CN106147494A - Copper sculpture epoxy acrylic anticorrosion water-soluble paint and preparation method thereof in a kind of purification air chamber - Google Patents

Copper sculpture epoxy acrylic anticorrosion water-soluble paint and preparation method thereof in a kind of purification air chamber Download PDF

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Publication number
CN106147494A
CN106147494A CN201610524519.9A CN201610524519A CN106147494A CN 106147494 A CN106147494 A CN 106147494A CN 201610524519 A CN201610524519 A CN 201610524519A CN 106147494 A CN106147494 A CN 106147494A
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China
Prior art keywords
water
air chamber
copper sculpture
soluble paint
alcohol
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CN201610524519.9A
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Chinese (zh)
Inventor
刘勇
安施军
薛焕刚
丁莉莉
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Tongling Qingtongshida Sculpture Co Ltd
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Tongling Qingtongshida Sculpture Co Ltd
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Priority to CN201610524519.9A priority Critical patent/CN106147494A/en
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C09D151/08—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04—Acids; Metal salts or ammonium salts thereof
    • C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/10—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers containing more than one epoxy radical per molecule
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • C09D5/10—Anti-corrosive paints containing metal dust
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention discloses copper sculpture epoxy acrylic anticorrosion water-soluble paint in a kind of purification air chamber, it is to be prepared by the raw material of following weight parts: epoxy resin E 44 40 60, ethylene glycol monobutyl ether 10 15, n-butyl alcohol 15 25, eucalyptus oil 0.1 0.15, Fructus Citri Limoniae oil 0.1 0.2, methacrylic acid 68, styrene 46, butyl acrylate 35, benzoyl peroxide 0.5 1, N, N diformyl ethanol 46, titania nanotube 46, nanometer germanium 0.1 0.15, nano-tourmaline powder 0.3 0.5, phenylpropyl alcohol triazole 0.3 0.5, γ mercaptopropyltriethoxysilane 0.1 0.15, sodium alginate 0.3 0.5, water 100 120.The copper sculpture water paint of the present invention had both had excellent Corrosion Protection, mechanical performance and lasting effectiveness, also has the effect purifying air, is conducive to improving indoor environmental quality.

Description

Copper sculpture epoxy-acrylic anticorrosion water-soluble paint and system thereof in a kind of purification air chamber Preparation Method
Technical field
The present invention relates to copper sculpture technical field of coatings, particularly relate to a kind of purify copper sculpture epoxy in air chamber- Acrylic acid anticorrosion water-soluble paint and preparation method thereof.
Background technology
Along with modern life level and the raising of aesthetic consciousness, this traditional arts and crafts of sculpture is more and more designed Teacher and masses like.Wherein copper sculpture not only pattern is unique, and has the highest enjoying value, with the sculpture phase of other materials Ratio, feature the most sturdy and durable, survivable, it is widely used.Copper sculpture without M R continually, but Under conditions of air humidity is excessive, use can have a strong impact on the quality of copper sculpture.For reducing corrosion, extend the use of copper sculpture In the life-span, the preventive measure being usually taken is that copper sculpture surface carries out protective treatment, wherein brushing paint be currently used relatively For extensive, economical and practical method.
Along with the enhancing of environmental consciousness, traditional solvent-borne corrosion resistant coating is gradually eliminated, high-performance, oligosaprobic water-repellent preservation Paint has become as development trend.More aqueous anticorrosion paint is applied mainly to have epoxy resin etc. at present.Document " acrylic acid-grafted changes Property epoxy resin anticorrosion emulsion research " use acrylic acid epoxy resin is carried out graft modification, the emulsion obtained has epoxy concurrently Resin and the advantage of acrylic resin, have good adhesive force and decay resistance.But, this method prepares the three of emulsion The dimension network structure degree of cross linking is relatively low, and resistance to water is not enough, and the protection to matrix surface is inadequate, have impact on its antiseptic property, and cannot The anticorrosion persistency that reply painting defect or breakdown of coating bring declines, and is further improved the most in actual applications.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of crosslinking degree height, good mechanical property, prevent Protect performance and by force and there is copper sculpture epoxy-acrylic anticorrosion water-soluble paint and preparation thereof in excellent persistent purification air chamber Method.
The present invention is achieved by the following technical solutions:
Copper sculpture epoxy-acrylic anticorrosion water-soluble paint in a kind of purification air chamber, it is to be prepared by the raw material of following weight parts:
Epoxy resin E-44 40-60, ethylene glycol monobutyl ether 10-15, n-butyl alcohol 15-25, eucalyptus oil 0.1-0.15, Fructus Citri Limoniae oil 0.1-0.2, methacrylic acid 6-8, styrene 4-6, butyl acrylate 3-5, benzoyl peroxide 0.5-1, N, N-diformyl Ethanol 4-6, titania nanotube 4-6, nanometer germanium 0.1-0.15, nano-tourmaline powder 0.3-0.5, phenylpropyl alcohol triazole 0.3- 0.5, gamma-mercaptopropyltriethoxysilane 0.1-0.15, sodium alginate 0.3-0.5, water 100-120；
Described titania nanotube is to use hydrothermal synthesis method to prepare, and caliber is 5-25nm, and pipe range is 500-1000nm.
A kind of purify the preparation method of copper sculpture epoxy-acrylic anticorrosion water-soluble paint in air chamber, comprise the following steps:
(1) titania nanotube is mixed with dehydrated alcohol by solid-liquid weight ratio 1:10-1:15 it is uniformly dispersed, be subsequently adding eucalyptus globulus Leaf oil, Fructus Citri Limoniae oil, phenylpropyl alcohol triazole and gamma-mercaptopropyltriethoxysilane stirring 6-12h, do gained solid vacuum after being centrifuged Dry, obtain Modified Titanium nanotube；
(2) by the Modified Titanium nanotube in (1), nanometer germanium, nano-tourmaline powder, N, the mixing dispersion of N-diformyl second alcohol and water Uniformly, obtain component A, the mixing of epoxy resin E-44, ethylene glycol monobutyl ether and n-butyl alcohol is warming up to 105-110 DEG C, the most slowly Dropping methacrylic acid, styrene, butyl acrylate and the mixed solution of benzoyl peroxide, and anti-in 115-120 DEG C of insulation Answer 2-4h, obtain B component, by uniform in 80-85 DEG C of mixing high-speed stirred to component A and B component, then anti-in 50-60 DEG C of insulation Answer 1-1.5h, obtain complex emulsions；
(3) grind uniformly after the complex emulsions in (2) being mixed with remaining raw material, copper sculpture ring in air chamber must be purified Oxygen-acrylic acid anticorrosion water-soluble paint.
The invention have the advantage that
The present invention first with titania nanotube to eucalyptus oil, Fructus Citri Limoniae oil, phenylpropyl alcohol triazole and γ-mercapto propyl-triethoxysilicane Alkane loads, and then carries out emulsion polymerization with epoxy resin and acrylate and obtains complex emulsions, can effectively promote The tridimensional network crosslinking degree of film, promotes the barrier propterty to matrix, can improve again the mechanical performance of film and stablize Property, and due to the load to composite corrosion inhibitor, the Copper substrate of paint film defect or breakage can be played good anticorrosion Effect, improves the persistency of surfacecti proteon.Meanwhile, by remaining raw material add with compounding so as to get copper sculpture water paint Comprehensive, lasting protection can be provided for matrix surface, have excellent Corrosion Protection, mechanical performance and lasting effectiveness concurrently, also There is the effect purifying air, be conducive to improving indoor environmental quality.
Detailed description of the invention
Copper sculpture epoxy-acrylic anticorrosion water-soluble paint in a kind of purification air chamber, the component by following weight (kg) is former Material is prepared from:
Epoxy resin E-44 40, ethylene glycol monobutyl ether 10, n-butyl alcohol 15, eucalyptus oil 0.1, Fructus Citri Limoniae oil 0.1, methacrylic acid 6, Styrene 4, butyl acrylate 3, benzoyl peroxide 0.5, N, N-diformyl ethanol 4, titania nanotube 4, nanometer germanium 0.1, nano-tourmaline powder 0.3, phenylpropyl alcohol triazole 0.3, gamma-mercaptopropyltriethoxysilane 0.1, sodium alginate 0.3, water 100；
Described titania nanotube is to use hydrothermal synthesis method to prepare, and caliber is 5nm, and pipe range is 500nm.
A kind of purify the preparation method of copper sculpture epoxy-acrylic anticorrosion water-soluble paint in air chamber, comprise the following steps:
(1) titania nanotube mixed with dehydrated alcohol by solid-liquid weight ratio 1:10 be uniformly dispersed, be subsequently adding eucalyptus oil, Fructus Citri Limoniae oil, phenylpropyl alcohol triazole and gamma-mercaptopropyltriethoxysilane stirring 6h, be vacuum dried gained solid after being centrifuged, must change Property titanium nanotube；
(2) by the Modified Titanium nanotube in (1), nanometer germanium, nano-tourmaline powder, N, the mixing dispersion of N-diformyl second alcohol and water Uniformly, obtain component A, the mixing of epoxy resin E-44, ethylene glycol monobutyl ether and n-butyl alcohol is warming up to 105 DEG C, is then slowly added dropwise The mixed solution of methacrylic acid, styrene, butyl acrylate and benzoyl peroxide, and in 115 DEG C of insulation reaction 2h, obtain B Component, by uniform in 80 DEG C of mixing high-speed stirred to component A and B component, then in 50 DEG C of insulation reaction 1h, obtains complex emulsions；
(3) grind uniformly after the complex emulsions in (2) being mixed with remaining raw material, copper sculpture ring in air chamber must be purified Oxygen-acrylic acid anticorrosion water-soluble paint.
Outward appearance: flat smooth, transparent；
Adhesive force: 1 grade；
Resistance to water: 1500h is unchanged；
Salt fog resistance: 1000h is unchanged.

Claims (2)

1. copper sculpture epoxy-acrylic anticorrosion water-soluble paint in a purification air chamber, it is characterised in that it is by following weight The raw material of part prepares:
Epoxy resin E-44 40-60, ethylene glycol monobutyl ether 10-15, n-butyl alcohol 15-25, eucalyptus oil 0.1-0.15, Fructus Citri Limoniae oil 0.1-0.2, methacrylic acid 6-8, styrene 4-6, butyl acrylate 3-5, benzoyl peroxide 0.5-1, N, N-diformyl Ethanol 4-6, titania nanotube 4-6, nanometer germanium 0.1-0.15, nano-tourmaline powder 0.3-0.5, phenylpropyl alcohol triazole 0.3- 0.5, gamma-mercaptopropyltriethoxysilane 0.1-0.15, sodium alginate 0.3-0.5, water 100-120；
Described titania nanotube is to use hydrothermal synthesis method to prepare, and caliber is 5-25nm, and pipe range is 500-1000nm.
The most according to claim 1 a kind of purify the preparation of copper sculpture epoxy-acrylic anticorrosion water-soluble paint in air chamber Method, it is characterised in that comprise the following steps:
(1) titania nanotube is mixed with dehydrated alcohol by solid-liquid weight ratio 1:10-1:15 it is uniformly dispersed, be subsequently adding eucalyptus globulus Leaf oil, Fructus Citri Limoniae oil, phenylpropyl alcohol triazole and gamma-mercaptopropyltriethoxysilane stirring 6-12h, do gained solid vacuum after being centrifuged Dry, obtain Modified Titanium nanotube；
(2) by the Modified Titanium nanotube in (1), nanometer germanium, nano-tourmaline powder, N, the mixing dispersion of N-diformyl second alcohol and water Uniformly, obtain component A, the mixing of epoxy resin E-44, ethylene glycol monobutyl ether and n-butyl alcohol is warming up to 105-110 DEG C, the most slowly Dropping methacrylic acid, styrene, butyl acrylate and the mixed solution of benzoyl peroxide, and anti-in 115-120 DEG C of insulation Answer 2-4h, obtain B component, by uniform in 80-85 DEG C of mixing high-speed stirred to component A and B component, then anti-in 50-60 DEG C of insulation Answer 1-1.5h, obtain complex emulsions；
(3) grind uniformly after the complex emulsions in (2) being mixed with remaining raw material, copper sculpture ring in air chamber must be purified Oxygen-acrylic acid anticorrosion water-soluble paint.
CN201610524519.9A 2016-07-06 2016-07-06 Copper sculpture epoxy acrylic anticorrosion water-soluble paint and preparation method thereof in a kind of purification air chamber Pending CN106147494A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109574631A (en) * 2019-01-23 2019-04-05 安徽省优丽斯新材科技有限公司 A kind of antibacterial environment protection anion quartz mesa material and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102585111A (en) * 2012-01-10 2012-07-18 江苏科技大学 Modified epoxy emulsion and preparation method thereof
CN103210120A (en) * 2010-10-13 2013-07-17 国民油井华高有限公司 Releasable corrosion inhibitors

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103210120A (en) * 2010-10-13 2013-07-17 国民油井华高有限公司 Releasable corrosion inhibitors
CN102585111A (en) * 2012-01-10 2012-07-18 江苏科技大学 Modified epoxy emulsion and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109574631A (en) * 2019-01-23 2019-04-05 安徽省优丽斯新材科技有限公司 A kind of antibacterial environment protection anion quartz mesa material and preparation method thereof
CN109574631B (en) * 2019-01-23 2022-04-19 安庆市江润微纳科技有限公司 Antibacterial environment-friendly negative ion quartz stone table surface material and preparation method thereof

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