CN105462494A - Coating containing purple fluorescent substances - Google Patents
Coating containing purple fluorescent substances Download PDFInfo
- Publication number
- CN105462494A CN105462494A CN201511017841.4A CN201511017841A CN105462494A CN 105462494 A CN105462494 A CN 105462494A CN 201511017841 A CN201511017841 A CN 201511017841A CN 105462494 A CN105462494 A CN 105462494A
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- coating containing
- coating
- containing purple
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D191/00—Coating compositions based on oils, fats or waxes; Coating compositions based on derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/22—Luminous paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention relates to a chemical industrial product, in particular to a coating containing purple fluorescent substances. The coating is prepared from, by weight, 6%-6.5% of calcium sulphide, 2.5%-3% of magnesium sulfide, 0.8%-1% of sodium sulphide, 0.08%-0.1% of strontium nitrate, 12%-17% of wax ester, 20%-30% of China wood oil, 10%-16% of epoxy resin, 3%-6% of modified alkyd resin, 12%-16% of palm olein ester, 5%-8% of methacrylic resin, 1%-3% of semi-matte acrylic paint, 3%-6% of novel photoinitiator, 5%-10% of polyvinyl butyral and the balance thinner. The coating can absorb light and emit purple light in the dark environment, light resistance and weather resistance are good, tinting strength and covering power are high, adhesive force is high, the coating is not easy to crack after use and can be used for objects such as guide boards, outdoor advertisements, roads at night and barrier signs.
Description
Technical field
The present invention relates to a kind of chemical industries, especially a kind of coating containing purple fluorescence material.
Background technology
There is the crackle that depth size is different in coating surface, as seen underlying surfaces from cracks, is then called " cracking "; As paint film presents the fine cracks of curvature of the spinal column decorative pattern sample, be then called " be full of cracks ".
Questions and prospect: one, priming paint and finish paint do not match, film produces string stress by ectocine (mechanical effect, temperature variation etc.), causes Alligatoring or cracking.Two, priming paint does not parch and namely applies (spray, brush, roller coat) finish paint, or the first layer finish paint is blocked up, without parching and be coated with second layer finish paint, makes external extension in two-layer paint inconsistent.Three, indoor paint is used for timber for outdoor or metallic surface priming paint.Four, wooden ground contains rosin without removing and process, with the passing of time can ooze out paint film, causes local be full of cracks.Five, moisture content is too high, and with the passing of time deforming causes cracking; Six, solidifying agent adds too much, or the solidifying agent of mistake in; Seven, construct blocked up; Eight, construction environment is severe, and the temperature difference is large, high humidity, and paint film, by cold and hot and flexible, causes be full of cracks.
Summary of the invention
The present invention is intended to solve the problems of the technologies described above, provide a kind of coating containing purple fluorescence material, it can send purple light under extinction dark surrounds, photostabilization, good weatherability, tinting strength, strong covering power, strong adhesion is not easy to crack after using, can be used for guideboard and outdoor advertising and night road and the object such as obstacle marking, its technical scheme adopted is as follows:
A coating containing purple fluorescence material, is characterized in that: its composition weight proportioning is:
Sulfurated lime 6 ~ 6.5%;
Magnesium sulfide 2.5 ~ 3%;
Sodium sulphite 0.8 ~ 1%;
Strontium nitrate 0.08 ~ 0.1%;
Wax ester 12 ~ 17%;
Tung oil 20 ~ 30%;
Epoxy resin 10 ~ 16%;
Modified alkyd resin 3 ~ 6%;
Palm olein ester 12 ~ 16%;
Methacrylic resin 5 ~ 8%;
Half sub-light acrylic paints 1 ~ 3%;
Novel photoinitiator 3 ~ 6%;
Polyvinyl butyral acetal 5 ~ 10%;
All the other are solvent or diluent.
On technique scheme basis, described alkali is sodium hydroxide, hydrated barta, ammoniacal liquor or zinc oxide.
On technique scheme basis, described modified alkyd resin is made by following steps:
A) amount taking hydroxylated material is the TriMethylolPropane(TMP) of 5 ~ 5.3 moles, the amount of hydroxylated material is the Tetra hydro Phthalic anhydride of 1.5 ~ 1.7 moles, the amount of hydroxylated material is the adipic anhydride of 0.7 ~ 0.92 mole and the amount of hydroxylated material be 0.7 ~ 0.92 different n-nonanoic acid;
B) different n-nonanoic acid, TriMethylolPropane(TMP), Tetra hydro Phthalic anhydride and adipic anhydride are put into reactor, be warming up to 85 ~ 100 degree, start to stir, 160 scholar 5 degree is warming up to again with the heat-up rate of 70 ~ 85 degree/h, release the water reacting and produce, be warming up to 210 scholar 5 degree, reaction to acid number is 18 ~ 20KOHmg/g, stopped reaction, be cooled to 140 degree, then adding solvent cut to mass concentration is 42%, obtains Synolac, wherein said solvent by 200# gasoline, trimethylbenzene and vinyl acetic monomer in mass ratio for 70:36:3 is made into.
On technique scheme basis, described novel photoinitiator is prepared by following methods: all represent with molar fraction below, by 1 part of light base benzophenone of 4-, 1 ~ 3 part of formaldehyde joins in reaction vessel, after mixing, add 0.0102 ~ 0.012 part of alkali and make catalyzer, under agitation, heating keeps micro-boiling (90 ~ 99 DEG C) 1h ~ 3h; Then increase the temperature to 140 ~ 160 DEG C, carry out Depressor response 10 ~ 15 minutes, be cooled to 90 DEG C ~ 110 DEG C to collect product after reaction terminates, product joined in the deionized water of 10 ~ 20 parts and precipitate, after suction filtration, obtain novel photoinitiator.
Tool of the present invention has the following advantages: can send purple light under extinction dark surrounds, photostabilization, good weatherability, tinting strength, strong covering power, and strong adhesion is not easy to crack after using, can be used for guideboard and outdoor advertising and night road and the object such as obstacle marking.
Embodiment
Embodiment 1
A kind of coating containing purple fluorescence material, it is characterized in that: its composition weight proportioning is: the sulfurated lime of 6.5%, the magnesium sulfide of 3%, the sodium sulphite of 0.8%, strontium nitrate, wax ester 12%, tung oil 20%, epoxy resin 10%, modified alkyd resin 3%, palm olein ester 12%, the sub-light acrylic paints 1% of methacrylic resin 5%, half, novel photoinitiator 3%, the polyvinyl butyral acetal 5% of 0.1%, all the other are solvent or diluent; Described novel photoinitiator is prepared by following methods: all represent with molar fraction below, and by 1 part of light base benzophenone of 4-, 1 ~ 3 part of formaldehyde joins in reaction vessel, after mixing, add 0.0102 part of alkali and make catalyzer, under agitation, heating keeps micro-boiling 90 DEG C of 1h; Then increase the temperature to 140 DEG C, carry out Depressor response 10 minutes, be cooled to 90 DEG C to collect product after reaction terminates, product joined in the deionized water of 10 parts and precipitate, after suction filtration, obtain novel photoinitiator.
Preferably, described alkali is sodium hydroxide.Described modified alkyd resin is made by following steps:
A) amount taking hydroxylated material is the TriMethylolPropane(TMP) of 5 moles, the amount of hydroxylated material is the Tetra hydro Phthalic anhydride of 1.5 moles, the amount of hydroxylated material is the adipic anhydride of 0.7 mole and the amount of hydroxylated material be 0.7 different n-nonanoic acid;
B) different n-nonanoic acid, TriMethylolPropane(TMP), Tetra hydro Phthalic anhydride and adipic anhydride are put into reactor, be warming up to 85 degree, start to stir, 160 degree are warming up to again with the heat-up rate of 70 degree/h, release the water reacting and produce, be warming up to 210 degree, reaction to acid number is 18KOHmg/g, stopped reaction, be cooled to 140 degree, then adding solvent cut to mass concentration is 42%, obtains Synolac, wherein said solvent by 200# gasoline, trimethylbenzene and vinyl acetic monomer in mass ratio for 70:36:3 is made into.
Photostabilization: pigment keeps its former coloured performance under certain illumination.General employing eight grades of tabulations are shown, eight grades best.
Weathering resistance: pigment, under certain natural or artificial climate condition, keeps the ability of its original performance.General employing Pyatyi tabulation is shown, Pyatyi is best.
Tinting strength: tinting pigment absorbs the ability of incident light.The available relative percentage being equivalent to normal pigment sample tinting strength represents.
Opacifying power: the ability covering substrate surface color in filmogen.In the colored paint of conventional covering 1 square area, the grams of contained pigment represents.
Its photostabilization is six grades by experiment, and weathering resistance is level Four, and tinting strength is 40%, and opacifying power is 4 grams/m.
Embodiment 2
A kind of coating containing purple fluorescence material, it is characterized in that: its composition weight proportioning is: the sulfurated lime of 6%, the magnesium sulfide of 3%, the sodium sulphite of 1%, strontium nitrate, wax ester 17%, tung oil 30%, epoxy resin 16%, modified alkyd resin 6%, palm olein ester 16%, the sub-light acrylic paints 3% of methacrylic resin 5 ~ 8%, half, novel photoinitiator 6%, the polyvinyl butyral acetal 10% of 0.08%, all the other are solvent or diluent; Described novel photoinitiator is prepared by following methods: all represent with molar fraction below, and by 1 part of light base benzophenone of 4-, 3 parts of formaldehyde join in reaction vessel, after mixing, add 0.012 part of alkali and make catalyzer, under agitation, heating keeps micro-boiling (99 DEG C) 3h; Then increase the temperature to 160 DEG C, carry out Depressor response 15 minutes, be cooled to 110 DEG C to collect product after reaction terminates, product joined in the deionized water of 20 parts and precipitate, after suction filtration, obtain novel photoinitiator.
Preferably, described alkali is ammoniacal liquor.Described modified alkyd resin is made by following steps:
A) amount taking hydroxylated material is the TriMethylolPropane(TMP) of 5.3 moles, the amount of hydroxylated material is the Tetra hydro Phthalic anhydride of 1.7 moles, the amount of hydroxylated material is the adipic anhydride of 0.92 mole and the amount of hydroxylated material be 0.92 different n-nonanoic acid;
B) different n-nonanoic acid, TriMethylolPropane(TMP), Tetra hydro Phthalic anhydride and adipic anhydride are put into reactor, be warming up to 100 degree, start to stir, 165 degree are warming up to again with the heat-up rate of 85 degree/h, release the water reacting and produce, be warming up to 215 degree, reaction to acid number is 20KOHmg/g, stopped reaction, be cooled to 140 degree, then adding solvent cut to mass concentration is 42%, obtains Synolac, wherein said solvent by 200# gasoline, trimethylbenzene and vinyl acetic monomer in mass ratio for 70:36:3 is made into.
Its photostabilization is seven grades by experiment, and weathering resistance is Pyatyi, and tinting strength is 42%, and opacifying power is 5 grams/m.
Describe the present invention by way of example above, but the invention is not restricted to above-mentioned specific embodiment, all any changes of doing based on the present invention or modification all belong to the scope of protection of present invention.
Claims (4)
1. the coating containing purple fluorescence material, is characterized in that: its composition weight proportioning is:
Sulfurated lime 6 ~ 6.5%;
Magnesium sulfide 2.5 ~ 3%;
Sodium sulphite 0.8 ~ 1%;
Strontium nitrate 0.08 ~ 0.1%;
Wax ester 12 ~ 17%;
Tung oil 20 ~ 30%;
Epoxy resin 10 ~ 16%;
Modified alkyd resin 3 ~ 6%;
Palm olein ester 12 ~ 16%;
Methacrylic resin 5 ~ 8%;
Half sub-light acrylic paints 1 ~ 3%;
Novel photoinitiator 3 ~ 6%;
Polyvinyl butyral acetal 5 ~ 10%;
All the other are solvent or diluent.
2. a kind of coating containing purple fluorescence material according to claim 1, is characterized in that: described alkali is sodium hydroxide, hydrated barta, ammoniacal liquor or zinc oxide.
3. a kind of coating containing purple fluorescence material according to claim 1, is characterized in that: described modified alkyd resin is made by following steps:
A) amount taking hydroxylated material is the TriMethylolPropane(TMP) of 5 ~ 5.3 moles, the amount of hydroxylated material is the Tetra hydro Phthalic anhydride of 1.5 ~ 1.7 moles, the amount of hydroxylated material is the adipic anhydride of 0.7 ~ 0.92 mole and the amount of hydroxylated material be 0.7 ~ 0.92 different n-nonanoic acid;
B) different n-nonanoic acid, TriMethylolPropane(TMP), Tetra hydro Phthalic anhydride and adipic anhydride are put into reactor, be warming up to 85 ~ 100 degree, start to stir, 160 scholar 5 degree is warming up to again with the heat-up rate of 70 ~ 85 degree/h, release the water reacting and produce, be warming up to 210 scholar 5 degree, reaction to acid number is 18 ~ 20KOHmg/g, stopped reaction, be cooled to 140 degree, then adding solvent cut to mass concentration is 42%, obtains Synolac, wherein said solvent by 200# gasoline, trimethylbenzene and vinyl acetic monomer in mass ratio for 70:36:3 is made into.
4. a kind of coating containing purple fluorescence material according to claim 1, it is characterized in that: described novel photoinitiator is prepared by following methods: all represent with molar fraction below, by 1 part of light base benzophenone of 4-, 1 ~ 3 part of formaldehyde joins in reaction vessel, after mixing, add 0.0102 ~ 0.012 part of alkali and make catalyzer, under agitation, heating keeps micro-boiling (90 ~ 99 DEG C) 1h ~ 3h; Then increase the temperature to 140 ~ 160 DEG C, carry out Depressor response 10 ~ 15 minutes, be cooled to 90 DEG C ~ 110 DEG C to collect product after reaction terminates, product joined in the deionized water of 10 ~ 20 parts and precipitate, after suction filtration, obtain novel photoinitiator.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511017841.4A CN105462494A (en) | 2015-12-29 | 2015-12-29 | Coating containing purple fluorescent substances |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511017841.4A CN105462494A (en) | 2015-12-29 | 2015-12-29 | Coating containing purple fluorescent substances |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105462494A true CN105462494A (en) | 2016-04-06 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201511017841.4A Pending CN105462494A (en) | 2015-12-29 | 2015-12-29 | Coating containing purple fluorescent substances |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1039259A (en) * | 1988-07-14 | 1990-01-31 | 沈阳市和平市政工程公司 | A kind of luminescent powder |
| CN102953533A (en) * | 2012-10-26 | 2013-03-06 | 浙江未来家木业有限公司 | Noctilucent floor board processing technology |
| CN103061487A (en) * | 2012-10-26 | 2013-04-24 | 浙江未来家木业有限公司 | Processing technique of noctilucent glazing floors |
| CN103778873A (en) * | 2014-01-21 | 2014-05-07 | 浙江海联电子股份有限公司 | Self-luminous dangerous mark top light |
| CN104371389A (en) * | 2014-11-17 | 2015-02-25 | 青岛厚科信息工程有限公司 | Coating material containing novel photo-initiator |
-
2015
- 2015-12-29 CN CN201511017841.4A patent/CN105462494A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1039259A (en) * | 1988-07-14 | 1990-01-31 | 沈阳市和平市政工程公司 | A kind of luminescent powder |
| CN102953533A (en) * | 2012-10-26 | 2013-03-06 | 浙江未来家木业有限公司 | Noctilucent floor board processing technology |
| CN103061487A (en) * | 2012-10-26 | 2013-04-24 | 浙江未来家木业有限公司 | Processing technique of noctilucent glazing floors |
| CN103778873A (en) * | 2014-01-21 | 2014-05-07 | 浙江海联电子股份有限公司 | Self-luminous dangerous mark top light |
| CN104371389A (en) * | 2014-11-17 | 2015-02-25 | 青岛厚科信息工程有限公司 | Coating material containing novel photo-initiator |
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Application publication date: 20160406 |
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