CN103923516A - Semitransparent grey plasticizing ink for screen printing - Google Patents
Semitransparent grey plasticizing ink for screen printing Download PDFInfo
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- CN103923516A CN103923516A CN201410181726.XA CN201410181726A CN103923516A CN 103923516 A CN103923516 A CN 103923516A CN 201410181726 A CN201410181726 A CN 201410181726A CN 103923516 A CN103923516 A CN 103923516A
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- plasticising
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- 238000007650 screen-printing Methods 0.000 title claims abstract description 10
- 239000011347 resin Substances 0.000 claims abstract description 14
- 229920005989 resin Polymers 0.000 claims abstract description 14
- 239000012046 mixed solvent Substances 0.000 claims abstract description 13
- 229920000083 poly(allylamine) Polymers 0.000 claims abstract description 9
- 239000000049 pigment Substances 0.000 claims abstract description 8
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000012463 white pigment Substances 0.000 claims abstract description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 17
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims description 12
- 239000011259 mixed solution Substances 0.000 claims description 12
- MMSGPUZNNKBAMN-UHFFFAOYSA-N 3-ethyl-4-hydroxyheptane-2,3,4-tricarboxylic acid Chemical compound CCC(C(O)=O)C(O)(C(O)=O)C(CC)(CC)C(O)=O MMSGPUZNNKBAMN-UHFFFAOYSA-N 0.000 claims description 7
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 6
- 239000000654 additive Substances 0.000 claims description 6
- 230000000996 additive effect Effects 0.000 claims description 6
- 239000006185 dispersion Substances 0.000 claims description 6
- 238000005282 brightening Methods 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 239000013530 defoamer Substances 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 239000004576 sand Substances 0.000 claims description 3
- 239000000080 wetting agent Substances 0.000 claims description 3
- 239000003112 inhibitor Substances 0.000 claims description 2
- 230000003647 oxidation Effects 0.000 claims description 2
- 238000007254 oxidation reaction Methods 0.000 claims description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 abstract description 6
- 239000004926 polymethyl methacrylate Substances 0.000 abstract description 6
- 239000011521 glass Substances 0.000 abstract description 5
- 239000004800 polyvinyl chloride Substances 0.000 abstract description 5
- 238000003860 storage Methods 0.000 abstract description 4
- 229920000915 polyvinyl chloride Polymers 0.000 abstract description 3
- 239000004014 plasticizer Substances 0.000 abstract description 2
- 239000004925 Acrylic resin Substances 0.000 abstract 1
- 229920000178 Acrylic resin Polymers 0.000 abstract 1
- DOOTYTYQINUNNV-UHFFFAOYSA-N Triethyl citrate Chemical compound CCOC(=O)CC(O)(C(=O)OCC)CC(=O)OCC DOOTYTYQINUNNV-UHFFFAOYSA-N 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 abstract 1
- -1 poly(allylamine) Polymers 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
- VMYFZRTXGLUXMZ-UHFFFAOYSA-N triethyl citrate Natural products CCOC(=O)C(O)(C(=O)OCC)C(=O)OCC VMYFZRTXGLUXMZ-UHFFFAOYSA-N 0.000 abstract 1
- 235000013769 triethyl citrate Nutrition 0.000 abstract 1
- 239000001069 triethyl citrate Substances 0.000 abstract 1
- 239000000976 ink Substances 0.000 description 46
- 230000000052 comparative effect Effects 0.000 description 11
- 229920001944 Plastisol Polymers 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 239000004999 plastisol Substances 0.000 description 7
- 239000000523 sample Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 238000007639 printing Methods 0.000 description 5
- 239000002904 solvent Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000002390 adhesive tape Substances 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 210000000795 conjunctiva Anatomy 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000009998 heat setting Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000003981 vehicle Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention relates to semitransparent grey plasticizing ink for screen printing. The ink comprises 28.0-32.0 parts of refined 1000-800 gloss oil, 1.3-1.5 parts of black pigment, 8.5-8.7 parts of white pigment, 25.0-28.0 parts of organosilicone modified acrylic resin, 15.0-25.0 parts of glycidyl methacrylate, 8.0-10.0 parts of triethyl citrate, 2.0-2.5 parts of poly(allylamine) and 50-60 parts of mixed solvent by weight. The ink does not contain plasticizers including phthalate and polyvinyl chloride resin but has flow property equivalent to that of the prior art, and has good storage stability and excellent adhesion to glass or PMMA (polymethylmethacrylate) substrates.
Description
Technical field
The invention belongs to the technical field of printing-ink, in particular, the present invention relates to semi-transparent grey plasticising ink for a kind of silk screen printing.
Background technology
Ink is the important materials for wrapping material printing, and it comprises main component and ancillary component by printing by pattern, the present stock curing ink of literal table, and they mix equably and form the gluey fluid of a kind of viscosity through repeat-rolling.Printing-ink is by dispersed pulpous state colloids mixing of material such as colorant, low-melting ink vehicle and auxiliary agent and solvents.The binder of solvent type ink consists of solid resin and a large amount of volatile organic solvent.After solid resin is dissolved in solvent, colorant is dispersed in binder, ink is printed to printed medium, the rapid volatile dry conjunctiva of solvent.
For ink, general expectation is used and can on printed medium, be produced aesthetic effect and the permanent printing characteristic keeping that simultaneously shows pleasant.The example of these printing characteristics comprises press quality, as optical density (OD), colourity etc.; And weather resistance, as water tolerance, resistance to fadedness, persistence, acidproof and alkaline-resisting etc.Plastisol ink composite is often known as plastisol ink, because the mode applying is utilized the fluid properties of plastisol before heating, by baking or thermofixation, causes the base resin in plastisol to be solidified into solid.In prior art, most plastisol is in the softening agent being dispersed in based on phthalic ester, also passes through in the composition of its polyvinyl chloride (PVC) RESINS that swelling occurs.Polyvinyl chloride (PVC) RESINS plastisol ink is widely used for silk screen printing operation.But due to the consideration of environment, health and safety, the use of these ink is subject to strict restriction just day by day.Therefore guaranteeing, under the prerequisite of ink quality, to develop performance identical with PVC plastisol, and the ink with less health and environmental risk and high tack becomes those skilled in the art's R&D direction.
Summary of the invention
In order to solve above-mentioned technical problem of the prior art, the object of the present invention is to provide semi-transparent grey plasticising ink for a kind of silk screen printing.
In order to realize foregoing invention object, the present invention has adopted following technical scheme:
Semi-transparent grey plasticising ink for silk screen printing of the present invention, it is characterized in that: the Seiko 1000-800 gloss oil that described ink contains 28.0～32.0 weight parts, the black pigment of 1.3～1.5 weight parts, the white pigment of 8.5～8.7 weight parts, the organosilicon modified crylic acid resin of 25.0～28.0 weight parts, the glycidyl methacrylate of 15.0～25.0 weight parts, the triethyl citric acid of 8.0～10.0 weight parts, the polyallylamine of 2.0～2.5 weight parts, the mixed solvent of 50～60 weight parts.
Wherein, the number-average molecular weight of described polyallylamine is 1000～3000.
Wherein, described mixed solvent consists of propyl carbinol, n-butyl acetate and acetone; And described propyl carbinol is 25～30 weight parts, n-butyl acetate is 12～15 weight parts, and acetone is 13～15 weight parts.
Wherein, described plasticising ink also comprises additive.And as preferably, described additive is selected from least one in wetting agent, brightening agent, oxidation inhibitor, stablizer or defoamer.
Wherein, the viscosity of described plasticising ink is about 20,000～200,000 centipoises.
Wherein, described plasticising ink adopts the preparation method who comprises the following steps to obtain:
(1), by the glycidyl methacrylate of 15.0～25.0 weight parts, the mixed solvent of 10.0～15.0 weight parts fully mixes and dissolves with alr mode, makes dispersion soln;
(2), by the black pigment of 1.3～1.5 weight parts, the dispersion soln that the white pigment of 8.5～8.7 weight parts and step (1) prepare, fully mixes and soaks with alr mode, makes the first mixed solution;
(3) by the organosilicon modified crylic acid resin of 25.0～28.0 weight parts, the mixed solvent of 40.0～45.0 weight parts fully mixes and dissolves with alr mode, makes the second mixed solution;
(4) the first mixed solution step (2) being obtained, the second mixed solution that step (3) obtains, Seiko 1000-800 gloss oil, the triethyl citric acid of 8.0～10.0 weight parts and the polyallylamine of 2.0～2.5 weight parts of 28.0～32.0 weight parts are fully mixed to get mixed liquor with alr mode;
(5) mixed liquor step (4) being obtained adopts sand mill to grind, and obtains the ink that fineness is less than 5 μ m.
Compared with prior art, semi-transparent grey plasticising ink of the present invention has following beneficial effect:
(1), in ink of the present invention, do not contain phthalic ester and polyvinyl chloride resin plasticiser; But its flowing property and prior art are suitable, there is good preservation stability, and also excellent to the tack of glass or PMMA base material.
(2) adopt dispersing method of the present invention, can reduce the surface tension of pigment and interlaminar resin, improve their wettability, can strengthen the grinding effect of ink, reduce jitter time, and make described ink there is good brightness effect, and suitable viscosity.
Embodiment
Below with reference to specific embodiment, semi-transparent grey plasticising ink of the present invention and preparation method thereof is described further, to help those skilled in the art to have more complete, accurate and deep understanding to inventive concept of the present invention, technical scheme.Applicant need to declare is that the description of related materials in embodiment, performance and technique etc. is all exemplary, and does not refer to the restriction to invention protection domain.
Semi-transparent grey plasticising ink of the present invention, the Seiko 1000-800 gloss oil that contains 28.0～32.0 weight parts, the black pigment of 1.3～1.5 weight parts, the white pigment of 8.5～8.7 weight parts, the organosilicon modified crylic acid resin of 25.0～28.0 weight parts, the glycidyl methacrylate of 15.0～25.0 weight parts, the triethyl citric acid of 8.0～10.0 weight parts, the mixed solvent of 50～60 weight parts; Wherein, described mixed solvent consists of propyl carbinol, n-butyl acetate and acetone; And described propyl carbinol is 25～30 weight parts, n-butyl acetate is 12～15 weight parts, and acetone is 13～15 weight parts.Described plasticising ink as required, also comprises additive, and described additive is selected from least one in wetting agent, brightening agent, antioxidant, stablizer or defoamer.
Following embodiment adopts the method comprising the following steps to obtain, and difference is only that the content of component is different:
(1), by the glycidyl methacrylate of 15.0～25.0 weight parts, the mixed solvent of 10.0～15.0 weight parts fully mixes and dissolves with alr mode, makes dispersion soln;
(2), by the black pigment of 1.3～1.5 weight parts, the dispersion soln that the white pigment of 8.5～8.7 weight parts and step (1) prepare, fully mixes and soaks with alr mode, makes the first mixed solution;
(3) by the organosilicon modified crylic acid resin of 25.0～28.0 weight parts, the mixed solvent of 40.0～45.0 weight parts fully mixes and dissolves with alr mode, makes the second mixed solution;
(4) the first mixed solution step (2) being obtained, the second mixed solution that step (3) obtains, Seiko 1000-800 gloss oil, the triethyl citric acid of 8.0～10.0 weight parts and the polyallylamine of 2.0～2.5 weight parts of 28.0～32.0 weight parts are fully mixed to get mixed liquor with alr mode;
(5) mixed liquor step (4) being obtained adopts sand mill to grind, and obtains the ink that fineness is less than 5 μ m.
In comparative example 1 and 2, in step (4), use different fluidizers, and all do not added polyallylamine.In comparative example 3, in step (4), used dibutyl phthalate to substitute triethyl citric acid.
Embodiment 1
Semi-transparent grey plasticising ink described in the present embodiment, the viscosity of described ink is about 80,000～150,000 centipoises, the component that it contains following parts by weight:
Embodiment 2
Semi-transparent grey plasticising ink described in the present embodiment, the viscosity of described ink is about 30,000～50,000 centipoises, the component that it contains following parts by weight:
Comparative example 1
Semi-transparent grey plasticising ink described in the present embodiment, the viscosity of described ink is about 50,000～100,000 centipoises, and it contains following heavy
Comparative example 2
Described semi-transparent grey plasticising ink, the component that it contains following parts by weight:
Comparative example 3
Described semi-transparent grey plasticising ink, the component that it contains following parts by weight:
Adopt conventional method for printing screen that the ink described in embodiment 1～2 and comparative example 1～3 is printed on glass and PMMA base material; Then at the temperature of 120 ± 1 ℃, carry out first baking; Then at the temperature of 150 ± 1 ℃, carry out second baking; After ink complete drying, adopt following methods to carry out tack experiment.Adopt the wide 3M adhesive tape (3MScotchTM Tape) of 20mm to paste the silk screen printing rete (base material is respectively glass and PMMA) after oven dry, with minimum angles, take off, the attached power of described ink is divided into 0～6 grade.Wherein 0 grade for be attached to China ink layer on adhesive tape be greater than 95%, 1 grade be 50～95%, 2 grades be 30～50%, 3 grades be 20～30%, 4 grades be 10～20%, 5 grades be 2～10%, 6 grades for being less than 2%.Test result is as shown in table 1.
Table 1 sticking power grade
| ? | Embodiment 1 | Embodiment 2 | Comparative example 1 | Comparative example 2 | Comparative example 3 |
| Glass | 6 | 6 | 5 | 5 | 4 |
| PMMA | 6 | 6 | 5 | 5 | 4 |
Each 20g of ink sample that gets embodiment 1-2 and comparative example 1-3 is placed in the thermostat container of 40 ℃, detects the stability in storage of ink sample at the temperature improving; Utilize probe to detect sample at interval of 12 hours, to determine that sample becomes the enough thick and time that cannot carry out silk screen printing, characterizes the time of stability in storage.Result shows: the ink sample of embodiment of the present invention can reach 30-40 days at the storage stability improving at temperature, suitable with comparative example.
In the present invention; for the ordinary skill in the art described; specific embodiment is just exemplarily described the present invention; obviously specific implementation of the present invention is not subject to the restrictions described above; as long as adopted the improvement of the various unsubstantialities that method of the present invention design and technical scheme carry out; or without improving, design of the present invention and technical scheme are directly applied to other occasion, all within protection scope of the present invention.
Claims (7)
1. a semi-transparent grey plasticising ink for silk screen printing, it is characterized in that: the Seiko 1000-800 gloss oil that described ink contains 28.0～32.0 weight parts, the black pigment of 1.3～1.5 weight parts, the white pigment of 8.5～8.7 weight parts, the organosilicon modified crylic acid resin of 25.0～28.0 weight parts, the glycidyl methacrylate of 15.0～25.0 weight parts, the triethyl citric acid of 8.0～10.0 weight parts, the polyallylamine of 2.0～2.5 weight parts, the mixed solvent of 50～60 weight parts.
2. semi-transparent grey plasticising ink according to claim 1, is characterized in that: the number-average molecular weight of described polyallylamine is 1000～3000.
3. semi-transparent grey plasticising ink according to claim 1, is characterized in that: described mixed solvent consists of propyl carbinol, n-butyl acetate and acetone; And described propyl carbinol is 25～30 weight parts, n-butyl acetate is 12～15 weight parts, and acetone is 13～15 weight parts.
4. semi-transparent grey plasticising ink according to claim 1, is characterized in that: described plasticising ink also comprises additive.
5. semi-transparent grey plasticising ink according to claim 4, is characterized in that: described additive is selected from least one in wetting agent, brightening agent, oxidation inhibitor, stablizer or defoamer.
6. semi-transparent grey plasticising ink according to claim 1, is characterized in that: described plasticising ink adopts the preparation method who comprises the following steps to obtain:
(1), by the glycidyl methacrylate of 15.0～25.0 weight parts, the mixed solvent of 10.0～15.0 weight parts fully mixes and dissolves with alr mode, makes dispersion soln;
(2), by the black pigment of 1.3～1.5 weight parts, the dispersion soln that the white pigment of 8.5～8.7 weight parts and step (1) prepare, fully mixes and soaks with alr mode, makes the first mixed solution;
(3) by the organosilicon modified crylic acid resin of 25.0～28.0 weight parts, the mixed solvent of 40.0～45.0 weight parts fully mixes and dissolves with alr mode, makes the second mixed solution;
(4) the first mixed solution step (2) being obtained, the second mixed solution that step (3) obtains, Seiko 1000-800 gloss oil, the triethyl citric acid of 8.0～10.0 weight parts and the polyallylamine of 2.0～2.5 weight parts of 28.0～32.0 weight parts are fully mixed to get mixed liquor with alr mode;
(5) mixed liquor step (4) being obtained adopts sand mill to grind, and obtains the ink that fineness is less than 5 μ m.
7. semi-transparent grey plasticising ink according to claim 6, is characterized in that: the viscosity of described plasticising ink is about 20,000～200,000 centipoises.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410181726.XA CN103923516B (en) | 2014-04-30 | 2014-04-30 | The semi-transparent grey plasticising ink of silk screen printing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410181726.XA CN103923516B (en) | 2014-04-30 | 2014-04-30 | The semi-transparent grey plasticising ink of silk screen printing |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103923516A true CN103923516A (en) | 2014-07-16 |
| CN103923516B CN103923516B (en) | 2015-08-26 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410181726.XA Expired - Fee Related CN103923516B (en) | 2014-04-30 | 2014-04-30 | The semi-transparent grey plasticising ink of silk screen printing |
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| Country | Link |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106497231A (en) * | 2016-10-31 | 2017-03-15 | 秦晴晴 | A kind of temperature sensitive ink for containing 1,2 biphenoxyl ethanes and preparation method thereof |
| WO2021239902A1 (en) * | 2020-05-29 | 2021-12-02 | Dover Europe Sarl | Opaque grey ink jet ink composition |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009185186A (en) * | 2008-02-07 | 2009-08-20 | Fujifilm Corp | Ink composition, inkjet-recording method, printed matter, and molded printed matter |
| CN101760073A (en) * | 2010-01-29 | 2010-06-30 | 蓝思科技（湖南）有限公司 | Colored translucent printing ink |
| CN102863849A (en) * | 2012-09-29 | 2013-01-09 | 苏州安洁科技股份有限公司 | IR (infrared) purple ink |
| CN103013225A (en) * | 2012-12-25 | 2013-04-03 | 广州慧谷工程材料有限公司 | IML gloss oil and IML printing ink and preparation method and application thereof |
| CN103666098A (en) * | 2013-12-05 | 2014-03-26 | 湖南互力达涂料科技有限公司 | Aqueous UV gravure varnish |
-
2014
- 2014-04-30 CN CN201410181726.XA patent/CN103923516B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009185186A (en) * | 2008-02-07 | 2009-08-20 | Fujifilm Corp | Ink composition, inkjet-recording method, printed matter, and molded printed matter |
| CN101760073A (en) * | 2010-01-29 | 2010-06-30 | 蓝思科技（湖南）有限公司 | Colored translucent printing ink |
| CN102863849A (en) * | 2012-09-29 | 2013-01-09 | 苏州安洁科技股份有限公司 | IR (infrared) purple ink |
| CN103013225A (en) * | 2012-12-25 | 2013-04-03 | 广州慧谷工程材料有限公司 | IML gloss oil and IML printing ink and preparation method and application thereof |
| CN103666098A (en) * | 2013-12-05 | 2014-03-26 | 湖南互力达涂料科技有限公司 | Aqueous UV gravure varnish |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106497231A (en) * | 2016-10-31 | 2017-03-15 | 秦晴晴 | A kind of temperature sensitive ink for containing 1,2 biphenoxyl ethanes and preparation method thereof |
| WO2021239902A1 (en) * | 2020-05-29 | 2021-12-02 | Dover Europe Sarl | Opaque grey ink jet ink composition |
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| CN103923516B (en) | 2015-08-26 |
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