CN108117797A - A kind of general compound oil ink of novel environment-friendly water-based plastic rotogravure - Google Patents
A kind of general compound oil ink of novel environment-friendly water-based plastic rotogravure Download PDFInfo
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- CN108117797A CN108117797A CN201810055417.6A CN201810055417A CN108117797A CN 108117797 A CN108117797 A CN 108117797A CN 201810055417 A CN201810055417 A CN 201810055417A CN 108117797 A CN108117797 A CN 108117797A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
Abstract
The present invention relates to a kind of novel environment-friendly water-based general compound oil ink of plastic rotogravure, including being made of the component of following weight proportion：10 35 parts of pigment, 30 35 parts of modified aqueous polyurethane resin, aqueous 10 15 parts of vinyl chloride-vinyl acetate resin, 0.5 1 parts of oxypolymer reinforcing agent, 0.5 1 parts of aqueous polyethylene wax micro mist, 0.3 0.5 parts of water-soluble nano silica, 0.01 part of polyethers aqueous defoamer, 13 parts of ethyl alcohol, 15 35 parts of water.The general compound oil ink of novel environment-friendly water-based plastic rotogravure of the present invention, water resistance is preferable, has compared with highly resistance station viscosity and can improve ink storage stability, and environmentally protective safe and preparation process advantages of simple is easy to large-scale production popularization and application.
Description
Technical field
The present invention relates to a kind of water-based plastic gravure composite printing inks, and in particular to one kind is using plastics as ground, applied to recessed
A kind of novel environment-friendly water-based general compound oil ink of plastic rotogravure of version printing mode.
Background technology
At present, gravure printing ink is very extensive in plastics package sector application, most of for food and day for being related to
The flexible package printing industry of articles for use packaging, most compound oil ink ink can be all used to toluene or esters in production or printing
Non-environmental protection and toxic solvent, not only have an impact to the physical and mental health of worker, on the other hand be not suitable for new environmental protection yet
Regulation and policy.It after new VOC substances discharge standard is put into effect, even more needs to carry out industrial upgrading, reduces or control VOC substances
Discharge.For this purpose, water-based ink comes into being.Water-based ink is the ink using water as solvent, and water is as the advantages of solvent：
It is nontoxic, free from extraneous odour, non-ignitable, and the discharge capacity of VOC is greatly lowered, reduce the pollution to environment.Water-based polyurethane ink
It is one kind of water-based ink, is mainly used in intaglio printing field, not only there is water-based ink safety and environmental protection, Er Qiejian
With excellent wearability and chemical resistance.
Water-based polyurethane ink is mainly using waterborne polyurethane resin as binder, but since waterborne polyurethane resin contains parent
Aqueous group, has the weakness of water resistance inadequate natural endowment, and performance can not match in excellence or beauty with traditional solvent borne polyurethane.In addition, water
Property polyurethane be prepared for non-renewable resources petroleum, how to improve the water resistance of water-based polyurethane ink, Yi Jiti
High renewable resource meets environmentally protective demand for development in the application of water-based polyurethane ink, be those skilled in the art urgently
The technical issues of need to solving.
The content of the invention
Present invention aim to address existing technical deficiency, provide a kind of water resistance preferably, have compared with highly resistance station viscosity
And ink storage stability can be improved, environmentally protective safe and preparation process advantages of simple is easy to large-scale production popularization and application
The general compound oil ink of novel environment-friendly water-based plastic rotogravure.
The technical solution adopted in the present invention is：A kind of general compound oil ink of novel environment-friendly water-based plastic rotogravure, including by
The component of following weight proportion is made：
The modified aqueous polyurethane resin is tung oil-modified water-based polyurethane resin or castor oil modified aqueous poly- ammonia
Ester resin or modification of flax oil waterborne polyurethane resin；
The pigment is carbon black or titanium cyanines indigo plant or paratonere or pigment yellow or titanium dioxide.
A kind of general compound oil ink of novel environment-friendly water-based plastic rotogravure, the preferred weight proportion of component are as follows：
The modified aqueous polyurethane resin is tung oil-modified water-based polyurethane resin or castor oil modified aqueous poly- ammonia
Ester resin or modification of flax oil waterborne polyurethane resin；
The pigment is carbon black or titanium cyanines indigo plant or paratonere or pigment yellow or titanium dioxide.
Preferably, when the pigment is titanium dioxide, the preferred weight proportion of titanium dioxide is 30-33 parts, the preferred weight of water
It matches as 17-25 parts.
Preferably, when the pigment is carbon black or titanium cyanines indigo plant or paratonere or pigment yellow, the preferred weight proportion of pigment is
12-15 parts, the preferred weight proportion of water is 25-35 parts.
Preferably, the carbon black in the pigment is colour black, and the blue titanium cyanines are pigment blue 15:3, the pigment
Red is pigment red 146, and the pigment yellow is pigment Yellow 14, and titanium dioxide is rutile-type.
Preferably, the water is the tap water or purified water of pH neutral values.
The effect of each component of the present invention is：The modified aqueous polyurethane resin of the present invention is plant oil modified aqueous polyurethane
Using plant oil modified waterborne polyurethane resin as main resin, as the main phragmoplast of ink, it is molten to dissolve in a variety of alcohols for resin
Agent and water, viscosity are suitable, dry release property is good, good, chemically and stability is good, under low temperature with other resins or auxiliary agent intermiscibility
Mobility it is very outstanding；Using aqueous vinyl chloride-vinyl acetate resin as assisted resin, there is good intermiscibility with other resins, print can be improved
It brushes the resistance to blocking of film forming, improve the performance of ink system, such as adhesiveness toughness hardness and chemical resistance；With oxypolymer
For adhesive promoter, adhesive force of the ink in printing ground can be improved；Polyethers aqueous defoamer energy suds and defoaming；Water
Property polyethylene wax micro mist can improve ink printing scraper adaptive, reduce scraper and printing plate abrasion, improve printed matter film forming
Resistance to bond；Water soluble silica can improve the resist blocking and that after product forms a film and can improve the storage stability of ink；Ethyl alcohol
The various resins in ink system and auxiliary agent are dissolved, suitable viscosity, control ink system are provided for ink and prints film forming
Smell and improve printing drying.
The present invention has the following advantages compared with prior art：
(1) present invention replaces original waterborne polyurethane resin using the modified aqueous polyurethane resin of vegetable oil, wherein
Tung oil-modified water-based polyurethane resin is prepared by introducing tung oil base on the main chain of aqueous polyurethane, makes linear water
Property polyurethane forms certain cross-linked structure, can improve the water resistance and solvent resistance of aqueous polyurethane.It is castor oil modified aqueous
Polyurethane resin is the three-functionality-degree using castor oil, certain crosslink density is formed in the synthesis of aqueous polyurethane, significantly
Improve the comprehensive performances such as the water-fast of waterborne polyurethane resin, heat resistance.Modification of flax oil waterborne polyurethane resin is equally to utilize
Three double bonds of linseed oil are crosslinked post-modification with aqueous polyurethane, can preferably improve the water resistance of waterborne polyurethane resin and resistance to
Solvent borne.It is main resin using plant oil modified waterborne polyurethane resin, can not only improves water-based plastic gravure composite printing ink
Water resistance and comprehensive performance, simultaneously because tung oil, castor oil and linseed oil are all widely present in nature, also improve life
Substance renewable resource meets environmentally protective demand for development in the application of water-based plastic gravure composite printing ink.
(2) the general compound oil ink of water-based plastic intaglio plate of the invention, without toluene and butanone or esters solvent, and it is low into
This high-performance can be packed in a variety of plastic film printings, be greatly decreased or control the discharge to VOC substances, and versatility is wide
The general compound oil ink of water-based plastic intaglio plate.
(3) the general compound oil ink of water-based plastic intaglio plate of the invention, is with the addition of water-soluble nano silica, can improve production
Product film forming after resist blocking and that and the storage stability of ink can be improved.
Specific embodiment：
To deepen the understanding of the present invention, below in conjunction with case study on implementation, the invention will be further described.The present invention can lead to
Cross following manner implementation：
Embodiment 1
A kind of general compound white ink of novel environment-friendly water-based plastic rotogravure, including the component system by following weight proportion
Into：32 parts of rutile type titanium white, tung oil-modified water-based 33 parts of polyurethane resin, aqueous 12 parts of vinyl chloride-vinyl acetate resin, oxypolymer
0.5 part of reinforcing agent, 0.5 part of aqueous polyethylene wax micro mist, 0.3 part of water-soluble nano silica, polyethers aqueous defoamer
0.01 part, 3 parts of ethyl alcohol, 18.69 parts of water.
Embodiment 2
A kind of general compound white ink of novel environment-friendly water-based plastic rotogravure, including the component system by following weight proportion
Into：15 parts of colour black, castor oil modified 33 parts of waterborne polyurethane resin, aqueous 15 parts of vinyl chloride-vinyl acetate resin, oxypolymer enhancing
0.5 part of agent, 0.6 part of aqueous polyethylene wax micro mist, 0.5 part of water-soluble nano silica, 0.01 part of polyethers aqueous defoamer,
3 parts of ethyl alcohol, 32.39 parts of water.
Embodiment 3
A kind of general compound white ink of novel environment-friendly water-based plastic rotogravure, including the component system by following weight proportion
Into：(pigment blue 15:3) 15 parts, 33 parts of modification of flax oil waterborne polyurethane resin, aqueous 15 parts of vinyl chloride-vinyl acetate resin, oxypolymer
0.5 part of reinforcing agent, 1 part of aqueous polyethylene wax micro mist, 0.5 part of water-soluble nano silica, polyethers aqueous defoamer 0.01
Part, 2.3 parts of ethyl alcohol, 32.69 parts of water.
Embodiment 4
A kind of general compound white ink of novel environment-friendly water-based plastic rotogravure, including the component system by following weight proportion
Into：15 parts of (pigment red 146), 33 parts of modification of flax oil waterborne polyurethane resin, aqueous 15 parts of vinyl chloride-vinyl acetate resin, oxypolymer increase
Strong 0.5 part of agent, 0.8 part of aqueous polyethylene wax micro mist, 0.5 part of water-soluble nano silica, polyethers aqueous defoamer 0.01
Part, 2.5 parts of ethyl alcohol, 32.69 parts of water.
Embodiment 5
A kind of general compound white ink of novel environment-friendly water-based plastic rotogravure, including the component system by following weight proportion
Into：13 parts of (pigment Yellow 14), tung oil-modified water-based 33 parts of polyurethane resin, aqueous 15 parts of vinyl chloride-vinyl acetate resin, oxypolymer enhancing
0.8 part of agent, 0.7 part of aqueous polyethylene wax micro mist, 0.5 part of water-soluble nano silica, 0.01 part of polyethers aqueous defoamer,
2.1 parts of ethyl alcohol, 34.69 parts of water.
Embodiment 6
A kind of general compound white ink of novel environment-friendly water-based plastic rotogravure, including the component system by following weight proportion
Into：30 parts of rutile type titanium white, tung oil-modified water-based 35 parts of polyurethane resin, aqueous 14 parts of vinyl chloride-vinyl acetate resin, oxypolymer
0.7 part of reinforcing agent, 0.5 part of aqueous polyethylene wax micro mist, 0.4 part of water-soluble nano silica, polyethers aqueous defoamer
0.01 part, 3 parts of ethyl alcohol, 16.59 parts of water.
Embodiment 7
A kind of general compound white ink of novel environment-friendly water-based plastic rotogravure, including the component system by following weight proportion
Into：12 parts of colour black, castor oil modified 34 parts of waterborne polyurethane resin, aqueous 15 parts of vinyl chloride-vinyl acetate resin, oxypolymer enhancing
1 part of agent, 1 part of aqueous polyethylene wax micro mist, 0.3 part of water-soluble nano silica, 0.01 part of polyethers aqueous defoamer, ethyl alcohol
3 parts, 33.69 parts of water.
Technological process：The preparation method of the general compound oil ink of novel environment-friendly water-based plastic rotogravure of the various embodiments described above is such as
Under：Use the equipment such as high speed dispersor, sand mill and filter；First part second alcohol and water is put into agitator tank, in low speed
In the case of scattered, plant oil modified waterborne polyurethane resin, aqueous vinyl chloride-vinyl acetate resin and polyethers aqueous defoamer are slowly put into,
It is uniform that speed high speed dispersion is tuned up again, until resin is completely dissolved or is uniformly mixed, then under same mixing speed, puts into face
Material, aqueous polyethylene wax micro mist disperse stirring 30 minutes.The good semi-finished product of dispersion mixing are gone on sand mill afterwards, are ground
After mill two to three times, then with an edition fineness measurement ink fineness is scraped, 3 parallel tests of progress are averaged, and fineness reaches or small
In 15 μm；Turn the remaining ethyl alcohol of next procedure input, water and oxypolymer reinforcing agent again, disperse ten minutes；Reaffirm ink
Fineness, color, gloss and adhesive force are qualified；Filter is turned over, with the filter bag less than 15 μm, press filtration packaging.
The performance of the general compound oil ink of novel environment-friendly water-based plastic rotogravure of each embodiment is obtained by above-mentioned preparation method
Parameter such as following table：
Water resistance test：
Water resistance test uses filter paper osmosis, is as follows：
1. above-mentioned preparation method is obtained into the general compound oil ink of novel environment-friendly water-based plastic rotogravure and the city of each embodiment
Common water-based plastic base gravure ink uniformly scrapes sample when at room temperature dry 24 is small on face；
2. after ten filter paper are completely immersed in water and are seeped water completely, scraping on sample for step 1 is uniformly affixed on, and uses glass plate
It is pressed 24 it is small when.
3. last after the ink specimen page drying of step 1, the number that the discoloration of sample and filter paper are colored is scraped in observation.
Criterion：Water resistance is from difference to 1-5 grade is divided into well, wherein 1 grade of filter paper dyeing 8-9, scrapes sample and seriously change
Become；2 grades of filter paper dyeing 6-7, scrape sample and substantially change；3 grades of filter paper dyeing 4-5, scrape sample and slightly change；4 grades of filter paper dye 2-3
, it scrapes sample and does not change substantially；5 grades of filter paper dyeing 0-1, scrape sample and do not change.
Water resistance test result is as follows：
To sum up, the fineness of the general compound oil ink of novel environment-friendly water-based plastic rotogravure of the invention, viscosity, adhesive force, covering
Power, tinting strength, tinting power comply with the national standard requirements, and water resistance is higher than common water borne base gravure ink on the market, and with ring
It protects and without toluene or butanone solvent, the discharge of VOC substances is greatly reduced, and preparation process is simple, manufacture is at low cost, tool
There is high-performance, be the novel product of light packaging type compound oil ink, be suitble to be widely popularized and apply.
Finally it should be noted that：The foregoing is only a preferred embodiment of the present invention, is not intended to limit the invention,
Within the spirit and principles of the invention, any modifications, equivalent replacements and improvements are made should be included in the present invention's
Within protection domain.
Claims (5)
1. a kind of general compound oil ink of novel environment-friendly water-based plastic rotogravure, which is characterized in that including the group by following weight proportion
Divide and be made：
The modified aqueous polyurethane resin is tung oil-modified water-based polyurethane resin or castor oil modified aqueous polyurethane tree
Fat or modification of flax oil waterborne polyurethane resin；
The pigment is carbon black or titanium cyanines indigo plant or paratonere or pigment yellow or titanium dioxide.
2. a kind of novel environment-friendly water-based general compound oil ink of plastic rotogravure according to claim 1, which is characterized in that including
It is made of the component of following weight proportion：
The modified aqueous polyurethane resin is tung oil-modified water-based polyurethane resin or castor oil modified aqueous polyurethane tree
Fat or modification of flax oil waterborne polyurethane resin；
The pigment is carbon black or titanium cyanines indigo plant or paratonere or pigment yellow or titanium dioxide.
3. a kind of novel environment-friendly water-based general compound oil ink of plastic rotogravure according to claim 1 or 2, which is characterized in that
When the pigment is titanium dioxide, the preferred weight proportion of titanium dioxide is 30-33 parts, and the preferred weight proportion of water is 17-25 parts.
4. a kind of novel environment-friendly water-based general compound oil ink of plastic rotogravure according to claim 1 or 2, which is characterized in that
When the pigment is carbon black or titanium cyanines indigo plant or paratonere or pigment yellow, the preferred weight proportion of pigment is 12-15 parts, and water is preferred
Weight proportion is 25-35 parts.
5. a kind of novel environment-friendly water-based general compound oil ink of plastic rotogravure according to claim 1 or 2, which is characterized in that
The carbon black in the pigment is colour black, and the blue titanium cyanines are pigment blue 15:3, the paratonere is pigment red 146,
The pigment yellow is pigment Yellow 14, and titanium dioxide is rutile-type.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810055417.6A CN108117797A (en) | 2018-01-19 | 2018-01-19 | A kind of general compound oil ink of novel environment-friendly water-based plastic rotogravure |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810055417.6A CN108117797A (en) | 2018-01-19 | 2018-01-19 | A kind of general compound oil ink of novel environment-friendly water-based plastic rotogravure |
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| CN108117797A true CN108117797A (en) | 2018-06-05 |
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Cited By (6)
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|---|---|---|---|---|
| CN108912824A (en) * | 2018-08-06 | 2018-11-30 | 中山市明日涂料材料有限公司 | A kind of antistatic aqueous plastic rotogravure printing ink of novel environment friendly |
| CN112210243A (en) * | 2020-10-13 | 2021-01-12 | 广西建泽环保科技有限公司 | Water-based gravure plastic composite ink |
| TWI718681B (en) * | 2019-09-25 | 2021-02-11 | 南亞塑膠工業股份有限公司 | Aqueous printing ink composition for gravure printing and manufacturing method thereof |
| CN113246626A (en) * | 2021-06-16 | 2021-08-13 | 上海景条印刷有限公司 | Gravure printing process for paper packaging box |
| CN113354980A (en) * | 2021-06-24 | 2021-09-07 | 河南功能高分子膜材料创新中心有限公司 | Universal water-based white ink and preparation method thereof |
| CN114574035A (en) * | 2022-03-21 | 2022-06-03 | 东莞市优特美智能科技有限公司 | 3D ink-jet printing process and ink for aluminum plate for hair straightening rod |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108912824A (en) * | 2018-08-06 | 2018-11-30 | 中山市明日涂料材料有限公司 | A kind of antistatic aqueous plastic rotogravure printing ink of novel environment friendly |
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| CN112210243A (en) * | 2020-10-13 | 2021-01-12 | 广西建泽环保科技有限公司 | Water-based gravure plastic composite ink |
| CN113246626A (en) * | 2021-06-16 | 2021-08-13 | 上海景条印刷有限公司 | Gravure printing process for paper packaging box |
| CN113354980A (en) * | 2021-06-24 | 2021-09-07 | 河南功能高分子膜材料创新中心有限公司 | Universal water-based white ink and preparation method thereof |
| CN114574035A (en) * | 2022-03-21 | 2022-06-03 | 东莞市优特美智能科技有限公司 | 3D ink-jet printing process and ink for aluminum plate for hair straightening rod |
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Application publication date: 20180605 |