CN105602319A - Oil paint containing luminous material - Google Patents
Oil paint containing luminous material Download PDFInfo
- Publication number
- CN105602319A CN105602319A CN201511022468.1A CN201511022468A CN105602319A CN 105602319 A CN105602319 A CN 105602319A CN 201511022468 A CN201511022468 A CN 201511022468A CN 105602319 A CN105602319 A CN 105602319A
- Authority
- CN
- China
- Prior art keywords
- percent
- paint
- ester
- luminescent material
- defoamer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/22—Luminous paints
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention relates to a chemical industrial product, in particular to oil paint containing a luminous material. The oil paint is prepared from the following components in percentage by weight: 5 to 6 percent of calcium sulfide, 0.08 to 0.12 percent of potassium sulphide, 0.8 to 1 percent of sodium sulphide, 1 to 1.5 percent of barium nitrate, 1 to 1.5 percent of indium nitrate, 10 to 15 percent of wax ester, 20 to 30 percent of tung oil, 10 to 16 percent of epoxy resin, 5 to 11 percent of acrylonitrile, 3 to 6 percent of adipic acid ester, 12 to 16 percent of carnauba wax ester, 5 to 8 percent of methacrylic resin, 0.5 to 1 percent of turpentine, 3 to 6 percent of photoinitiator, 5 to 10 percent of polyvinyl butyral, 3 to 5 percent of defoamer and the balance of thinner. The oil paint can be used for absorbing light, in particular to green light emitted under a dark environment, can be used for objects such as guideboards, outdoor advertisements, nighttime roads and obstacle tags, and has the advantages of high covering power, good gloss retention, color retention and weather resistance and high drying speed.
Description
Technical field
The present invention relates to a kind of chemical industry product, especially a kind of paint that contains luminescent material.
Background technology
Coating is a kind of material, and this material can be coated in object surface by different construction technologies, forms and adheres to jailGu, there is some strength, continuous solid film. The film common name film forming like this, claims again paint film or coating. Belong to and organiseWork macromolecular material, the film forming belongs to macromolecular compound type. According to the classification of current chemical products of modern times, be coated withMaterial belongs to fine chemical product. Modern coating is progressively becoming the polyfunctional engineering material of a class, is in chemical industryAn important industry.
Existing paint rate of drying is slow, affects production efficiency.
Summary of the invention
The present invention is intended to solve the problems of the technologies described above, and a kind of paint that contains luminescent material is provided, and it can extinction darkUnder environment, send green glow, strong covering power, gloss retention, colour retention and good weatherability, rate of drying is fast, can be used for guideboard and street corner is wideAccuse and night road and the object such as obstacle marking, its technical scheme adopting is as follows:
A paint that contains luminescent material, is characterized in that: its composition weight proportioning is: 5～6% calcium sulfide,0.08～0.12% potassium sulfide, 0.8～1% vulcanized sodium, 1～1.5% barium nitrate, 1～1.5% indium nitrate, wax ester10～15%; Tung oil 20～30%, epoxy resin 10～16%, acrylonitrile 5～11%, adipic acid fat 3～6%, palm wax ester12～16%, methacrylic resin 5～8%, turpentine oil 0.5～1%, light trigger 3～6%, polyvinyl butyral resin 5～10%, defoamer 3～5%, all the other are solvent or diluent. Light trigger plays decisive role to solidification rate. Light trigger is subject to ultravioletAfter irradiation, light absorbing energy, splits into 2 living radicals, causes photosensitive resin and reactive diluent and occurs chain poly-Close, make adhesive crosslinking curing, be characterized in quick, environmental protection, energy-conservation. Initiator molecule at ultraviolet region (250～400nm) orVisible region (400～800nm) has certain extinction ability, is directly or indirectly absorbing after luminous energy, and initiator molecule jumps from ground stateAdjourn excited singlet, between being, alter and jump to excited triplet state; At excited singlet or triplet state experience unimolecule or bimolecularAfter chemical action, the biologically active fragment that generation can trigger monomer polymerization.
Gloss retention, colour retention, weatherability and the rate of drying of the more common alkyd resins of acrylic acid modified alkyd resin all haveObviously improve. First make the acrylic acid addition polymer containing carboxyl or hydroxyl, epoxy radicals, then with dryness or semi-drying oil and polynaryThe monoglyceride esterification that alcohol makes, then make acrylic acid modified alkyd resin with polyacid esterification.
On technique scheme basis, described adipic acid fat is dioleyl adipate or adipic acid dilauryl ester.
On technique scheme basis, described palm wax ester is palm grease, palm kernel ester or palm olein ester.
Preferably, described light trigger is diaryl group iodized salt, triaryl salt compounded of iodine, alkyl salt compounded of iodine or the luxuriant iron of isopropylbenzeneHexafluorophosphate.
Preferably, described defoamer is polysiloxane defoamers.
Tool of the present invention has the following advantages: can under extinction dark surrounds, send green glow, strong covering power, gloss retention, colour retention andGood weatherability, rate of drying is fast, can be used for guideboard and outdoor advertising and night road and the object such as obstacle marking.
Detailed description of the invention
Embodiment 1
A paint that contains luminescent material, is characterized in that: its composition weight proportioning is: 6% calcium sulfide, 0.08%Potassium sulfide, 1% vulcanized sodium, 1.5% barium nitrate, 1% indium nitrate, wax ester 15%; Tung oil 30%, epoxy resin10%, acrylonitrile 11%, adipic acid fat 3%, palm wax ester 16%, methacrylic resin 5%, turpentine oil 1%, light trigger6%, polyvinyl butyral resin 10%, defoamer 3%, all the other are solvent or diluent.
Preferably, described palm wax ester is palm grease, and described light trigger is diaryl group iodized salt, and described defoamer isPolysiloxane defoamers.
Embodiment 2
A paint that contains luminescent material, is characterized in that: its composition weight proportioning is: 6% calcium sulfide, 0.08%Potassium sulfide, 1% vulcanized sodium, 1% barium nitrate, 1.2% indium nitrate, wax ester 10%; Tung oil 20%, epoxy resin16%, acrylonitrile 8%, adipic acid fat 5%, palm wax ester 16%, methacrylic resin 5%, turpentine oil 0.8%, light-initiatedAgent 4%, polyvinyl butyral resin 8%, defoamer 4%, all the other are solvent or diluent.
On technique scheme basis, described palm wax ester is palm olein ester, and described light trigger is that isopropylbenzene is luxuriantIron hexafluorophosphate, described defoamer is polysiloxane defoamers.
Embodiment 3
A paint that contains luminescent material, is characterized in that: its composition weight proportioning is: 6% calcium sulfide, 0.1%Potassium sulfide, 0.9% vulcanized sodium, 1% barium nitrate, 1.5% indium nitrate, wax ester 12%; Tung oil 25%, epoxy resin12%, acrylonitrile 8%, adipic acid fat 4%, palm wax ester 15%, methacrylic resin 7%, turpentine oil 0.8%, light-initiatedAgent 3%, polyvinyl butyral resin 10%, defoamer 3%, all the other are solvent or diluent.
Described adipic acid fat is dioleyl adipate, and described palm wax ester is palm kernel ester, and described light trigger is alkaneBase salt compounded of iodine.
Preferably, described defoamer is polysiloxane defoamers.
Describe the present invention with way of example above, but the invention is not restricted to above-mentioned specific embodiment, all based onAny change or modification that the present invention does all belong to the scope of protection of present invention.
Claims (5)
1. a paint that contains luminescent material, is characterized in that: its composition weight proportioning is:
Calcium sulfide 5～6%;
Potassium sulfide 0.08～0.12%;
Vulcanized sodium 0.8～1%;
Barium nitrate 1～1.5%;
Indium nitrate 1～1.5%;
Wax ester 10～15%;
Tung oil 20～30%;
Epoxy resin 10～16%;
Acrylonitrile 5～11%;
Acrylic acid modified alkyd resin 3～6%;
Palm wax ester 12～16%;
Methacrylic resin 5～8%;
Turpentine oil 0.5～1%;
Light trigger 3～6%;
Polyvinyl butyral resin 5～10%;
Defoamer 3～5%;
All the other are solvent or diluent.
2. a kind of paint that contains luminescent material according to claim 1, is characterized in that: described adipic acid fat for oneself twoAcid two oil base esters or adipic acid dilauryl ester.
3. a kind of paint that contains luminescent material according to claim 1, is characterized in that: described palm wax ester is palmGrease, palm kernel ester or palm olein ester.
4. a kind of paint that contains luminescent material according to claim 1, is characterized in that: described light trigger is two virtuesThe luxuriant iron hexafluorophosphate of base salt compounded of iodine, triaryl salt compounded of iodine, alkyl salt compounded of iodine or isopropylbenzene.
5. a kind of paint that contains luminescent material according to claim 1, is characterized in that: described defoamer is poly-silicaAlkane defoamer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511022468.1A CN105602319A (en) | 2015-12-29 | 2015-12-29 | Oil paint containing luminous material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511022468.1A CN105602319A (en) | 2015-12-29 | 2015-12-29 | Oil paint containing luminous material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105602319A true CN105602319A (en) | 2016-05-25 |
Family
ID=55982692
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201511022468.1A Pending CN105602319A (en) | 2015-12-29 | 2015-12-29 | Oil paint containing luminous material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105602319A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114454964A (en) * | 2022-02-10 | 2022-05-10 | 张家港天乐橡塑科技股份有限公司 | Luminous fender |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1039259A (en) * | 1988-07-14 | 1990-01-31 | 沈阳市和平市政工程公司 | A kind of luminescent powder |
| CN102953533A (en) * | 2012-10-26 | 2013-03-06 | 浙江未来家木业有限公司 | Noctilucent floor board processing technology |
| CN103061487A (en) * | 2012-10-26 | 2013-04-24 | 浙江未来家木业有限公司 | Processing technique of noctilucent glazing floors |
| CN103778873A (en) * | 2014-01-21 | 2014-05-07 | 浙江海联电子股份有限公司 | Self-luminous dangerous mark top light |
| CN104371386A (en) * | 2014-11-13 | 2015-02-25 | 青岛厚科信息工程有限公司 | Quick-drying paint |
-
2015
- 2015-12-29 CN CN201511022468.1A patent/CN105602319A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1039259A (en) * | 1988-07-14 | 1990-01-31 | 沈阳市和平市政工程公司 | A kind of luminescent powder |
| CN102953533A (en) * | 2012-10-26 | 2013-03-06 | 浙江未来家木业有限公司 | Noctilucent floor board processing technology |
| CN103061487A (en) * | 2012-10-26 | 2013-04-24 | 浙江未来家木业有限公司 | Processing technique of noctilucent glazing floors |
| CN103778873A (en) * | 2014-01-21 | 2014-05-07 | 浙江海联电子股份有限公司 | Self-luminous dangerous mark top light |
| CN104371386A (en) * | 2014-11-13 | 2015-02-25 | 青岛厚科信息工程有限公司 | Quick-drying paint |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114454964A (en) * | 2022-02-10 | 2022-05-10 | 张家港天乐橡塑科技股份有限公司 | Luminous fender |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
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| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20160525 |