CN105969160A - Environment-friendly water-based self-luminous coating with good weather fastness - Google Patents

Environment-friendly water-based self-luminous coating with good weather fastness Download PDF

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Publication number
CN105969160A
CN105969160A CN201610311028.6A CN201610311028A CN105969160A CN 105969160 A CN105969160 A CN 105969160A CN 201610311028 A CN201610311028 A CN 201610311028A CN 105969160 A CN105969160 A CN 105969160A
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environment
friendly water
based self
luminous
percent
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CN201610311028.6A
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Inventor
郭君建
汝宗林
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Suzhou Dian Yue New Building Materials Co Ltd
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Suzhou Dian Yue New Building Materials Co Ltd
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Priority to CN201610311028.6A priority Critical patent/CN105969160A/en
Publication of CN105969160A publication Critical patent/CN105969160A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • C09D175/14Polyurethanes having carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/04Ingredients characterised by their shape and organic or inorganic ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/346Clay
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/16Solid spheres
    • C08K7/18Solid spheres inorganic
    • C08K7/20Glass
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/22Luminous paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • C09D7/62Additives non-macromolecular inorganic modified by treatment with other compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/10Transparent films; Clear coatings; Transparent materials

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses environment-friendly water-based self-luminous coating with good weather fastness. The environment-friendly water-based self-luminous coating is prepared from the following raw materials in percentage: 10 to 50 percent of hydroxyl acrylic resin emulsion, 1 to 20 percent of light diffusion agent, 10 to 60 percent of long-afterglow noctilucent powder, 0.1 to 5 percent of modified bentonite, 0.05 to 1 percent of water-based organic silicon defoamer, 0.05 to 1 percent of water-based organic silicon flatting agent and 5 to 30 percent of isocyanate prepolymer. In the environment-friendly water-based self-luminous coating disclosed by the invention, all raw materials are in mutual synergy, so that the environment-friendly water-based self-luminous coating has a very good adhesive force and is suitable for the surfaces of materials such as metal, plastics, ceramics, woodware and wall bodies, can absorb energy of sunlight can in daytime, can naturally emit lights at night and is high in light transmittance, high in luminous intensity, gentle in light rays, long in afterglow time and clear in vision sensing effect; the environment-friendly water-based self-luminous coating can be sprayed on the surface of a material, the weather fastness is good, and the service life is prolonged by five times or more.

Description

A kind of environment-friendly water-based self-luminous paint of good weatherability
Technical field
The present invention relates to self-luminescent material, be specifically related to the environment-friendly water-based spontaneous of a kind of good weatherability Optical coating.
Background technology
Self-luminous paint is widely used in traffic signs, urban beautification etc. at present.It is by spontaneous Optical coating is sprayed at the material surfaces such as display metallic article, woodwork, ground and forms light emitting layer, Having light when, light emitting layer stores light at short notice, and to reach luminous energy saturated, without light Time, the luminous energy self-luminescence stored more than 10 hours.But existing self-luminous paint is generally deposited In following deficiency: one is that the self-radiation mark coating light transmittance sprayed is low, luminous intensity is weak, people Noctovision sensory effects unintelligible;Two is that described self-emission display apparatus is usually placed in outdoor Extreme climate environment in, expose to the weather and sleet corrodes, its self-luminous paint through long-term Layer the most aging crackle, peeling, seriously reduce the service life of self-emission display apparatus.
Summary of the invention
For the deficiencies in the prior art, the invention provides a kind of good weatherability environment-friendly water-based from Luminous paint, good weatherability and light transmittance are high, and luminous intensity is high.
For realizing object above, the present invention is achieved by the following technical programs:
The environment-friendly water-based self-luminous paint of a kind of good weatherability, by the raw material group of following degree Become: Hydroxylated acrylic resin emulsion 10-50%, light diffusing agent 1-20%, long afterglow luminous powder 10-60%, modified alta-mud 0.1-5%, waterborne organic silicon defoamer 0.05-1%, aqueous are organic Silicon levelling agent 0.05-1%, isocyanate prepolymer 5-30%.
Preferably, it is made up of the raw material of following degree: Hydroxylated acrylic resin emulsion 35%, light diffusing agent 10%, long afterglow luminous powder 36%, thixotropic agent 2.5%, defoamer 0.7%, Levelling agent 0.8%, isocyanate prepolymer 15%.
Preferably, in described Hydroxylated acrylic resin emulsion, hydroxyl value is 20-200, and solid content is 30%-60%.
Preferably, described light diffusing agent is glass microballoon or acrylate resins microballon.
Preferably, the particle diameter of described light diffusing agent is 2-5 μm.
Preferably, described long afterglow luminous powder is rare earth silicate or rare earth aluminate.
The method have the benefit that the self-luminous paint of the present invention uses aqueous materials, prepared product Aqueous, environmental protective;Use Hydroxylated acrylic resin emulsion as base material, isocyanate prepolymer conduct Firming agent makes the good weatherability of system, and light transmittance is high, light transmittance up to more than 95%, thus Make light intensity high;The modified alta-mud added can well improve luminescent powder as thixotropic agent Settleability, the addition of light dispersant makes that light is dispersed to be opened, thus strengthens intensity of illumination.This The mutual synergism of each raw material in invention so that coating has good adhesive force, it is adaptable to gold The material surfaces such as genus, plastics, pottery, woodenware, body of wall, absorb the ability of sunlight daytime, Night is naturally luminous, and light transmittance is high, and luminous intensity is high, and light is soft, and persistence is long, can More than continuous illumination 12h, visual perception's effect is clear;And this spray painting is in material surface, Coating flat smooth, good weatherability, can improve more than 5 times service life.
Detailed description of the invention
For making the purpose of the embodiment of the present invention, technical scheme and advantage clearer, below will knot Close the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely retouched State, it is clear that described embodiment is a part of embodiment of the present invention rather than whole realities Execute example.Based on the embodiment in the present invention, those of ordinary skill in the art are not making creation The every other embodiment obtained under property work premise, broadly falls into the scope of protection of the invention.
Embodiment 1:
The environment-friendly water-based self-luminous paint of a kind of good weatherability, by the raw material group of following degree Become: Hydroxylated acrylic resin emulsion 35%, glass microballoon light diffusing agent 10%, rare earth silicate Long afterglow luminous powder 36%, thixotropic agent 2.5%, defoamer 0.7%, levelling agent 0.8%, different Cyanate prepolymer 15%;Wherein, in Hydroxylated acrylic resin emulsion, hydroxyl value is 100, Gu Content is 50%, and the particle diameter of glass microballoon light diffusing agent is 2 μm.
The preparation method of the environment-friendly water-based self-luminous paint of good weatherability, step is as follows: by proportioning Weigh each raw material, mixing, join in blender, stir 20-30min under room temperature, to obtain final product.
Embodiment 2:
The environment-friendly water-based self-luminous paint of a kind of good weatherability, by the raw material group of following degree Become: Hydroxylated acrylic resin emulsion 30%, acrylate resins microballon light diffusing agent 9%, rare earth Aluminate long afterglow luminescent powder 45%, modified alta-mud 4%, waterborne organic silicon defoamer 1%, Waterborne organic silicon levelling agent 1%, isocyanate prepolymer 10%;Wherein, hydroxy acrylic acid tree In fat liquor, hydroxyl value is 80, and solid content is 40%, the grain of acrylate resins microballon light diffusing agent Footpath is 3 μm.
Preparation method is with embodiment 1.
Embodiment 3:
The environment-friendly water-based self-luminous paint of a kind of good weatherability, by the raw material group of following degree Become: Hydroxylated acrylic resin emulsion 50%, glass microballoon light diffusing agent 5%, rare earth silicate Long afterglow luminous powder 22%, modified alta-mud 2%, waterborne organic silicon defoamer 0.5%, aqueous Organosilicon levelling agent 0.5%, isocyanate prepolymer 20%;Wherein, Hydroxylated acrylic resin In emulsion, hydroxyl value is 150, and solid content is 60%, and the particle diameter of glass microballoon light diffusing agent is 5 μm.
Preparation method is with embodiment 1.
Embodiment 4:
The environment-friendly water-based self-luminous paint of a kind of good weatherability, by the raw material group of following degree Become: Hydroxylated acrylic resin emulsion 25%, acrylate resins microballon light diffusing agent 5%, rare earth Silicate long-afterglow luminescent powder 50%, modified alta-mud 0.8%, waterborne organic silicon defoamer 0.1%, waterborne organic silicon levelling agent 0.1%, isocyanate prepolymer 19%;Wherein, hydroxyl In emulsion acrylic resin, hydroxyl value is 200, and solid content is 30%, and acrylate resins microballon light expands The particle diameter of powder is 4 μm..
Preparation method is with embodiment 1.
Embodiment 5:
The environment-friendly water-based self-luminous paint of a kind of good weatherability, by the raw material group of following degree Become: Hydroxylated acrylic resin emulsion 40%, glass microballoon light diffusing agent 8%, rare earth aluminate Long afterglow luminous powder 40%, modified alta-mud 1.7%, waterborne organic silicon defoamer 0.5%, water Property organosilicon levelling agent 0.8%, isocyanate prepolymer 9%;Wherein, Hydroxylated acrylic resin In emulsion, hydroxyl value is 50, and solid content is 40%, and the particle diameter of glass microballoon light diffusing agent is 2 μm.
Preparation method is with embodiment 1.
To sum up, the self-luminous paint aqueous, environmental protective that the embodiment of the present invention 1 prepares, easy to use, Good weatherability, luminous intensity is high and persistence is long, sustainable luminescence at night more than 12h, thoroughly Light rate is up to 95%, and service life can improve more than 5 times.
Above example only in order to technical scheme to be described, is not intended to limit;Although With reference to previous embodiment, the present invention is described in detail, those of ordinary skill in the art It is understood that the technical scheme described in foregoing embodiments still can be modified by it, Or wherein portion of techniques feature is carried out equivalent;And these amendments or replacement, not The essence making appropriate technical solution departs from the spirit and scope of various embodiments of the present invention technical scheme.

Claims (6)

1. the environment-friendly water-based self-luminous paint of a good weatherability, it is characterised in that by following hundred Proportion by subtraction content raw material composition: Hydroxylated acrylic resin emulsion 10-50%, light diffusing agent 1-20%, Long afterglow luminous powder 10-60%, modified alta-mud 0.1-5%, waterborne organic silicon defoamer 0.05-1%, waterborne organic silicon levelling agent 0.05-1%, isocyanate prepolymer 5-30%.
2. the environment-friendly water-based self-luminous paint of good weatherability as claimed in claim 1, its feature It is, is made up of the raw material of following degree: Hydroxylated acrylic resin emulsion 35%, light Diffusant 10%, long afterglow luminous powder 36%, thixotropic agent 2.5%, defoamer 0.7%, levelling Agent 0.8%, isocyanate prepolymer 15%.
3. the environment-friendly water-based self-luminous paint of good weatherability as claimed in claim 2, its feature Being, in described Hydroxylated acrylic resin emulsion, hydroxyl value is 20-200, and solid content is 30%-60%.
4. the environment-friendly water-based self-luminous paint of good weatherability as claimed in claim 2, its feature Being, described light diffusing agent is glass microballoon or acrylate resins microballon.
5. the environment-friendly water-based self-luminous paint of good weatherability as claimed in claim 4, its feature Being, the particle diameter of described light diffusing agent is 2-5 μm.
6. the environment-friendly water-based self-luminous paint of good weatherability as claimed in claim 2, its feature Being, described long afterglow luminous powder is rare earth silicate or rare earth aluminate.
CN201610311028.6A 2016-05-10 2016-05-10 Environment-friendly water-based self-luminous coating with good weather fastness Pending CN105969160A (en)

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106758686A (en) * 2017-03-02 2017-05-31 周抒函 A kind of outdoor energy-accumulating luminous crystal floor tile
CN106833201A (en) * 2017-02-08 2017-06-13 刘海泉 A kind of energy-accumulating luminous resin glue of overlength afterglow and preparation method thereof
CN106995648A (en) * 2017-04-18 2017-08-01 德阳森华涂料化工有限公司 Waterborne metallic paint with super-weathering resistance
CN107603447A (en) * 2017-10-30 2018-01-19 天津美士邦涂料化工有限公司 A kind of polyurethane luminous paint
CN107746667A (en) * 2017-10-30 2018-03-02 天津美士邦涂料化工有限公司 A kind of preparation method of polyurethane luminous paint
CN108219650A (en) * 2018-01-25 2018-06-29 华南协同创新研究院 A kind of environmental protection light diffusion coating and preparation method thereof
CN108727734A (en) * 2018-05-25 2018-11-02 东南大学 A kind of energy-saving self-luminous composite floor board and preparation method thereof
WO2022121462A1 (en) * 2020-12-07 2022-06-16 Oppo广东移动通信有限公司 Luminescent paint and preparation method therefor, casing assembly, and electronic device
CN114686030A (en) * 2020-12-28 2022-07-01 广东三和化工科技有限公司 Noctilucent aerosol paint and preparation method thereof

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CN101555376A (en) * 2009-05-07 2009-10-14 广东工业大学 Method for preparing multi-color long afterglow water borne luminescent coatings
CN101948658A (en) * 2010-09-26 2011-01-19 上海朗琦土木工程技术有限公司 Road guardrail coating with width marking and warning function and preparation method thereof
CN102051102A (en) * 2009-11-09 2011-05-11 李新春 Noctilucent powder paint

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CN101555376A (en) * 2009-05-07 2009-10-14 广东工业大学 Method for preparing multi-color long afterglow water borne luminescent coatings
CN102051102A (en) * 2009-11-09 2011-05-11 李新春 Noctilucent powder paint
CN101948658A (en) * 2010-09-26 2011-01-19 上海朗琦土木工程技术有限公司 Road guardrail coating with width marking and warning function and preparation method thereof

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106833201A (en) * 2017-02-08 2017-06-13 刘海泉 A kind of energy-accumulating luminous resin glue of overlength afterglow and preparation method thereof
CN106758686A (en) * 2017-03-02 2017-05-31 周抒函 A kind of outdoor energy-accumulating luminous crystal floor tile
CN106995648A (en) * 2017-04-18 2017-08-01 德阳森华涂料化工有限公司 Waterborne metallic paint with super-weathering resistance
CN107603447A (en) * 2017-10-30 2018-01-19 天津美士邦涂料化工有限公司 A kind of polyurethane luminous paint
CN107746667A (en) * 2017-10-30 2018-03-02 天津美士邦涂料化工有限公司 A kind of preparation method of polyurethane luminous paint
CN108219650A (en) * 2018-01-25 2018-06-29 华南协同创新研究院 A kind of environmental protection light diffusion coating and preparation method thereof
CN108219650B (en) * 2018-01-25 2020-12-22 华南协同创新研究院 Environment-friendly light diffusion coating and preparation method thereof
CN108727734A (en) * 2018-05-25 2018-11-02 东南大学 A kind of energy-saving self-luminous composite floor board and preparation method thereof
WO2022121462A1 (en) * 2020-12-07 2022-06-16 Oppo广东移动通信有限公司 Luminescent paint and preparation method therefor, casing assembly, and electronic device
CN114686030A (en) * 2020-12-28 2022-07-01 广东三和化工科技有限公司 Noctilucent aerosol paint and preparation method thereof

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Application publication date: 20160928