A kind of floor of Herba Euphorbiae Humifusae processing technology
Technical field
The invention belongs to floor manufacture field, be specifically related to a kind of ornamental better, the longer floor of Herba Euphorbiae Humifusae processing technology of fluorescent lifetime.
Background technology
The floor of selling in the market, the general wood grain that adopts in its surface is as decoration, its decorative effect is comparatively single, more existing producers are the ornamental of raising floor, noctilucence composition is added in floor paint, if application publication number is " treatment process of coating noctilucent material on wooden floor " that " CN 102011479 A " announces, comprise and tongue and groove processing is carried out to shaping floor; End face on floor carries out polishing, and end face sandblasting after a polish; At floor end face even application white bottom, drying, solidification are carried out to described white bottom; Use the mode of sander or hand-sand, sanding process is carried out to the white bottom of floor end face; Oil paint coating is carried out to floor; At floor end face coating Noctilucent material.Floor is made to have illumination effect by this PROCESS FOR TREATMENT, more attractive in appearance.But only Noctilucent material is coated on the end face on floor, form Linear luminous lines, and Noctilucent material is coated in floor surface.Because common luminescent powder has certain radioactivity, be unsuitable for generally applying in living environment, so cannot large area use, simultaneously can destroy its crystal structure because of long-term extraneous collision or friction lose luminous usefulness because Noctilucent material is coated on floor surface.Practical application effect is poor, and light-emitting zone is uneven, easily occurs the not luminous or thorough not luminescence phenomenon in local, and floor surface affects the attractive in appearance of floor because the oxidation of luminescent powder also there will be color spot.Due to poor practicability, in actual production or life, we did not see floor of Herba Euphorbiae Humifusae at all, can only rest in theory, actual large amount cannot produce common applying in living environment.
Summary of the invention
The object of the invention is to provide a kind of environmental protection for solving the problem, energy-conservation, the life-span long, floor of Herba Euphorbiae Humifusae processing technology very attractive in appearance.
Above-mentioned technical purpose of the present invention is achieved by the following technical programs:
A kind of floor of Herba Euphorbiae Humifusae processing technology, is characterized in that: comprise the following steps:
(1) Manufacture of Floor slab;
(2) floor slab one is obtained to noctilucence priming paint on the floor slab obtained by step (1);
(3) floor slab two is obtained to elastic primer, wear-resistant primer and hardening primer on the floor slab one obtained by step (2);
(4) all over finish paint, floor of Herba Euphorbiae Humifusae is obtained to 2-5 on the floor slab two obtained by step (3).
Also need in actual production to dry after japanning, also need after partially desiccated step to carry out sanding, as following steps:
Floor slab-noctilucence priming paint-infrared baking-sanding-elastic primer-infrared baking-sanding-wear-resistant primer-infrared baking-hardening primer-infrared baking-sanding-wear-resistant primer-infrared baking-sanding-infrared baking-sanding-finish paint-infrared baking-sanding-finish paint-infrared baking-finish paint-infrared baking-finish paint.
As preferably, containing luminescent powder, organic resin, organic solvent and auxiliary agent in described noctilucence priming paint, the luminescent powder containing weight ratio 20-30% in described noctilucence priming paint; Described organic resin is one or more in acrylic resin, epoxy resin, polyurethane resin, mylar, pvc resin or polyvinyl butyral resin, and described auxiliary agent comprises anti-settling agent and curing compound; Described anti-settling agent is silica or high viscosity resins; Described noctilucence base coat thickness is 100-200um; Described luminescent powder grain diameter is 800-1200 order.
Luminescent powder has frangible crystal structure, meets the features such as metal is oxidizable; noctilucence priming paint is applied to the noctilucent coating of the innermost layer formation internal layer of floor surface by this technique; wear-resistant primer and multiple tracks finish paint can protect the luminescent powder in noctilucence priming paint to make its not easily abrasion better; stop to prevent it to be oxidized with the contact of extraneous metal simultaneously; strengthen the weather resisteant of noctilucence priming paint; ensure that floor has permanently effective luminescent properties, extend the life-span of noctilucence priming paint luminescence.
Noctilucence priming paint applies finish paint outward again makes floor light when noctilucence produce through topcoat the effect that full, soft, the illusion be similar to as jelly has again better glossiness, the penetrating sense of light and third dimension by force, greatly improve aesthetics and the texture on floor.
The great easy precipitation of ratio due to luminescent powder, is added into high viscosity resins or anti-settling agent and curing compound when being mixed with noctilucence priming paint, and adopts the method for namely joining namely, can make it have good adhesive power, control its curing rate and effectively prevent its rapid precipitation.
When noctilucent coating thickness is 100-200um, ideal luminosity and fluorescent lifetime can be obtained.
As preferably, described luminescent powder is red luminescent powder or blue luminescent powder or purple luminescent powder or green luminescent powder or yellow luminescent powder.
As preferably, the Ingredients Weight proportioning of described red luminescent powder is: barium sulfate 45-50%, magnesium sulfate 25-35%, zinc oxide 3-5%, lithium phosphate 3-5%, copper nitrate 4-5%, europium 2-3%, silica 3%-5%, red lead 2-4.
As preferably, the Ingredients Weight proportioning of described blue luminescent powder is barium sulfate 45-50%, magnesium sulfate 25-35%, zinc oxide 3-5%, red lead 2-4%.
As preferably, the Ingredients Weight proportioning of described purple luminescent powder is: calcium sulfide 58-63%, magnesium sulfide 20-24%, vulcanized sodium 7-10%, strontium nitrate 1-3%, europium 2-3%, silica 3-5%, alumina 1-3%, red lead 2-4%.
As preferably, the Ingredients Weight proportioning of described green luminescent powder is: calcium sulfide 45-50%, potassium sulfide 2-3 %, vulcanized sodium 9-11%, barium nitrate 8-14%, europium 2-3%, indium nitrate 9-11%, silica 3-5%, red lead 2-4%.
As preferably, the Ingredients Weight proportioning of described yellow luminescent powder is: barium sulphide 48-52%, magnesium sulfide 38-40%, aluminium sulfide 1-3%, potassium nitrate 1-3 %, europium 2-3%, silica 3-5%, alumina 1-3%, red lead 2-4%.
The chromatography combination of illumination effect can be pure color also can be multiple color.Various informative, rich color.
Tradition luminescent powder formula:
Red: 55 grams, barium sulfate, 40 grams, magnesium sulfate, lithium phosphate 2 grams, copper nitrate 3 grams.
Blue: calcium sulfide 63 grams, 5 grams, sodium sulphate, potassium sulfate 5 grams, strontium sulfate 10 grams, 6 grams, sodium chloride, silver nitrate 1 gram, magnesium sulfide 10 grams.
Purple: calcium sulfide 63 grams, magnesium sulfide 26 grams, 10 grams, vulcanized sodium, strontium nitrate 1 gram.
Green: calcium sulfide 55 grams, potassium sulfide 1 gram, 10 grams, vulcanized sodium, barium nitrate 12 grams, indium nitrate 13 grams.
Yellow: barium sulphide 55 grams, magnesium sulfide 40 grams, aluminium sulfide 2 grams, 3 grams, potassium nitrate.
Feature: extinction 10-20 minute, fluorescent lifetime only has 5-8 hour, has radioactivity, does not have adhesive power, and floor luminescent lifetime is short.
The luminescent powder that the present invention prepares is "dead", light decay is little, have certain adhesive power, lux maintenance is high, color rendering property good, long service life, luminous intensity are high, high color purity, structure are highly stable.Thus substantially increase the performance of floor of Herba Euphorbiae Humifusae.
Extinction 10-20 minute after the noctilucence priming paint film forming that the present invention obtains, can at dark place continuous illumination 10-12 hour.And extinction and luminescence process can Infinite Cyclic.
The container of enamel or glass-lined should be used during preparation luminescent powder, with homogenizer dispersion, avoid using the heavy metal objects such as ironware as far as possible, in order to avoid luminescent powder oxidation blackening reduces luminosity.
The compound method of luminescent powder is as follows: after preparing raw material, high temperature resistant crucible is placed on hot body and heats, raw material is placed in pot, temperature is 130-150 degree, burn after 60 minutes, choose not panchromatic impurity, then burned raw material is placed in ball mill and wears into fine powder and to be soaked in water again precipitation, remove clear water, the powder avaled is placed in drying box dry.
Noctilucence priming paint can use the techniques such as brushing, roller coating, spraying, blade coating, the spraying of pouring curtain.Luminous paint must stir before using, and is adjusted to working viscosity with thinner.
As preferably, described floor slab is wooden floor slab or multi-layer solid wood composite floor slab; Described floor slab is provided with solid decorative patterns or the grain of wood groove of indent, in the decorative pattern region that described noctilucence priming paint is overlying on described floor slab or grain of wood groove.
When floor slab arranges decorative pattern, the demand of colony can be used according to difference, floor arranges decorative pattern, as when child room uses, can some cartoon patterns be set on floor slab, then at the coating of cartoon pattern region or serigraphy noctilucence priming paint.Noctilucence priming paint extinction, highlighted cartoon pattern to noctilucence priming paint luminescence in evening, because noctilucent coating is internal layer daytime, topcoat is outer, cartoon pattern third dimension is stronger, permeability is good, increases the smart of stiff decorative pattern, makes pattern modelling vivid.
When floor slab arranges grain of wood groove, can go grain of wood bossing noctilucence priming paint by sand after having gone up noctilucence priming paint in step (2), retain its grain of wood trench portions noctilucence priming paint, obtained floor is in grain of wood trench portions luminescence at night, the wood grain on monoblock floor is highlighted in the form of light, very attractive in appearance.
As preferably, described step (2) is also included in the front upper light priming paint of noctilucence priming paint.
After carrying out necessary pretreatment to floor slab before construction, upper light priming paint together, can improve luminosity like this, extend fluorescent lifetime.
In sum, the present invention has following beneficial effect:
1, the noctilucence priming paint of the present invention's preparation is nontoxic, harmless, nothing is radiated, environmentally safe; upper multi-layer wear-resistant priming paint and finish paint; make the wear-resisting revolution in floor obtained up to more than 6000 turns; greatly strengthen the weatherability on floor; also protect well simultaneously the luminescent powder in noctilucence priming paint make its not easily abrasion destroy its crystal structure; and stop to prevent it to be oxidized with the contact of extraneous metal; strengthen the weather resisteant of noctilucence priming paint; thus ensure that obtained floor of Herba Euphorbiae Humifusae has permanently effective luminescent properties; extend the luminescent lifetime of floor of Herba Euphorbiae Humifusae
2, the floor of Herba Euphorbiae Humifusae that the present invention obtains large batch ofly can put into production and apply at large in living environment, and practicality is good, can play well to intersperse, beautify the living environment, and can also meet the individual demand of different use crowd simultaneously.
3, the floor that obtains of the present invention, goes up multiple tracks finish paint outward again at noctilucence priming paint, makes floor can also send unique solid, full, soft, agile light at night.
Detailed description of the invention
This specific embodiment is only explanation of the invention; it is not limitation of the present invention; those skilled in the art can make to the present embodiment the amendment not having creative contribution as required after reading this manual, as long as but be all subject to the protection of Patent Law in right of the present invention.
Embodiment one:
A kind of floor of Herba Euphorbiae Humifusae processing technology, is characterized in that: comprise the following steps:
(1) Manufacture of Floor slab;
(2) floor slab one is obtained to noctilucence priming paint on the floor slab obtained by step (1);
(3) floor slab two is obtained to elastic primer, wear-resistant primer and hardening primer on the floor slab one obtained by step (2);
(4) all over finish paint, floor of Herba Euphorbiae Humifusae is obtained to 2-5 on the floor slab two obtained by step (3).
Also need to carry out drying and processing after every one japanning operation, also need after partially desiccated treatment process to carry out sanding process.Detailed step is as follows:
Floor slab-noctilucence priming paint-infrared baking-sanding-elastic primer-infrared baking-sanding-wear-resistant primer-infrared baking-hardening primer-infrared baking-sanding-wear-resistant primer-infrared baking-sanding-infrared baking-sanding-finish paint-infrared baking-sanding-finish paint-infrared baking-finish paint-infrared baking-finish paint.
Containing luminescent powder, organic resin, organic solvent and auxiliary agent in noctilucence priming paint, the luminescent powder containing weight ratio 20% in noctilucence priming paint; Organic resin can select in acrylic resin, epoxy resin, polyurethane resin, mylar, pvc resin, polyvinyl butyral resin any one, auxiliary agent comprises anti-settling agent and curing compound; The anti-settling agent that the present embodiment is selected is silica.Noctilucence base coat thickness is 100um; Described luminescent powder grain diameter is 800 orders.
The floor slab that the present embodiment is selected is wooden floor slab.Floor slab also can arrange decorative pattern miscellaneous according to the difference of customer demand or environment for use, and decorative pattern is the solid figure being arranged on indent on floor slab, and noctilucence basecoat paint is in decorative pattern region.
Luminescent powder in noctilucence priming paint can according to user's demand or one or more the chromatography selected according to decorative pattern style in red luminescent powder, blue luminescent powder, purple luminescent powder, green luminescent powder, yellow luminescent powder with decorative pattern, as chromatography or the chromatography etc. that is red, blue, purple, green, yellow five kinds of luminescent powders of: the chromatography of red, blue two kinds of luminescent powders or purple, green, yellow three kinds of luminescent powders.
The Ingredients Weight proportioning of red luminescent powder is: barium sulfate 45%, magnesium sulfate 25%, zinc oxide 3%, lithium phosphate 3%, copper nitrate 4%, europium 2%, silica 3%, red lead 2%; The Ingredients Weight proportioning of described blue luminescent powder is barium sulfate 45%, magnesium sulfate 25%, zinc oxide 3%, red lead 2%; The Ingredients Weight proportioning of described purple luminescent powder is: calcium sulfide 58%, magnesium sulfide 20%, vulcanized sodium 7%, strontium nitrate 1%, europium 2%, silica 3%, alumina 1%, red lead 2%; The Ingredients Weight proportioning of described green luminescent powder is: calcium sulfide 45%, potassium sulfide 2%, vulcanized sodium 9%, barium nitrate 8%, europium 2%, indium nitrate 9%, silica 3%, red lead 2%; The Ingredients Weight proportioning of described yellow luminescent powder is: barium sulphide 48%, magnesium sulfide 38%, aluminium sulfide 1%, potassium nitrate 1%, europium 2%, silica 3%, alumina 1%, red lead 2%.
The floor properties that the present embodiment technique obtains is shown in contrast table 1.
Embodiment two:
The proportioning that be in each composition different from above-described embodiment, the present embodiment selects multi-layer solid wood composite floor slab.
Detailed step is as follows:
Floor slab-light priming paint-noctilucence priming paint-infrared baking-sanding-elastic primer-infrared baking-sanding-wear-resistant primer-infrared baking-hardening primer-infrared baking-sanding-wear-resistant primer-infrared baking-sanding-infrared baking-sanding-finish paint-infrared baking-sanding-finish paint-infrared baking-finish paint.
Luminescent powder containing weight ratio 30% in noctilucence priming paint; Noctilucence base coat thickness is 200um; Described luminescent powder grain diameter is 1200 orders.The anti-settling agent that the present embodiment is selected is high viscosity resins.
The Ingredients Weight proportioning of red luminescent powder is: barium sulfate 50%, magnesium sulfate 35%, zinc oxide 5%, lithium phosphate 5%, copper nitrate 5%, europium 3%, silica 5%, red lead 4%; The Ingredients Weight proportioning of blue luminescent powder is barium sulfate 50%, magnesium sulfate 35%, zinc oxide 5%, red lead 4%; The Ingredients Weight proportioning of purple luminescent powder is: calcium sulfide 563%, magnesium sulfide 24%, vulcanized sodium 10%, strontium nitrate 3%, europium 3%, silica 5%, alumina 3%, red lead 4%; The Ingredients Weight proportioning of green luminescent powder is: calcium sulfide 50%, potassium sulfide 3 %, vulcanized sodium 11%, barium nitrate 14%, europium 3%, indium nitrate 11%, silica 5%, red lead 4%; The Ingredients Weight proportioning of described yellow luminescent powder is: barium sulphide 52%, magnesium sulfide 40%, aluminium sulfide 3%, potassium nitrate 3 %, europium 3%, silica 5%, alumina 3%, red lead 4%.
The floor properties that the present embodiment technique obtains is shown in contrast table 1.
Embodiment three:
Different from above-described embodiment be in, the present embodiment selects floor slab to be solid wood ancient imitation floor board slab, be included in described step (1) on floor slab and manufacture grain of wood groove, sanding wood grain bossing priming paint during sanding noctilucence priming paint, retain its wood grain trench portions priming paint, the wood grain on monoblock floor, in wood grain trench portions luminescence at night, highlights by obtained floor in the form of light, very attractive in appearance.
Detailed step is as follows:
Floor slab-noctilucence priming paint-infrared baking-sanding-elastic primer-infrared baking-sanding-wear-resistant primer-infrared baking-hardening primer-infrared baking-sanding-wear-resistant primer-infrared baking-sanding-infrared baking-sanding-finish paint-infrared baking-sanding-finish paint-infrared baking-finish paint.
Luminescent powder containing weight ratio 25% in noctilucence priming paint; Described noctilucence base coat thickness is 100-200um; Described luminescent powder grain diameter is 800-1200 order.The anti-settling agent that the present embodiment is selected is silica or high viscosity resins.
The Ingredients Weight proportioning of red luminescent powder is: barium sulfate 48%, magnesium sulfate 32%, zinc oxide 4%, lithium phosphate 4%, copper nitrate 4.7%, europium 2.7%, silica 4%, red lead 3%; The Ingredients Weight proportioning of blue luminescent powder is barium sulfate 48%, magnesium sulfate 30%, zinc oxide 4%, red lead 3%; The Ingredients Weight proportioning of purple luminescent powder is: calcium sulfide 61%, magnesium sulfide 23%, vulcanized sodium 9%, strontium nitrate 2%, europium 1.7%, silica 4%, alumina 2%, red lead 3%; The Ingredients Weight proportioning of green luminescent powder is: calcium sulfide 48%, potassium sulfide 1%, vulcanized sodium 10%, barium nitrate 13%, europium 2.7%, indium nitrate 10%, silica 4%, red lead 3%; The Ingredients Weight proportioning of yellow luminescent powder is: barium sulphide 50%, magnesium sulfide 39%, aluminium sulfide 2%, potassium nitrate 2%, europium 2.7%, silica 4%, alumina 2%, red lead 3%.
The floor properties that the present embodiment technique obtains is shown in contrast table 1.
Comparative example one:
Obtained floor of Herba Euphorbiae Humifusae in noctilucence priming paint is applied to by the luminescent powder of following one-tenth assignment system.
Red: 55 grams, barium sulfate, 40 grams, magnesium sulfate, lithium phosphate 2 grams, copper nitrate 3 grams.
Blue: calcium sulfide 63 grams, 5 grams, sodium sulphate, potassium sulfate 5 grams, strontium sulfate 10 grams, 6 grams, sodium chloride, silver nitrate 1 gram, magnesium sulfide 10 grams.
Purple: calcium sulfide 63 grams, magnesium sulfide 26 grams, 10 grams, vulcanized sodium, strontium nitrate 1 gram.
Green: calcium sulfide 55 grams, potassium sulfide 1 gram, 10 grams, vulcanized sodium, barium nitrate 12 grams, indium nitrate 13 grams.
Yellow: barium sulphide 55 grams, magnesium sulfide 40 grams, aluminium sulfide 2 grams, 3 grams, potassium nitrate.
With the floor of Herba Euphorbiae Humifusae extinction 10-20 minute that above-mentioned luminescent powder is obtained, fluorescent lifetime only has 5-8 hour, has radioactivity, and floor luminescent lifetime is short.
The floor properties that this comparative example obtains is shown in contrast table 1.
Comparative example two:
The processing technology of floor of Herba Euphorbiae Humifusae is as follows: floor slab-elastic primer-infrared baking-sanding-wear-resistant primer-infrared baking-hardening primer-infrared baking-sanding-wear-resistant primer-infrared baking-sanding-infrared baking-sanding-finish paint-infrared baking-sanding-finish paint-infrared baking-noctilucence priming paint-infrared baking-finish paint.
The floor properties that this comparative example obtains is shown in contrast table 1.
Table 1:
"dead", light decay is little, have certain adhesive power, lux maintenance is high, color rendering property good, long service life, luminous intensity are high, high color purity, structure are highly stable.
What paint film adhesion reflected is the adhesive strength of paint to wooden floor, and this index is defective also illustrates that the paint quality on floor is poor, and oil paint cracking in use may be caused even to peel off, and affects the application life on floor equally.National Specification high-class product wooden floor paint film adhesion index is 0 ~ 1 grade; Grade A≤2 grade; Certified products≤3 grade.
The present invention obtained ground floor of Herba Euphorbiae Humifusae, environmental protection, energy-conservation.Practically can to put into production in a large number, to apply in living environment at large.And change the unicity of existing general floorings decoration, make that the floor in life is more attractive in appearance, individual character, agile.