CN105504930A - Resin oil paint capable of emitting purple fluorescent light - Google Patents

Resin oil paint capable of emitting purple fluorescent light Download PDF

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Publication number
CN105504930A
CN105504930A CN201511019446.XA CN201511019446A CN105504930A CN 105504930 A CN105504930 A CN 105504930A CN 201511019446 A CN201511019446 A CN 201511019446A CN 105504930 A CN105504930 A CN 105504930A
Authority
CN
China
Prior art keywords
percent
parts
paint
emulsifying agent
resene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201511019446.XA
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Chinese (zh)
Inventor
李姗姗
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Qingdao Beidou Xingyun Communication Technology Co Ltd
Original Assignee
Qingdao Beidou Xingyun Communication Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by Qingdao Beidou Xingyun Communication Technology Co Ltd filed Critical Qingdao Beidou Xingyun Communication Technology Co Ltd
Priority to CN201511019446.XA priority Critical patent/CN105504930A/en
Publication of CN105504930A publication Critical patent/CN105504930A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C09D4/06Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/22Luminous paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

The invention relates to a chemical industry product, and particularly relates to resin oil paint capable of emitting purple fluorescent light. The resin oil paint comprises the following components by weight percent: 6 to 6.5 percent of calcium sulfide, 2.5 to 3 percent of magnesium sulfide, 0.8 to 1 percent of sodium sulfide, 0.08 to 0.1 percent of strontium nitrate, 15 to 20 percent of rosin, 20 to 30 percent of asphalt, 12 to 16 percent of epoxy resin, 5 to 10 percent of acrylonitrile, 3 to 6 percent of phthalate anhydride, 10 to 15 percent of tung oil, 5 to 8 percent of secondary film forming substance, 1 to 3 percent of phosphoric acid, 3 to 6 percent of zeolite powder, 5 to 10 percent of polyvinyl butyral, 3 to 5 percent of defoaming agent, 1 to 3 percent of emulsifier and the balance of paint thinner. The resin oil paint can absorb light and emit ultraviolet fluorescent light in a dark environment, is high in covering capacity, small in toxicity, good in pinhole resistance, capable of effectively inhibiting foams with the defoaming agent, relatively low in requirement on the construction environment and applicable to objects such as billboards, street advertisements, night roads and barrier markers and the like.

Description

A kind of resene paint sending purple fluorescence
Technical field
The present invention relates to a kind of chemical industries, especially a kind of resene paint sending purple fluorescence.
Background technology
Coating is a kind of material, and this material can be coated in article surface by different construction technologies, forms adhere well, has some strength, continuous print solid film.The film common name film of such formation, also known as paint film or coating.Belong to organic chemical industry's macromolecular material, the film formed belongs to macromolecular compound type.The classification of the Chemicals of passing through according to the modern times, coating belongs to fine chemical product.Modern coating is progressively becoming the polyfunctional engineering materials of a class, is an important industry in chemical industry.
When painting, easily there is at coating surface the needle point pore phenomenon that a kind of depression is revealed the exact details.This tip-like aperture is just as acupuncture aperture, and aperture is at 100 microns.Affect attractive in appearance, the subject matter reason producing it has one, plate surface process is bad, many wollines, wood thorn, fill difficulty; Two, bottom does not parch completely, just construction second time.Three, the paint prepared does not leave standstill for some time, and paint viscosity is high, and bubble is not eliminated.Four, one-off construction is blocked up.Five, solidifying agent, the supporting mistake of thinner; Six, solidifying agent add-on is too much.Seven, environment temperature and humidity is high; Eight, moisture content is high.
Summary of the invention
The present invention is intended to solve the problems of the technologies described above, provide a kind of resene paint sending purple fluorescence, it can send purple fluorescence, strong covering power under extinction dark surrounds, toxicity is little, solidifying agent is less, and anti-pin hole ability is good, and construction stability is good, having defoamer can effectively suppress bubble to produce, lower to the requirement of construction environment, can be used for guideboard and outdoor advertising and night road and the object such as obstacle marking, its technical scheme adopted is as follows:
A kind of resene paint sending purple fluorescence, it is characterized in that: its composition weight proportioning is: the sulfurated lime of 6 ~ 6.5%, the magnesium sulfide of 2.5 ~ 3%, the sodium sulphite of 0.8 ~ 1%, strontium nitrate, rosin 15 ~ 20%, pitch 20 ~ 30%, epoxy resin 12 ~ 16%, vinyl cyanide 5 ~ 10%, phthalate anhydride 3 ~ 6%, tung oil 10 ~ 15%, film forming subsidiary material matter 5 ~ 8%, phosphatase 11 ~ 3%, zeolite powder 3 ~ 6%, polyvinyl butyral acetal 5 ~ 10%, defoamer 3 ~ 5%, the emulsifying agent 1 ~ 3% of 0.08 ~ 0.1%, all the other are solvent or diluent.
On technique scheme basis, described solvent or diluent is mixed according to 2:3:2:1:2:1 by N-BUTYL ACETATE, ethyl acetate, ethanol, dimethylbenzene, ethylene glycol ether acetate, mibk.
On technique scheme basis, described emulsifying agent is made up of each component of following masses number: zinc peroxide 3-9 part, paraffin 2-7 part, vinylcarbinol polyethers 3-7 part, solubility promoter 5-9 part, ethylene glycol 1-5 part, glycerine 2-6 part, zinc 1,2-propylene bisdithiocarbamate 3-5 part, adding deionized water to total mass is 100 parts.
On technique scheme basis, described defoamer by following constitutive material by weight: high fatty alcohol 40 ~ 85 parts, polyether modified siloxane 5 ~ 15 parts, emulsifying agent 5 ~ 10 parts, Span series emulsifying agent 6 ~ 10 parts, silicon-dioxide 8 ~ 22 parts, deionized water 100 ~ 500 parts preparation.
Tool of the present invention has the following advantages: can send purple fluorescence under extinction dark surrounds, strong covering power, toxicity is little, solidifying agent is less, anti-pin hole ability is good, and construction stability is good, and having defoamer can effectively suppress bubble to produce, lower to the requirement of construction environment, can be used for guideboard and outdoor advertising and night road and the object such as obstacle marking.
Embodiment
Embodiment 1
A kind of resene paint sending purple fluorescence, it is characterized in that: its composition weight proportioning is: the sulfurated lime of 6.5%, the magnesium sulfide of 2.5%, the sodium sulphite of 1%, the strontium nitrate of 0.08%, rosin 15%, pitch 20%, epoxy resin 12%, vinyl cyanide 5%, phthalate anhydride 3%, tung oil 10%, film forming subsidiary material matter 5%, phosphatase 11 %, zeolite powder 3%, polyvinyl butyral acetal 5%, defoamer 3%, emulsifying agent 1%, all the other are solvent or diluent, described defoamer is by following constitutive material by weight: high fatty alcohol 40 parts, polyether modified siloxane 5 parts, emulsifying agent 5 parts, Span series emulsifying agent 6 parts, silicon-dioxide 8 parts, deionized water 100 parts preparation.
On technique scheme basis, described solvent or diluent is mixed according to 2:3:2:1:2:1 by N-BUTYL ACETATE, ethyl acetate, ethanol, dimethylbenzene, ethylene glycol ether acetate, mibk.
On technique scheme basis, described emulsifying agent is made up of each component of following masses number: zinc peroxide 3 parts, 2 parts, paraffin, vinylcarbinol polyethers 3 parts, solubility promoter 5 parts, ethylene glycol 1 part, glycerine 2 parts, zinc 1,2-propylene bisdithiocarbamate 3 parts, and adding deionized water to total mass is 100 parts.
Embodiment 2
A kind of resene paint sending purple fluorescence, it is characterized in that: its composition weight proportioning is: the sulfurated lime of 6.5%, the magnesium sulfide of 3%, the sodium sulphite of 1%, the strontium nitrate of 0.08%, rosin 20%, pitch 30%, epoxy resin 16%, vinyl cyanide 10%, phthalate anhydride 6%, tung oil 15%, film forming subsidiary material matter 8%, phosphoric acid 3%, zeolite powder 6%, polyvinyl butyral acetal 10%, defoamer 3 ~ 5%, emulsifying agent 3%, all the other are solvent or diluent, described defoamer is by following constitutive material by weight: high fatty alcohol 85 parts, polyether modified siloxane 15 parts, emulsifying agent 10 parts, Span series emulsifying agent 10 parts, silicon-dioxide 22 parts, deionized water 500 parts preparation.
On technique scheme basis, described solvent or diluent is mixed according to 2:3:2:1:2:1 by N-BUTYL ACETATE, ethyl acetate, ethanol, dimethylbenzene, ethylene glycol ether acetate, mibk.
On technique scheme basis, described emulsifying agent is made up of each component of following masses number: zinc peroxide 3-9 part, paraffin 2-7 part, vinylcarbinol polyethers 3-7 part, solubility promoter 5-9 part, ethylene glycol 1-5 part, glycerine 2-6 part, zinc 1,2-propylene bisdithiocarbamate 3-5 part, adding deionized water to total mass is 100 parts.
Embodiment 3
A kind of resene paint sending purple fluorescence, it is characterized in that: its composition weight proportioning is: the sulfurated lime of 6%, the magnesium sulfide of 2.8%, the sodium sulphite of 0.9%, the strontium nitrate of 0.1%, rosin 18%, pitch 25%, epoxy resin 12 ~ 16%, vinyl cyanide 8%, phthalate anhydride 4%, tung oil 12%, film forming subsidiary material matter 7%, phosphoric acid 2%, zeolite powder 5%, polyvinyl butyral acetal 8%, defoamer 4%, emulsifying agent 2%, all the other are solvent or diluent, described defoamer is by following constitutive material by weight: high fatty alcohol 50 parts, polyether modified siloxane 10 parts, emulsifying agent 8 parts, Span series emulsifying agent 8 parts, silicon-dioxide 20 parts, deionized water 300 parts preparation.
On technique scheme basis, described solvent or diluent is mixed according to 2:3:2:1:2:1 by N-BUTYL ACETATE, ethyl acetate, ethanol, dimethylbenzene, ethylene glycol ether acetate, mibk.
On technique scheme basis, described emulsifying agent is made up of each component of following masses number: zinc peroxide 6 parts, 6 parts, paraffin, vinylcarbinol polyethers 6 parts, solubility promoter 8 parts, ethylene glycol 4 parts, glycerine 3 parts, zinc 1,2-propylene bisdithiocarbamate 4 parts, and adding deionized water to total mass is 100 parts.
Describe the present invention by way of example above, but the invention is not restricted to above-mentioned specific embodiment, all any changes of doing based on the present invention or modification all belong to the scope of protection of present invention.

Claims (4)

1. one kind can send the resene paint of purple fluorescence, it is characterized in that: its composition weight proportioning is: the sulfurated lime of 6 ~ 6.5%, the magnesium sulfide of 2.5 ~ 3%, the sodium sulphite of 0.8 ~ 1%, strontium nitrate, rosin 15 ~ 20%, pitch 20 ~ 30%, epoxy resin 12 ~ 16%, vinyl cyanide 5 ~ 10%, phthalate anhydride 3 ~ 6%, tung oil 10 ~ 15%, film forming subsidiary material matter 5 ~ 8%, phosphatase 11 ~ 3%, zeolite powder 3 ~ 6%, polyvinyl butyral acetal 5 ~ 10%, defoamer 3 ~ 5%, the emulsifying agent 1 ~ 3% of 0.08 ~ 0.1%, all the other are solvent or diluent.
2. a kind of resene paint sending purple fluorescence according to claim 1, is characterized in that: described solvent or diluent is mixed according to 2:3:2:1:2:1 by N-BUTYL ACETATE, ethyl acetate, ethanol, dimethylbenzene, ethylene glycol ether acetate, mibk.
3. a kind of resene paint sending purple fluorescence according to claim 1, it is characterized in that: described emulsifying agent is made up of each component of following masses number: zinc peroxide 3-9 part, paraffin 2-7 part, vinylcarbinol polyethers 3-7 part, solubility promoter 5-9 part, ethylene glycol 1-5 part, glycerine 2-6 part, zinc 1,2-propylene bisdithiocarbamate 3-5 part, adding deionized water to total mass is 100 parts.
4. a kind of resene paint sending purple fluorescence according to claim 1, is characterized in that: described defoamer by following constitutive material by weight: high fatty alcohol 40 ~ 85 parts, polyether modified siloxane 5 ~ 15 parts, emulsifying agent 5 ~ 10 parts, Span series emulsifying agent 6 ~ 10 parts, silicon-dioxide 8 ~ 22 parts, deionized water 100 ~ 500 parts preparation.
CN201511019446.XA 2015-12-29 2015-12-29 Resin oil paint capable of emitting purple fluorescent light Pending CN105504930A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201511019446.XA CN105504930A (en) 2015-12-29 2015-12-29 Resin oil paint capable of emitting purple fluorescent light

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201511019446.XA CN105504930A (en) 2015-12-29 2015-12-29 Resin oil paint capable of emitting purple fluorescent light

Publications (1)

Publication Number Publication Date
CN105504930A true CN105504930A (en) 2016-04-20

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Application Number Title Priority Date Filing Date
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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1039259A (en) * 1988-07-14 1990-01-31 沈阳市和平市政工程公司 A kind of luminescent powder
CN102953533A (en) * 2012-10-26 2013-03-06 浙江未来家木业有限公司 Noctilucent floor board processing technology
CN103061487A (en) * 2012-10-26 2013-04-24 浙江未来家木业有限公司 Processing technique of noctilucent glazing floors
CN103778873A (en) * 2014-01-21 2014-05-07 浙江海联电子股份有限公司 Self-luminous dangerous mark top light
CN104403393A (en) * 2014-11-24 2015-03-11 青岛市市南区隆德中医药研究所 Resinae paint

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1039259A (en) * 1988-07-14 1990-01-31 沈阳市和平市政工程公司 A kind of luminescent powder
CN102953533A (en) * 2012-10-26 2013-03-06 浙江未来家木业有限公司 Noctilucent floor board processing technology
CN103061487A (en) * 2012-10-26 2013-04-24 浙江未来家木业有限公司 Processing technique of noctilucent glazing floors
CN103778873A (en) * 2014-01-21 2014-05-07 浙江海联电子股份有限公司 Self-luminous dangerous mark top light
CN104403393A (en) * 2014-11-24 2015-03-11 青岛市市南区隆德中医药研究所 Resinae paint

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Application publication date: 20160420