CN105419638A - Paint containing photo-induced energy-storage luminous powder - Google Patents
Paint containing photo-induced energy-storage luminous powder Download PDFInfo
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- CN105419638A CN105419638A CN201510998899.5A CN201510998899A CN105419638A CN 105419638 A CN105419638 A CN 105419638A CN 201510998899 A CN201510998899 A CN 201510998899A CN 105419638 A CN105419638 A CN 105419638A
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D191/00—Coating compositions based on oils, fats or waxes; Coating compositions based on derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/22—Luminous paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Paints Or Removers (AREA)
Abstract
The invention relates to a chemical industrial product, and especially relates to a paint containing photo-induced energy-storage luminous powder. The paint containing the photo-induced energy-storage luminous powder comprises the following components by weight ratio: 5-5.5% of barium sulfide, 3-4% of magnesium sulfide, 1.5-2.2% of aluminum sulfide, 2-3% of potassium nitrate, 20-30% of tung oil, 10-16% of epoxy resin, 5-11% of acrylonitrile, 3-6% of modified alkyd resin, 5-8% of methacrylic resin, 0.5-1% of turpentine, 1-3% of a propylene pigment, 3-6% of a photoinitiator, 5-10% of polyvinyl butyral, 3-5% of an antifoaming agent and the balance of a thinner. The paint containing the photo-induced energy-storage luminous powder has the advantages of strong covering power, good gloss retention, color retention and weatherability, and fast drying speed; can absorb yellow light emitted under dark environment, and can be used for objects such as guideboards, outdoor advertisements, night roads and obstacle marks.
Description
Technical field
The present invention relates to a kind of chemical industries, especially a kind of paint containing photo-induced energy storage luminescent powder.
Background technology
Coating is a kind of material, and this material can be coated in article surface by different construction technologies, forms adhere well, has some strength, continuous print solid film.The film common name film of such formation, also known as paint film or coating.Belong to organic chemical industry's macromolecular material, the film formed belongs to macromolecular compound type.The classification of the Chemicals of passing through according to the modern times, coating belongs to fine chemical product.Modern coating is progressively becoming the polyfunctional engineering materials of a class, is an important industry in chemical industry.
Existing paint rate of drying is slow, affects production efficiency.
Summary of the invention
The present invention is intended to solve the problems of the technologies described above, provide a kind of paint containing photo-induced energy storage luminescent powder, its strong covering power, gloss retention, tint retention and good weatherability, rate of drying is fast, gold-tinted can be sent by extinction under dark surrounds, can be used for guideboard and outdoor advertising and night road and the object such as obstacle marking, its technical scheme adopted is as follows:
A kind of paint containing photo-induced energy storage luminescent powder, it is characterized in that: its composition weight proportioning is: the barium sulphide of 5 ~ 5.5%, the magnesium sulfide of 3 ~ 4%, the aluminium sulfide of 1.5 ~ 2.2%, saltpetre, tung oil 20 ~ 30%, epoxy resin 10 ~ 16%, vinyl cyanide 5 ~ 11%, modified alkyd resin 3 ~ 6%, methacrylic resin 5 ~ 8%, turps 0.5 ~ 1%, acrylic paints 1 ~ 3%, light trigger 3 ~ 6%, polyvinyl butyral acetal 5 ~ 10%, the defoamer 3 ~ 5% of 2 ~ 3%, all the other are solvent or diluent.
On technique scheme basis, described short chain fatty acid is cocinic acid, laurostearic acid or sad, and described octadecane alkene vegetable oil acid is soy(a)-bean oil fatty acid, cotton oil lipid acid, linseed oil fatty acid.
On technique scheme basis, described palm wax ester is palm grease, palm-kernel ester or palm olein ester.
On technique scheme basis, described light trigger is the luxuriant iron hexafluorophosphate of diaryl group iodized salt, triaryl salt compounded of iodine, alkyl salt compounded of iodine or isopropyl benzene.
On technique scheme basis, the preparation method of described modified alkyd resin, it comprises the following steps: a) by 8 ~ 12 parts, the lipid acid of short chain, terephthalic acid 2 ~ 4 parts, octadecane alkene vegetable oil acid 6 ~ 10 parts, monopentaerythritol 10 ~ 15 parts, phthalic anhydride 23 ~ 28 parts, glycerine 1 ~ 4 part, dibasic alcohol 6 ~ 10 parts, agent 0.05 ~ 0.2 part of losing lustre, dimethylbenzene 3 ~ 6 parts of input reactors, be uniformly mixed;
B) in reactor, pass into nitrogen or carbon-dioxide protecting gas, oxygen in removing reactor, is then warming up to 180 ~ 190 degree, and insulation esterification 3 ~ 4 hours, is then warming up to 190 degree ~ 210 degree and carries out esterification;
C) be cooled to 160 ~ 170 degree, add latting drown aromatic solvent 20 ~ 25 parts, continue to be cooled to 75 ~ 85 degree, add latting drown low boiling ester kind solvent 4 ~ 8 parts, filter and obtain modification.
Tool of the present invention has the following advantages: strong covering power, gloss retention, tint retention and good weatherability, and rate of drying is fast, can send gold-tinted by extinction under dark surrounds, can be used for guideboard and outdoor advertising and night road and the object such as obstacle marking.
Embodiment
Embodiment 1
A kind of paint containing photo-induced energy storage luminescent powder, it is characterized in that: its composition weight proportioning is: the barium sulphide of 5%, the magnesium sulfide of 3%, the aluminium sulfide of 2%, the saltpetre of 3%, tung oil 30%, epoxy resin 16%, vinyl cyanide 11%, modified alkyd resin 6%, methacrylic resin 8%, turps 1%, acrylic paints 3%, light trigger 6%, polyvinyl butyral acetal 10%, defoamer 5%, all the other are solvent or diluent, the preparation method of described modified alkyd resin, it comprises the following steps: a) by 12 parts, the lipid acid of short chain, terephthalic acid 4 parts, octadecane alkene vegetable oil acid 10 parts, monopentaerythritol 15 parts, phthalic anhydride 28 parts, glycerine 4 parts, dibasic alcohol 10 parts, to lose lustre agent 0.2 part, in dimethylbenzene 6 parts of input reactors, be uniformly mixed,
B) in reactor, pass into nitrogen or carbon-dioxide protecting gas, oxygen in removing reactor, is then warming up to 180 ~ 190 degree, and insulation esterification 3 ~ 4 hours, is then warming up to 190 degree ~ 210 degree and carries out esterification;
C) be cooled to 160 ~ 170 degree, add latting drown aromatic solvent 25 parts, continue to be cooled to 75 ~ 85 degree, add latting drown low boiling ester kind solvent 8 parts, filter and obtain modification.
Preferably, described short chain fatty acid is cocinic acid, laurostearic acid or sad, and described octadecane alkene vegetable oil acid is soy(a)-bean oil fatty acid, cotton oil lipid acid, linseed oil fatty acid.Preferably, described palm wax ester is palm grease, and described light trigger is diaryl group iodized salt, and described latting drown low boiling ester kind solvent is vinyl acetic monomer.
Embodiment 2
A kind of paint containing photo-induced energy storage luminescent powder, it is characterized in that: its composition weight proportioning is: the barium sulphide of 5.5%, the magnesium sulfide of 3%, the aluminium sulfide of 2.2%, the saltpetre of 2%, tung oil 20%, epoxy resin 10%, vinyl cyanide 5%, modified alkyd resin 3%, methacrylic resin 5%, turps 0.5%, acrylic paints 1 ~ 3%, light trigger 3%, polyvinyl butyral acetal 5%, defoamer 3%, all the other are solvent or diluent, the preparation method of described modified alkyd resin, it comprises the following steps: a) by 8 parts, the lipid acid of short chain, terephthalic acid 2 parts, octadecane alkene vegetable oil acid 6 parts, monopentaerythritol 10 parts, phthalic anhydride 23 parts, glycerine 1 part, dibasic alcohol 6 parts, to lose lustre agent 0.05 part, in dimethylbenzene 3 parts of input reactors, be uniformly mixed,
B) in reactor, pass into nitrogen or carbon-dioxide protecting gas, oxygen in removing reactor, is then warming up to 180 degree, and insulation esterification 3 ~ 4 hours, is then warming up to 190 degree ~ 210 degree and carries out esterification;
C) be cooled to 160 ~ 170 degree, add latting drown aromatic solvent 20 parts, continue to be cooled to 75 ~ 85 degree, add latting drown low boiling ester kind solvent 4 parts, filter and obtain modification.
Preferably, described short chain fatty acid is cocinic acid, laurostearic acid or sad, and described octadecane alkene vegetable oil acid is soy(a)-bean oil fatty acid, cotton oil lipid acid, linseed oil fatty acid.Preferably, described palm wax ester is palm-kernel ester, and described light trigger is the luxuriant iron hexafluorophosphate of isopropyl benzene.
Embodiment 3
A kind of paint containing photo-induced energy storage luminescent powder, it is characterized in that: its composition weight proportioning is: the barium sulphide of 5%, the magnesium sulfide of 4%, the aluminium sulfide of 2%, the saltpetre tung oil 28% of 2.5%, epoxy resin 15%, vinyl cyanide 12%, modified alkyd resin 8%, methacrylic resin 9%, turps 2%, acrylic paints 3%, light trigger 6%, polyvinyl butyral acetal 10%, defoamer 5%, all the other are solvent or diluent, the preparation method of described modified alkyd resin, it comprises the following steps: a) by 12 parts, the lipid acid of short chain, terephthalic acid 4 parts, octadecane alkene vegetable oil acid 10 parts, monopentaerythritol 15 parts, phthalic anhydride 28 parts, glycerine 4 parts, dibasic alcohol 10 parts, to lose lustre agent 0.5 part, in dimethylbenzene 6 parts of input reactors, be uniformly mixed,
B) in reactor, pass into nitrogen or carbon-dioxide protecting gas, oxygen in removing reactor, is then warming up to 180 ~ 190 degree, and insulation esterification 3 ~ 4 hours, is then warming up to 190 degree ~ 210 degree and carries out esterification;
C) be cooled to 160 ~ 170 degree, add latting drown aromatic solvent 30 parts, continue to be cooled to 75 ~ 85 degree, add latting drown low boiling ester kind solvent 10 parts, filter and obtain modification.
Preferably, described short chain fatty acid is cocinic acid, laurostearic acid or sad, and described octadecane alkene vegetable oil acid is soy(a)-bean oil fatty acid, cotton oil lipid acid, linseed oil fatty acid.Preferably, described palm wax ester is palm grease, and described light trigger is diaryl group iodized salt.
Describe the present invention by way of example above, but the invention is not restricted to above-mentioned specific embodiment, all any changes of doing based on the present invention or modification all belong to the scope of protection of present invention.
Claims (5)
1. the paint containing photo-induced energy storage luminescent powder, it is characterized in that: its composition weight proportioning is: the barium sulphide of 5 ~ 5.5%, the magnesium sulfide of 3 ~ 4%, the aluminium sulfide of 1.5 ~ 2.2%, saltpetre, tung oil 20 ~ 30%, epoxy resin 10 ~ 16%, vinyl cyanide 5 ~ 11%, modified alkyd resin 3 ~ 6%, methacrylic resin 5 ~ 8%, turps 0.5 ~ 1%, acrylic paints 1 ~ 3%, light trigger 3 ~ 6%, polyvinyl butyral acetal 5 ~ 10%, the defoamer 3 ~ 5% of 2 ~ 3%, all the other are solvent or diluent.
2. a kind of paint containing photo-induced energy storage luminescent powder according to claim 1, it is characterized in that, described short chain fatty acid is cocinic acid, laurostearic acid or sad, and described octadecane alkene vegetable oil acid is soy(a)-bean oil fatty acid, cotton oil lipid acid, linseed oil fatty acid.
3. a kind of paint containing photo-induced energy storage luminescent powder according to claim 2, is characterized in that: described palm wax ester is palm grease, palm-kernel ester or palm olein ester.
4. a kind of paint containing photo-induced energy storage luminescent powder according to claim 1, is characterized in that: described light trigger is the luxuriant iron hexafluorophosphate of diaryl group iodized salt, triaryl salt compounded of iodine, alkyl salt compounded of iodine or isopropyl benzene.
5. according to a kind of paint containing photo-induced energy storage luminescent powder according to claim 1, it is characterized in that: the preparation method of described modified alkyd resin, it comprises the following steps: a) by 8 ~ 12 parts, the lipid acid of short chain, terephthalic acid 2 ~ 4 parts, octadecane alkene vegetable oil acid 6 ~ 10 parts, monopentaerythritol 10 ~ 15 parts, phthalic anhydride 23 ~ 28 parts, glycerine 1 ~ 4 part, dibasic alcohol 6 ~ 10 parts, agent 0.05 ~ 0.2 part of losing lustre, dimethylbenzene 3 ~ 6 parts of input reactors, be uniformly mixed;
B) in reactor, pass into nitrogen or carbon-dioxide protecting gas, oxygen in removing reactor, is then warming up to 180 ~ 190 degree, and insulation esterification 3 ~ 4 hours, is then warming up to 190 degree ~ 210 degree and carries out esterification;
C) be cooled to 160 ~ 170 degree, add latting drown aromatic solvent 20 ~ 25 parts, continue to be cooled to 75 ~ 85 degree, add latting drown low boiling ester kind solvent 4 ~ 8 parts, filter and obtain modification.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201510998899.5A CN105419638A (en) | 2015-12-26 | 2015-12-26 | Paint containing photo-induced energy-storage luminous powder |
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CN201510998899.5A CN105419638A (en) | 2015-12-26 | 2015-12-26 | Paint containing photo-induced energy-storage luminous powder |
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CN201510998899.5A Pending CN105419638A (en) | 2015-12-26 | 2015-12-26 | Paint containing photo-induced energy-storage luminous powder |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105838190A (en) * | 2016-05-04 | 2016-08-10 | 南京高崎电机有限公司 | Paint with noctilucent function |
CN105949941A (en) * | 2016-05-04 | 2016-09-21 | 南京高崎电机有限公司 | Noctilucence paint |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1039259A (en) * | 1988-07-14 | 1990-01-31 | 沈阳市和平市政工程公司 | A kind of luminescent powder |
CN102953533A (en) * | 2012-10-26 | 2013-03-06 | 浙江未来家木业有限公司 | Noctilucent floor board processing technology |
CN103061487A (en) * | 2012-10-26 | 2013-04-24 | 浙江未来家木业有限公司 | Processing technique of noctilucent glazing floors |
CN103778873A (en) * | 2014-01-21 | 2014-05-07 | 浙江海联电子股份有限公司 | Self-luminous dangerous mark top light |
CN104449373A (en) * | 2014-11-17 | 2015-03-25 | 青岛厚科信息工程有限公司 | Conversion-type paint |
-
2015
- 2015-12-26 CN CN201510998899.5A patent/CN105419638A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1039259A (en) * | 1988-07-14 | 1990-01-31 | 沈阳市和平市政工程公司 | A kind of luminescent powder |
CN102953533A (en) * | 2012-10-26 | 2013-03-06 | 浙江未来家木业有限公司 | Noctilucent floor board processing technology |
CN103061487A (en) * | 2012-10-26 | 2013-04-24 | 浙江未来家木业有限公司 | Processing technique of noctilucent glazing floors |
CN103778873A (en) * | 2014-01-21 | 2014-05-07 | 浙江海联电子股份有限公司 | Self-luminous dangerous mark top light |
CN104449373A (en) * | 2014-11-17 | 2015-03-25 | 青岛厚科信息工程有限公司 | Conversion-type paint |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105838190A (en) * | 2016-05-04 | 2016-08-10 | 南京高崎电机有限公司 | Paint with noctilucent function |
CN105949941A (en) * | 2016-05-04 | 2016-09-21 | 南京高崎电机有限公司 | Noctilucence paint |
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Application publication date: 20160323 |