CN106758686A - A kind of outdoor energy-accumulating luminous crystal floor tile - Google Patents
A kind of outdoor energy-accumulating luminous crystal floor tile Download PDFInfo
- Publication number
- CN106758686A CN106758686A CN201710121058.5A CN201710121058A CN106758686A CN 106758686 A CN106758686 A CN 106758686A CN 201710121058 A CN201710121058 A CN 201710121058A CN 106758686 A CN106758686 A CN 106758686A
- Authority
- CN
- China
- Prior art keywords
- floor tile
- resin glue
- ground
- luminescent
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000013078 crystal Substances 0.000 title claims abstract description 20
- 239000011347 resin Substances 0.000 claims abstract description 45
- 229920005989 resin Polymers 0.000 claims abstract description 45
- 239000003292 glue Substances 0.000 claims abstract description 43
- 239000011248 coating agent Substances 0.000 claims abstract description 29
- 238000000576 coating method Methods 0.000 claims abstract description 29
- 239000000843 powder Substances 0.000 claims abstract description 22
- 239000004579 marble Substances 0.000 claims abstract description 20
- 239000011241 protective layer Substances 0.000 claims abstract description 20
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 19
- 239000004576 sand Substances 0.000 claims abstract description 18
- 239000011449 brick Substances 0.000 claims abstract description 17
- 239000011521 glass Substances 0.000 claims abstract description 17
- 239000005368 silicate glass Substances 0.000 claims abstract description 12
- 229910001385 heavy metal Inorganic materials 0.000 claims abstract description 10
- 150000002736 metal compounds Chemical class 0.000 claims abstract description 10
- 239000002245 particle Substances 0.000 claims abstract description 10
- 239000011324 bead Substances 0.000 claims abstract description 9
- 239000007822 coupling agent Substances 0.000 claims description 15
- 238000003756 stirring Methods 0.000 claims description 15
- 239000003795 chemical substances by application Substances 0.000 claims description 14
- 229920000768 polyamine Polymers 0.000 claims description 14
- 239000013530 defoamer Substances 0.000 claims description 11
- 239000006097 ultraviolet radiation absorber Substances 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 238000010521 absorption reaction Methods 0.000 claims description 6
- 238000009738 saturating Methods 0.000 claims description 6
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 5
- -1 drier Substances 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 5
- 239000004575 stone Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 abstract description 9
- 230000000694 effects Effects 0.000 abstract description 8
- 238000005286 illumination Methods 0.000 abstract description 4
- 239000004566 building material Substances 0.000 abstract description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 18
- 239000003973 paint Substances 0.000 description 16
- 230000006872 improvement Effects 0.000 description 12
- 239000002253 acid Substances 0.000 description 7
- 230000008901 benefit Effects 0.000 description 7
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 4
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 4
- 230000006835 compression Effects 0.000 description 3
- 238000007906 compression Methods 0.000 description 3
- 238000005034 decoration Methods 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 231100000252 nontoxic Toxicity 0.000 description 3
- 230000003000 nontoxic effect Effects 0.000 description 3
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000004134 energy conservation Methods 0.000 description 2
- 239000010433 feldspar Substances 0.000 description 2
- 238000004020 luminiscence type Methods 0.000 description 2
- 229910017604 nitric acid Inorganic materials 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- 230000003678 scratch resistant effect Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000004381 surface treatment Methods 0.000 description 2
- 238000002834 transmittance Methods 0.000 description 2
- 241000533950 Leucojum Species 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- MCPKSFINULVDNX-UHFFFAOYSA-N drometrizole Chemical compound CC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MCPKSFINULVDNX-UHFFFAOYSA-N 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 230000004313 glare Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000002285 radioactive effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000001932 seasonal effect Effects 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
Classifications
-
- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01C—CONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
- E01C17/00—Pavement lights, i.e. translucent constructions forming part of the surface
-
- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01C—CONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
- E01C15/00—Pavings specially adapted for footpaths, sidewalks or cycle tracks
-
- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01C—CONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
- E01C2201/00—Paving elements
- E01C2201/04—Paving elements consisting of natural stones and a binder
Landscapes
- Engineering & Computer Science (AREA)
- Architecture (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Paints Or Removers (AREA)
- Floor Finish (AREA)
Abstract
The present invention discloses a kind of outdoor energy-accumulating luminous crystal floor tile, belongs to energy-saving building material technical field, including ground, the luminescent coating being arranged on ground and the protective layer being arranged on luminescent coating;The ground is using the one kind in natural marble or acidproof brick;The luminescent coating uses energy-accumulating luminous resin glue, and by weight, luminous resin glue is obtained by 20 40 parts of luminescent powders, 50 70 parts of acrylic sizes, 5 15 parts of auxiliary agents without heavy metal compound;The protective layer uses the height that thickness is the silicate glass sand of 1mm 2mm, size is 1mm 6mm, and bead or thickness are any one in 2mm 8mm ultra-clear glasses face thoroughly, wherein, the particle diameter of silicate glass sand is 2 120 mesh.Obtained floor tile illumination effect of the invention is good, is not required to power consumption, and the luminescent material in low cost, and floor tile is safe and harmless.
Description
Technical field
The present invention relates to a kind of floor tile, and in particular to a kind of outdoor energy-accumulating luminous crystal floor tile, belong to energy-saving building material technology
Field.
Background technology
Square general at present or street can spread on the ground in order to realize illuminating road surface or increase night decorative effect
If light-emitting floor tile.Existing light-emitting floor tile needs internally to install illuminating lamp and it is lighted with power on, and power consumption is big, wave
Take the energy;Or using luminous pigment or reflecting coating brushing on brick body surface, this method is luminous or reflecting effect is not obvious,
And abrasion again clearly;In addition, traditional luminous paint using sulfide as luminescent material is the extension sunset glow time, often
Radioactive element is added, the person is caused harm, and luminescent lifetime is shorter.
The content of the invention
For the problem that above-mentioned prior art is present, the present invention provides a kind of outdoor energy-accumulating luminous crystal floor tile, obtained
Floor tile illumination effect is good, is not required to power consumption, and the luminescent material in low cost, and floor tile is safe and harmless.
To achieve these goals, a kind of outdoor energy-accumulating luminous crystal floor tile that the present invention is used, including ground, be arranged on
Luminescent coating on ground and the protective layer being arranged on luminescent coating;
The ground is using the one kind in natural marble or acidproof brick;
The luminescent coating uses energy-accumulating luminous resin glue, and by weight, luminous resin glue is by 20-40 parts of luminescent powder, 50-70
Part acrylic size, the 5-15 parts of auxiliary agent without heavy metal compound are obtained;
The protective layer uses silicate glass sand, height saturating bead or thickness that size be 1mm-6mm of the thickness for 1mm-2mm
It is any one in 2mm-8mm ultra-clear glasses face, wherein, the particle diameter of silicate glass sand is 2-120 mesh.
Used as improvement, the luminescent powder particle diameter is 100-300 mesh, and described auxiliary agent is inhaled by defoamer, drier, ultraviolet
Receive agent, coupling agent, polyamine wax according to(0.3-0.5):(0.1-0.35):0.4:1.6:1.4 prepare.
Used as improvement, described luminous resin glue includes following components:Luminescent powder, 30 parts;Acrylic size, 60 parts;
Auxiliary agent without heavy metal compound, 10 parts.
Used as improvement, the auxiliary agent includes the component of following proportioning, by defoamer, drier, ultra-violet absorber, coupling
Agent, polyamine wax are according to 0.4:0.35:0.4:1.6:1.4 proportions.
Used as improvement, the viscosity of the acrylic size is 2000-5000 pools.
Used as improvement, by mass percentage, the acidproof brick is grouped into by following content groups, 60%-70%SiO2、
0.1%-0.8%MgO、20%-30%Al2O3、0.5%-3%Na2O、0.5%-3%FeO、1.5%-2%K2O and 0.3%-1%CaO.
Used as improvement, the natural marble uses natural Snow Flower White marble, the natural marmorean water suction of Snow Flower White
Rate is 0.92%, and bulk density is 2.7g/cm3。
In addition, present invention also offers a kind of preparation method of luminous resin glue described in any of the above-described, including following step
Suddenly:
1)Using the agitator tank for not containing metallics, speed of agitator is not less than 1500rpm, and summer whipping temp is no more than 60
DEG C, winter whipping temp is not less than 30 DEG C;
2)Acrylic size, polyamine wax are added in agitator tank, luminescent powder is added, after stirring 15-20min, froth breaking is added
Agent, ultra-violet absorber, coupling agent, drier, after stirring 10min, add 0.1 times of curing agent of acrylic size content,
Uniform stirring 15min can obtain luminous resin glue.
As improvement, the length and width size of the ground is 100mm*100mm, 100mm*200mm, 200mm*200mm,
150mm*150mm、150mm*300mm、300mm*300mm、300mm*600mm、600mm*600mm、350mm*350mm、
Any one in 350mm*700mm, 700mm*700mm, 400mm*400mm, 400mm*800mm or 800mm*800mm, the hair
Light coating, the size of protective layer coordinate with ground.
Using natural marble or acidproof brick as ground, acidproof brick is with quartz, feldspar, clay as main former to the present invention
Material, the resistant material being made is decomposed through high-temperature oxydation, and high with acid-alkali-resistant degree, water absorption rate is low, not oxidizable at normal temperatures, no
Easily by performances such as medium pollutions, in addition to hydrofluoric acid and hot phosphoric acid, to acids such as warm villaumite water, hydrochloric acid, sulfuric acid, nitric acid and in normal temperature
Under any concentration bases, have excellent anti-rotten effect;Natural marble, kind background color is white, and lines distribution or gray line
Pass through plate face, lines skewness, luminosity is fabulous, can be up to 120 degree.
Using luminous resin glue as energy-accumulating luminous coating, the luminous resin glue has decoration performance good, energy saving, nothing
Malicious, "dead", long-term luminous excellent performance, luminosity can be adjusted, and storage stability is good, low cost, economic benefit and
The significant advantage of social benefit, its every technical performance index is superior to other energy-accumulating luminous paints, with extensive popularization
Prospect.
In addition, the present invention uses silicate glass sand, bead thoroughly high or ultra-clear glasses face as the protection of luminescent coating
Layer, wherein glass sand has advantages below, and transparency is good, hardness is high, particle diameter distribution is uniform;Glass sand good dispersion, with resin
It is good with other compositions intermiscibility in paint systems;Glass sand is filled through repeatedly surface treatment in paint systems, and paint film is not
Band blue light, recoatability is good;In high-grade scratch resistant finish paint, hardness, the toughness of finish paint can be increased, improve the scratch resistance of paint film
Can, with photoextinction, the weatherability of paint film can be improved.The saturating bead of height of use, compression strength reaches 3300kg/cm2,
Four hours weightlessness 0.005mg/cm are boiled in 20%HCL solution2.The ultra-clear glasses face of use, is a kind of high-quality, multi-functional
Novel high-grade glass kind, light transmittance is up to more than 91.5%, and its self-destruction rate is low, solid colour, visible light transmissivity are high, penetrating
Property is good.
Specific embodiment
To make the object, technical solutions and advantages of the present invention of greater clarity, below by embodiment, the present invention is entered
Row is further described.However, it should be understood that the specific embodiments described herein are merely illustrative of the present invention, and without
In limitation the scope of the present invention.
Unless otherwise defined, all of technical term used herein and scientific terminology are led with technology of the invention is belonged to
The implication that the technical staff in domain is generally understood that is identical, and the term for being used in the description of the invention herein is intended merely to retouch
State the purpose of specific embodiment, it is not intended that in the limitation present invention.
A kind of outdoor energy-accumulating luminous crystal floor tile, including ground, the luminescent coating that is arranged on ground and be arranged on luminous
Protective layer on coating;
The ground is using the one kind in natural marble or acidproof brick;
The luminescent coating uses energy-accumulating luminous resin glue, and by weight, luminous resin glue is by 20-40 parts of luminescent powder, 50-70
Part acrylic size, the 5-15 parts of auxiliary agent without heavy metal compound are obtained;
The protective layer uses silicate glass sand, height saturating bead or thickness that size be 1mm-6mm of the thickness for 1mm-2mm
It is any one in 2mm-8mm ultra-clear glasses face, wherein, the particle diameter of silicate glass sand is 2-120 mesh.
It with quartz, feldspar, clay is primary raw material that acidproof brick is, by mass percentage, the acidproof brick is contained by following
Amount component composition, 60%-70%SiO2、0.1%-0.8%MgO、20%-30%Al2O3、0.5%-3%Na2O、0.5%-3%FeO、1.5%-
2%K2O and 0.3%-1%CaO.Acidproof brick decomposes the resistant material being made, water absorption rate high with acid-alkali-resistant degree through high-temperature oxydation
It is low, it is not oxidizable at normal temperatures, be difficult by performances such as medium pollutions, in addition to hydrofluoric acid and hot phosphoric acid, to warm villaumite water, hydrochloric acid,
The bases of the acids such as sulfuric acid, nitric acid and any concentration at normal temperatures, there is excellent anti-rotten effect;Natural marble, kind
Background color is white, and lines distribution or gray line pass through plate face, and lines skewness, luminosity is fabulous, can be up to 120 degree.
Using silicate glass sand, bead thoroughly high or ultra-clear glasses face as luminescent coating protective layer, wherein glass
Sand has advantages below, and transparency is good, hardness is high, particle diameter distribution is uniform;Glass sand good dispersion, in resin and paint systems
Other compositions intermiscibility it is good;Glass sand is filled through repeatedly surface treatment in paint systems, and paint film is without blue light, recoating
Property is good;In high-grade scratch resistant finish paint, hardness, the toughness of finish paint can be increased, the scratch resistance energy of paint film be improved, with delustring
Effect, can improve the weatherability of paint film.The saturating bead of height of use, compression strength reaches 3300kg/cm2, in 20%HCL solution
Boil four hours weightlessness 0.005mg/cm2.The ultra-clear glasses face of use, is a kind of high-quality, multifunctional novel high-grade glass
Kind, up to more than 91.5%, its self-destruction rate is low, solid colour, visible light transmissivity are high, and permeability is good for light transmittance.
Used as the improvement of embodiment, the luminescent powder particle diameter is 100-300 mesh, described auxiliary agent by defoamer, drier,
Ultra-violet absorber, coupling agent, polyamine wax according to(0.3-0.5):(0.1-0.35):0.4:1.6:1.4 prepare.Defoamer can be with
Using the fatty acid ester compounded thing of higher alcohols, drier be able to can be used using dibutyl tin laurate, ultra-violet absorber
UV-P, coupling agent can use common silane coupler.Above-mentioned each component, those skilled in the art can use and realize phase
Other materials of function are answered come for producing.When using, because luminescent powder is divided into green-yellow light, blue green light, day blue light, purple light, white
Light, feux rouges, therefore using fluorescent pigment, dyestuff, the luminous front and rear color of adjustment, fluorescer adding proportion is about luminescent powder weight
The 1% ~ 5% of amount, it is possible to use general dye, pigmented tinting.
Used as the further preferred of embodiment, described luminous resin glue includes following components:Luminescent powder, 30 parts;Propylene
Acid resin glue, 60 parts;Auxiliary agent without heavy metal compound, 10 parts.
Used as the improvement of embodiment, the auxiliary agent includes the component of following proportioning, is inhaled by defoamer, drier, ultraviolet
Agent, coupling agent, polyamine wax are received according to 0.4:0.35:0.4:1.6:1.4 proportions.
Used as the improvement of embodiment, the viscosity of the acrylic size is 2000-5000 pools.
Used as the improvement of embodiment, the natural marble uses natural Snow Flower White marble, the natural Snow Flower White Dali
The water absorption rate of stone is 0.92%, and bulk density is 2.7g/cm3.Snowflake white marble be free of any dyestuff, with it is nontoxic, tasteless,
The advantages of pollution-free, anticorrosive, acid and alkali-resistance, uprising solarization, nondiscolouring.
Embodiment one
A kind of outdoor energy-accumulating luminous crystal floor tile, including ground, the luminescent coating that is arranged on ground and it is arranged on luminescent coating
On protective layer;
The ground uses natural marble, the natural marble to use natural Snow Flower White marble, and the natural Snow Flower White is big
The water absorption rate of reason stone is 0.92%, and bulk density is 2.7g/cm3;
The luminescent coating uses energy-accumulating luminous resin glue, and by weight, luminous resin glue is by 20 parts of luminescent powders, 50 parts of propylene
Acid resin glue, 5 parts of auxiliary agents without heavy metal compound are obtained, wherein, the auxiliary agent is inhaled by defoamer, drier, ultraviolet
Agent, coupling agent, polyamine wax are received according to 0.3:0.1:0.4:1.6:1.4 prepare, and the specific preparation process of luminous resin glue is as follows:
1)Using the agitator tank for not containing metallics, speed of agitator is not less than 1500rpm, and Various Seasonal whipping temp is different,
Summer whipping temp is no more than 60 DEG C, and winter whipping temp is not less than 30 DEG C;
2)Acrylic size, polyamine wax are added in agitator tank, luminescent powder is added, after stirring 15-20min, froth breaking is added
Agent, ultra-violet absorber, coupling agent, drier, after stirring 10min, add 0.1 times of curing agent of acrylic size content
(P-hydroxybenzenyl sulfonate), uniform stirring 15min can luminous resin glue;
The resin glue that will be prepared is placed on ground, and then protective layer is placed on resin glue, and the protective layer is using thick
The silicate glass sand for 1mm-2mm is spent, wherein, the particle diameter of silicate glass sand is 2-120 mesh;
Using light-emitting floor tile obtained in the present invention, due to containing luminous resin glue, it has and absorbs and store luminous energy, evening daytime
Ornament lamp can be replaced, the product with its decorative exterior wall and various structures with the performance of more than continuous illumination 12h after darkness
It is nontoxic, "dead", it is a kind of functional ornamentation coating for integrating decoration, energy-conservation and environmental protection.
Obtained light-emitting floor tile, according to actual needs, can produce according to different specifications, such as 100mm*100mm,
100mm*200mm、200mm*200mm、150mm*150mm、150mm*300mm、300mm*300mm、300mm*600mm、
600mm*600mm, 350mm*350mm, 350mm*700mm, 700mm*700mm, 400mm*400mm, 400mm*800mm or
800mm*800mm etc..
To the light-emitting floor tile in embodiment one, through national building materials, test center tests, related data such as following table
1:
The detection information of the light-emitting floor tile of table 1
Analytical table 1 understands that wearability, frost resistance, compression strength, radioactivity of the crystal floor tile etc. meet national standard.
Embodiment two
A kind of outdoor energy-accumulating luminous crystal floor tile, including ground, the luminescent coating that is arranged on ground and it is arranged on luminescent coating
On protective layer;
The ground uses acidproof brick, the acidproof brick to be grouped into by following content groups, 60%-70%SiO2、0.1%-0.8%MgO、
20%-30%Al2O3、0.5%-3%Na2O、0.5%-3%FeO、1.5%-2%K2O and 0.3%-1%CaO;
The luminescent coating uses energy-accumulating luminous resin glue, and by weight, luminous resin glue is by 40 parts of luminescent powders, 70 parts of propylene
Acid resin glue, 15 parts of auxiliary agents without heavy metal compound are obtained, wherein, the auxiliary agent is inhaled by defoamer, drier, ultraviolet
Agent, coupling agent, polyamine wax are received according to 0.5:0.35:0.4:1.6:1.4 prepare, and the specific preparation process of luminous resin glue is as follows:
1)Using the agitator tank for not containing metallics, speed of agitator is not less than 1500rpm, and summer whipping temp is no more than 60
DEG C, winter whipping temp is not less than 30 DEG C;
2)Acrylic size, polyamine wax are added in agitator tank, luminescent powder is added, after stirring 15-20min, froth breaking is added
Agent, ultra-violet absorber, coupling agent, drier, after stirring 10min, add 0.1 times of curing agent of acrylic size content,
Uniform stirring 15min can obtain luminous resin glue;
The resin glue that will be prepared is placed on ground, and then protective layer is placed on resin glue, and the protective layer uses chi
Very little is the saturating bead of the height of 1mm-6mm;
Using light-emitting floor tile obtained in the present invention, due to containing luminous resin glue, it has and absorbs and store luminous energy, evening daytime
Ornament lamp can be replaced, the product with its decorative exterior wall and various structures with the performance of more than continuous illumination 12h after darkness
It is nontoxic, "dead", it is a kind of functional ornamentation coating for integrating decoration, energy-conservation and environmental protection.
Obtained light-emitting floor tile, according to actual needs, can produce according to different specification, such as 100*100,200*100,
200*200,150*300,300*300,300*600 or 600*600 etc..
Embodiment three
A kind of outdoor energy-accumulating luminous crystal floor tile, including ground, the luminescent coating that is arranged on ground and it is arranged on luminescent coating
On protective layer;
The ground is grouped into using the one kind in natural marble or acidproof brick, the acidproof brick by following content groups, 60%-
70%SiO2、0.1%-0.8%MgO、20%-30%Al2O3、0.5%-3%Na2O、0.5%-3%FeO、1.5%-2%K2O and 0.3%-1%
CaO;The natural marble uses natural Snow Flower White marble, and the natural marmorean water absorption rate of Snow Flower White is 0.92%, volume
Density is 2.7g/cm3, flexing resistance 9.2Mpa;
The luminescent coating uses energy-accumulating luminous resin glue, and by weight, luminous resin glue is by 30 parts of luminescent powders, 60 parts of propylene
Acid resin glue, 10 parts of auxiliary agents without heavy metal compound are obtained, wherein, the auxiliary agent is inhaled by defoamer, drier, ultraviolet
Agent, coupling agent, polyamine wax are received according to 4:0.1:0.4:1.6:1.4 prepare, and the specific preparation process of luminous resin glue is as follows:
1)Using the agitator tank for not containing metallics, speed of agitator is not less than 1500rpm, and summer whipping temp is no more than 60
DEG C, winter whipping temp is not less than 30 DEG C;
2)Acrylic size, polyamine wax are added in agitator tank, luminescent powder is added, after stirring 18min, addition defoamer,
Ultra-violet absorber, coupling agent, drier, after stirring 10min, add 0.1 times of curing agent of acrylic size content, uniformly
Stirring 15min can obtain luminous resin glue, and the resin glue belongs to A grades, can be used for all of position by detection, its radioactivity,
Avoid causing harm the person.Because the overlength afterglow luminescence powder that the resin glue is used is lighting with fine durability
Powder, its luminescence process is physical process, luminescent lifetime more than 10 years, considerably beyond luminous with sulfide as luminescent material
The luminescent lifetime of coating;
The resin glue that will be prepared is placed on ground, and then protective layer is placed on resin glue, and the protective layer is using thick
It is 2mm-8mm ultra-clear glasses face to spend;
Obtained light-emitting floor tile, according to actual needs, can produce, such as 150mm*300mm, 300mm* according to different specifications
300mm、300mm*600mm、600mm*600mm、350mm*350mm、350mm*700mm、700mm*700mm、400mm*
400mm, 400mm*800mm or 800mm*800mm etc..
Common floor tile, the single and energy-accumulating luminous crystal floor tile color of color is gorgeous, and night can discharge radiance, energy-accumulating luminous
Floor tile has pollution-free, water resistance, mainly absorbs the visible rays such as sunlight, light, ultraviolet, veiling glare, and it can be followed infinitely
Ring is used, the material is "dead" element.The sunset glow duration of the brick can reach 8-12 hours, greatly saved electric power into
This, accomplishes the effect of economical environment-protective, environmental protection, beautifying city.
Presently preferred embodiments of the present invention is the foregoing is only, is not intended to limit the invention, it is all in essence of the invention
Any modification, equivalent or improvement made within god and principle etc., should be included within the scope of the present invention.
Claims (9)
1. a kind of outdoor energy-accumulating luminous crystal floor tile, it is characterised in that including ground, the luminescent coating being arranged on ground and
It is arranged on the protective layer on luminescent coating;
The ground is using the one kind in natural marble or acidproof brick;
The luminescent coating uses energy-accumulating luminous resin glue, and by weight, luminous resin glue is by 20-40 parts of luminescent powder, 50-70
Part acrylic size, the 5-15 parts of auxiliary agent without heavy metal compound are obtained;
The protective layer uses silicate glass sand, height saturating bead or thickness that size be 1mm-6mm of the thickness for 1mm-2mm
It is any one in 2mm-8mm ultra-clear glasses face, wherein, the particle diameter of silicate glass sand is 2-120 mesh.
2. the outdoor energy-accumulating luminous crystal floor tile of one kind according to claim 1, it is characterised in that the luminescent powder particle diameter is
100-300 mesh, described auxiliary agent by defoamer, drier, ultra-violet absorber, coupling agent, polyamine wax according to(0.3-0.5):
(0.1-0.35):0.4:1.6:1.4 prepare.
3. the outdoor energy-accumulating luminous crystal floor tile of one kind according to claim 2, it is characterised in that described luminous resin glue
Including following components:Luminescent powder, 30 parts;Acrylic size, 60 parts;Auxiliary agent without heavy metal compound, 10 parts.
4. the outdoor energy-accumulating luminous crystal floor tile of one kind according to claim 3, it is characterised in that the auxiliary agent includes following
The component of proportioning, by defoamer, drier, ultra-violet absorber, coupling agent, polyamine wax according to 0.4:0.35:0.4:1.6:1.4
Proportions.
5. the outdoor energy-accumulating luminous crystal floor tile of one kind according to claim 4, it is characterised in that the acrylic size
Viscosity be 2000-5000 pool.
6. the outdoor energy-accumulating luminous crystal floor tile of one kind according to claim 1, it is characterised in that by mass percentage,
The acidproof brick is grouped into by following content groups, 60%-70%SiO2、0.1%-0.8%MgO、20%-30%Al2O3、0.5%-3%
Na2O、0.5%-3%FeO、1.5%-2%K2O and 0.3%-1%CaO.
7. a kind of outdoor energy-accumulating luminous crystal floor tile according to claim 1 or 6, it is characterised in that the natural marble
Stone uses natural Snow Flower White marble, and the natural marmorean water absorption rate of Snow Flower White is 0.92%, and bulk density is 2.7g/cm3。
8. the preparation method of luminous resin glue described in a kind of any one of claim 1-7, it is characterised in that comprise the following steps:
1)Using the agitator tank for not containing metallics, speed of agitator is not less than 1500rpm, and summer whipping temp is no more than 60
DEG C, winter whipping temp is not less than 30 DEG C;
2)Acrylic size, polyamine wax are added in agitator tank, luminescent powder is added, after stirring 15-20min, froth breaking is added
Agent, ultra-violet absorber, coupling agent, drier, after stirring 10min, add 0.1 times of curing agent of acrylic size content,
Uniform stirring 15min can obtain luminous resin glue.
9. the outdoor energy-accumulating luminous crystal floor tile of one kind according to claim 1, it is characterised in that the length and width chi of the ground
It is very little for 100mm*100mm, 100mm*200mm, 200mm*200mm, 150mm*150mm, 150mm*300mm, 300mm*300mm,
300mm*600mm、600mm*600mm、350mm*350mm、350mm*700mm、700mm*700mm、400mm*400mm、
Any one in 400mm*800mm or 800mm*800mm, the luminescent coating, the size of protective layer coordinate with ground.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201710121058.5A CN106758686A (en) | 2017-03-02 | 2017-03-02 | A kind of outdoor energy-accumulating luminous crystal floor tile |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201710121058.5A CN106758686A (en) | 2017-03-02 | 2017-03-02 | A kind of outdoor energy-accumulating luminous crystal floor tile |
Publications (1)
Publication Number | Publication Date |
---|---|
CN106758686A true CN106758686A (en) | 2017-05-31 |
Family
ID=58959681
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201710121058.5A Pending CN106758686A (en) | 2017-03-02 | 2017-03-02 | A kind of outdoor energy-accumulating luminous crystal floor tile |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN106758686A (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108839399A (en) * | 2018-06-15 | 2018-11-20 | 周抒函 | A kind of luminous brick and preparation method thereof |
CN109094164A (en) * | 2018-06-15 | 2018-12-28 | 周抒函 | A kind of luminescent screen and preparation method thereof |
CN109233403A (en) * | 2017-06-05 | 2019-01-18 | 天津众升自发光材料科技有限公司 | A kind of wear-resisting luminous resin glue, preparation method and application |
CN110540728A (en) * | 2019-09-16 | 2019-12-06 | 周立军 | energy-storage self-luminous material, preparation method and application thereof, self-luminous particles and self-luminous brick |
CN110919831A (en) * | 2019-11-21 | 2020-03-27 | 佛山欧神诺陶瓷有限公司 | Energy-storage luminous ceramic tile and preparation method thereof |
CN114454964A (en) * | 2022-02-10 | 2022-05-10 | 张家港天乐橡塑科技股份有限公司 | Luminous fender |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1096016A (en) * | 1993-06-05 | 1994-12-07 | 岑绍辉 | Artificial luminous marble |
CN2410117Y (en) * | 2000-02-22 | 2000-12-13 | 刘红梅 | Ceramic tile made of crystal |
CN2692198Y (en) * | 2003-08-23 | 2005-04-13 | 张昆 | Long effect road boundary stone |
CN101070948A (en) * | 2007-05-11 | 2007-11-14 | 杨毅男 | Environment-protection energy-accumulated self-illuminating and light-reflecting structure |
CN202430934U (en) * | 2012-01-05 | 2012-09-12 | 佛山欧神诺陶瓷股份有限公司 | Fluorescent anti-counterfeiting composite tile |
CN103603475A (en) * | 2013-11-21 | 2014-02-26 | 陈奎鹏 | Novel self-luminous building brick and manufacturing method thereof |
CN204282721U (en) * | 2014-11-17 | 2015-04-22 | 李洪基 | Compound microlite ceramic tile |
CN104559625A (en) * | 2013-10-28 | 2015-04-29 | 常州光辉化工有限公司 | Hot-melt self-luminous road marking coating and production process thereof |
CN105969160A (en) * | 2016-05-10 | 2016-09-28 | 宿州典跃新型建筑材料有限公司 | Environment-friendly water-based self-luminous coating with good weather fastness |
-
2017
- 2017-03-02 CN CN201710121058.5A patent/CN106758686A/en active Pending
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1096016A (en) * | 1993-06-05 | 1994-12-07 | 岑绍辉 | Artificial luminous marble |
CN2410117Y (en) * | 2000-02-22 | 2000-12-13 | 刘红梅 | Ceramic tile made of crystal |
CN2692198Y (en) * | 2003-08-23 | 2005-04-13 | 张昆 | Long effect road boundary stone |
CN101070948A (en) * | 2007-05-11 | 2007-11-14 | 杨毅男 | Environment-protection energy-accumulated self-illuminating and light-reflecting structure |
CN202430934U (en) * | 2012-01-05 | 2012-09-12 | 佛山欧神诺陶瓷股份有限公司 | Fluorescent anti-counterfeiting composite tile |
CN104559625A (en) * | 2013-10-28 | 2015-04-29 | 常州光辉化工有限公司 | Hot-melt self-luminous road marking coating and production process thereof |
CN103603475A (en) * | 2013-11-21 | 2014-02-26 | 陈奎鹏 | Novel self-luminous building brick and manufacturing method thereof |
CN204282721U (en) * | 2014-11-17 | 2015-04-22 | 李洪基 | Compound microlite ceramic tile |
CN105969160A (en) * | 2016-05-10 | 2016-09-28 | 宿州典跃新型建筑材料有限公司 | Environment-friendly water-based self-luminous coating with good weather fastness |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109233403A (en) * | 2017-06-05 | 2019-01-18 | 天津众升自发光材料科技有限公司 | A kind of wear-resisting luminous resin glue, preparation method and application |
CN108839399A (en) * | 2018-06-15 | 2018-11-20 | 周抒函 | A kind of luminous brick and preparation method thereof |
CN109094164A (en) * | 2018-06-15 | 2018-12-28 | 周抒函 | A kind of luminescent screen and preparation method thereof |
CN110540728A (en) * | 2019-09-16 | 2019-12-06 | 周立军 | energy-storage self-luminous material, preparation method and application thereof, self-luminous particles and self-luminous brick |
CN110919831A (en) * | 2019-11-21 | 2020-03-27 | 佛山欧神诺陶瓷有限公司 | Energy-storage luminous ceramic tile and preparation method thereof |
CN114454964A (en) * | 2022-02-10 | 2022-05-10 | 张家港天乐橡塑科技股份有限公司 | Luminous fender |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN106758686A (en) | A kind of outdoor energy-accumulating luminous crystal floor tile | |
CN103740215B (en) | A kind of high-performance building heat-reflecting insulating coating and its preparation method and application | |
CN102786229B (en) | There is glass or the crystallized glass article of decorative coveringn | |
CN105567021B (en) | A kind of aqueous cold pigment multifunctional thermal-insulation exterior wall true stone paint and preparation method thereof | |
CN104559625A (en) | Hot-melt self-luminous road marking coating and production process thereof | |
WO2017028471A1 (en) | Water-based reflective heat-insulating faux stone texture coating system for construction and preparation method thereof | |
CN105219146B (en) | A kind of aqueous colorful stone-like coating system | |
CN110004789A (en) | A kind of porous pavement and its construction method having self-luminous and reflection function concurrently | |
CN104293104B (en) | Noctilucent epoxy coiled material and preparation method thereof | |
CN108084752A (en) | A kind of tunnel inorganic aqueous energy-accumulating luminous paint and preparation method | |
CN109704735A (en) | A kind of energy saving luminous ceramics and preparation method thereof | |
CN101157573B (en) | Method for preparing colour glaze | |
CN101586017B (en) | Storage light-emitting silicone sealant | |
CN102585621B (en) | Smell purified and energy-saving decorating paint | |
CN101612627B (en) | Method for preparing stained glass grains with discarded and used glass and application thereof | |
CN102174282A (en) | Methods for preparing inorganic noctilucent, fluorescent and reflective materials and application of inorganic luminescent, fluorescent, reflective materials in high-temperature toughened glass printing ink | |
CN206800127U (en) | A kind of luminescence crystal floor tile of outdoor use | |
CN102898185B (en) | Production process of luminous ceramic product | |
CN112979240A (en) | High-reflectivity water permeable brick | |
CN206591396U (en) | Outdoor use accumulation of energy floor tile | |
CN202730010U (en) | Extra-long afterglow luminescent glass particle | |
CN206828390U (en) | A kind of energy-accumulating luminous glass of overlength afterglow | |
CN204454881U (en) | With the overlength afterglow fluorescent glass particle of luminous paint layer | |
CN101429354B (en) | Luminous paint and method for preparing same | |
CN107780594A (en) | A kind of self-luminous printing opacity green concrete structure and its preparation technology |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
TA01 | Transfer of patent application right | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20181210 Address after: 301600 Tianjin Jinghai District Shuangtang Town Old 104 National Road Shuangtang Town Zengfutang Village Applicant after: Tianjin glowing Mstar Technology Ltd Address before: 157500 East 95 Railway Street, Bamiantong Town, Muling City, Mudanjiang City, Heilongjiang Province Applicant before: Zhou Shuhan |
|
RJ01 | Rejection of invention patent application after publication | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170531 |