CN109266093A - A kind of aqueous soluble protection ink - Google Patents
A kind of aqueous soluble protection ink Download PDFInfo
- Publication number
- CN109266093A CN109266093A CN201710565587.4A CN201710565587A CN109266093A CN 109266093 A CN109266093 A CN 109266093A CN 201710565587 A CN201710565587 A CN 201710565587A CN 109266093 A CN109266093 A CN 109266093A
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- CN
- China
- Prior art keywords
- parts
- protection ink
- film
- ink
- protection
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to a kind of aqueous solubles to protect ink, includes 70~80 parts of sulphonic resin, 8~15 parts of filler, 5~12 parts of auxiliary agent according to protection ink described in mass parts meter.The protection ink film-forming temperature is low, and can quickly move back film in aqueous solution, and residual rate is low；High temperature resistant after film forming, and do not dissolve in other organic solvents；Achievable form a film moves back the mechanized operation of film, saves labour turnover；Pollution-free, zero-emission is environmental-friendly.
Description
Technical field
The invention belongs to ink material fields, are related to a kind of protection ink, are specifically designed a kind of aqueous soluble protection ink.
Background technique
Oily field is being protected, there are various protection oil, but at present on the market mainly with aqueous and oiliness protection oil.
Aqueous protection oil is few on the market at present, and oiliness has blue glue, PE film etc., in contrast, aqueous more environmentally friendly, nothing
Pollution, worker operation are safer.And it is all the stripping film to form a film that the type of film, which is even more most of in current city, although stripping film
Be current main way, but there is removing to bother during operation, need to consume artificial process, and at present manually at
This is more expensive.
106366759 A of CN discloses a kind of hydrolyzable type glass protection ink and the preparation method and application thereof, including with
The raw material of lower mass parts: 40-45 parts of water-based acrylic resin, 25-30 parts of aqueous polyester resin, 7-12 parts of lagoriolite, swelling
It is 2.5-3 parts native, 1-1.5 parts of defoaming agent, 1-1.5 parts of levelling agent, 12-18.5 parts of water.Ink raw materials of the present invention are simple, nontoxic, oily
Black pH value is substantially in neutrality within the scope of 7-7.5, corrosion-free to halftone and construction personnel.But the protection ink need to be
Toasting at 150 DEG C can just form a film, and film build method energy consumption is high.
102786839 A of CN discloses a kind of glass protection ink and preparation method thereof, include by weight percentage with
Lower component: polyurethane acrylic resin 10%~30%；Epoxy acrylic resin 5%~30%；Phenolic resin 5%~40%；
Acrylic monomers 20%~50%；Initiator 2%~10%；Adhesion promoter 1%~5%；Thixotropic agent 1%~5%；Dispersion
Agent 0.5%~2%；Surfactant 0.2%~4%；Pigment 1%~5% and filler 10%~30%.The glass protection
Ink is functional to glass protection, demoulding is easy and easy to operate.But the ink film forming needs high-temperature baking, and moves back
Film need to carry out in alkaline solution, and the feature of environmental protection is poor.
Summary of the invention
In order to solve the above technical problems, the present invention provides a kind of aqueous soluble protection ink, the protection ink film forming temperature
It spends low, and can quickly move back film in aqueous solution, residual rate is low；High temperature resistant after film forming, and do not dissolve in other organic solvents；It can be achieved
Film forming moves back the mechanized operation of film, saves labour turnover；Pollution-free, zero-emission is environmental-friendly.
In order to achieve the above objectives, the invention adopts the following technical scheme:
The present invention provides a kind of aqueous soluble protection ink, which is characterized in that according to protection ink packet described in mass parts meter
Include following components:
70~80 parts of sulphonic resin；
8~15 parts of filler；
5~12 parts of auxiliary agent.
Wherein, the mass parts of sulphonic resin can be 70 parts, 71 parts, 72 parts, 73 parts, 74 parts, 75 parts, 76 parts, 77 parts, 78
Part, 79 parts or 80 parts etc.；The mass parts of filler can be 8 parts, 9 parts, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts or 15 parts etc.；It helps
The mass parts of agent can be 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts or 12 parts etc., it is not limited to cited number
Value, other interior unlisted numerical value of above-mentioned each numberical range are equally applicable.
Include following components according to protection ink described in mass parts meter as currently preferred technical solution:
72~78 parts of sulphonic resin；
10~12 parts of filler；
8~10 parts of auxiliary agent.
Include following components according to protection ink described in mass parts meter as currently preferred technical solution:
75 parts of sulphonic resin；
11 parts of filler；
9 parts of auxiliary agent.
As currently preferred technical solution, the sulphonic resin is that company of Japanese Goo Chemical Co., Ltd. mentions
The Z-221 resin of confession.
Wherein, the major parameter of Z-221 resin is solid content 20%, viscosity 5mPas, pH 4.5~6.5.
As currently preferred technical solution, the filler is kaolin.
It include: silica according to kaolinic component described in mass fraction meter as currently preferred technical solution
52%~56%, aluminum oxide 43~47%, surplus is water.
Wherein, the mass fraction of the silica can be 52%, 52.5%, 53%, 53.5%, 54%, 54.5%,
55%, 55.5% or 56% etc., the mass fraction of the aluminum oxide can be 43%, 43.5%, 44%, 44.5%,
45%, 45.5%, 46%, 46.5% or 47% etc., it is not limited to cited numerical value, in above-mentioned each numberical range other
Unlisted numerical value is equally applicable.
Wherein, kaolinic other parameters are whiteness: greater than 91, granularity: 92% less than 2 μm, and 325 screen residues: less than
0.005%, oil factor: 50~65g/100g, PH:6~8.
As currently preferred technical solution, the auxiliary agent includes defoaming agent and levelling agent.
As currently preferred technical solution, the mass parts of the defoaming agent are 1~2 part, such as 1 part, 1.1 parts, 1.2
Part, 1.3 parts, 1.4 parts, 1.5 parts, 1.6 parts, 1.7 parts, 1.8 parts, 1.9 parts or 2 parts etc., it is not limited to cited numerical value,
Other unlisted numerical value are equally applicable in the numberical range.
Preferably, the mass parts of the levelling agent are 4~10 parts, such as 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7
Part, 7.5 parts, 8 parts, 8.5 parts, 9 parts, 9.5 parts or 10 parts etc., it is not limited to cited numerical value, in the numberical range its
His unlisted numerical value is equally applicable.
As currently preferred technical solution, the defoaming agent is polyether-modified dimethyl silicone polymer.
Wherein, the parameter of polyether-modified dimethyl silicone polymer is solid content 96%, and density 1g/mL, flash-point is greater than 100.
As currently preferred technical solution, the levelling agent is polyhydroxycarboxylicacid amides.
Wherein, the parameter of polyhydroxycarboxylicacid amides is solid content 52%, density 0.93g/mL, flash-point 29.
Compared with prior art, the present invention at least has the advantages that
(1) a kind of aqueous soluble provided by the invention protects ink, and the protection ink film-forming temperature is low, and film-forming temperature is low
In 55 DEG C, and film can be quickly moved back in aqueous solution, residual rate is only 0.015%；
(2) a kind of aqueous soluble provided by the invention protects ink, high temperature resistant after the protection ink film forming, and does not dissolve in
Other organic solvents；
(3) a kind of aqueous soluble provided by the invention protects ink, and the protection ink can realize that film forming moves back the machinery of film
Change operation, saves labour turnover；
(4) a kind of aqueous soluble provided by the invention protects ink, and the protection ink is pollution-free, zero-emission, environment friend
It is good.
Specific embodiment
Of the invention for ease of understanding, it is as follows that the present invention enumerates embodiment.Those skilled in the art are it will be clearly understood that the implementation
Example is only to aid in the understanding present invention, should not be regarded as a specific limitation of the invention.
Embodiment 1
A kind of aqueous soluble protection ink, the protection ink includes following components in parts by weight:
Wherein, it is divided into silica 52%, aluminum oxide 47% and water 1% for kaolinic group.
Embodiment 2
A kind of aqueous soluble protection ink, the protection ink includes following components in parts by weight:
Wherein, it is divided into silica 56%, aluminum oxide 43% and water 1% for kaolinic group.
Embodiment 3
A kind of aqueous soluble protection ink, the protection ink includes following components in parts by weight:
Wherein, it is divided into silica 54.5%, aluminum oxide 45% and water 0.5% for kaolinic group.
Embodiment 4
A kind of aqueous soluble protection ink, the protection ink includes following components in parts by weight:
Wherein, it is divided into silica 54%, aluminum oxide 45.5% and water 0.5% for kaolinic group.
Embodiment 5
A kind of aqueous soluble protection ink, the protection ink includes following components in parts by weight:
Wherein, it is divided into silica 55%, aluminum oxide 44.5% and water 0.5% for kaolinic group.
Embodiment 6
A kind of glass protection ink is divided into silica 50%, aluminum oxide 40% and water in addition to kaolinic group
Outside 10%, other conditions are same as Example 5.
Embodiment 7
A kind of glass protection ink is divided into silica 60%, aluminum oxide 30% and water in addition to kaolinic group
Outside 10%, other conditions are same as Example 5.
Comparative example 1
A kind of glass protection ink, the protection ink includes following components in parts by weight:
Comparative example 2
A kind of aqueous soluble protection ink, the protection ink includes following components in parts by weight:
Wherein, it is divided into silica 55%, aluminum oxide 44.5% and water 0.5% for kaolinic group.
Comparative example 3
A kind of aqueous soluble protection ink, the protection ink includes following components in parts by weight:
Wherein, it is divided into silica 55%, aluminum oxide 44.5% and water 0.5% for kaolinic group.
To the film-forming temperature of embodiment 1-7 and comparative example 1-3, residual rate and heat-resisting quantity after moving back film can be carried out survey
Examination, the results are shown in Table 1.
Wherein, the ink gross mass that the residual quantity that film residual rate is glass surface ink after moving back film accounts for glass surface coating is moved back
Percentage.
Wherein, high temperature resistance is time for not falling off after the protection ink forms a film at 200 DEG C.
Table 1
| Project | Film-forming temperature/DEG C | Residual rate | High temperature resistance/h |
| Embodiment 1 | 50 | 0.010% | 12 |
| Embodiment 2 | 52 | 0.015% | 12 |
| Embodiment 3 | 55 | 0.013% | 12 |
| Embodiment 4 | 53 | 0.015% | 12 |
| Embodiment 5 | 52 | 0.012% | 12 |
| Embodiment 6 | 54 | 0.012% | 12 |
| Embodiment 7 | 55 | 0.011% | 12 |
| Comparative example 1 | 183 | 2% | 2 |
| Comparative example 2 | 156 | 0.025% | 3 |
| Comparative example 3 | 60 | 0.11% | 12 |
As it can be seen from table 1 the aqueous soluble that embodiment 1-7 is provided protects the film-forming temperature of ink at 50~55 DEG C, and
Residual rate is between 0.010%~0.015%, and 12h is not fallen off at 200 DEG C.And comparative example 1 does not use sulfo group tree
Rouge, film-forming temperature is up to 183 DEG C, and residual rate is 2%, and 2h can only be kept at 200 DEG C, and overall performance and embodiment 1-7 are provided
Aqueous soluble protection ink performance gap it is larger.And the mass parts of sulphonic resin are respectively smaller than or are greater than in comparative example 2 and 3
Defined numerical value, the film-forming temperature of comparative example 2 is up to 156 DEG C, and 3h can only be kept at 200 DEG C, and the residual rate of comparative example 3 is
0.11%.
The Applicant declares that the present invention is explained by the above embodiments detailed process equipment and process flow of the invention,
But the present invention is not limited to the above detailed process equipment and process flow, that is, it is above-mentioned detailed not mean that the present invention must rely on
Process equipment and process flow could be implemented.It should be clear to those skilled in the art, any improvement in the present invention,
Addition, selection of concrete mode of equivalence replacement and auxiliary element to each raw material of product of the present invention etc., all fall within of the invention
Within protection scope and the open scope.
Claims (10)
1. a kind of aqueous soluble protects ink, which is characterized in that according to protection ink described in mass parts meter include following components:
70~80 parts of sulphonic resin；
8~15 parts of filler；
5~12 parts of auxiliary agent.
2. protection ink according to claim 1, which is characterized in that according to described in mass parts meter protection ink include following
Component:
72~78 parts of sulphonic resin；
10~12 parts of filler；
8~10 parts of auxiliary agent.
3. protection ink according to claim 1 or 2, which is characterized in that include according to protection ink described in mass parts meter
Following components:
75 parts of sulphonic resin；
11 parts of filler；
9 parts of auxiliary agent.
4. protection ink according to claim 1-3, which is characterized in that the sulphonic resin is Japanese mutual induction
Learn the Z-221 resin that company of Industrial Co., Ltd provides.
5. protection ink according to claim 1-4, which is characterized in that the filler is kaolin.
6. protection ink according to claim 5, which is characterized in that according to kaolinic group of subpackage described in mass fraction meter
Include: silica 52%~56%, aluminum oxide 43~47%, surplus are water.
7. protection ink according to claims 1 to 6, which is characterized in that the auxiliary agent includes defoaming agent and levelling agent.
8. according to the described in any item protection ink of claim 7, which is characterized in that the mass parts of the defoaming agent are 1~2
Part；
Preferably, the mass parts of the levelling agent are 4~10 parts.
9. protection ink according to claim 7 or 8, which is characterized in that the defoaming agent is polyether-modified poly dimethyl
Siloxanes.
10. according to the described in any item protection ink of claim 7-9, which is characterized in that the levelling agent is polyhydroxycarboxyliacid acid
Amide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710565587.4A CN109266093A (en) | 2017-07-12 | 2017-07-12 | A kind of aqueous soluble protection ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710565587.4A CN109266093A (en) | 2017-07-12 | 2017-07-12 | A kind of aqueous soluble protection ink |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109266093A true CN109266093A (en) | 2019-01-25 |
Family
ID=65147638
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710565587.4A Pending CN109266093A (en) | 2017-07-12 | 2017-07-12 | A kind of aqueous soluble protection ink |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112694803A (en) * | 2020-12-31 | 2021-04-23 | 江西赐彩新材料股份有限公司 | Anti-collision water-based liquid film capable of being automatically implemented and removed |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5913972A (en) * | 1996-04-22 | 1999-06-22 | Dainichiseika Color & Chemicals Mfg. Co., Ltd. | Aqueous pigment dispersion, water-soluble resin, production process of the resin, and equipment suitable for use with the dispersion |
| CN101333355A (en) * | 2008-07-07 | 2008-12-31 | 一可油墨涂料（深圳）有限公司 | Strippable water-soluble silk screen ink for temporary protection |
| CN102786839A (en) * | 2012-07-31 | 2012-11-21 | 佛山市三求电子材料有限公司 | Glass protecting ink and preparation method thereof |
| JP2013107952A (en) * | 2011-11-18 | 2013-06-06 | Toyo Ink Sc Holdings Co Ltd | Water-based pigment ink for inkjet |
| CN104788626A (en) * | 2015-03-31 | 2015-07-22 | 中科院广州化学有限公司 | Hydrothermal sensitive modified epoxy acrylate as well as preparation method and application thereof |
| CN105038401A (en) * | 2015-08-14 | 2015-11-11 | 华南理工大学 | Washable touch screen temporary protection ink as well as preparation method and application thereof |
| CN105462461A (en) * | 2014-09-30 | 2016-04-06 | 株式会社尼欧斯 | Waterborne primer composition for peeling coating and coating peeling method |
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2017
- 2017-07-12 CN CN201710565587.4A patent/CN109266093A/en active Pending
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|---|---|---|---|---|
| US5913972A (en) * | 1996-04-22 | 1999-06-22 | Dainichiseika Color & Chemicals Mfg. Co., Ltd. | Aqueous pigment dispersion, water-soluble resin, production process of the resin, and equipment suitable for use with the dispersion |
| CN101333355A (en) * | 2008-07-07 | 2008-12-31 | 一可油墨涂料（深圳）有限公司 | Strippable water-soluble silk screen ink for temporary protection |
| JP2013107952A (en) * | 2011-11-18 | 2013-06-06 | Toyo Ink Sc Holdings Co Ltd | Water-based pigment ink for inkjet |
| CN102786839A (en) * | 2012-07-31 | 2012-11-21 | 佛山市三求电子材料有限公司 | Glass protecting ink and preparation method thereof |
| CN105462461A (en) * | 2014-09-30 | 2016-04-06 | 株式会社尼欧斯 | Waterborne primer composition for peeling coating and coating peeling method |
| CN104788626A (en) * | 2015-03-31 | 2015-07-22 | 中科院广州化学有限公司 | Hydrothermal sensitive modified epoxy acrylate as well as preparation method and application thereof |
| CN105038401A (en) * | 2015-08-14 | 2015-11-11 | 华南理工大学 | Washable touch screen temporary protection ink as well as preparation method and application thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112694803A (en) * | 2020-12-31 | 2021-04-23 | 江西赐彩新材料股份有限公司 | Anti-collision water-based liquid film capable of being automatically implemented and removed |
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| PB01 | Publication | ||
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Application publication date: 20190125 |