CN107746624A - A kind of printing-ink containing plant oil base - Google Patents

A kind of printing-ink containing plant oil base Download PDF

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Publication number
CN107746624A
CN107746624A CN201711188721.XA CN201711188721A CN107746624A CN 107746624 A CN107746624 A CN 107746624A CN 201711188721 A CN201711188721 A CN 201711188721A CN 107746624 A CN107746624 A CN 107746624A
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CN
China
Prior art keywords
parts
printing
oil
ink containing
containing plant
Prior art date
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Pending
Application number
CN201711188721.XA
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Chinese (zh)
Inventor
李峰
郑志龙
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ANHUI MENGNIU COLOR PRINTING PACKAGING Co Ltd
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ANHUI MENGNIU COLOR PRINTING PACKAGING Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by ANHUI MENGNIU COLOR PRINTING PACKAGING Co Ltd filed Critical ANHUI MENGNIU COLOR PRINTING PACKAGING Co Ltd
Priority to CN201711188721.XA priority Critical patent/CN107746624A/en
Publication of CN107746624A publication Critical patent/CN107746624A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/102Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/033Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/06Printing inks based on fatty oils

Abstract

The invention discloses a kind of printing-ink containing plant oil base, it is divided into according to raw material weight component, 48 52 parts of waterborne polyurethane resin, 24 28 parts of vegetable oil, 12 16 parts of aqueous pigment, 55 59 parts of polyethylene glycol, 37 parts of tartaric acid, 2.2 2.6 parts of nano diatomite, 1.6 2.0 parts of bentonite, 1.3 1.7 parts of carbon black powder, 0.4 0.8 parts of silicon dioxide powder, 15 parts of dispersant, 26 parts of organic silicon defoamer, 15 parts of antioxidant, 72 76 parts of deionized water.Using technical solution of the present invention, it is stirred using the cleaner body material of waterborne polyurethane resin, vegetable oil, aqueous pigment, polyethylene glycol, tartaric acid, dispersant, antioxidant, deionized water, the oil base that vegetable oil contains to be stirred material connectivity enhancing, and add the use of nano diatomite, bentonite, carbon black powder, silicon dioxide powder, so that overall performance improves when ink prints, printing quality is improved.

Description

A kind of printing-ink containing plant oil base
Technical field
The present invention relates to the technical field of printing-ink production, more particularly to a kind of printing-ink containing plant oil base.
Background technology
Printing-ink is a kind of common printed matter coloured material, mainly by compositions such as pigment, link stuff, inserts Form, be a kind of pulpous state adherent that is coloured, having certain fluidity.Want to obtain gratifying printing effect, actually make There is certain requirement to the color of ink, printing adaptability, rate of drying during, while also to be possessed according to use environment The features such as water-fast, fast light, acid and alkali-resistance, low toxic and environment-friendly, following printing-ink developing direction must be directed towards low toxicity, quick-drying, color Naturally various and multifunction direction is developed, however existing ink generally existing not enough environmental protection, viscosity control it is uneven, with Base material adhesive force is bad and the shortcomings of the preferable ink of partial properties holds at high price, therefore, necessary to improve printing The formula and technique of ink, accelerate the transition of industry, to reach the production model of high-efficiency environment friendly, therefore, it is proposed that one kind contains There is printing-ink of plant oil base and preparation method thereof.
The content of the invention
To solve the defects of prior art, the invention discloses a kind of printing-ink containing plant oil base.
The invention discloses a kind of printing-ink containing plant oil base, it is divided into according to raw material weight component, water-based poly- ammonia Ester resin 48-52 parts, vegetable oil 24-28 parts, aqueous pigment 12-16 parts, polyethylene glycol 55-59 parts, tartaric acid 3-7 parts, nanometer Diatomite 2.2-2.6 parts, bentonite 1.6-2.0 parts, carbon black powder 1.3-1.7 parts, silicon dioxide powder 0.4-0.8 parts, dispersant 1-5 Part, organic silicon defoamer 2-6 parts, antioxidant 1-5 parts, deionized water 72-76 parts.
Preferably, a kind of printing-ink containing plant oil base, is divided into, waterborne polyurethane resin according to raw material weight component 49-51 parts, vegetable oil 25-27 parts, aqueous pigment 13-15 parts, polyethylene glycol 56-58 parts, tartaric acid 4-6 parts, nano diatomite 2.3-2.5 parts, bentonite 1.7-1.9 parts, carbon black powder 1.4-1.6 parts, silicon dioxide powder 0.5-0.7 parts, dispersant 2-4 parts, have Machine silicon defoaming agent 3-5 parts, antioxidant 2-4 parts, deionized water 73-75 parts.
Preferably, a kind of printing-ink containing plant oil base, is divided into, waterborne polyurethane resin according to raw material weight component 50 parts, 26 parts of vegetable oil, 14 parts of aqueous pigment, 57 parts of polyethylene glycol, 5 parts of tartaric acid, 2.4 parts of nano diatomite, bentonite 1.8 Part, 1.5 parts of carbon black powder, 0.6 part of silicon dioxide powder, 3 parts of dispersant, 4 parts of organic silicon defoamer, 3 parts of antioxidant, deionized water 74 parts.
Preferably, the vegetable oil is soya-bean oil, peanut oil, rapeseed oil, one or more mixtures of sesame oil.
Preferably, the dispersant is microcrystalline wax.
Preferably, the antioxidant is carrotene, one or two kinds of mixtures of flavones.
A kind of printing-ink containing plant oil base, its preparation method are as follows:
1)Weigh waterborne polyurethane resin, vegetable oil, aqueous pigment, polyethylene glycol, tartaric acid, dispersant, antioxidant, go from Sub- water is put into mixer, is warming up to 500-600 DEG C, the stirring reaction 1- under the rotating speed of 1500-2000 revs/min of rotating speed 2h, it is standby;
2)Weigh receive nano diatomite, bentonite, carbon black powder, silicon dioxide powder input grinder in, after grinding cross 800- 900 mesh sieves, it is standby to obtain mixed-powder;
3)Again to step 2)The mixed-powder input step 1 of middle acquisition)In, and organic silicon defoamer is added, temperature control is in 80- 90 DEG C, 2000-2500 revs/min of stirring 2-3h of rotating speed, then 35-40 DEG C is cooled to, stand and place 0.5-1h;
4)To step 3)It is middle to stand the filtered final off-set oil black liquid that obtain needs of mixed liquor placed.
Beneficial effect is:Using waterborne polyurethane resin, vegetable oil, aqueous pigment, polyethylene glycol, tartaric acid, dispersant, The cleaner body material of antioxidant, deionized water is stirred, and the oil base that vegetable oil contains make it that being stirred material connects Connecing property strengthens, and deionized water is environmentally friendly solution, avoids, using the higher organic solvent of pollution level, being advantageous in production process Environmental protection and security protection, and add the use of nano diatomite, bentonite, carbon black powder, silicon dioxide powder so that ink prints Overall performance improves during brush, improves printing quality.
Embodiment
Embodiment 1
The invention discloses a kind of printing-ink containing plant oil base, it is divided into according to raw material weight component, aqueous polyurethane tree 48 parts of fat, 24 parts of vegetable oil, 12 parts of aqueous pigment, 55 parts of polyethylene glycol, 3 parts of tartaric acid, 2.2 parts of nano diatomite, bentonite 1.6 parts, 1.3 parts of carbon black powder, 0.4 part of silicon dioxide powder, 1 part of dispersant, 2 parts of organic silicon defoamer, 1 part of antioxidant, go from Sub- 72 parts of water.
The vegetable oil is soya-bean oil, peanut oil, rapeseed oil, one or more mixtures of sesame oil.
The dispersant is microcrystalline wax.
The antioxidant is carrotene, one or two kinds of mixtures of flavones.
A kind of printing-ink containing plant oil base, its preparation method are as follows:
1)Weigh waterborne polyurethane resin, vegetable oil, aqueous pigment, polyethylene glycol, tartaric acid, dispersant, antioxidant, go from Sub- water is put into mixer, is warming up to 500 DEG C, and stirring reaction 1h, standby under the rotating speed of 1500 revs/min of rotating speed;
2)Weigh receive nano diatomite, bentonite, carbon black powder, silicon dioxide powder input grinder in, after grinding cross 800 mesh Sieve, it is standby to obtain mixed-powder;
3)Again to step 2)The mixed-powder input step 1 of middle acquisition)In, and organic silicon defoamer is added, temperature control is 80 DEG C, 2000 revs/min of stirring 2h of rotating speed, then 35 DEG C are cooled to, stand and place 0.5h;
4)To step 3)It is middle to stand the filtered final off-set oil black liquid that obtain needs of mixed liquor placed.
Embodiment 2
The invention discloses a kind of printing-ink containing plant oil base, it is divided into according to raw material weight component, aqueous polyurethane tree 49 parts of fat, 25 parts of vegetable oil, 13 parts of aqueous pigment, 56 parts of polyethylene glycol, 4 parts of tartaric acid, 2.3 parts of nano diatomite, bentonite 1.7 parts, 1.4 parts of carbon black powder, 0.5 part of silicon dioxide powder, 2 parts of dispersant, 3 parts of organic silicon defoamer, 2 parts of antioxidant, go from Sub- 73 parts of water.
The vegetable oil is soya-bean oil, peanut oil, rapeseed oil, one or more mixtures of sesame oil.
The dispersant is microcrystalline wax.
The antioxidant is carrotene, one or two kinds of mixtures of flavones.
A kind of printing-ink containing plant oil base, its preparation method are as follows:
1)Weigh waterborne polyurethane resin, vegetable oil, aqueous pigment, polyethylene glycol, tartaric acid, dispersant, antioxidant, go from Sub- water is put into mixer, is warming up to 520 DEG C, and stirring reaction 1.2h, standby under the rotating speed of 1600 revs/min of rotating speed;
2)Weigh receive nano diatomite, bentonite, carbon black powder, silicon dioxide powder input grinder in, after grinding cross 820 mesh Sieve, it is standby to obtain mixed-powder;
3)Again to step 2)The mixed-powder input step 1 of middle acquisition)In, and organic silicon defoamer is added, temperature control is 82 DEG C, 2100 revs/min of stirring 2.2h of rotating speed, then 36 DEG C are cooled to, stand and place 0.6h;
4)To step 3)It is middle to stand the filtered final off-set oil black liquid that obtain needs of mixed liquor placed.
Embodiment 3
The invention discloses a kind of printing-ink containing plant oil base, it is divided into according to raw material weight component, aqueous polyurethane tree 50 parts of fat, 26 parts of vegetable oil, 14 parts of aqueous pigment, 57 parts of polyethylene glycol, 5 parts of tartaric acid, 2.4 parts of nano diatomite, bentonite 1.8 parts, 1.5 parts of carbon black powder, 0.6 part of silicon dioxide powder, 3 parts of dispersant, 4 parts of organic silicon defoamer, 3 parts of antioxidant, go from Sub- 74 parts of water.
The vegetable oil is soya-bean oil, peanut oil, rapeseed oil, one or more mixtures of sesame oil.
The dispersant is microcrystalline wax.
The antioxidant is carrotene, one or two kinds of mixtures of flavones.
A kind of printing-ink containing plant oil base, its preparation method are as follows:
1)Weigh waterborne polyurethane resin, vegetable oil, aqueous pigment, polyethylene glycol, tartaric acid, dispersant, antioxidant, go from Sub- water is put into mixer, is warming up to 540 DEG C, and stirring reaction 1.5h, standby under the rotating speed of 1700 revs/min of rotating speed;
2)Weigh receive nano diatomite, bentonite, carbon black powder, silicon dioxide powder input grinder in, after grinding cross 860 mesh Sieve, it is standby to obtain mixed-powder;
3)Again to step 2)The mixed-powder input step 1 of middle acquisition)In, and organic silicon defoamer is added, temperature control is 85 DEG C, 2300 revs/min of stirring 2.5h of rotating speed, then 37 DEG C are cooled to, stand and place 0.7h;
4)To step 3)It is middle to stand the filtered final off-set oil black liquid that obtain needs of mixed liquor placed.
Embodiment 4
The invention discloses a kind of printing-ink containing plant oil base, it is divided into according to raw material weight component, one kind contains plant The printing-ink of oil base, it is divided into according to raw material weight component, 51 parts of waterborne polyurethane resin, 27 parts of vegetable oil, aqueous pigment 15 Part, 58 parts of polyethylene glycol, 6 parts of tartaric acid, 2.5 parts of nano diatomite, 1.9 parts of bentonite, 1.6 parts of carbon black powder, silicon dioxide powder 0.7 part, 4 parts of dispersant, 5 parts of organic silicon defoamer, 4 parts of antioxidant, 75 parts of deionized water.
The vegetable oil is soya-bean oil, peanut oil, rapeseed oil, one or more mixtures of sesame oil.
The dispersant is microcrystalline wax.
The antioxidant is carrotene, one or two kinds of mixtures of flavones.
A kind of printing-ink containing plant oil base, its preparation method are as follows:
1)Weigh waterborne polyurethane resin, vegetable oil, aqueous pigment, polyethylene glycol, tartaric acid, dispersant, antioxidant, go from Sub- water is put into mixer, is warming up to 580 DEG C, and stirring reaction 1.8h, standby under the rotating speed of 1800 revs/min of rotating speed;
2)Weigh receive nano diatomite, bentonite, carbon black powder, silicon dioxide powder input grinder in, after grinding cross 880 mesh Sieve, it is standby to obtain mixed-powder;
3)Again to step 2)The mixed-powder input step 1 of middle acquisition)In, and organic silicon defoamer is added, temperature control is 88 DEG C, 2400 revs/min of stirring 2.8h of rotating speed, then 38 DEG C are cooled to, stand and place 0.8h;
4)To step 3)It is middle to stand the filtered final off-set oil black liquid that obtain needs of mixed liquor placed.
Embodiment 5
The invention discloses a kind of printing-ink containing plant oil base, it is divided into according to raw material weight component, aqueous polyurethane tree 52 parts of fat, 28 parts of vegetable oil, 16 parts of aqueous pigment, 59 parts of polyethylene glycol, 7 parts of tartaric acid, 2.6 parts of nano diatomite, bentonite 2.0 parts, 1.7 parts of carbon black powder, 0.8 part of silicon dioxide powder, 5 parts of dispersant, 6 parts of organic silicon defoamer, 5 parts of antioxidant, go from Sub- 76 parts of water.
The vegetable oil is soya-bean oil, peanut oil, rapeseed oil, one or more mixtures of sesame oil.
The dispersant is microcrystalline wax.
The antioxidant is carrotene, one or two kinds of mixtures of flavones.
A kind of printing-ink containing plant oil base, its preparation method are as follows:
1)Weigh waterborne polyurethane resin, vegetable oil, aqueous pigment, polyethylene glycol, tartaric acid, dispersant, antioxidant, go from Sub- water is put into mixer, is warming up to 600 DEG C, and stirring reaction 2h, standby under the rotating speed of 2000 revs/min of rotating speed;
2)Weigh receive nano diatomite, bentonite, carbon black powder, silicon dioxide powder input grinder in, after grinding cross 900 mesh Sieve, it is standby to obtain mixed-powder;
3)Again to step 2)The mixed-powder input step 1 of middle acquisition)In, and organic silicon defoamer is added, temperature control is 90 DEG C, 2500 revs/min of stirring 3h of rotating speed, then 40 DEG C are cooled to, stand and place 1h;
4)To step 3)It is middle to stand the filtered final off-set oil black liquid that obtain needs of mixed liquor placed.
Finally it should be noted that:Above example only not limits technology described in the invention to illustrate the present invention Scheme;Therefore, although this specification with reference to above-mentioned each embodiment to present invention has been detailed description, this Field it is to be appreciated by one skilled in the art that still can be modified to the present invention or equivalent substitution;And all do not depart from this The technical scheme of the spirit and scope of invention and its improvement, it all should cover in scope of the presently claimed invention.

Claims (7)

  1. A kind of 1. printing-ink containing plant oil base, it is characterised in that:It is divided into according to raw material weight component, aqueous polyurethane tree Fat 48-52 parts, vegetable oil 24-28 parts, aqueous pigment 12-16 parts, polyethylene glycol 55-59 parts, tartaric acid 3-7 parts, nanometer diatom Native 2.2-2.6 parts, bentonite 1.6-2.0 parts, carbon black powder 1.3-1.7 parts, silicon dioxide powder 0.4-0.8 parts, dispersant 1-5 parts, Organic silicon defoamer 2-6 parts, antioxidant 1-5 parts, deionized water 72-76 parts.
  2. A kind of 2. printing-ink containing plant oil base according to claim 1, it is characterised in that:According to raw material weight group Part is divided into, waterborne polyurethane resin 49-51 parts, vegetable oil 25-27 parts, aqueous pigment 13-15 parts, polyethylene glycol 56-58 parts, wine Stone acid 4-6 parts, nano diatomite 2.3-2.5 parts, bentonite 1.7-1.9 parts, carbon black powder 1.4-1.6 parts, silicon dioxide powder 0.5- 0.7 part, dispersant 2-4 parts, organic silicon defoamer 3-5 parts, antioxidant 2-4 parts, deionized water 73-75 parts.
  3. A kind of 3. printing-ink containing plant oil base according to claim 1, it is characterised in that:According to raw material weight group Part is divided into, 50 parts of waterborne polyurethane resin, 26 parts of vegetable oil, 14 parts of aqueous pigment, 57 parts of polyethylene glycol, tartaric acid 5 part, nanometer 2.4 parts of diatomite, 1.8 parts of bentonite, 1.5 parts of carbon black powder, 0.6 part of silicon dioxide powder, 3 parts of dispersant, organic silicon defoamer 4 Part, 3 parts of antioxidant, 74 parts of deionized water.
  4. A kind of 4. printing-ink containing plant oil base according to claim 1, it is characterised in that:The vegetable oil is beans Oil, peanut oil, rapeseed oil, one or more mixtures of sesame oil.
  5. A kind of 5. printing-ink containing plant oil base according to claim 1, it is characterised in that:The dispersant is micro- Spar wax.
  6. A kind of 6. printing-ink containing plant oil base according to claim 1, it is characterised in that:The antioxidant is One or two kinds of mixtures of carrotene, flavones.
  7. A kind of 7. printing-ink containing plant oil base, it is characterised in that:Its preparation method is as follows:
    1)Weigh waterborne polyurethane resin, vegetable oil, aqueous pigment, polyethylene glycol, tartaric acid, dispersant, antioxidant, go from Sub- water is put into mixer, is warming up to 500-600 DEG C, the stirring reaction 1- under the rotating speed of 1500-2000 revs/min of rotating speed 2h, it is standby;
    2)Weigh receive nano diatomite, bentonite, carbon black powder, silicon dioxide powder input grinder in, after grinding cross 800- 900 mesh sieves, it is standby to obtain mixed-powder;
    3)Again to step 2)The mixed-powder input step 1 of middle acquisition)In, and organic silicon defoamer is added, temperature control is in 80- 90 DEG C, 2000-2500 revs/min of stirring 2-3h of rotating speed, then 35-40 DEG C is cooled to, stand and place 0.5-1h;
    4)To step 3)It is middle to stand the filtered final off-set oil black liquid that obtain needs of mixed liquor placed.
CN201711188721.XA 2017-11-24 2017-11-24 A kind of printing-ink containing plant oil base Pending CN107746624A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112625494A (en) * 2020-12-25 2021-04-09 苏州市和好塑业有限公司 Printing ink, preparation method and application thereof
CN112831217A (en) * 2019-11-25 2021-05-25 怀化市恒大彩印包装有限公司 Printing ink
CN113462229A (en) * 2021-07-02 2021-10-01 陆济林 Antibacterial heat-resistant environment-friendly printing ink and preparation method thereof
CN114163868A (en) * 2021-07-05 2022-03-11 广东新辉化学有限公司 Waterborne polyurethane ink binder and preparation method thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1676556A (en) * 2004-03-30 2005-10-05 天津科技大学 Screen printing water-soluble ink

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1676556A (en) * 2004-03-30 2005-10-05 天津科技大学 Screen printing water-soluble ink

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112831217A (en) * 2019-11-25 2021-05-25 怀化市恒大彩印包装有限公司 Printing ink
CN112625494A (en) * 2020-12-25 2021-04-09 苏州市和好塑业有限公司 Printing ink, preparation method and application thereof
CN113462229A (en) * 2021-07-02 2021-10-01 陆济林 Antibacterial heat-resistant environment-friendly printing ink and preparation method thereof
CN114163868A (en) * 2021-07-05 2022-03-11 广东新辉化学有限公司 Waterborne polyurethane ink binder and preparation method thereof

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Application publication date: 20180302