| CN101469153A (en) | Environment friendly transparent iron oxide black superfine aqueous color sizing dispersion and preparation thereof | |
| CN102993864B (en) | Aqueous traffic paint and preparation method thereof | |
| CN111040512A (en) | Water-based flexographic printing ink for thin film printing and preparation method thereof | |
| CN114045067A (en) | Four-color ink for water-based gravure cigarette packet and preparation method thereof | |
| CN112280417A (en) | Water-based wood paint | |
| CN107746624A (en) | A kind of printing-ink containing plant oil base | |
| CN111454611A (en) | Printing ink for colorful tipping paper and preparation method thereof | |
| CN103254686A (en) | High-covering property glass lens ink and preparation method thereof | |
| CN103305113A (en) | Anti-sinking PU extra-clear primer and preparation method thereof | |
| CN112341923B (en) | Water-based color modifier and preparation method thereof | |
| CN113004757A (en) | Dyed sand slurry, artificial colored sand and preparation method | |
| CN112662228A (en) | Water-soluble environment-friendly gravure ink and preparation method thereof | |
| CN109679473B (en) | Environment-friendly water-based pencil color paint suitable for wood pencils and preparation method and application thereof | |
| CN109401435B (en) | Wear-resistant water-based ink and preparation process thereof | |
| CN101469154A (en) | Environment friendly transparent iron oxide red superfine aqueous color sizing dispersion and preparation thereof | |
| CN113088173B (en) | Multicolor low-gloss water-based acrylic polyurethane finish paint for railway passenger cars and preparation method thereof | |
| CN110607090A (en) | High-molecular dispersing agent for water-based paint and preparation method thereof | |
| CN114196255B (en) | Water-based polyurethane ink for gravure printing | |
| CN101302374A (en) | Method for improving water-based flexographic plate printing ink re-dissolubility | |
| CN116200075B (en) | High-resolution anti-counterfeiting electronic ink and preparation method thereof | |
| CN112011217A (en) | High-concentration water-based preprinting ink and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20220215 |