CN109021692A - A kind of advertising and printing water-based ink - Google Patents

A kind of advertising and printing water-based ink Download PDF

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Publication number
CN109021692A
CN109021692A CN201811206238.4A CN201811206238A CN109021692A CN 109021692 A CN109021692 A CN 109021692A CN 201811206238 A CN201811206238 A CN 201811206238A CN 109021692 A CN109021692 A CN 109021692A
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CN
China
Prior art keywords
parts
agent
based ink
advertising
printing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201811206238.4A
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Chinese (zh)
Inventor
朱爱林
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Yangzhong Printing Co Ltd
Original Assignee
Jiangsu Yangzhong Printing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu Yangzhong Printing Co Ltd filed Critical Jiangsu Yangzhong Printing Co Ltd
Priority to CN201811206238.4A priority Critical patent/CN109021692A/en
Publication of CN109021692A publication Critical patent/CN109021692A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/106Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D11/107Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

The present invention provides a kind of advertising and printing water-based inks, by weight, comprising: 40-80 parts of acrylic resin, 3-30 parts of organic pigment, 0.5-1 parts of levelling agent, 1-3 parts of emulsifier, 0.1-1 parts of dispersing agent, 0.1-2 parts of auxiliary agent, 5-10 parts of dehydrated alcohol, 5-10 parts of isopropanol, 10-30 parts of deionized water;The acrylic resin is polymerized by one of methyl methacrylate, methacrylic acid-beta-hydroxy ethyl ester, butyl acrylate or various of monomer.The application overcomes solvent-based ink, and surface is easy skinning when not in use, and solvent volatilization easily causes air pollution, using it is dangerous not environmentally the technical issues of, also overcome dry slow of traditional water-based ink, abrasion resistance can poor, the inadequate technical problem of brightness;Unexpected synergistic effect, each ingredient and structure synergistic effect are produced by raw material compounding, so that ink excellent combination property, has good fluidity, clear patterns, colour-fast discoloration after good dispersion, printing, wearability is good, and use is environmentally protective.

Description

A kind of advertising and printing water-based ink
Technical field
The present invention relates to printing material technical fields, and in particular to a kind of advertising and printing water-based ink.
Technical background
Printing industry as industrial important component, used in solvent based coating, traditional ink needs It is diluted processing by organic solvent, not only needs to consume fossil energy, organic solvent also contains a large amount of benzene, toluene, two The poisonous and harmful substances such as toluene, volatilization phase some are up to the more than ten years.In addition, in printing process to the health of worker and around Environment all generates adverse effect, workplace and storage condition, and there is also inflammable and explosive security risks, and production cost is higher.
In today that environmental pollution and production environment increasingly attract people's attention safely, non-toxic ink will instead of traditional ink It is inexorable trend.In numerous environment-friendlyink inks, water-based ink is more promising one kind.Compared with other print ink, The bulk solvent of water-based ink is water, since it is free of volatility toxic organic solvents, cleanliness without any pollution after water volatilization, printing behaviour Author's safe and healthy nonhazardous in use, is a kind of novel printing material of energy-saving and environment friendly, completely eliminates molten The harm of venomous injurant confrontation human body in based ink has safety and environmental protection, nontoxic, non-ignitable relative to solvent-based ink It is not quick-fried, be practically free of the advantages that VOC, in environmentally friendly, healthy, safety have unrivaled advantage, can be used for substituting tradition Solvent-based ink.
Water-based ink can solve current packaging and discharge present in printing industry and dirt because of its excellent environmental-protecting performance It is the problem of dye, receive more and more attention, become the main object studied from now on, meanwhile, its use will also be replaced For traditional solvent-based ink.Water-based ink and its relevant raw materials have clearly been classified as the emphasis of Future Development research by China With the Main way of ink industry development.
As social progress and people are to the awareness and understanding of going deep into of advertising, advertising is rapidly developed, extensively It accuses and has become businessman and the majority of consumers and establish a kind of more convenient and fast mode contacted, and outdoor advertising industry is strong with it Visual impact and competitive cost receive the favor of vast advertisement producer, have at the same time to the quality of advertisement Higher requirement.
Ink is essential a kind of material in advertising and printing, it expresses the pattern and text stock by printing On.The quality of ink performance decides the quality of advertising and printing, and ink in the prior art is broadly divided into solvent type and aqua type, Solvent type ink is although dry fast, but surface is easy skinning when not in use, and solvent volatilization easily causes air pollution, Not environmentally aqua type ink is not easy skinning with dangerous, but dry slow, and heat resistance, glossiness, abrasion resistance can be poor, Brightness is inadequate.
Therefore, a kind of anti-wear is developed to have excellent performance, fast drying, accorded with water-based ink using environmentally protective advertising and printing The market demand is closed, there is extensive market value and application prospect, there is positive effect to the development for promoting advertising sector.
Summary of the invention
In view of the above-mentioned problems in the prior art, the present invention provides a kind of advertising and printing water-based inks.
The following technical solution is employed by the present invention:
A kind of advertising and printing water-based ink, by weight, comprising: 40-80 parts of acrylic resin, organic pigment 3-30 Part, 0.5-1 parts of levelling agent, 1-3 parts of emulsifier, 0.1-1 parts of dispersing agent, 0.1-2 parts of auxiliary agent, 5-10 parts of dehydrated alcohol, isopropanol 5-10 parts, 10-30 parts of deionized water;The acrylic resin is by methyl methacrylate, methacrylic acid-beta-hydroxy ethyl ester, third One of olefin(e) acid butyl ester or various of monomer are polymerized.
Preferably, the organic pigment is to fold azo pigments, fold phthalocyanine color or fold quinacridone pigment.
In above-mentioned technical proposal, organic pigment is the present-color material of water-based ink, and good stability can guarantee oil The persistence of mass colour coloured silk, it is colour-fast for a long time.
Preferably, the levelling agent is polyacrylate flow agent, cellaburate levelling agent or polyvinyl butyral Levelling agent.
Preferably, the emulsifier is phenethyl phenol polyethenoxy ether, ethoxylated dodecyl alcohol, polyoxyethylene oleic acid ester Or polyacrylamide amine emulsifier.
Preferably, the dispersing agent is calgon or polycarboxylate sodium.
Preferably, the auxiliary agent is defoaming agent and pH value stabilizer.
Preferably, the defoaming agent is polyoxyethylene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether or polydimethylsiloxanes Alkane;The pH value stabilizer is triethanolamine buffer or dimethylacetamide amine buffering agent.
In above-mentioned technical proposal, three kinds of defoaming agents are with good performance, and wherein polypropylene glycerol aether can not only press down System and elimination bubble, while the transfer performance of ink also can be improved.
The invention has the advantages that:
Overcoming solvent-based ink, surface is easy skinning when not in use, and solvent volatilization easily causes air pollution, makes With it is dangerous not environmentally the technical issues of, also overcome dry slow of traditional water-based ink, abrasion resistance can be poor, and brightness is inadequate Technical problem;
Unexpected synergistic effect, each ingredient and structure synergistic effect are produced by raw material compounding, so that ink is comprehensive Conjunction is had excellent performance, and has good fluidity, particle uniform and smooth is not stratified, good dispersion, be not easy to be oxidized, quick-drying, adhesion are good, Clear patterns, colour-fast discoloration after printing, wearability is good, and use is environmentally protective;
Using organic pigment, the volatilization of carcinogen is avoided, it is ensured that the health of printing worker;Avoid combustible material Release, ensure that the safety of production environment.
Specific embodiment
The present invention is specifically described below with reference to embodiment:
Embodiment 1
A kind of advertising and printing water-based ink, by weight, comprising: 50 parts of acrylic resin, 15 parts of organic pigment, levelling 0.8 part of agent, 2 parts of emulsifier, 0.8 part of dispersing agent, 1 part of auxiliary agent, 10 parts of dehydrated alcohol, 10 parts of isopropanol, 10 parts of deionized water;Institute Acrylic resin is stated to be formed by methyl methacrylate, methacrylic acid-beta-hydroxy ethyl ester, butyl acrylate.
The organic pigment is to fold azo pigments.The levelling agent is polyacrylate flow agent.The emulsifier is Phenethyl phenol polyethenoxy ether.
The dispersing agent is calgon.The auxiliary agent is defoaming agent and pH value stabilizer;The defoaming agent is polyoxy Ethylene polyoxy propyl alcohol amidogen ether;The pH value stabilizer is the triethanolamine buffer that PH is 8.5.
Embodiment 2
A kind of advertising and printing water-based ink, by weight, comprising: 40 parts of acrylic resin, 3 parts of organic pigment, levelling 0.5 part of agent, 1 part of emulsifier, 0.1 part of dispersing agent, 0.1 part of auxiliary agent, 5 parts of dehydrated alcohol, 5 parts of isopropanol, 30 parts of deionized water;Institute Acrylic resin is stated to be formed by methyl methacrylate polymerization.
The organic pigment is to fold phthalocyanine color.The levelling agent is cellaburate levelling agent.The emulsifier is Ethoxylated dodecyl alcohol.
The dispersing agent is polycarboxylate sodium.The auxiliary agent is defoaming agent and pH value stabilizer;The defoaming agent is polyoxy Propylene glycerin ether;The pH value stabilizer is dimethylacetamide amine buffering agent.
Embodiment 3
A kind of advertising and printing water-based ink, by weight, comprising: 80 parts of acrylic resin, 30 parts of organic pigment, levelling 1 part of agent, 3 parts of emulsifier, 1 part of dispersing agent, 2 parts of auxiliary agent, 10 parts of dehydrated alcohol, 10 parts of isopropanol, 10 parts of deionized water;Described third Olefin(e) acid resin is formed by methacrylic acid-beta-hydroxy ethyl ester and butyl acrylate.
The organic pigment is to fold quinacridone pigment.The levelling agent is polyvinyl butyral levelling agent.It is described Emulsifier is polyoxyethylene oleic acid ester.
The dispersing agent is polycarboxylate sodium.The auxiliary agent is defoaming agent and pH value stabilizer;The defoaming agent is poly- two Methylsiloxane;The pH value stabilizer is dimethylacetamide amine buffering agent.
Embodiment 4
A kind of advertising and printing water-based ink, by weight, comprising: 60 parts of acrylic resin, 5 parts of organic pigment, levelling 0.5 part of agent, 1 part of emulsifier, 0.8 part of dispersing agent, 0.1 part of auxiliary agent, 8 parts of dehydrated alcohol, 8 parts of isopropanol, 20 parts of deionized water;Institute Acrylic resin is stated to be formed by methyl methacrylate and butyl acrylate.
The organic pigment is to fold phthalocyanine color.The levelling agent is polyacrylate flow agent.The emulsifier is Polyacrylamide amine emulsifier.
The dispersing agent is polycarboxylate sodium.The auxiliary agent is defoaming agent and pH value stabilizer;The defoaming agent is poly- two Methylsiloxane;The pH value stabilizer is triethanolamine buffer.
Certainly, the above description is not a limitation of the present invention, and the present invention is also not limited to the example above, this technology neck The variations, modifications, additions or substitutions that the technical staff in domain is made within the essential scope of the present invention also should belong to of the invention Protection scope.

Claims (7)

1. a kind of advertising and printing water-based ink, which is characterized in that by weight, comprising:
40-80 parts of acrylic resin, 3-30 parts of organic pigment, 0.5-1 parts of levelling agent, 1-3 parts of emulsifier, 0.1-1 parts of dispersing agent, 0.1-2 parts of auxiliary agent, 5-10 parts of dehydrated alcohol, 5-10 parts of isopropanol, 10-30 parts of deionized water;The acrylic resin is by methyl One of methyl acrylate, methacrylic acid-beta-hydroxy ethyl ester, butyl acrylate or various of monomer are polymerized.
2. a kind of advertising and printing water-based ink according to claim 1, which is characterized in that the organic pigment is to fold Azo pigments folds phthalocyanine color or folds quinacridone pigment.
3. a kind of advertising and printing water-based ink according to claim 1, which is characterized in that the levelling agent is polypropylene Acid esters levelling agent, cellaburate levelling agent or polyvinyl butyral levelling agent.
4. a kind of advertising and printing water-based ink according to claim 1, which is characterized in that the emulsifier is phenethyl Phenol polyethenoxy ether, ethoxylated dodecyl alcohol, polyoxyethylene oleic acid ester or polyacrylamide amine emulsifier.
5. a kind of advertising and printing water-based ink according to claim 1, which is characterized in that the dispersing agent is six inclined phosphorus Sour sodium or polycarboxylate sodium.
6. a kind of advertising and printing water-based ink according to claim 1, which is characterized in that the auxiliary agent be defoaming agent and PH value stabilizer.
7. a kind of advertising and printing water-based ink according to claim 6, which is characterized in that the defoaming agent is polyoxy second Alkene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether or dimethyl silicone polymer;
The pH value stabilizer is triethanolamine buffer or dimethylacetamide amine buffering agent.
CN201811206238.4A 2018-10-17 2018-10-17 A kind of advertising and printing water-based ink Withdrawn CN109021692A (en)

Priority Applications (1)

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CN201811206238.4A CN109021692A (en) 2018-10-17 2018-10-17 A kind of advertising and printing water-based ink

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811206238.4A CN109021692A (en) 2018-10-17 2018-10-17 A kind of advertising and printing water-based ink

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114045067A (en) * 2021-12-16 2022-02-15 中山市中益油墨涂料有限公司 Four-color ink for water-based gravure cigarette packet and preparation method thereof
CN115785733A (en) * 2022-11-17 2023-03-14 怀化天马隆旭印务有限公司 Water-based acrylate ink composition and preparation method and application thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114045067A (en) * 2021-12-16 2022-02-15 中山市中益油墨涂料有限公司 Four-color ink for water-based gravure cigarette packet and preparation method thereof
CN115785733A (en) * 2022-11-17 2023-03-14 怀化天马隆旭印务有限公司 Water-based acrylate ink composition and preparation method and application thereof
CN115785733B (en) * 2022-11-17 2023-10-31 怀化天马隆旭印务有限公司 Water-based acrylic ester ink composition and preparation method and application thereof

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Application publication date: 20181218