CN106833201A - A kind of energy-accumulating luminous resin glue of overlength afterglow and preparation method thereof - Google Patents
A kind of energy-accumulating luminous resin glue of overlength afterglow and preparation method thereof Download PDFInfo
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- CN106833201A CN106833201A CN201710069226.0A CN201710069226A CN106833201A CN 106833201 A CN106833201 A CN 106833201A CN 201710069226 A CN201710069226 A CN 201710069226A CN 106833201 A CN106833201 A CN 106833201A
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- Prior art keywords
- resin glue
- energy
- parts
- luminous resin
- luminescent powder
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/22—Luminous paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention discloses energy-accumulating luminous resin glue of a kind of overlength afterglow and preparation method thereof, belongs to luminous resin glue field, and resin glue includes luminescent powder, 20 40 parts；Acrylic size, 50 70 parts；Auxiliary agent without heavy metal compound, 5 15 parts；The luminescent powder particle diameter is 100 300 mesh；Described auxiliary agent by defoamer, drier, ultra-violet absorber, coupling agent, polyamine wax according to（0.3‑0.5）：（0.1‑0.35）：0.4：1.6：1.4 prepare.The energy-accumulating luminous resin glue of overlength afterglow of the invention has decoration performance good, energy saving, it is nontoxic, "dead", long-term luminous excellent performance, luminosity can be adjusted, and storage stability is good, low cost, economic benefit and the significant advantage of social benefit, its every technical performance index is superior to other energy-accumulating luminous paints, with extensive promotion prospect.
Description
Technical field
The present invention relates to energy-accumulating luminous resin glue of a kind of overlength afterglow and preparation method thereof, belong to luminous resin glue field.
Background technology
Traditional luminous paint using sulfide as luminescent material be extension persistence, often add radioactivity without
Element, causes harm to the person, and luminescent lifetime is shorter.
Luminous resin glue is made up of special processing process by a certain percentage of resin glue, various fillers and auxiliary agent.Hair
Photopolymer resin glue is that a class absorbs and excites luminous energy and store, and light is excited after stopping again the energy of storage in the form of luminous energy
Slow release is out, it is possible to continue several or even more than ten hour luminescent material.This absorption-light-store-send out again
Light, it is possible to which it is similar that the electric discharge of charging one one of the unlimited process for repeating and battery recharges the repetitive process discharged again and again
's.
Existing luminous resin glue makes coating be prone to layering and deposited phenomenon because luminous powder density is big, and luminous
The storage stability of resin glue is poor.
The content of the invention
For the problem that above-mentioned prior art is present, the present invention provides a kind of energy-accumulating luminous resin glue of overlength afterglow and its system
Preparation Method, luminous resin glue is obtained has good storage stability, and overcome is easy to coating because luminous powder density is big
The layering of generation and deposited phenomenon.
To achieve these goals, the energy-accumulating luminous resin glue of a kind of overlength afterglow that the present invention is used, by weight, bag
Include following components：
Luminescent powder, 20-40 parts；
Acrylic size, 50-70 parts；
Auxiliary agent without heavy metal compound, 5-15 parts；
The luminescent powder particle diameter is 100-300 mesh；
The component of described auxiliary agent including following proportioning, defoamer, drier, ultra-violet absorber, coupling agent, polyamine wax according to
（0.3-0.5）：（0.1-0.35）：0.4：1.6：1.4 prepare.
Used as improvement, by weight, the luminous resin glue includes following components：
Luminescent powder, 30 parts；
Acrylic size, 60 parts；
Auxiliary agent without heavy metal compound, 10 parts.
Used as improvement, the auxiliary agent includes the component of following proportioning, by defoamer, drier, ultra-violet absorber, coupling
Agent, polyamine wax are according to 0.4：0.35：0.4：1.6：1.4 proportions.
Used as improvement, the viscosity of the acrylic size is 2000-5000 pools.
In addition, present invention also offers a kind of preparation side of the energy-accumulating luminous resin glue of overlength afterglow described in any of the above-described
Method, specifically includes following steps：
1）Using the agitator tank for not containing metallics, speed of agitator is not less than 1500 rpm, and summer whipping temp is no more than 60
DEG C, winter whipping temp is not less than 30 DEG C；
2）Acrylic size, polyamine wax are added in agitator tank, luminescent powder is added, after stirring 15-20min, froth breaking is added
Agent, ultra-violet absorber, coupling agent, drier, after stirring 10min, add 10:1 curing agent（The ratio of acrylate glue is
10th, the ratio of curing agent is 1）Uniform stirring 15min can obtain luminous resin glue.
The overlength afterglow luminescent powder that uses of the present invention can with more than continuous illumination 12h, therefore, obtained overlength afterglow accumulation of energy
Luminous resin glue also there is daytime can absorb and store luminous energy, and it can be used with the performance of more than continuous illumination 12h after evening darkness
Decorative exterior wall and various structures can replace ornament lamp.The product is nontoxic, "dead", is a kind of collection decoration, energy-conservation and ring
The functional ornamentation coating in one is protected, with extensive development prospect.
Obtained luminous resin glue of the invention has good storage stability, overcomes existing resin glue because luminescent powder is close
Degree makes the incident layering of coating and deposited phenomenon greatly.
The resin glue belongs to A grades, can be used for all of position, it is to avoid the person is caused harm by detection, its radioactivity.
Because the overlength afterglow luminescent powder that the resin glue is used is the luminescent powder with fine durability, its luminescence process is physics mistake
Journey, luminescent lifetime more than 10 years, considerably beyond the luminescent lifetime of the luminous paint with sulfide as luminescent material.
The energy-accumulating luminous resin glue of overlength afterglow of the invention is good with decoration performance, and energy saving is nontoxic, "dead",
Long-term luminous excellent performance, luminosity can be adjusted, and storage stability is good, low cost, and economic benefit and social benefit are notable
Advantage, its every technical performance index is superior to other energy-accumulating luminous paints, with extensive promotion prospect.
Brief description of the drawings
Fig. 1 is the design sketch on daytime of the prepared resin glue of the present invention；
Fig. 2 is the night design sketch of the prepared resin glue of the present invention.
Specific embodiment
To make the object, technical solutions and advantages of the present invention of greater clarity, below by drawings and Examples, to this
Invention is further elaborated.However, it should be understood that the specific embodiments described herein are merely illustrative of the present invention,
The scope being not intended to limit the invention.
Unless otherwise defined, all of technical term used herein and scientific terminology are led with technology of the invention is belonged to
The implication that the technical staff in domain is generally understood that is identical, and the term for being used in the description of the invention herein is intended merely to retouch
State the purpose of specific embodiment, it is not intended that in the limitation present invention.
Embodiment one
A kind of preparation method of the energy-accumulating luminous resin glue of overlength afterglow, specifically includes following steps：
1）Using the agitator tank for not containing metallics, speed of agitator is not less than 1500 rpm, and summer whipping temp is no more than 60
DEG C, winter whipping temp is not less than 30 DEG C；
2）By weight, 50 parts of acrylic size, wherein 2.8 parts of polyamine wax, acrylic size are added in agitator tank
Viscosity be 2000-5000 pools, add 20 parts of luminescent powder, luminescent powder particle diameter is 100-300 mesh, and after stirring 15min, addition disappears
0.6 part of infusion, 0.2 part of drier, 0.8 part of ultra-violet absorber, 3.2 parts of coupling agent, after stirring 10min, add 10:1 consolidates
Agent（The ratio of acrylate glue is that the ratio of 10, curing agent is 1）Uniform stirring 15min can obtain luminous resin glue.
Embodiment two
A kind of preparation method of the energy-accumulating luminous resin glue of overlength afterglow, specifically includes following steps：
1）Using the agitator tank for not containing metallics, speed of agitator is not less than 1500 rpm, and winter whipping temp is 35 DEG C；
2）By weight, 60 parts of acrylic size, wherein 4.2 parts of polyamine wax, acrylic size are added in agitator tank
Viscosity be 2000-3000 pools, add 30 parts of luminescent powder, luminescent powder particle diameter is 100-300 mesh, and after stirring 15min, addition disappears
0.9 part of infusion, 0.3 part of drier, 1.2 parts of ultra-violet absorber, 4.8 parts of coupling agent, after stirring 10min, add 10:1 consolidates
Agent（The ratio of acrylate glue is that the ratio of 10, curing agent is 1）Uniform stirring 15min can obtain luminous resin glue.
Embodiment three
A kind of preparation method of the energy-accumulating luminous resin glue of overlength afterglow, specifically includes following steps：
1）Using the agitator tank for not containing metallics, speed of agitator is not less than 1500 rpm, and summer whipping temp is 50 DEG C；
2）By weight, 70 parts of acrylic size, wherein 4.2 parts of polyamine wax, acrylic size are added in agitator tank
Viscosity be 4000-5000 pools, add 40 parts of luminescent powder, luminescent powder particle diameter is 100-300 mesh, and after stirring 15min, addition disappears
1.2 parts of infusion, 1.05 parts of drier, 1.2 parts of ultra-violet absorber, 4.8 parts of coupling agent, after stirring 10min, add 10:1 consolidates
Agent（The ratio of acrylate glue is that the ratio of 10, curing agent is 1）Uniform stirring 15min can obtain luminous resin glue.
Example IV
A kind of preparation method of the energy-accumulating luminous resin glue of overlength afterglow, specifically includes following steps：
1）Using the agitator tank for not containing metallics, speed of agitator is not less than 1500 rpm, and winter whipping temp is 40 DEG C；
2）By weight, 60 parts of acrylic size, wherein 3.5 parts of polyamine wax, acrylic size are added in agitator tank
Viscosity be 2000-2500 pools, add 30 parts of luminescent powder, luminescent powder particle diameter is 100-300 mesh, and after stirring 15min, addition disappears
0.75 part of infusion, 0.75 part of drier, 1 part of ultra-violet absorber, 4 parts of coupling agent, after stirring 10min, add 10:1 solidification
Agent（The ratio of acrylate glue is that the ratio of 10, curing agent is 1）Uniform stirring 15min can obtain luminous resin glue.
When using, because luminescent powder is divided into green-yellow light, blue green light, day blue light, purple light, white light, feux rouges, therefore using glimmering
Delustering pigment, dyestuff, the luminous front and rear color of adjustment, fluorescer adding proportion are about the 1% ~ 5% of luminescent powder weight, it is possible to use one
As dye, pigmented tinting.Specifically used effect is referring to Fig. 1, Fig. 2.
The overlength afterglow luminescent powder that uses of the present invention can with more than continuous illumination 12h, therefore, obtained overlength afterglow accumulation of energy
Luminous resin glue also there is daytime can absorb and store luminous energy, and it can be used with the performance of more than continuous illumination 12h after evening darkness
Decorative exterior wall and various structures can replace ornament lamp.The product is nontoxic, "dead", is a kind of collection decoration, energy-conservation and ring
The functional ornamentation coating in one is protected, with extensive development prospect.
Obtained luminous resin glue of the invention has good storage stability, overcomes existing resin glue because luminescent powder is close
Degree makes the incident layering of coating and deposited phenomenon greatly.
The resin glue belongs to A grades, can be used for all of position, it is to avoid the person is caused harm by detection, its radioactivity.
Because the overlength afterglow luminescent powder that the resin glue is used is the luminescent powder with fine durability, its luminescence process is physics mistake
Journey, luminescent lifetime more than 10 years, considerably beyond the luminescent lifetime of the luminous paint with sulfide as luminescent material.
The energy-accumulating luminous resin glue of overlength afterglow of the invention is good with decoration performance, and energy saving is nontoxic, "dead",
Long-term luminous excellent performance, luminosity can be adjusted, and storage stability is good, low cost, and economic benefit and social benefit are notable
Advantage, its every technical performance index is superior to other energy-accumulating luminous paints, with extensive promotion prospect.
Presently preferred embodiments of the present invention is the foregoing is only, is not intended to limit the invention, it is all in essence of the invention
Any modification, equivalent or improvement made within god and principle etc., should be included within the scope of the present invention.
Claims (5)
1. the energy-accumulating luminous resin glue of a kind of overlength afterglow, it is characterised in that by weight, including following components：
Luminescent powder, 20-40 parts；
Acrylic size, 50-70 parts；
Auxiliary agent without heavy metal compound, 5-15 parts；
The luminescent powder particle diameter is 100-300 mesh；
The component of described auxiliary agent including following proportioning, defoamer, drier, ultra-violet absorber, coupling agent, polyamine wax according to
（0.3-0.5）：（0.1-0.35）：0.4：1.6：1.4 prepare.
2. the energy-accumulating luminous resin glue of a kind of overlength afterglow according to claim 1, it is characterised in that by weight, bag
Include following components：
Luminescent powder, 30 parts；
Acrylic size, 60 parts；
Auxiliary agent without heavy metal compound, 10 parts.
3. the energy-accumulating luminous resin glue of a kind of overlength afterglow according to claim 1, it is characterised in that the auxiliary agent include with
The component of lower proportioning, by defoamer, drier, ultra-violet absorber, coupling agent, polyamine wax according to 0.4：0.35：0.4：1.6：
1.4 proportions.
4. a kind of energy-accumulating luminous resin glue of overlength afterglow according to claim 1, it is characterised in that the acrylic resin
The viscosity of glue is moored for 2000-5000.
5. a kind of preparation method of the energy-accumulating luminous resin glue of overlength afterglow described in any one of claim 1-4, it is characterised in that tool
Body is comprised the following steps：
1）Using the agitator tank for not containing metallics, speed of agitator is not less than 1500 rpm, and summer whipping temp is no more than 60
DEG C, winter whipping temp is not less than 30 DEG C；
2）Acrylic size, polyamine wax are added in agitator tank, luminescent powder is added, after stirring 15-20min, froth breaking is added
Agent, ultra-violet absorber, coupling agent, drier, after stirring 10min, add 10:1 curing agent（The ratio of acrylate glue is
10th, the ratio of curing agent is 1）Uniform stirring 15min can obtain luminous resin glue.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710069226.0A CN106833201A (en) | 2017-02-08 | 2017-02-08 | A kind of energy-accumulating luminous resin glue of overlength afterglow and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710069226.0A CN106833201A (en) | 2017-02-08 | 2017-02-08 | A kind of energy-accumulating luminous resin glue of overlength afterglow and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106833201A true CN106833201A (en) | 2017-06-13 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710069226.0A Pending CN106833201A (en) | 2017-02-08 | 2017-02-08 | A kind of energy-accumulating luminous resin glue of overlength afterglow and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113801524A (en) * | 2021-09-23 | 2021-12-17 | 福建省三棵树新材料有限公司 | Warm-color long-afterglow energy-storage luminescent coating and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1380364A (en) * | 2002-05-17 | 2002-11-20 | 盖广清 | Water energy-storing luminescent paint |
| CN102372964A (en) * | 2010-08-10 | 2012-03-14 | 南通五联品牌策划有限公司 | Luminous coating |
| CN102732112A (en) * | 2011-04-02 | 2012-10-17 | 盘锦辽河油田金宇建筑材料有限公司 | Energy-storing long-acting luminescent coating |
| CN105969160A (en) * | 2016-05-10 | 2016-09-28 | 宿州典跃新型建筑材料有限公司 | Environment-friendly water-based self-luminous coating with good weather fastness |
-
2017
- 2017-02-08 CN CN201710069226.0A patent/CN106833201A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1380364A (en) * | 2002-05-17 | 2002-11-20 | 盖广清 | Water energy-storing luminescent paint |
| CN102372964A (en) * | 2010-08-10 | 2012-03-14 | 南通五联品牌策划有限公司 | Luminous coating |
| CN102732112A (en) * | 2011-04-02 | 2012-10-17 | 盘锦辽河油田金宇建筑材料有限公司 | Energy-storing long-acting luminescent coating |
| CN105969160A (en) * | 2016-05-10 | 2016-09-28 | 宿州典跃新型建筑材料有限公司 | Environment-friendly water-based self-luminous coating with good weather fastness |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113801524A (en) * | 2021-09-23 | 2021-12-17 | 福建省三棵树新材料有限公司 | Warm-color long-afterglow energy-storage luminescent coating and preparation method thereof |
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Application publication date: 20170613 |
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