CN106147518A - Mosquito-proof indoor copper sculpture epoxy acrylic anticorrosion water-soluble paint of a kind of expelling parasite and preparation method thereof - Google Patents
Mosquito-proof indoor copper sculpture epoxy acrylic anticorrosion water-soluble paint of a kind of expelling parasite and preparation method thereof Download PDFInfo
- Publication number
- CN106147518A CN106147518A CN201610526363.8A CN201610526363A CN106147518A CN 106147518 A CN106147518 A CN 106147518A CN 201610526363 A CN201610526363 A CN 201610526363A CN 106147518 A CN106147518 A CN 106147518A
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- Prior art keywords
- water
- mosquito
- copper sculpture
- expelling parasite
- soluble paint
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Abstract
The invention discloses the mosquito-proof indoor copper sculpture epoxy acrylic anticorrosion water-soluble paint of a kind of expelling parasite, it is to be prepared by the raw material of following weight parts: epoxy resin E 44 40 60, Blumea oil 0.1 0.15, Rhizoma Acori Graminei oil 0.1 0.15, ethylene glycol monobutyl ether 10 15, n-butanol 15 25, Radix Stemonae fluidextract 0.3 0.5, golden cypress liquid extract 0.1 0.2, methacrylic acid 68, styrene 46, butyl acrylate 35, benzoyl peroxide 0.5 1, N, N diformyl ethanol 46, titania nanotube 35, phenylpropyl alcohol triazole 0.3 0.5, γ mercaptopropyltriethoxysilane 0.1 0.15, borax 0.1 0.15, water 100 120.The copper sculpture water paint of the present invention has excellent Corrosion Protection, mechanical performance and lasting validity, also effect of repelling mosquitoes and preventing insects.
Description
Technical field
The present invention relates to copper sculpture technical field of coatings, particularly relate to the mosquito-proof indoor copper sculpture epoxy of a kind of expelling parasite-
Acrylic acid anticorrosion water-soluble paint and preparation method thereof.
Background technology
With the raising of modern life level and aesthetic consciousness, this traditional arts and crafts of sculpture is more and more designed
Teacher and masses like.Wherein copper sculpture not only pattern is unique, and has very high enjoying value, the sculpture phase with other materials
Ratio, also feature sturdy and durable, survivable, is widely used.Copper sculpture is not necessarily to M R continually, but
Use under conditions of air humidity is excessive can have a strong impact on the quality of copper sculpture.For reducing corrosion, extend the use of copper sculpture
In the life-span, the preventive measure being usually taken is to carry out protective treatment to copper sculpture surface, and wherein brushing paint is to use relatively at present
For extensive, economical and practical method.
With the enhancing of environmental consciousness, traditional solvent-borne corrosion resistant coating is gradually eliminated, high-performance, oligosaprobic water-repellent preservation
Paint has become as development trend.More aqueous anticorrosion paint is applied mainly to have epoxy resin etc. at present.Document " acrylic acid-grafted changes
Property epoxy resin anticorrosion emulsion research " use acrylic acid carry out graft modification to epoxy resin, the emulsion obtaining has epoxy concurrently
Resin and the advantage of acrylic resin, have good adhesive force and decay resistance.But, this method prepares the three of emulsion
The dimension network structure degree of cross linking is relatively low, and resistance to water is not enough, and the protection to matrix surface is inadequate, have impact on its antiseptic property, and cannot
The anticorrosion persistence that reply painting defect or breakdown of coating bring declines, and is therefore further improved in actual applications.
Content of the invention
The object of the invention is contemplated to make up the defect of prior art, provides a kind of crosslinking degree height, good mechanical property, prevents
Protect performance and by force and there is the mosquito-proof indoor copper sculpture epoxy-acrylic anticorrosion water-soluble paint of excellent persistent expelling parasite and preparation thereof
Method.
The present invention is achieved by the following technical solutions:
The mosquito-proof indoor copper sculpture epoxy-acrylic anticorrosion water-soluble paint of a kind of expelling parasite, it is to be prepared by the raw material of following weight parts:
Epoxy resin E-44 40-60, Blumea oil 0.1-0.15, Rhizoma Acori Graminei oil 0.1-0.15, ethylene glycol monobutyl ether 10-15, positive fourth
Alcohol 15-25, Radix Stemonae fluidextract 0.3-0.5, golden cypress liquid extract 0.1-0.2, methacrylic acid 6-8, styrene 4-6, acrylic acid fourth
Ester 3-5, benzoyl peroxide 0.5-1, N, N-diformyl ethanol 4-6, titania nanotube 3-5, phenylpropyl alcohol triazole 0.3-
0.5, gamma-mercaptopropyltriethoxysilane 0.1-0.15, borax 0.1-0.15, water 100-120；
Described titania nanotube is to use hydrothermal synthesis method to prepare, and caliber is 5-25nm, and pipe range is 500-1000nm.
The preparation method of the mosquito-proof indoor copper sculpture epoxy-acrylic anticorrosion water-soluble paint of a kind of expelling parasite, comprises the following steps:
(1) it titania nanotube is mixed with absolute ethyl alcohol than 1:10-1:15 by solid-liquid weight is uniformly dispersed, be subsequently adding Chinese mugwort
Leaf oil, Rhizoma Acori Graminei oil, phenylpropyl alcohol triazole and gamma-mercaptopropyltriethoxysilane stirring 6-12h, by gained solid vacuum after centrifuging
It is dried, obtain Modified Titanium nanotube；
(2) by the Modified Titanium nanotube in (1) and N, the mixing of N-diformyl second alcohol and water is uniformly dispersed, and obtains component A, by epoxy
Resin E-44, ethylene glycol monobutyl ether and n-butanol mixing are warming up to 105-110 DEG C, are then slowly added dropwise methacrylic acid, benzene second
The mixed solution of alkene, butyl acrylate and benzoyl peroxide, and in 115-120 DEG C of insulation reaction 2-4h, obtain B component, by A group
Divide and B component is uniform in 80-85 DEG C of mixing high-speed stirred, then in 50-60 DEG C of insulation reaction 1-1.5h, obtain complex emulsions；
(3) grind uniformly after the complex emulsions in (2) being mixed with remaining raw material, obtain the mosquito-proof indoor copper sculpture ring of expelling parasite
Oxygen-acrylic acid anticorrosion water-soluble paint.
The invention have the advantage that
The present invention first with titania nanotube to Blumea oil, Rhizoma Acori Graminei oil, phenylpropyl alcohol triazole and γ-mercapto propyl triethoxy
Silane loads, and then carries out emulsion polymerization with epoxy resin and acrylate and obtains complex emulsions, can effectively carry
Rise the tridimensional network crosslinking degree of film, promote barrier propterty to matrix, the mechanical performance of film and steady can be improved again
Qualitative, and due to the load to composite corrosion inhibitor, good anticorrosion can be played to the metal of paint film defect or breakage
Effect, improves the persistence of surfacecti proteon.Meanwhile, by remaining raw material add with compounding so as to get copper sculpture water paint
Comprehensive, lasting protection can be provided for matrix surface, have excellent Corrosion Protection, mechanical performance and lasting validity concurrently, also
There is effect of repelling mosquitoes and preventing insects.
Detailed description of the invention
The mosquito-proof indoor copper sculpture epoxy-acrylic anticorrosion water-soluble paint of a kind of expelling parasite, the component by following weight (kg) is former
Material is prepared from:
Epoxy resin E-44 40, Blumea oil 0.1, Rhizoma Acori Graminei oil 0.1, ethylene glycol monobutyl ether 10, n-butanol 15, Radix Stemonae fluidextract
0.3, golden cypress liquid extract 0.1, methacrylic acid 6, styrene 4, butyl acrylate 3, benzoyl peroxide 0.5, N, N-bis-formyl
Base ethanol 4, titania nanotube 3, phenylpropyl alcohol triazole 0.3, gamma-mercaptopropyltriethoxysilane 0.1, borax 0.1, water 100；
Described titania nanotube is to use hydrothermal synthesis method to prepare, and caliber is 5nm, and pipe range is 500nm.
The preparation method of the mosquito-proof indoor copper sculpture epoxy-acrylic anticorrosion water-soluble paint of a kind of expelling parasite, comprises the following steps:
(1) titania nanotube mixed with absolute ethyl alcohol than 1:10 by solid-liquid weight be uniformly dispersed, be subsequently adding Blumea oil,
Gained solid is vacuum dried after centrifuging by Rhizoma Acori Graminei oil, phenylpropyl alcohol triazole and gamma-mercaptopropyltriethoxysilane stirring 6h,
Modified Titanium nanotube；
(2) by the Modified Titanium nanotube in (1) and N, the mixing of N-diformyl second alcohol and water is uniformly dispersed, and obtains component A, by epoxy
Resin E-44, ethylene glycol monobutyl ether and n-butanol mixing be warming up to 105 DEG C, be then slowly added dropwise methacrylic acid, styrene, third
Olefin(e) acid butyl ester and the mixed solution of benzoyl peroxide, and in 115 DEG C of insulation reaction 2h, obtain B component, by component A and B component in
80 DEG C of mixing high-speed stirred are uniform, then in 50 DEG C of insulation reaction 1h, obtain complex emulsions；
(3) grind uniformly after the complex emulsions in (2) being mixed with remaining raw material, obtain the mosquito-proof indoor copper sculpture ring of expelling parasite
Oxygen-acrylic acid anticorrosion water-soluble paint.
Outward appearance: flat smooth, transparent；
Adhesive force: 1 grade；
Resistance to water: 1500h is unchanged；
Salt fog resistance: 1000h is unchanged.
Claims (2)
1. an expelling parasite mosquito-proof indoor copper sculpture epoxy-acrylic anticorrosion water-soluble paint, it is characterised in that it is by following weight
The raw material of part prepares:
Epoxy resin E-44 40-60, Blumea oil 0.1-0.15, Rhizoma Acori Graminei oil 0.1-0.15, ethylene glycol monobutyl ether 10-15, positive fourth
Alcohol 15-25, Radix Stemonae fluidextract 0.3-0.5, golden cypress liquid extract 0.1-0.2, methacrylic acid 6-8, styrene 4-6, acrylic acid fourth
Ester 3-5, benzoyl peroxide 0.5-1, N, N-diformyl ethanol 4-6, titania nanotube 3-5, phenylpropyl alcohol triazole 0.3-
0.5, gamma-mercaptopropyltriethoxysilane 0.1-0.15, borax 0.1-0.15, water 100-120；
Described titania nanotube is to use hydrothermal synthesis method to prepare, and caliber is 5-25nm, and pipe range is 500-1000nm.
2. the preparation of the mosquito-proof indoor copper sculpture epoxy-acrylic anticorrosion water-soluble paint of a kind of expelling parasite according to claim 1
Method, it is characterised in that comprise the following steps:
(1) it titania nanotube is mixed with absolute ethyl alcohol than 1:10-1:15 by solid-liquid weight is uniformly dispersed, be subsequently adding Chinese mugwort
Leaf oil, Rhizoma Acori Graminei oil, phenylpropyl alcohol triazole and gamma-mercaptopropyltriethoxysilane stirring 6-12h, by gained solid vacuum after centrifuging
It is dried, obtain Modified Titanium nanotube；
(2) by the Modified Titanium nanotube in (1) and N, the mixing of N-diformyl second alcohol and water is uniformly dispersed, and obtains component A, by epoxy
Resin E-44, ethylene glycol monobutyl ether and n-butanol mixing are warming up to 105-110 DEG C, are then slowly added dropwise methacrylic acid, benzene second
The mixed solution of alkene, butyl acrylate and benzoyl peroxide, and in 115-120 DEG C of insulation reaction 2-4h, obtain B component, by A group
Divide and B component is uniform in 80-85 DEG C of mixing high-speed stirred, then in 50-60 DEG C of insulation reaction 1-1.5h, obtain complex emulsions；
(3) grind uniformly after the complex emulsions in (2) being mixed with remaining raw material, obtain the mosquito-proof indoor copper sculpture ring of expelling parasite
Oxygen-acrylic acid anticorrosion water-soluble paint.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610526363.8A CN106147518A (en) | 2016-07-06 | 2016-07-06 | Mosquito-proof indoor copper sculpture epoxy acrylic anticorrosion water-soluble paint of a kind of expelling parasite and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610526363.8A CN106147518A (en) | 2016-07-06 | 2016-07-06 | Mosquito-proof indoor copper sculpture epoxy acrylic anticorrosion water-soluble paint of a kind of expelling parasite and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106147518A true CN106147518A (en) | 2016-11-23 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610526363.8A Pending CN106147518A (en) | 2016-07-06 | 2016-07-06 | Mosquito-proof indoor copper sculpture epoxy acrylic anticorrosion water-soluble paint of a kind of expelling parasite and preparation method thereof |
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| CN (1) | CN106147518A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107254245A (en) * | 2017-07-03 | 2017-10-17 | 四川马可视觉网络科技有限公司 | Insect prevention fluorescence poster paint |
| CN109819980B (en) * | 2019-04-02 | 2021-04-06 | 哈工大机器人（山东）智能装备研究院 | Slow-release mosquito-proof insect-repellent incense bead and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102585111A (en) * | 2012-01-10 | 2012-07-18 | 江苏科技大学 | Modified epoxy emulsion and preparation method thereof |
| CN103210120A (en) * | 2010-10-13 | 2013-07-17 | 国民油井华高有限公司 | Releasable corrosion inhibitors |
-
2016
- 2016-07-06 CN CN201610526363.8A patent/CN106147518A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103210120A (en) * | 2010-10-13 | 2013-07-17 | 国民油井华高有限公司 | Releasable corrosion inhibitors |
| CN102585111A (en) * | 2012-01-10 | 2012-07-18 | 江苏科技大学 | Modified epoxy emulsion and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107254245A (en) * | 2017-07-03 | 2017-10-17 | 四川马可视觉网络科技有限公司 | Insect prevention fluorescence poster paint |
| CN109819980B (en) * | 2019-04-02 | 2021-04-06 | 哈工大机器人（山东）智能装备研究院 | Slow-release mosquito-proof insect-repellent incense bead and preparation method thereof |
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Application publication date: 20161123 |