A kind of floor of Herba Euphorbiae Humifusae processing technology
Technical field
The invention belongs to the floor manufacture field, be specifically related to a kind of ornamental better, the long floor of Herba Euphorbiae Humifusae processing technology of fluorescent lifetime.
Background technology
The floor of selling in the market, the general wood grain that adopts in its surface is as decoration, its decorative effect is comparatively single, more existing producers are for improving the ornamental of floor, in floor paint, add the noctilucence composition, be " treatment process of coating noctilucent material on wooden floor " that " CN 102011479 A " announce such as application publication number, comprise tongue and groove processing is carried out on the floor of moulding; End face on the floor carries out polishing, and the end face sandblast after polishing; At the even application white of floor end face bottom, described white bottom is carried out drying, curing; Use the mode of sander or hand-sand, the white bottom of floor end face is carried out sanding process; Oil paint coating is carried out on the floor; Apply Noctilucent material at the floor end face.Make the floor have illumination effect by this PROCESS FOR TREATMENT, more attractive in appearance.But only Noctilucent material is coated on the end face on floor, form the Linear luminous lines, and Noctilucent material is coated in floor surface.Because common luminescent powder has certain radioactivity, be unsuitable for generally applying in the living environment, so can't large tracts of land use, can lose luminous usefulness because long-term extraneous collision or friction destroy its crystal structure owing to Noctilucent material is coated on floor surface simultaneously.Practical application effect is relatively poor, and light-emitting zone is inhomogeneous, the not luminous or thorough luminescence phenomenon not in part occurs easily, and floor surface affects the attractive in appearance of floor because color spot also can appear in the oxidation of luminescent powder.Because poor practicability, we did not see floor of Herba Euphorbiae Humifusae at all in actual production or life, can only rest in theory, can't actual large amount produce common applying in the living environment.
Summary of the invention
The objective of the invention is provides a kind of environmental protection, long, very attractive in appearance floor of Herba Euphorbiae Humifusae processing technology of energy-conservation, life-span for addressing the above problem.
Above-mentioned technical purpose of the present invention is achieved by the following technical programs:
A kind of floor of Herba Euphorbiae Humifusae processing technology is characterized in that: may further comprise the steps:
(1) Manufacture of Floor slab;
(2) noctilucence priming paint on the floor slab that is made by step (1) is obtained floor slab one;
(3) elastic primer, wear-resistant primer and hardening primer on the floor slab one that is made by step (2) are made floor slab two;
(4) 2-5 on the floor slab two that is made by step (3) is obtained floor of Herba Euphorbiae Humifusae all over finish paint.
Also need to behind japanning, dry in the actual production, also need carry out sanding after the partially desiccated step, such as following steps:
Floor slab-noctilucence priming paint-infrared baking-sanding-elastic primer-infrared baking-sanding-wear-resistant primer-infrared baking-hardening primer-infrared baking-sanding-wear-resistant primer-infrared baking-sanding-infrared baking-sanding-finish paint-infrared baking-sanding-finish paint-infrared baking-finish paint-infrared baking-finish paint.
As preferably, contain luminescent powder, organic resin, organic solvent and auxiliary agent in the described noctilucence priming paint, contain the luminescent powder of weight ratio 20-30% in the described noctilucence priming paint; Described organic resin is one or more in acrylic resin, epoxy resin, polyurethane resin, mylar, pvc resin or the polyvinyl butyral resin, and described auxiliary agent comprises anti-settling agent and curing compound; Described anti-settling agent is silica or high viscosity resins; Described noctilucence priming paint thickness is 100-200um; Described luminescent powder grain diameter is the 800-1200 order.
Luminescent powder has the characteristics such as frangible crystal structure, the easy oxidation of chance metal; this technique is applied to noctilucence priming paint the noctilucent coating of the innermost layer formation internal layer of floor surface; wear-resistant primer and multiple tracks finish paint can protect the luminescent powder in the noctilucence priming paint to make it be difficult for abrasion better; stop simultaneously its oxidation of contact preventing with extraneous metal; strengthen the weather resisteant of noctilucence priming paint; guarantee that the floor has permanently effective luminescent properties, prolonged the luminous life-span of noctilucence priming paint.
Noctilucence priming paint applies finish paint outward again and makes floor light when noctilucence pass topcoat to produce the effect that full, soft, the illusion be similar to as the jelly have again better glossiness, penetrating sense and the third dimension of light are strong, have greatly promoted aesthetics and the texture on floor.
Because the great easy precipitation of ratio of luminescent powder is added into high viscosity resins or anti-settling agent and curing compound when being mixed with noctilucence priming paint, and adopts and namely join the i.e. method of usefulness, can make it have preferably adhesive power, control its curing rate and effectively prevent its rapid precipitation.
When noctilucent coating thickness is 100-200um, can obtain comparatively desirable luminosity and fluorescent lifetime.
As preferably, described luminescent powder is red luminescent powder or blue luminescent powder or purple luminescent powder or green luminescent powder or yellow luminescent powder.
As preferably, the composition weight proportion of described red luminescent powder is: barium sulfate 45-50%, magnesium sulfate 25-35%, zinc oxide 3-5%, lithium phosphate 3-5%, copper nitrate 4-5%, europium 2-3%, silica 3%-5%, red lead 2-4.
As preferably, the composition weight proportion of described blue luminescent powder is barium sulfate 45-50%, magnesium sulfate 25-35%, zinc oxide 3-5%, red lead 2-4%.
As preferably, the composition weight proportion of described purple luminescent powder is: calcium sulfide 58-63%, magnesium sulfide 20-24%, vulcanized sodium 7-10%, strontium nitrate 1-3%, europium 2-3%, silica 3-5%, alumina 1-3%, red lead 2-4%.
As preferably, the composition weight proportion of described green luminescent powder is: calcium sulfide 45-50%, potassium sulfide 2-3 %, vulcanized sodium 9-11%, barium nitrate 8-14%, europium 2-3%, indium nitrate 9-11%, silica 3-5%, red lead 2-4%.
As preferably, the composition weight proportion of described yellow luminescent powder is: barium sulphide 48-52%, magnesium sulfide 38-40%, aluminium sulfide 1-3%, potassium nitrate 1-3 %, europium 2-3%, silica 3-5%, alumina 1-3%, red lead 2-4%.
Illumination effect can be that pure color also can be the chromatography combination of multiple color.Various informative, rich color.
Tradition luminescent powder prescription:
Red: barium sulfate 55 grams, magnesium sulfate 40 grams, lithium phosphate 2 grams, copper nitrate 3 grams.
Blue: calcium sulfide 63 grams, sodium sulphate 5 grams, potassium sulfate 5 grams, strontium sulfate 10 grams, sodium chloride 6 grams, silver nitrate 1 gram, magnesium sulfide 10 grams.
Purple: calcium sulfide 63 grams, magnesium sulfide 26 grams, vulcanized sodium 10 grams, strontium nitrate 1 gram.
Green: calcium sulfide 55 grams, potassium sulfide 1 gram, vulcanized sodium 10 grams, barium nitrate 12 grams, indium nitrate 13 grams.
Yellow: barium sulphide 55 grams, magnesium sulfide 40 grams, aluminium sulfide 2 grams, potassium nitrate 3 grams.
Characteristics: extinction 10-20 minute, fluorescent lifetime only had 5-8 hour, has radioactivity, does not have adhesive power, and the floor luminescent lifetime is short.
The present invention prepare luminescent powder "dead", light decay is little, have certain adhesive power, lux maintenance high, color rendering property is good, long service life, luminous intensity height, high color purity, structure are highly stable.Thereby greatly improved the performance of floor of Herba Euphorbiae Humifusae.
After the noctilucence priming paint film forming that the present invention makes extinction 10-20 minute, can continue luminous 10-12 hour at the dark place.But and extinction and luminescence process Infinite Cyclic.
Should use the container of enamel or glass-lined during the preparation luminescent powder, disperse with homogenizer, avoid using the heavy metal objects such as ironware as far as possible, in order to avoid luminescent powder oxidation blackening reduces luminosity.
The compound method of luminescent powder is as follows: after preparing raw material, high temperature resistant crucible is placed on the hot body heats, raw material is placed in the pot, temperature is the 130-150 degree, burn after 60 minutes, choose not panchromatic impurity, then burned raw material is placed on and wears into the fine powder precipitation that is soaked in water again in the ball mill, remove clear water, the powder that avales is placed on dry getting final product in the drying box.
Noctilucence priming paint can be used the techniques such as brushing, roller coating, spraying, blade coating, the spraying of pouring curtain.Luminous paint must stir before using, and is adjusted to working viscosity with thinner.
As preferably, described floor slab is wooden floor slab or multi-layer solid wood composite floor slab; Be provided with solid decorative patterns or the grain of wood groove of indent on the described floor slab, described noctilucence priming paint is overlying in the decorative pattern zone or grain of wood groove of described floor slab.
When floor slab arranges decorative pattern, can use according to difference the demand of colony, on the floor decorative pattern is set, as when child room uses, can some cartoon patterns be set at floor slab, apply or serigraphy noctilucence priming paint in the cartoon pattern zone again.Daytime noctilucence priming paint extinction, to the luminous cartoon pattern that highlights of noctilucence priming paint in evening, because noctilucent coating is internal layer, topcoat is outer, the cartoon pattern third dimension is stronger, permeability good, increases the smart of stiff decorative pattern, makes pattern modelling vivid.
When floor slab arranges grain of wood groove, step (2) but in gone up noctilucence priming paint after sand go grain of wood bossing noctilucence priming paint, keep its grain of wood channel portions noctilucence priming paint, the floor that makes night grain of wood channel portions luminous, the wood grain on the monoblock floor form with light is highlighted, very attractive in appearance.
As preferably, described step (2) also is included in the front upper light priming paint of noctilucence priming paint.
After before the construction floor slab being carried out necessary preliminary treatment, upper together light priming paint can improve luminosity like this, prolongs fluorescent lifetime.
In sum, the present invention has following beneficial effect:
1; the noctilucence priming paint of the present invention's preparation is nontoxic; harmless; without radiation; environmentally safe; upper multi-layer wear-resistant priming paint and finish paint; make the wear-resisting revolution in the floor that makes turn above up to 6000; greatly strengthened the weatherability on floor; while is also protected well the luminescent powder in the noctilucence priming paint to make it be difficult for abrasion and destroys its crystal structure; and stop its oxidation of contact preventing with extraneous metal; strengthen the weather resisteant of noctilucence priming paint; thereby guarantee that the floor of Herba Euphorbiae Humifusae that makes has permanently effective luminescent properties; prolonged the luminescent lifetime of floor of Herba Euphorbiae Humifusae
2, the floor of Herba Euphorbiae Humifusae that makes of the present invention can large batch ofly put into production and apply at large in the living environment, and practicality is good, can play well and intersperse, beautifies the living environment, and can also satisfy different use crowds' individual demand simultaneously.
3, the multiple tracks finish paint is gone up on the floor that makes of the present invention again outside noctilucence priming paint, makes the floor can also send unique solid, full, soft, agile light at night.
The specific embodiment
This specific embodiment only is explanation of the invention; it is not limitation of the present invention; those skilled in the art can make the modification that does not have creative contribution to present embodiment as required after reading this manual, but as long as all are subject to the protection of Patent Law in claim scope of the present invention.
Embodiment one:
A kind of floor of Herba Euphorbiae Humifusae processing technology is characterized in that: may further comprise the steps:
(1) Manufacture of Floor slab;
(2) noctilucence priming paint on the floor slab that is made by step (1) is obtained floor slab one;
(3) elastic primer, wear-resistant primer and hardening primer on the floor slab one that is made by step (2) are made floor slab two;
(4) 2-5 on the floor slab two that is made by step (3) is obtained floor of Herba Euphorbiae Humifusae all over finish paint.
Also need carry out drying and processing after per one japanning operation, also need carry out sanding after the partially desiccated treatment process and process.Detailed step is as follows:
Floor slab-noctilucence priming paint-infrared baking-sanding-elastic primer-infrared baking-sanding-wear-resistant primer-infrared baking-hardening primer-infrared baking-sanding-wear-resistant primer-infrared baking-sanding-infrared baking-sanding-finish paint-infrared baking-sanding-finish paint-infrared baking-finish paint-infrared baking-finish paint.
Contain luminescent powder, organic resin, organic solvent and auxiliary agent in the noctilucence priming paint, contain the luminescent powder of weight ratio 20% in the noctilucence priming paint; Organic resin can be selected any one in acrylic resin, epoxy resin, polyurethane resin, mylar, pvc resin, the polyvinyl butyral resin, and auxiliary agent comprises anti-settling agent and curing compound; The anti-settling agent that present embodiment is selected is silica.Noctilucence priming paint thickness is 100um; Described luminescent powder grain diameter is 800 orders.
The floor slab that present embodiment is selected is the wooden floor slab.Also decorative pattern miscellaneous can be set according to the difference of customer demand or environment for use on the floor slab, decorative pattern is the solid figure that is arranged on indent on the floor slab, and noctilucence priming paint is sprayed at the decorative pattern zone.
Luminescent powder in the noctilucence priming paint can according to user's demand or with decorative pattern select one or more chromatography in red luminescent powder, blue luminescent powder, purple luminescent powder, green luminescent powder, the yellow luminescent powder according to the decorative pattern style, such as the chromatography of: the chromatography of the chromatography of red, blue two kinds of luminescent powders or purple, green, yellow three kinds of luminescent powders or red, blue, purple, green, five kinds of luminescent powders of yellow etc.
The composition weight proportion of red luminescent powder is: barium sulfate 45%, magnesium sulfate 25%, zinc oxide 3%, lithium phosphate 3%, copper nitrate 4%, europium 2%, silica 3%, red lead 2%; The composition weight proportion of described blue luminescent powder is barium sulfate 45%, magnesium sulfate 25%, zinc oxide 3%, red lead 2%; The composition weight proportion of described purple luminescent powder is: calcium sulfide 58%, magnesium sulfide 20%, vulcanized sodium 7%, strontium nitrate 1%, europium 2%, silica 3%, alumina 1%, red lead 2%; The composition weight proportion of described green luminescent powder is: calcium sulfide 45%, potassium sulfide 2%, vulcanized sodium 9%, barium nitrate 8%, europium 2%, indium nitrate 9%, silica 3%, red lead 2%; The composition weight proportion of described yellow luminescent powder is: barium sulphide 48%, magnesium sulfide 38%, aluminium sulfide 1%, potassium nitrate 1%, europium 2%, silica 3%, alumina 1%, red lead 2%.
The floor properties that present embodiment technique makes is seen contrast table 1.
Embodiment two:
The different proportionings that are in each composition from above-described embodiment, present embodiment is selected the multi-layer solid wood composite floor slab.
Detailed step is as follows:
Floor slab-light priming paint-noctilucence priming paint-infrared baking-sanding-elastic primer-infrared baking-sanding-wear-resistant primer-infrared baking-hardening primer-infrared baking-sanding-wear-resistant primer-infrared baking-sanding-infrared baking-sanding-finish paint-infrared baking-sanding-finish paint-infrared baking-finish paint.
The luminescent powder that contains weight ratio 30% in the noctilucence priming paint; Noctilucence priming paint thickness is 200um; Described luminescent powder grain diameter is 1200 orders.The anti-settling agent that present embodiment is selected is high viscosity resins.
The composition weight proportion of red luminescent powder is: barium sulfate 50%, magnesium sulfate 35%, zinc oxide 5%, lithium phosphate 5%, copper nitrate 5%, europium 3%, silica 5%, red lead 4%; The composition weight proportion of blue luminescent powder is barium sulfate 50%, magnesium sulfate 35%, zinc oxide 5%, red lead 4%; The composition weight proportion of purple luminescent powder is: calcium sulfide 563%, magnesium sulfide 24%, vulcanized sodium 10%, strontium nitrate 3%, europium 3%, silica 5%, alumina 3%, red lead 4%; The composition weight proportion of green luminescent powder is: calcium sulfide 50%, potassium sulfide 3 %, vulcanized sodium 11%, barium nitrate 14%, europium 3%, indium nitrate 11%, silica 5%, red lead 4%; The composition weight proportion of described yellow luminescent powder is: barium sulphide 52%, magnesium sulfide 40%, aluminium sulfide 3%, potassium nitrate 3 %, europium 3%, silica 5%, alumina 3%, red lead 4%.
The floor properties that present embodiment technique makes is seen contrast table 1.
Embodiment three:
Different from above-described embodiment be in, it is solid wood ancient imitation floor board slab that present embodiment is selected floor slab, be included in the described step (1) and make grain of wood groove on the floor slab, sanding wood grain bossing priming paint during sanding noctilucence priming paint, keep its wood grain channel portions priming paint, the floor that makes night the wood grain channel portions luminous, the wood grain on the monoblock floor form with light is highlighted, very attractive in appearance.
Detailed step is as follows:
Floor slab-noctilucence priming paint-infrared baking-sanding-elastic primer-infrared baking-sanding-wear-resistant primer-infrared baking-hardening primer-infrared baking-sanding-wear-resistant primer-infrared baking-sanding-infrared baking-sanding-finish paint-infrared baking-sanding-finish paint-infrared baking-finish paint.
The luminescent powder that contains weight ratio 25% in the noctilucence priming paint; Described noctilucence priming paint thickness is 100-200um; Described luminescent powder grain diameter is the 800-1200 order.The anti-settling agent that present embodiment is selected is silica or high viscosity resins.
The composition weight proportion of red luminescent powder is: barium sulfate 48%, magnesium sulfate 32%, zinc oxide 4%, lithium phosphate 4%, copper nitrate 4.7%, europium 2.7%, silica 4%, red lead 3%; The composition weight proportion of blue luminescent powder is barium sulfate 48%, magnesium sulfate 30%, zinc oxide 4%, red lead 3%; The composition weight proportion of purple luminescent powder is: calcium sulfide 61%, magnesium sulfide 23%, vulcanized sodium 9%, strontium nitrate 2%, europium 1.7%, silica 4%, alumina 2%, red lead 3%; The composition weight proportion of green luminescent powder is: calcium sulfide 48%, potassium sulfide 1%, vulcanized sodium 10%, barium nitrate 13%, europium 2.7%, indium nitrate 10%, silica 4%, red lead 3%; The composition weight proportion of yellow luminescent powder is: barium sulphide 50%, magnesium sulfide 39%, aluminium sulfide 2%, potassium nitrate 2%, europium 2.7%, silica 4%, alumina 2%, red lead 3%.
The floor properties that present embodiment technique makes is seen contrast table 1.
Comparative Examples one:
Applied in the noctilucence priming paint by the luminescent powder of following one-tenth assignment system and to make floor of Herba Euphorbiae Humifusae.
Red: barium sulfate 55 grams, magnesium sulfate 40 grams, lithium phosphate 2 grams, copper nitrate 3 grams.
Blue: calcium sulfide 63 grams, sodium sulphate 5 grams, potassium sulfate 5 grams, strontium sulfate 10 grams, sodium chloride 6 grams, silver nitrate 1 gram, magnesium sulfide 10 grams.
Purple: calcium sulfide 63 grams, magnesium sulfide 26 grams, vulcanized sodium 10 grams, strontium nitrate 1 gram.
Green: calcium sulfide 55 grams, potassium sulfide 1 gram, vulcanized sodium 10 grams, barium nitrate 12 grams, indium nitrate 13 grams.
Yellow: barium sulphide 55 grams, magnesium sulfide 40 grams, aluminium sulfide 2 grams, potassium nitrate 3 grams.
The floor of Herba Euphorbiae Humifusae extinction that makes with above-mentioned luminescent powder 10-20 minute, fluorescent lifetime only has 5-8 hour, has radioactivity, and the floor luminescent lifetime is short.
The floor properties that this Comparative Examples makes is seen contrast table 1.
Comparative Examples two:
The processing technology of floor of Herba Euphorbiae Humifusae is as follows: floor slab-elastic primer-infrared baking-sanding-wear-resistant primer-infrared baking-hardening primer-infrared baking-sanding-wear-resistant primer-infrared baking-sanding-infrared baking-sanding-finish paint-infrared baking-sanding-finish paint-infrared baking-noctilucence priming paint-infrared baking-finish paint.
The floor properties that this Comparative Examples makes is seen contrast table 1.
Table 1:
"dead", light decay is little, have certain adhesive power, lux maintenance high, color rendering property is good, long service life, luminous intensity height, high color purity, structure are highly stable.
Paint film adhesion reflection be paint to the adhesive strength of wooden floor, this index is defective to illustrate that also the paint quality on floor is relatively poor, in use may cause oil paint cracking even peels off, and affects equally the application life on floor.National Specification high-class product wooden floor paint film adhesion index is 0~1 grade; Grade A≤2 grade; Certified products≤3 grade.
The present invention makes ground floor of Herba Euphorbiae Humifusae, environmental protection, energy-conservation.Practical can putting into production in a large number applies in the living environment at large.And changed the unicity that existing general floorings is decorated, made more attractive in appearance, the individual character, agile in floor in the life.