CN105462463A - Paint capable of emitting yellow fluorescence - Google Patents
Paint capable of emitting yellow fluorescence Download PDFInfo
- Publication number
- CN105462463A CN105462463A CN201511019744.9A CN201511019744A CN105462463A CN 105462463 A CN105462463 A CN 105462463A CN 201511019744 A CN201511019744 A CN 201511019744A CN 105462463 A CN105462463 A CN 105462463A
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- CN
- China
- Prior art keywords
- parts
- paint
- methacrylic acid
- yellow fluorescence
- acid
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D191/00—Coating compositions based on oils, fats or waxes; Coating compositions based on derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/22—Luminous paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention relates to paint, in particular to paint capable of emitting yellow fluorescence. The paint is prepared from barium sulfide, magnesium sulfide, aluminum sulfide, potassium nitrate, modified alkyd resin, tung oil, an epoxy resin composition, terephthalic acid, palm kernel ester, ethyl methacrylate, acrylic pigment, polyvinyl butyral, a defoaming agent and the balance thinner, wherein the defoaming agent is prepared from higher aliphatic alcohol, polyether-modified polysiloxane, an emulsifier, a span-series emulsifier, silicon dioxide and deionized water. The paint can absorb light to emit the yellow fluorescence in a light-absorbing dark environment; a paint film forms a high net structure after being dried, and therefore ageing is not prone to occur; the paint film is flexible and tough and firm, therefore, the rub resistance and the water resistance are good, damp and hot conditions and mould can be prevented, and the mineral oil resistance and the alcohols solvent resistance are good; the silicon dioxide serves as a carrier and an emulsifying auxiliary agent, and therefore the more preferable stability and reinforcing ability are achieved.
Description
Technical field
The present invention relates to a kind of coating, especially a kind of paint sending yellow fluorescence.
Background technology
Film because being subject to the impact of the ambient conditionss such as solar radiation, temperature variation, wind and weather, there will be fade, variable color, be full of cracks, a series of aging phenomenon such as efflorescence and strength degradation.The erosion resistance of a lot of coating is not strong at present, cannot meet the needs that people improve day by day.Coating is a kind of material, and this material can be coated in article surface by different construction technologies, forms adhere well, has some strength, continuous print solid film.The film common name film of such formation, also known as paint film or coating.Belong to organic chemical industry's macromolecular material, the film formed belongs to macromolecular compound type.The classification of the Chemicals of passing through according to the modern times, coating belongs to fine chemical product.Modern coating is progressively becoming the polyfunctional engineering materials of a class, is an important industry in chemical industry.
Summary of the invention
The present invention is intended to solve the problems of the technologies described above, provide a kind of paint sending yellow fluorescence, it can send yellow fluorescence under extinction dark surrounds, height of formation reticulated structure after drying varniss, not easily aging, paint film is pliable and tough strong, rub resistance, water-tolerant, alkaline-resisting, anti-damp and hot, mould proof, salt fog excellent performance, anti-mineral oil, anti-alcoholic solvent are good, silicon-dioxide is as carrier and emulsion adjuvant, there is more superior stability, reinforcing, the dual function of silicon-dioxide, make defoamer stability and suppress the effect of foam better; Paint film water tolerance after baking, insulativity, oil-proofness improve all greatly, and its technical scheme adopted is as follows:
A kind of paint sending yellow fluorescence, it is characterized in that: its composition weight proportioning is: the barium sulphide of 5 ~ 5.5%, the magnesium sulfide of 3 ~ 4%, 1.5 ~ 2.2% aluminium sulfide, the saltpetre of 2 ~ 3%, modified alkyd resin, the tung oil of 16 ~ 27%, composition epoxy resin, the terephthalic acid of 3 ~ 5%, palm-kernel ester, the methacrylic acid second fat of 5 ~ 8%, acrylic paints, the polyvinyl butyral acetal of 5 ~ 10%, the defoamer of 3 ~ 5% of 1 ~ 3% of 10 ~ 15% of 10 ~ 18% of 35 ~ 43%, all the other are solvent or diluent.
On technique scheme basis, the preparation method of described modified alkyd resin comprises the following steps: a) by lipid acid 11-30 part, polyvalent alcohol 11-40 part, MALEIC ANHYDRIDE 0.5-2 part, diprotic acid 12-30 part, catalyzer 0-0.033 part adds in reaction vessel, under agitation progressively be warming up to 180-240 DEG C, deviate from micromolecular water in reaction process, control column temperature 98-105 DEG C, react to acid number and be less than 10mgKOH/g;
B) be cooled to below solvent boiling point, add solvent 7-10 part and stir, and temperature is remained on 110-150 DEG C;
C) mixture of (methyl) vinylformic acid 2-6 part and (methyl) acrylic ester monomer, styrene monomer 5-30 part and initiator 0.3-1 part is at the uniform velocity dripped with 2.5-3hr, after dripping, residue initiator 0-2 part is become 3 parts, per hourly add portion, finally continue at 110-150 DEG C of reaction 3hr;
D) be cooled to below added solvent boiling point, add remaining 10-20 part solvent, stir, obtain watersoluble modified Synolac.
On technique scheme basis, described methacrylic acid second fat is prepared by following steps: adopt esterification process technique, with methacrylic acid and dehydrated alcohol for raw material, under the effect of catalyzer and stopper, reaction generates β-dimethyl-aminoethylmethacrylate and water, wherein, the consumption mol ratio of methacrylic acid and ethanol is 2:1 ~ 5:1, the quality of catalyzer is 2% ~ 4% of the quality summation of methacrylic acid and ethanol in reactor, the quality of stopper is 0.005% ~ 0.1% of the quality summation of methacrylic acid and ethanol in reactor, and temperature of reaction controls at 90 ~ 102 DEG C.
On technique scheme basis, described defoamer by following constitutive material by weight: high fatty alcohol 40 ~ 85 parts, polyether modified siloxane 5 ~ 15 parts, emulsifying agent 5 ~ 10 parts, Span series emulsifying agent 6 ~ 10 parts, silicon-dioxide 8 ~ 22 parts, deionized water 100 ~ 500 parts preparation.
Tool of the present invention has the following advantages: can send yellow fluorescence under extinction dark surrounds, height of formation reticulated structure after drying varniss, not easily aging, paint film is pliable and tough strong, rub resistance, water-tolerant, alkaline-resisting, anti-damp and hot, mould proof, salt fog excellent performance, anti-mineral oil, anti-alcoholic solvent are good, silicon-dioxide is as carrier and emulsion adjuvant, there is more superior stability, reinforcing, the dual function of silicon-dioxide, make defoamer stability and suppress the effect of foam better; Paint film water tolerance after baking, insulativity, oil-proofness improve all greatly.
Embodiment
Embodiment 1
A kind of paint sending yellow fluorescence, it is characterized in that: its composition weight proportioning is: the barium sulphide of 5.5%, the magnesium sulfide of 4%, the aluminium sulfide of 2.2%, the saltpetre of 2%, the modified alkyd resin of 43%, the tung oil of 27%, the composition epoxy resin of 18%, the terephthalic acid of 5%, the palm-kernel ester of 15%, the methacrylic acid second fat of 8%, the acrylic paints of 3%, the polyvinyl butyral acetal of 10%, the defoamer of 5%, all the other are solvent or diluent, described defoamer is by following constitutive material by weight: high fatty alcohol 85 parts, polyether modified siloxane 15 parts, emulsifying agent 10 parts, Span series emulsifying agent 10 parts, silicon-dioxide 22 parts, deionized water 500 parts preparation.
Preferably, the preparation method of described modified alkyd resin comprises the following steps: a) by 11 parts, lipid acid, polyvalent alcohol 40 parts, MALEIC ANHYDRIDE 0.5 part, diprotic acid 30 parts, catalyzer 0-0.033 part adds in reaction vessel, under agitation progressively be warming up to 180-240 DEG C, deviate from micromolecular water in reaction process, control column temperature 98-105 DEG C, react to acid number and be less than 10mgKOH/g;
B) be cooled to below solvent boiling point, add solvent 7 parts and stir, and temperature is remained on 110-150 DEG C;
C) mixture of 6 parts, (methyl) vinylformic acid and (methyl) acrylic ester monomer, styrene monomer 15 parts and initiator 1 part is at the uniform velocity dripped with 2.5-3hr, initiator 2 parts will be remained after dripping and become 3 parts, per hourly add portion, finally continue at 110-150 DEG C of reaction 3hr;
D) be cooled to below added solvent boiling point, add remaining 20 parts of solvents, stir, obtain watersoluble modified Synolac.
Preferably, described methacrylic acid second fat is prepared by following steps: adopt esterification process technique, with methacrylic acid and dehydrated alcohol for raw material, under the effect of catalyzer and stopper, reaction generates β-dimethyl-aminoethylmethacrylate and water, wherein, the consumption mol ratio of methacrylic acid and ethanol is 2:1, the quality of catalyzer is 2% of the quality summation of methacrylic acid and ethanol in reactor, the quality of stopper is 0.005%% of the quality summation of methacrylic acid and ethanol in reactor, and temperature of reaction controls at 90 DEG C.
Embodiment 2
A kind of paint sending yellow fluorescence, it is characterized in that: its composition weight proportioning is: the barium sulphide of 5%, the magnesium sulfide of 4%, the aluminium sulfide of 2%, the saltpetre of 2%, the modified alkyd resin of 35%, the tung oil of 16%, the composition epoxy resin of 10%, the terephthalic acid of 3%, the palm-kernel ester of 10%, the methacrylic acid second fat of 5%, the acrylic paints of 1%, the polyvinyl butyral acetal of 5%, the defoamer of 3%, all the other are solvent or diluent, described defoamer is by following constitutive material by weight: high fatty alcohol 40 parts, polyether modified siloxane 5 parts, emulsifying agent 5 parts, Span series emulsifying agent 6 parts, silicon-dioxide 8 parts, deionized water 100 parts preparation.
Preferably, the preparation method of described modified alkyd resin comprises the following steps: a) by 11 parts, lipid acid, polyvalent alcohol 30 parts, MALEIC ANHYDRIDE 2 parts, diprotic acid 30 parts, catalyzer 0-0.033 part adds in reaction vessel, under agitation progressively be warming up to 180-240 DEG C, deviate from micromolecular water in reaction process, control column temperature 98-105 DEG C, react to acid number and be less than 10mgKOH/g;
B) be cooled to below solvent boiling point, add solvent 7-10 part and stir, and temperature is remained on 110-150 DEG C;
C) mixture of 5 parts, (methyl) vinylformic acid and (methyl) acrylic ester monomer, styrene monomer 20 parts and initiator 0.8 part is at the uniform velocity dripped with 2.5-3hr, initiator 1 part will be remained after dripping and become 3 parts, per hourly add portion, finally continue at 110-150 DEG C of reaction 3hr;
D) be cooled to below added solvent boiling point, add remaining 15 parts of solvents, stir, obtain watersoluble modified Synolac.
Preferably, described methacrylic acid second fat is prepared by following steps: adopt esterification process technique, with methacrylic acid and dehydrated alcohol for raw material, under the effect of catalyzer and stopper, reaction generates β-dimethyl-aminoethylmethacrylate and water, wherein, the consumption mol ratio of methacrylic acid and ethanol is 2:1, the quality of catalyzer is 4% of the quality summation of methacrylic acid and ethanol in reactor, the quality of stopper is 0.1% of the quality summation of methacrylic acid and ethanol in reactor, and temperature of reaction controls at 102 DEG C.
Describe the present invention by way of example above, but the invention is not restricted to above-mentioned specific embodiment, all any changes of doing based on the present invention or modification all belong to the scope of protection of present invention.
Claims (4)
1. one kind can send the paint of yellow fluorescence, it is characterized in that: its composition weight proportioning is: the barium sulphide of 5 ~ 5.5%, the magnesium sulfide of 3 ~ 4%, 1.5 ~ 2.2% aluminium sulfide, the saltpetre of 2 ~ 3%, modified alkyd resin, the tung oil of 16 ~ 27%, composition epoxy resin, the terephthalic acid of 3 ~ 5%, palm-kernel ester, the methacrylic acid second fat of 5 ~ 8%, acrylic paints, the polyvinyl butyral acetal of 5 ~ 10%, the defoamer of 3 ~ 5% of 1 ~ 3% of 10 ~ 15% of 10 ~ 18% of 35 ~ 43%, all the other are solvent or diluent.
2. a kind of paint sending yellow fluorescence according to claim 1, it is characterized in that: the preparation method of described modified alkyd resin comprises the following steps: a) by lipid acid 11-30 part, polyvalent alcohol 11-40 part, MALEIC ANHYDRIDE 0.5-2 part, diprotic acid 12-30 part, catalyzer 0-0.033 part adds in reaction vessel, under agitation progressively be warming up to 180-240 DEG C, deviate from micromolecular water in reaction process, control column temperature 98-105 DEG C, react to acid number and be less than 10mgKOH/g;
B) be cooled to below solvent boiling point, add solvent 7-10 part and stir, and temperature is remained on 110-150 DEG C;
C) mixture of (methyl) vinylformic acid 2-6 part and (methyl) acrylic ester monomer, styrene monomer 5-30 part and initiator 0.3-1 part is at the uniform velocity dripped with 2.5-3hr, after dripping, residue initiator 0-2 part is become 3 parts, per hourly add portion, finally continue at 110-150 DEG C of reaction 3hr;
D) be cooled to below added solvent boiling point, add remaining 10-20 part solvent, stir, obtain watersoluble modified Synolac.
3. a kind of paint sending yellow fluorescence according to claim 2, it is characterized in that: described methacrylic acid second fat is prepared by following steps: adopt esterification process technique, with methacrylic acid and dehydrated alcohol for raw material, under the effect of catalyzer and stopper, reaction generates β-dimethyl-aminoethylmethacrylate and water, wherein, the consumption mol ratio of methacrylic acid and ethanol is 2:1 ~ 5:1, the quality of catalyzer is 2% ~ 4% of the quality summation of methacrylic acid and ethanol in reactor, the quality of stopper is 0.005% ~ 0.1% of the quality summation of methacrylic acid and ethanol in reactor, temperature of reaction controls at 90 ~ 102 DEG C.
4. a kind of paint sending yellow fluorescence according to claim 2, is characterized in that: described defoamer by following constitutive material by weight: high fatty alcohol 40 ~ 85 parts, polyether modified siloxane 5 ~ 15 parts, emulsifying agent 5 ~ 10 parts, Span series emulsifying agent 6 ~ 10 parts, silicon-dioxide 8 ~ 22 parts, deionized water 100 ~ 500 parts preparation.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511019744.9A CN105462463A (en) | 2015-12-29 | 2015-12-29 | Paint capable of emitting yellow fluorescence |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511019744.9A CN105462463A (en) | 2015-12-29 | 2015-12-29 | Paint capable of emitting yellow fluorescence |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105462463A true CN105462463A (en) | 2016-04-06 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201511019744.9A Pending CN105462463A (en) | 2015-12-29 | 2015-12-29 | Paint capable of emitting yellow fluorescence |
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| CN (1) | CN105462463A (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1039259A (en) * | 1988-07-14 | 1990-01-31 | 沈阳市和平市政工程公司 | A kind of luminescent powder |
| CN102953533A (en) * | 2012-10-26 | 2013-03-06 | 浙江未来家木业有限公司 | Noctilucent floor board processing technology |
| CN103061487A (en) * | 2012-10-26 | 2013-04-24 | 浙江未来家木业有限公司 | Processing technique of noctilucent glazing floors |
| CN103778873A (en) * | 2014-01-21 | 2014-05-07 | 浙江海联电子股份有限公司 | Self-luminous dangerous mark top light |
| CN104449289A (en) * | 2014-11-24 | 2015-03-25 | 青岛市市南区隆德中医药研究所 | Environment-friendly oil paint |
| CN104877084A (en) * | 2014-12-04 | 2015-09-02 | 北京金汇利应用化工制品有限公司 | Aqueous acrylic acid modified alkyd resin and water dispersion thereof |
-
2015
- 2015-12-29 CN CN201511019744.9A patent/CN105462463A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1039259A (en) * | 1988-07-14 | 1990-01-31 | 沈阳市和平市政工程公司 | A kind of luminescent powder |
| CN102953533A (en) * | 2012-10-26 | 2013-03-06 | 浙江未来家木业有限公司 | Noctilucent floor board processing technology |
| CN103061487A (en) * | 2012-10-26 | 2013-04-24 | 浙江未来家木业有限公司 | Processing technique of noctilucent glazing floors |
| CN103778873A (en) * | 2014-01-21 | 2014-05-07 | 浙江海联电子股份有限公司 | Self-luminous dangerous mark top light |
| CN104449289A (en) * | 2014-11-24 | 2015-03-25 | 青岛市市南区隆德中医药研究所 | Environment-friendly oil paint |
| CN104877084A (en) * | 2014-12-04 | 2015-09-02 | 北京金汇利应用化工制品有限公司 | Aqueous acrylic acid modified alkyd resin and water dispersion thereof |
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Application publication date: 20160406 |
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