CN106758686A - A kind of outdoor energy-accumulating luminous crystal floor tile - Google Patents

A kind of outdoor energy-accumulating luminous crystal floor tile Download PDF

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Publication number
CN106758686A
CN106758686A CN201710121058.5A CN201710121058A CN106758686A CN 106758686 A CN106758686 A CN 106758686A CN 201710121058 A CN201710121058 A CN 201710121058A CN 106758686 A CN106758686 A CN 106758686A
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China
Prior art keywords
floor tile
resin glue
ground
luminescent
parts
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CN201710121058.5A
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Chinese (zh)
Inventor
周抒函
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Tianjin glowing Mstar Technology Ltd
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周抒函
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Priority to CN201710121058.5A priority Critical patent/CN106758686A/en
Publication of CN106758686A publication Critical patent/CN106758686A/en
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    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C17/00Pavement lights, i.e. translucent constructions forming part of the surface
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C15/00Pavings specially adapted for footpaths, sidewalks or cycle tracks
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C2201/00Paving elements
    • E01C2201/04Paving elements consisting of natural stones and a binder

Abstract

The present invention discloses a kind of outdoor energy-accumulating luminous crystal floor tile, belongs to energy-saving building material technical field, including ground, the luminescent coating being arranged on ground and the protective layer being arranged on luminescent coating;The ground is using the one kind in natural marble or acidproof brick;The luminescent coating uses energy-accumulating luminous resin glue, and by weight, luminous resin glue is obtained by 20 40 parts of luminescent powders, 50 70 parts of acrylic sizes, 5 15 parts of auxiliary agents without heavy metal compound;The protective layer uses the height that thickness is the silicate glass sand of 1mm 2mm, size is 1mm 6mm, and bead or thickness are any one in 2mm 8mm ultra-clear glasses face thoroughly, wherein, the particle diameter of silicate glass sand is 2 120 mesh.Obtained floor tile illumination effect of the invention is good, is not required to power consumption, and the luminescent material in low cost, and floor tile is safe and harmless.

Description

A kind of outdoor energy-accumulating luminous crystal floor tile
Technical field
The present invention relates to a kind of floor tile, and in particular to a kind of outdoor energy-accumulating luminous crystal floor tile, belong to energy-saving building material technology Field.
Background technology
Square general at present or street can spread on the ground in order to realize illuminating road surface or increase night decorative effect If light-emitting floor tile.Existing light-emitting floor tile needs internally to install illuminating lamp and it is lighted with power on, and power consumption is big, wave Take the energy;Or using luminous pigment or reflecting coating brushing on brick body surface, this method is luminous or reflecting effect is not obvious, And abrasion again clearly;In addition, traditional luminous paint using sulfide as luminescent material is the extension sunset glow time, often Radioactive element is added, the person is caused harm, and luminescent lifetime is shorter.
The content of the invention
For the problem that above-mentioned prior art is present, the present invention provides a kind of outdoor energy-accumulating luminous crystal floor tile, obtained Floor tile illumination effect is good, is not required to power consumption, and the luminescent material in low cost, and floor tile is safe and harmless.
To achieve these goals, a kind of outdoor energy-accumulating luminous crystal floor tile that the present invention is used, including ground, be arranged on Luminescent coating on ground and the protective layer being arranged on luminescent coating;
The ground is using the one kind in natural marble or acidproof brick;
The luminescent coating uses energy-accumulating luminous resin glue, and by weight, luminous resin glue is by 20-40 parts of luminescent powder, 50-70 Part acrylic size, the 5-15 parts of auxiliary agent without heavy metal compound are obtained;
The protective layer uses silicate glass sand, height saturating bead or thickness that size be 1mm-6mm of the thickness for 1mm-2mm It is any one in 2mm-8mm ultra-clear glasses face, wherein, the particle diameter of silicate glass sand is 2-120 mesh.
Used as improvement, the luminescent powder particle diameter is 100-300 mesh, and described auxiliary agent is inhaled by defoamer, drier, ultraviolet Receive agent, coupling agent, polyamine wax according to(0.3-0.5):(0.1-0.35):0.4:1.6:1.4 prepare.
Used as improvement, described luminous resin glue includes following components:Luminescent powder, 30 parts;Acrylic size, 60 parts; Auxiliary agent without heavy metal compound, 10 parts.
Used as improvement, the auxiliary agent includes the component of following proportioning, by defoamer, drier, ultra-violet absorber, coupling Agent, polyamine wax are according to 0.4:0.35:0.4:1.6:1.4 proportions.
Used as improvement, the viscosity of the acrylic size is 2000-5000 pools.
Used as improvement, by mass percentage, the acidproof brick is grouped into by following content groups, 60%-70%SiO2、 0.1%-0.8%MgO、20%-30%Al2O3、0.5%-3%Na2O、0.5%-3%FeO、1.5%-2%K2O and 0.3%-1%CaO.
Used as improvement, the natural marble uses natural Snow Flower White marble, the natural marmorean water suction of Snow Flower White Rate is 0.92%, and bulk density is 2.7g/cm3
In addition, present invention also offers a kind of preparation method of luminous resin glue described in any of the above-described, including following step Suddenly:
1)Using the agitator tank for not containing metallics, speed of agitator is not less than 1500rpm, and summer whipping temp is no more than 60 DEG C, winter whipping temp is not less than 30 DEG C;
2)Acrylic size, polyamine wax are added in agitator tank, luminescent powder is added, after stirring 15-20min, froth breaking is added Agent, ultra-violet absorber, coupling agent, drier, after stirring 10min, add 0.1 times of curing agent of acrylic size content, Uniform stirring 15min can obtain luminous resin glue.
As improvement, the length and width size of the ground is 100mm*100mm, 100mm*200mm, 200mm*200mm, 150mm*150mm、150mm*300mm、300mm*300mm、300mm*600mm、600mm*600mm、350mm*350mm、 Any one in 350mm*700mm, 700mm*700mm, 400mm*400mm, 400mm*800mm or 800mm*800mm, the hair Light coating, the size of protective layer coordinate with ground.
Using natural marble or acidproof brick as ground, acidproof brick is with quartz, feldspar, clay as main former to the present invention Material, the resistant material being made is decomposed through high-temperature oxydation, and high with acid-alkali-resistant degree, water absorption rate is low, not oxidizable at normal temperatures, no Easily by performances such as medium pollutions, in addition to hydrofluoric acid and hot phosphoric acid, to acids such as warm villaumite water, hydrochloric acid, sulfuric acid, nitric acid and in normal temperature Under any concentration bases, have excellent anti-rotten effect;Natural marble, kind background color is white, and lines distribution or gray line Pass through plate face, lines skewness, luminosity is fabulous, can be up to 120 degree.
Using luminous resin glue as energy-accumulating luminous coating, the luminous resin glue has decoration performance good, energy saving, nothing Malicious, "dead", long-term luminous excellent performance, luminosity can be adjusted, and storage stability is good, low cost, economic benefit and The significant advantage of social benefit, its every technical performance index is superior to other energy-accumulating luminous paints, with extensive popularization Prospect.
In addition, the present invention uses silicate glass sand, bead thoroughly high or ultra-clear glasses face as the protection of luminescent coating Layer, wherein glass sand has advantages below, and transparency is good, hardness is high, particle diameter distribution is uniform;Glass sand good dispersion, with resin It is good with other compositions intermiscibility in paint systems;Glass sand is filled through repeatedly surface treatment in paint systems, and paint film is not Band blue light, recoatability is good;In high-grade scratch resistant finish paint, hardness, the toughness of finish paint can be increased, improve the scratch resistance of paint film Can, with photoextinction, the weatherability of paint film can be improved.The saturating bead of height of use, compression strength reaches 3300kg/cm2, Four hours weightlessness 0.005mg/cm are boiled in 20%HCL solution2.The ultra-clear glasses face of use, is a kind of high-quality, multi-functional Novel high-grade glass kind, light transmittance is up to more than 91.5%, and its self-destruction rate is low, solid colour, visible light transmissivity are high, penetrating Property is good.
Specific embodiment
To make the object, technical solutions and advantages of the present invention of greater clarity, below by embodiment, the present invention is entered Row is further described.However, it should be understood that the specific embodiments described herein are merely illustrative of the present invention, and without In limitation the scope of the present invention.
Unless otherwise defined, all of technical term used herein and scientific terminology are led with technology of the invention is belonged to The implication that the technical staff in domain is generally understood that is identical, and the term for being used in the description of the invention herein is intended merely to retouch State the purpose of specific embodiment, it is not intended that in the limitation present invention.
A kind of outdoor energy-accumulating luminous crystal floor tile, including ground, the luminescent coating that is arranged on ground and be arranged on luminous Protective layer on coating;
The ground is using the one kind in natural marble or acidproof brick;
The luminescent coating uses energy-accumulating luminous resin glue, and by weight, luminous resin glue is by 20-40 parts of luminescent powder, 50-70 Part acrylic size, the 5-15 parts of auxiliary agent without heavy metal compound are obtained;
The protective layer uses silicate glass sand, height saturating bead or thickness that size be 1mm-6mm of the thickness for 1mm-2mm It is any one in 2mm-8mm ultra-clear glasses face, wherein, the particle diameter of silicate glass sand is 2-120 mesh.
It with quartz, feldspar, clay is primary raw material that acidproof brick is, by mass percentage, the acidproof brick is contained by following Amount component composition, 60%-70%SiO2、0.1%-0.8%MgO、20%-30%Al2O3、0.5%-3%Na2O、0.5%-3%FeO、1.5%- 2%K2O and 0.3%-1%CaO.Acidproof brick decomposes the resistant material being made, water absorption rate high with acid-alkali-resistant degree through high-temperature oxydation It is low, it is not oxidizable at normal temperatures, be difficult by performances such as medium pollutions, in addition to hydrofluoric acid and hot phosphoric acid, to warm villaumite water, hydrochloric acid, The bases of the acids such as sulfuric acid, nitric acid and any concentration at normal temperatures, there is excellent anti-rotten effect;Natural marble, kind Background color is white, and lines distribution or gray line pass through plate face, and lines skewness, luminosity is fabulous, can be up to 120 degree.
Using silicate glass sand, bead thoroughly high or ultra-clear glasses face as luminescent coating protective layer, wherein glass Sand has advantages below, and transparency is good, hardness is high, particle diameter distribution is uniform;Glass sand good dispersion, in resin and paint systems Other compositions intermiscibility it is good;Glass sand is filled through repeatedly surface treatment in paint systems, and paint film is without blue light, recoating Property is good;In high-grade scratch resistant finish paint, hardness, the toughness of finish paint can be increased, the scratch resistance energy of paint film be improved, with delustring Effect, can improve the weatherability of paint film.The saturating bead of height of use, compression strength reaches 3300kg/cm2, in 20%HCL solution Boil four hours weightlessness 0.005mg/cm2.The ultra-clear glasses face of use, is a kind of high-quality, multifunctional novel high-grade glass Kind, up to more than 91.5%, its self-destruction rate is low, solid colour, visible light transmissivity are high, and permeability is good for light transmittance.
Used as the improvement of embodiment, the luminescent powder particle diameter is 100-300 mesh, described auxiliary agent by defoamer, drier, Ultra-violet absorber, coupling agent, polyamine wax according to(0.3-0.5):(0.1-0.35):0.4:1.6:1.4 prepare.Defoamer can be with Using the fatty acid ester compounded thing of higher alcohols, drier be able to can be used using dibutyl tin laurate, ultra-violet absorber UV-P, coupling agent can use common silane coupler.Above-mentioned each component, those skilled in the art can use and realize phase Other materials of function are answered come for producing.When using, because luminescent powder is divided into green-yellow light, blue green light, day blue light, purple light, white Light, feux rouges, therefore using fluorescent pigment, dyestuff, the luminous front and rear color of adjustment, fluorescer adding proportion is about luminescent powder weight The 1% ~ 5% of amount, it is possible to use general dye, pigmented tinting.
Used as the further preferred of embodiment, described luminous resin glue includes following components:Luminescent powder, 30 parts;Propylene Acid resin glue, 60 parts;Auxiliary agent without heavy metal compound, 10 parts.
Used as the improvement of embodiment, the auxiliary agent includes the component of following proportioning, is inhaled by defoamer, drier, ultraviolet Agent, coupling agent, polyamine wax are received according to 0.4:0.35:0.4:1.6:1.4 proportions.
Used as the improvement of embodiment, the viscosity of the acrylic size is 2000-5000 pools.
Used as the improvement of embodiment, the natural marble uses natural Snow Flower White marble, the natural Snow Flower White Dali The water absorption rate of stone is 0.92%, and bulk density is 2.7g/cm3.Snowflake white marble be free of any dyestuff, with it is nontoxic, tasteless, The advantages of pollution-free, anticorrosive, acid and alkali-resistance, uprising solarization, nondiscolouring.
Embodiment one
A kind of outdoor energy-accumulating luminous crystal floor tile, including ground, the luminescent coating that is arranged on ground and it is arranged on luminescent coating On protective layer;
The ground uses natural marble, the natural marble to use natural Snow Flower White marble, and the natural Snow Flower White is big The water absorption rate of reason stone is 0.92%, and bulk density is 2.7g/cm3
The luminescent coating uses energy-accumulating luminous resin glue, and by weight, luminous resin glue is by 20 parts of luminescent powders, 50 parts of propylene Acid resin glue, 5 parts of auxiliary agents without heavy metal compound are obtained, wherein, the auxiliary agent is inhaled by defoamer, drier, ultraviolet Agent, coupling agent, polyamine wax are received according to 0.3:0.1:0.4:1.6:1.4 prepare, and the specific preparation process of luminous resin glue is as follows:
1)Using the agitator tank for not containing metallics, speed of agitator is not less than 1500rpm, and Various Seasonal whipping temp is different, Summer whipping temp is no more than 60 DEG C, and winter whipping temp is not less than 30 DEG C;
2)Acrylic size, polyamine wax are added in agitator tank, luminescent powder is added, after stirring 15-20min, froth breaking is added Agent, ultra-violet absorber, coupling agent, drier, after stirring 10min, add 0.1 times of curing agent of acrylic size content (P-hydroxybenzenyl sulfonate), uniform stirring 15min can luminous resin glue;
The resin glue that will be prepared is placed on ground, and then protective layer is placed on resin glue, and the protective layer is using thick The silicate glass sand for 1mm-2mm is spent, wherein, the particle diameter of silicate glass sand is 2-120 mesh;
Using light-emitting floor tile obtained in the present invention, due to containing luminous resin glue, it has and absorbs and store luminous energy, evening daytime Ornament lamp can be replaced, the product with its decorative exterior wall and various structures with the performance of more than continuous illumination 12h after darkness It is nontoxic, "dead", it is a kind of functional ornamentation coating for integrating decoration, energy-conservation and environmental protection.
Obtained light-emitting floor tile, according to actual needs, can produce according to different specifications, such as 100mm*100mm, 100mm*200mm、200mm*200mm、150mm*150mm、150mm*300mm、300mm*300mm、300mm*600mm、 600mm*600mm, 350mm*350mm, 350mm*700mm, 700mm*700mm, 400mm*400mm, 400mm*800mm or 800mm*800mm etc..
To the light-emitting floor tile in embodiment one, through national building materials, test center tests, related data such as following table 1:
The detection information of the light-emitting floor tile of table 1
Analytical table 1 understands that wearability, frost resistance, compression strength, radioactivity of the crystal floor tile etc. meet national standard.
Embodiment two
A kind of outdoor energy-accumulating luminous crystal floor tile, including ground, the luminescent coating that is arranged on ground and it is arranged on luminescent coating On protective layer;
The ground uses acidproof brick, the acidproof brick to be grouped into by following content groups, 60%-70%SiO2、0.1%-0.8%MgO、 20%-30%Al2O3、0.5%-3%Na2O、0.5%-3%FeO、1.5%-2%K2O and 0.3%-1%CaO;
The luminescent coating uses energy-accumulating luminous resin glue, and by weight, luminous resin glue is by 40 parts of luminescent powders, 70 parts of propylene Acid resin glue, 15 parts of auxiliary agents without heavy metal compound are obtained, wherein, the auxiliary agent is inhaled by defoamer, drier, ultraviolet Agent, coupling agent, polyamine wax are received according to 0.5:0.35:0.4:1.6:1.4 prepare, and the specific preparation process of luminous resin glue is as follows:
1)Using the agitator tank for not containing metallics, speed of agitator is not less than 1500rpm, and summer whipping temp is no more than 60 DEG C, winter whipping temp is not less than 30 DEG C;
2)Acrylic size, polyamine wax are added in agitator tank, luminescent powder is added, after stirring 15-20min, froth breaking is added Agent, ultra-violet absorber, coupling agent, drier, after stirring 10min, add 0.1 times of curing agent of acrylic size content, Uniform stirring 15min can obtain luminous resin glue;
The resin glue that will be prepared is placed on ground, and then protective layer is placed on resin glue, and the protective layer uses chi Very little is the saturating bead of the height of 1mm-6mm;
Using light-emitting floor tile obtained in the present invention, due to containing luminous resin glue, it has and absorbs and store luminous energy, evening daytime Ornament lamp can be replaced, the product with its decorative exterior wall and various structures with the performance of more than continuous illumination 12h after darkness It is nontoxic, "dead", it is a kind of functional ornamentation coating for integrating decoration, energy-conservation and environmental protection.
Obtained light-emitting floor tile, according to actual needs, can produce according to different specification, such as 100*100,200*100, 200*200,150*300,300*300,300*600 or 600*600 etc..
Embodiment three
A kind of outdoor energy-accumulating luminous crystal floor tile, including ground, the luminescent coating that is arranged on ground and it is arranged on luminescent coating On protective layer;
The ground is grouped into using the one kind in natural marble or acidproof brick, the acidproof brick by following content groups, 60%- 70%SiO2、0.1%-0.8%MgO、20%-30%Al2O3、0.5%-3%Na2O、0.5%-3%FeO、1.5%-2%K2O and 0.3%-1% CaO;The natural marble uses natural Snow Flower White marble, and the natural marmorean water absorption rate of Snow Flower White is 0.92%, volume Density is 2.7g/cm3, flexing resistance 9.2Mpa;
The luminescent coating uses energy-accumulating luminous resin glue, and by weight, luminous resin glue is by 30 parts of luminescent powders, 60 parts of propylene Acid resin glue, 10 parts of auxiliary agents without heavy metal compound are obtained, wherein, the auxiliary agent is inhaled by defoamer, drier, ultraviolet Agent, coupling agent, polyamine wax are received according to 4:0.1:0.4:1.6:1.4 prepare, and the specific preparation process of luminous resin glue is as follows:
1)Using the agitator tank for not containing metallics, speed of agitator is not less than 1500rpm, and summer whipping temp is no more than 60 DEG C, winter whipping temp is not less than 30 DEG C;
2)Acrylic size, polyamine wax are added in agitator tank, luminescent powder is added, after stirring 18min, addition defoamer, Ultra-violet absorber, coupling agent, drier, after stirring 10min, add 0.1 times of curing agent of acrylic size content, uniformly Stirring 15min can obtain luminous resin glue, and the resin glue belongs to A grades, can be used for all of position by detection, its radioactivity, Avoid causing harm the person.Because the overlength afterglow luminescence powder that the resin glue is used is lighting with fine durability Powder, its luminescence process is physical process, luminescent lifetime more than 10 years, considerably beyond luminous with sulfide as luminescent material The luminescent lifetime of coating;
The resin glue that will be prepared is placed on ground, and then protective layer is placed on resin glue, and the protective layer is using thick It is 2mm-8mm ultra-clear glasses face to spend;
Obtained light-emitting floor tile, according to actual needs, can produce, such as 150mm*300mm, 300mm* according to different specifications 300mm、300mm*600mm、600mm*600mm、350mm*350mm、350mm*700mm、700mm*700mm、400mm* 400mm, 400mm*800mm or 800mm*800mm etc..
Common floor tile, the single and energy-accumulating luminous crystal floor tile color of color is gorgeous, and night can discharge radiance, energy-accumulating luminous Floor tile has pollution-free, water resistance, mainly absorbs the visible rays such as sunlight, light, ultraviolet, veiling glare, and it can be followed infinitely Ring is used, the material is "dead" element.The sunset glow duration of the brick can reach 8-12 hours, greatly saved electric power into This, accomplishes the effect of economical environment-protective, environmental protection, beautifying city.
Presently preferred embodiments of the present invention is the foregoing is only, is not intended to limit the invention, it is all in essence of the invention Any modification, equivalent or improvement made within god and principle etc., should be included within the scope of the present invention.

Claims (9)

1. a kind of outdoor energy-accumulating luminous crystal floor tile, it is characterised in that including ground, the luminescent coating being arranged on ground and It is arranged on the protective layer on luminescent coating;
The ground is using the one kind in natural marble or acidproof brick;
The luminescent coating uses energy-accumulating luminous resin glue, and by weight, luminous resin glue is by 20-40 parts of luminescent powder, 50-70 Part acrylic size, the 5-15 parts of auxiliary agent without heavy metal compound are obtained;
The protective layer uses silicate glass sand, height saturating bead or thickness that size be 1mm-6mm of the thickness for 1mm-2mm It is any one in 2mm-8mm ultra-clear glasses face, wherein, the particle diameter of silicate glass sand is 2-120 mesh.
2. the outdoor energy-accumulating luminous crystal floor tile of one kind according to claim 1, it is characterised in that the luminescent powder particle diameter is 100-300 mesh, described auxiliary agent by defoamer, drier, ultra-violet absorber, coupling agent, polyamine wax according to(0.3-0.5): (0.1-0.35):0.4:1.6:1.4 prepare.
3. the outdoor energy-accumulating luminous crystal floor tile of one kind according to claim 2, it is characterised in that described luminous resin glue Including following components:Luminescent powder, 30 parts;Acrylic size, 60 parts;Auxiliary agent without heavy metal compound, 10 parts.
4. the outdoor energy-accumulating luminous crystal floor tile of one kind according to claim 3, it is characterised in that the auxiliary agent includes following The component of proportioning, by defoamer, drier, ultra-violet absorber, coupling agent, polyamine wax according to 0.4:0.35:0.4:1.6:1.4 Proportions.
5. the outdoor energy-accumulating luminous crystal floor tile of one kind according to claim 4, it is characterised in that the acrylic size Viscosity be 2000-5000 pool.
6. the outdoor energy-accumulating luminous crystal floor tile of one kind according to claim 1, it is characterised in that by mass percentage, The acidproof brick is grouped into by following content groups, 60%-70%SiO2、0.1%-0.8%MgO、20%-30%Al2O3、0.5%-3% Na2O、0.5%-3%FeO、1.5%-2%K2O and 0.3%-1%CaO.
7. a kind of outdoor energy-accumulating luminous crystal floor tile according to claim 1 or 6, it is characterised in that the natural marble Stone uses natural Snow Flower White marble, and the natural marmorean water absorption rate of Snow Flower White is 0.92%, and bulk density is 2.7g/cm3
8. the preparation method of luminous resin glue described in a kind of any one of claim 1-7, it is characterised in that comprise the following steps:
1)Using the agitator tank for not containing metallics, speed of agitator is not less than 1500rpm, and summer whipping temp is no more than 60 DEG C, winter whipping temp is not less than 30 DEG C;
2)Acrylic size, polyamine wax are added in agitator tank, luminescent powder is added, after stirring 15-20min, froth breaking is added Agent, ultra-violet absorber, coupling agent, drier, after stirring 10min, add 0.1 times of curing agent of acrylic size content, Uniform stirring 15min can obtain luminous resin glue.
9. the outdoor energy-accumulating luminous crystal floor tile of one kind according to claim 1, it is characterised in that the length and width chi of the ground It is very little for 100mm*100mm, 100mm*200mm, 200mm*200mm, 150mm*150mm, 150mm*300mm, 300mm*300mm, 300mm*600mm、600mm*600mm、350mm*350mm、350mm*700mm、700mm*700mm、400mm*400mm、 Any one in 400mm*800mm or 800mm*800mm, the luminescent coating, the size of protective layer coordinate with ground.
CN201710121058.5A 2017-03-02 2017-03-02 A kind of outdoor energy-accumulating luminous crystal floor tile Pending CN106758686A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108839399A (en) * 2018-06-15 2018-11-20 周抒函 A kind of luminous brick and preparation method thereof
CN109094164A (en) * 2018-06-15 2018-12-28 周抒函 A kind of luminescent screen and preparation method thereof
CN109233403A (en) * 2017-06-05 2019-01-18 天津众升自发光材料科技有限公司 A kind of wear-resisting luminous resin glue, preparation method and application
CN110540728A (en) * 2019-09-16 2019-12-06 周立军 energy-storage self-luminous material, preparation method and application thereof, self-luminous particles and self-luminous brick
CN110919831A (en) * 2019-11-21 2020-03-27 佛山欧神诺陶瓷有限公司 Energy-storage luminous ceramic tile and preparation method thereof
CN114454964A (en) * 2022-02-10 2022-05-10 张家港天乐橡塑科技股份有限公司 Luminous fender

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CN2692198Y (en) * 2003-08-23 2005-04-13 张昆 Long effect road boundary stone
CN101070948A (en) * 2007-05-11 2007-11-14 杨毅男 Environment-protection energy-accumulated self-illuminating and light-reflecting structure
CN202430934U (en) * 2012-01-05 2012-09-12 佛山欧神诺陶瓷股份有限公司 Fluorescent anti-counterfeiting composite tile
CN104559625A (en) * 2013-10-28 2015-04-29 常州光辉化工有限公司 Hot-melt self-luminous road marking coating and production process thereof
CN103603475A (en) * 2013-11-21 2014-02-26 陈奎鹏 Novel self-luminous building brick and manufacturing method thereof
CN204282721U (en) * 2014-11-17 2015-04-22 李洪基 Compound microlite ceramic tile
CN105969160A (en) * 2016-05-10 2016-09-28 宿州典跃新型建筑材料有限公司 Environment-friendly water-based self-luminous coating with good weather fastness

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109233403A (en) * 2017-06-05 2019-01-18 天津众升自发光材料科技有限公司 A kind of wear-resisting luminous resin glue, preparation method and application
CN108839399A (en) * 2018-06-15 2018-11-20 周抒函 A kind of luminous brick and preparation method thereof
CN109094164A (en) * 2018-06-15 2018-12-28 周抒函 A kind of luminescent screen and preparation method thereof
CN110540728A (en) * 2019-09-16 2019-12-06 周立军 energy-storage self-luminous material, preparation method and application thereof, self-luminous particles and self-luminous brick
CN110919831A (en) * 2019-11-21 2020-03-27 佛山欧神诺陶瓷有限公司 Energy-storage luminous ceramic tile and preparation method thereof
CN114454964A (en) * 2022-02-10 2022-05-10 张家港天乐橡塑科技股份有限公司 Luminous fender

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