CN1096016A - Artificial luminous marble - Google Patents

Artificial luminous marble Download PDF

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Publication number
CN1096016A
CN1096016A CN 93106578 CN93106578A CN1096016A CN 1096016 A CN1096016 A CN 1096016A CN 93106578 CN93106578 CN 93106578 CN 93106578 A CN93106578 A CN 93106578A CN 1096016 A CN1096016 A CN 1096016A
Authority
CN
China
Prior art keywords
marble
luminous
artificial
surface layer
light emitting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN 93106578
Other languages
Chinese (zh)
Inventor
岑绍辉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN 93106578 priority Critical patent/CN1096016A/en
Publication of CN1096016A publication Critical patent/CN1096016A/en
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
    • C04B41/48—Macromolecular compounds
    • C04B41/4826—Polyesters
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/54—Substitutes for natural stone, artistic materials or the like
    • C04B2111/542—Artificial natural stone
    • C04B2111/545—Artificial marble
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/80—Optical properties, e.g. transparency or reflexibility

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Finishing Walls (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Macromonomer-Based Addition Polymer (AREA)

Abstract

The present invention discloses a kind of artificial luminous marble, based on polyester type or composite artificial marble production technique, introduces the light emitting sheet surface layer, goods show as the natural marble proterties daytime, night, decorative pattern was luminous, and luminosity is big especially, and fluorescent lifetime was more than 12 hours.Be applicable to building wall ground veneer and make tea table face and artwork.

Description

Artificial luminous marble
The present invention relates to artificial luminous marble, belong to the artificial stone-like material field, international classification number C04.
Existing artificial luminous marble production technique is invented just like application number 92103179.3(in the patent documentation) described, description be the manufacture method of cement mo(u)ld (comprising high-alumina cement and magnesia) artificial luminous marble.Because of cement particle and assorted obstruction of expecting the luminescent powder optical channel, luminous efficiency is low, thereby mixes more luminescent powder and still fail to obtain satisfied luminosity, is difficult to move towards practicability.
Order of the present invention is based on existing polyester type or composite artificial marble production technique, introduces the light emitting sheet surface layer, provides a kind of luminosity big, really presents the extraordinary dalle of luminous reason parmelia saxatilis line.
The present invention realizes like this.Make binding agent with transparent or light unsaturated polyester resin, luminescent powder through certain moulding process, forms the light emitting sheet surface layer of polyester artificial marble as luminous agent and filler under the solidifying agent effect.Treat that upper layer fully solidifies back cast structural sheet, promptly makes after the slaking fully and shows as the natural marble proterties daytime, the luminous artificial luminous marble of decorative pattern at night.
In the light-emitting area layer material,, both can constitute, also can mix formation with certain proportion with luminescent powder and ballast, stone flour, hard glass pearl hard transparent materials such as (or) chunk glasss by luminescent powder as the filler part.The light emitting sheet surface layer filler that constitutes of luminescent powder and hard glass pearl particularly, luminous can not hindered by transparent material, and luminous efficiency is big, and luminescent powder and resin demand reduce, and cost is lower, and the while product surface has " crystal face " refracted light effect.With the light emitting sheet surface layer that the luminescent powder of different colors is made, can form the luminous reason parmelia saxatilis line of different colors.
The filler of light emitting sheet surface layer also can be mixed with certain proportion with luminescent powder, hard transparent material and constituted by light emitting sheet surface layer particle, luminous ceramic glaze particle or these particles after the sclerosis.
The light emitting sheet surface layer of artificial luminous marble both can be that the part decorative pattern is luminous, also can be that whole decorative patterns are luminous, and particular case should be decided on actual needs.Non-luminous figure manufacture method is with the conventional polyester marble.
In addition, also can add auxiliary agents such as UV light absorber, white dyes in the light emitting sheet surface layer.
The structural sheet of artificial luminous marble both can be made by vibrin, also can make of inorganic materials such as high-alumina cement, or inorganic materials impregnated in the organic monomer through certain technology polymerization making.Former approach is pure polyester type, and the latter two are so-called compound artificial luminous marble.
This artificial luminous marble of the present invention, show as the natural marble proterties daytime, present beautiful luminous reason parmelia saxatilis line night, all above the cement mo(u)ld artificial luminous marble, luminosity is big for every performance index, can supply anxious illumination and low illumination, fluorescent lifetime was more than 12 hours, both can make building decorative plates, and can make artwork and tea table face etc. again, market outlook are wide.
For example, adopt 300 parts of 196# unsaturated polyester resins, 450 parts of luminescent powders, (red, yellow, green each 150 parts), 450 parts on hard glass pearl, each 12 parts of cyclohexanone peroxide slurry and cobalt naphthenate styrene solution are made the light emitting sheet surface layer through certain technology, fully solidify back cast structural sheet, slaking promptly makes the artificial luminous marble of three kinds of photochromic decorative patterns fully.

Claims (7)

1, artificial luminous marble, it is as follows to it is characterized by implementation method: make binding agent with transparent or light unsaturated polyester resin, luminescent powder is as luminous agent and filler, through certain moulding process, under the solidifying agent effect, form the light emitting sheet surface layer of polyester artificial marble, treat that upper layer fully solidifies back cast structural sheet, promptly makes artificial luminous marble after the slaking fully.
2, by the artificial luminous marble of claim 1 defined, it is characterized by the filler part of light emitting sheet surface layer, both can constitute separately, also can mix formation with ballast, stone flour, hard transparent material (chunk glass or hard glass pearl) with certain proportion by luminescent powder by luminescent powder.
3, by the artificial luminous marble of claim 1 defined, it is characterized by the filler of light emitting sheet surface layer, also can mix with certain proportion with luminescent powder and hard transparent material and constitute by light emitting sheet surface layer particle, luminous ceramic glaze particle or these particles after the sclerosis.
4, by the artificial luminous marble of claim 1 defined, it is characterized by the light emitting sheet surface layer both can be that whole decorative patterns are luminous, also can be that the part decorative pattern is luminous.
5, by the artificial luminous marble of claim 1 defined, but it is characterized by both bill coloured light of light emitting sheet surface layer, also can send out polychromatic light.
6,, it is characterized by in the light emitting sheet surface layer and also can add auxiliary agents such as UV light absorber, white dyes by the artificial luminous marble of claim 1 defined.
7, by the artificial luminous marble of claim 1 defined, it is characterized by structural sheet and both can make by vibrin, also can impregnated in the organic monomer and make through certain technology polymerization with inorganic materials making or inorganic materials.
CN 93106578 1993-06-05 1993-06-05 Artificial luminous marble Pending CN1096016A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 93106578 CN1096016A (en) 1993-06-05 1993-06-05 Artificial luminous marble

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 93106578 CN1096016A (en) 1993-06-05 1993-06-05 Artificial luminous marble

Publications (1)

Publication Number Publication Date
CN1096016A true CN1096016A (en) 1994-12-07

Family

ID=4986296

Family Applications (1)

Application Number Title Priority Date Filing Date
CN 93106578 Pending CN1096016A (en) 1993-06-05 1993-06-05 Artificial luminous marble

Country Status (1)

Country Link
CN (1) CN1096016A (en)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102774066A (en) * 2012-08-27 2012-11-14 高炳申 Overlong-afterglow shining artificial stone and preparation method thereof
CN102935738A (en) * 2011-08-16 2013-02-20 张磊 Novel artificial marble
CN104446143A (en) * 2014-11-19 2015-03-25 广西利升石业有限公司 Preparation method of artificial stone from colored glass particles
EP2791075A4 (en) * 2011-12-13 2015-10-28 Lg Hausys Ltd Synthetic marble with high hardness and method of manufacturing the same
CN105968763A (en) * 2016-06-12 2016-09-28 安徽广燕新材料科技有限责任公司 Preparation method of artificial stone material with good heat stability, high hardness and good toughness
CN106082785A (en) * 2016-06-12 2016-11-09 安徽广燕新材料科技有限责任公司 A kind of preparation method of artificial stone used for building exterior wall
CN106758686A (en) * 2017-03-02 2017-05-31 周抒函 A kind of outdoor energy-accumulating luminous crystal floor tile
CN107032661A (en) * 2016-12-02 2017-08-11 天津裕丰源环保科技有限公司 A kind of luminous waste stone dust artificial stone
CN110372413A (en) * 2019-08-20 2019-10-25 西安鸿钧睿泽新材料科技有限公司 A kind of energy-accumulating luminous type artificial stone and its manufacturing method

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102935738B (en) * 2011-08-16 2016-02-10 张磊 Novel artificial marble
CN102935738A (en) * 2011-08-16 2013-02-20 张磊 Novel artificial marble
EP2791075A4 (en) * 2011-12-13 2015-10-28 Lg Hausys Ltd Synthetic marble with high hardness and method of manufacturing the same
CN102774066B (en) * 2012-08-27 2014-12-17 高炳申 Overlong-afterglow shining artificial stone and preparation method thereof
CN102774066A (en) * 2012-08-27 2012-11-14 高炳申 Overlong-afterglow shining artificial stone and preparation method thereof
CN104446143B (en) * 2014-11-19 2016-07-06 广西利升石业有限公司 The preparation method that stained glass particulates is applied to artificial hilllock stone
CN104446143A (en) * 2014-11-19 2015-03-25 广西利升石业有限公司 Preparation method of artificial stone from colored glass particles
CN105968763A (en) * 2016-06-12 2016-09-28 安徽广燕新材料科技有限责任公司 Preparation method of artificial stone material with good heat stability, high hardness and good toughness
CN106082785A (en) * 2016-06-12 2016-11-09 安徽广燕新材料科技有限责任公司 A kind of preparation method of artificial stone used for building exterior wall
CN107032661A (en) * 2016-12-02 2017-08-11 天津裕丰源环保科技有限公司 A kind of luminous waste stone dust artificial stone
CN106758686A (en) * 2017-03-02 2017-05-31 周抒函 A kind of outdoor energy-accumulating luminous crystal floor tile
CN110372413A (en) * 2019-08-20 2019-10-25 西安鸿钧睿泽新材料科技有限公司 A kind of energy-accumulating luminous type artificial stone and its manufacturing method
CN110372413B (en) * 2019-08-20 2021-08-31 西安鸿钧睿泽新材料科技有限公司 Energy-storage luminous artificial stone and manufacturing method thereof

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C06 Publication
PB01 Publication
C01 Deemed withdrawal of patent application (patent law 1993)
WD01 Invention patent application deemed withdrawn after publication