CN103952033A - Universal ink as well as preparation method and use method thereof - Google Patents
Universal ink as well as preparation method and use method thereof Download PDFInfo
- Publication number
- CN103952033A CN103952033A CN201410175666.0A CN201410175666A CN103952033A CN 103952033 A CN103952033 A CN 103952033A CN 201410175666 A CN201410175666 A CN 201410175666A CN 103952033 A CN103952033 A CN 103952033A
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- China
- Prior art keywords
- agent
- acrylic resin
- paste composition
- solvent
- color paste
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000002360 preparation method Methods 0.000 title claims description 9
- 238000000034 method Methods 0.000 title claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 47
- 239000000203 mixture Substances 0.000 claims abstract description 38
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 31
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 31
- 239000002904 solvent Substances 0.000 claims abstract description 21
- 239000000080 wetting agent Substances 0.000 claims abstract description 16
- 239000002318 adhesion promoter Substances 0.000 claims abstract description 14
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 14
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 28
- 238000003756 stirring Methods 0.000 claims description 17
- 239000013530 defoamer Substances 0.000 claims description 16
- 239000006185 dispersion Substances 0.000 claims description 14
- HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 claims description 12
- BQFCCCIRTOLPEF-UHFFFAOYSA-N chembl1976978 Chemical compound CC1=CC=CC=C1N=NC1=C(O)C=CC2=CC=CC=C12 BQFCCCIRTOLPEF-UHFFFAOYSA-N 0.000 claims description 11
- 239000004922 lacquer Substances 0.000 claims description 8
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical group O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 5
- 239000000463 material Substances 0.000 abstract description 9
- 239000004568 cement Substances 0.000 abstract description 7
- 239000002184 metal Substances 0.000 abstract description 7
- 229910052751 metal Inorganic materials 0.000 abstract description 7
- 239000011521 glass Substances 0.000 abstract description 6
- 239000004033 plastic Substances 0.000 abstract description 6
- 238000007639 printing Methods 0.000 abstract description 6
- 239000002270 dispersing agent Substances 0.000 abstract description 3
- 150000002739 metals Chemical class 0.000 abstract description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 229910000278 bentonite Inorganic materials 0.000 abstract 1
- 239000000440 bentonite Substances 0.000 abstract 1
- 239000000919 ceramic Substances 0.000 abstract 1
- 238000010023 transfer printing Methods 0.000 abstract 1
- 239000002023 wood Substances 0.000 abstract 1
- -1 pottery Substances 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 238000009863 impact test Methods 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- 208000037656 Respiratory Sounds Diseases 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 239000003981 vehicle Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention provides universal ink. The universal ink is composed of a main agent and a curing agent, wherein the mass ratio of the main agent to the curing agent is (15 to 45): (5 to 12); per 100 g of the main agent contains 28-45 g of hydroxy acrylic resin, 4-9 g of adhesion promoter, 30-50 g of colour paste composition, 2-8 g of bentonite, 0.1-1 g of levelling agent and 5-15 g of solvent A, wherein the colour paste composition contains hydroxy acrylic resin, a defoaming agent, a dispersing agent, a wetting agent, toner and a solvent B. The universal ink provided by the invention can be used on the surfaces of various different base materials, for example, the surfaces of various metals, plastic, ceramic, glass, wood, cement and the like by silk printing or transfer printing, and has excellent adhesive force on various base materials, which is capable of achieving more than 4B, thus effectively solving the problem of the need of preparing different ink for clients aiming at different base materials; moreover, the universal ink provided by the invention is excellent in alcohol resistance, high-temperature resistance and low-temperature resistance, proper in hardness, and capable of effectively meeting the needs of clients.
Description
Technical field
The present invention relates to a kind of ink, relate in particular to a kind of general ink and preparation method thereof and using method.
Background technology
Ink (ink, printing ink) is the important materials for printing, and it is by printing on pattern, the present stock of literal table.Ink comprises main component and ancillary component, and they mix equably and form the gluey fluid of a kind of stickiness through repeat-rolling.Formed by pigment, low-melting ink vehicle and auxiliary agent and solvent etc.For various printings such as books and periodicals, packing and decorating, building decorations.Along with social demand increases, ink kind and output is respective extension and growth also.
Existing ink divides a lot of kinds, and metaphor metal base just adopts metal ink special, while use, just can adhere on glass baseplate.While use on plastic rubber substrate, can not adhere to yet.When plastic cement ink special uses on metal or glass baseplate so, can not adhere to yet.Only be divided into metal ink special, plastic cement ink special, glass ink special etc.
Summary of the invention
Object of the present invention overcomes above-mentioned deficiency, and a kind of general ink is provided, can silk-screen on various substrate surface, there is good sticking power.
First aspect of the present invention is to provide a kind of general ink, formed by host and solidifying agent, the mass ratio of host and solidifying agent is (15-45): (5-12), described in every 100g, in host, comprise: Hydroxylated acrylic resin 28-45g, adhesion promoter 4-9g, color paste composition 30-50g, wilkinite 2-8g, flow agent 0.1-1g and solvent orange 2 A 5-15g, wherein
In described color paste composition, comprise: Hydroxylated acrylic resin, defoamer, dispersion agent, wetting agent, toner and solvent B, and the mass ratio of Hydroxylated acrylic resin, defoamer, dispersion agent, wetting agent, toner and solvent B is (5-15): (0.1-1): (1-5): (0.1-1): (5-15): (20-30).
Preferably, described in every 100g, in host, comprise:: Hydroxylated acrylic resin 35-45g, adhesion promoter 3-6g, color paste composition 35-45g, wilkinite 3-6g, flow agent 0.3-0.8g, solvent orange 2 A 8-12g.
Further preferably, in every 100g universal lacquer, comprise: Hydroxylated acrylic resin 38-40g, adhesion promoter 4-5.5g, color paste composition 38-42g, wilkinite 4-5.5g, flow agent 0.4-0.6g, solvent orange 2 A 9-11g.
Still more preferably, in every 100g universal lacquer, comprise: Hydroxylated acrylic resin 38g, adhesion promoter 5g, color paste composition 41.5g, wilkinite 5g, flow agent 0.5g, solvent orange 2 A 10g.
Preferably, in described color paste composition, the mass ratio of Hydroxylated acrylic resin, defoamer, dispersion agent, wetting agent, toner and solvent B is (8-12): (0.3-0.8): (2-4): (0.3-0.8): (8-12): (24-28).
Further preferably, in described color paste composition, the mass ratio of Hydroxylated acrylic resin, defoamer, dispersion agent, wetting agent, toner and solvent B is (9-11): (0.4-0.6): (2.5-3.5): (0.4-0.6): (9-11): (25-27).
Still more preferably, in described color paste composition, the mass ratio of Hydroxylated acrylic resin, defoamer, dispersion agent, wetting agent, toner and solvent B is 10:0.5:3:0.5:10:26.
Wherein, described solvent orange 2 A is ketones solvent, is preferably isophorone.
Wherein, described solvent B is ketones solvent, for example: acetone, butanone, pimelinketone etc.
Preferably, described solvent B is pimelinketone.
Second aspect of the present invention is to provide the preparation method of the general ink described in first aspect of a kind of the present invention, each component of the universal lacquer described in first aspect of the present invention was both mixed and obtained, and wherein said color paste composition is mixed to get by its each component.
Specifically comprise the following steps:
Step 1, puts into Hydroxylated acrylic resin and adhesion promoter in stirrer and is uniformly mixed;
Step 2, joins color paste composition in stirrer and is uniformly mixed;
Step 3, slowly joins wilkinite and flow agent in stirrer, is uniformly mixed;
Step 4, adds the solvent orange 2 A to stir until both mixed;
Wherein, described color paste composition is prepared from by the following method:
A, Hydroxylated acrylic resin, defoamer, dispersion agent and wetting agent are put into and produced in container; B, toner is slowly added to then rapid stirring under low rate mixing; C, add solvent B, rapid stirring mixes; D, mixture is milled until fineness≤5 μ m.
Preferably, in step 1, the speed of Hydroxylated acrylic resin and adhesion promoter being put into turn/min of 600-1000 in stirrer stirs 2-8min.
Preferably, in step 2, color paste composition is joined in stirrer, stir 8-14min with the speed of 600-1000in.
Preferably, in step 3, wilkinite and flow agent are slowly joined in stirrer, stir 15-30min with the speed of turn/min of 1100-1500.
Preferably, in b, under the low rate mixing of turn at 300-800/min, toner is slowly added, stir 8-14min with the speed of turn/min of 1100-1500.
Preferably, in c, add solvent B, with the speed rapid stirring 8-14min of turn/min of 100-1500.
The 3rd aspect of the present invention is to provide the using method of the general ink described in first aspect of a kind of the present invention, host in general ink described in first aspect of the present invention and solidifying agent are used with after appropriate pimelinketone mixing 10min, mix in latter 4 hours and be finished.
General ink provided by the invention can silk-screen or bat printing at various different substrate materials faces, the surfaces such as such as various metals, plastic cement, pottery, glass, timber, cement, good to various base material sticking power, more than can reaching 4B, efficiently solving client needs the problem of different ink for subsequent use for different substrate materials, and the present invention has good ethanol-tolerant performance, high temperature resistant, low temperature resistant, and hardness is suitable, can effectively meet client's demand.
Embodiment
In the following embodiment of the present invention, Hydroxylated acrylic resin is the 2288A Hydroxylated acrylic resin purchased from Dongguan City Jun Lei Chemical Co., Ltd., and defoamer is BYK141 defoamer, dispersant B YK110, and wetting agent is BYK103 wetting dispersing agent.
Below in conjunction with concrete embodiment, the invention will be further described, to understand better the present invention.
Embodiment 1
A kind of general ink, is made up of host and solidifying agent, and the weight ratio of host and solidifying agent is 3:1.
The preparation of universal lacquer
Formula: Hydroxylated acrylic resin 38kg, adhesion promoter 5kg, color paste composition 41.5kg, wilkinite 5kg, flow agent 0.5kg, isophorone 10kg.
Preparation technology: Hydroxylated acrylic resin and adhesion promoter are dropped in stirrer, and 800 turn/min stir 5 minutes; Add color paste composition, 800 turn/min stir 10 minutes; Under the condition of 800 turn/min, wilkinite and flow agent are slowly added, then 1200 turn stirring 20 minutes; Stir and go directly evenly with Xi Ji limit, isophorone limit.
Wherein, the formula of color paste composition is: Hydroxylated acrylic resin 10kg, defoamer 0.5kg, dispersion agent 3kg, wetting agent 0.5kg, toner 10kg, pimelinketone 26kg.Hydroxylated acrylic resin, defoamer, dispersion agent, wetting agent are put into and produced in container; Then toner is slowly added, 500 turn/min are stirred to and add, then 1200 turn/min stir 10 minutes; Pimelinketone is washed to machine washing bucket, 1200 turn/min stir 10 minutes again; Finally obtain color paste composition (taking in proportion while preparing universal lacquer) by the mill 3-5 μ m fineness of going directly for 3 times of three-roller.
The preparation of solidifying agent
Bayer Bitterfeld GmbH 3390 solidifying agent 70kg are mixed with N-BUTYL ACETATE 30kg and both obtain (while preparing universal paint, taking in proportion).
When use, the ratio that is 3:1 according to the weight ratio of host and solidifying agent, gets general host and solidifying agent and mixes use after 10 minutes, mixes in latter 4 hours and is finished.
Embodiment 2-5
Embodiment 2-5 difference from Example 1 is the proportioning difference (composition of color paste composition and solidifying agent etc. are identical) of host, specifically in table 1.
The composition and ratio of host in table 1 embodiment 2-5
| ? | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 |
| Hydroxylated acrylic resin (kg) | 35 | 40 | 45 | 32 |
| Adhesion promoter (kg) | 7 | 5 | 6 | 4 |
| Color paste composition (kg) | 42 | 38 | 34 | 48 |
| Wilkinite (kg) | 7 | 5 | 4 | 6 |
| Flow agent (kg) | 0.5 | 0.5 | 0.8 | 0.8 |
| Isophorone (kg) | 8.5 | 11.5 | 10.2 | 9.2 |
Embodiment 6-9
Embodiment 6-9 difference from Example 1 is the proportioning difference of color paste composition, specifically in table 2.
The composition and ratio of color paste composition in table 2 embodiment 6-9
| ? | Embodiment 6 | Embodiment 7 | Embodiment 8 | Embodiment 9 |
| Hydroxylated acrylic resin (kg) | 8 | 12 | 15 | 10 |
| Defoamer (kg) | 0.6 | 0.4 | 0.5 | 0.5 |
| Dispersion agent (kg) | 2 | 4 | 3 | 2 |
| Wetting agent (kg) | 0.6 | 0.6 | 0.5 | 0.6 |
| Toner (kg) | 12 | 8 | 12 | 11 |
| Pimelinketone (kg) | 26.8 | 25 | 19 | 25.9 |
Get the general ink that embodiment 1-9 provides, its sticking power, ethanol-tolerant performance, hardness etc. are detected, also carry out high and low temperature impact test, wherein, sticking power detects with reference to ASTM D3359-1997 " PASS test "; Ethanol-tolerant performance detects with reference to GB/T23989-2009 " the resistance to solvent wiping assay method of coating "; Hardness detects with reference to GB/T6739-2006 " paint and varnish pencil method is measured hardness of paint film "; High and low temperature impact test: test specimen is put into proofing box, fasten chamber door, carry out loop test by the program of setting from 85 DEG C (4 hours times)～-40 DEG C (4 hours times), until there is the defects such as crackle, bubbling, obvious loss of gloss or variable color on test specimen, record cycle index.Detected result as shown in Table 3 and Table 4.
The sticking power detected result of the general ink of table 3
More than general ink provided by the invention all can reach 4B to the sticking power of various base material (metal, plastic cement, pottery, glass, timber, cement etc.) as shown in Table 3, meet the requirement of ink to sticking power, can only use the present invention, the use at all base materials may be realized, the requirement of the various different grounds of client can be reached.
Other performance test results of the general ink of table 4
| ? | Ethanol-tolerant (175g power/time) | Hardness | High and low temperature impact test |
| Embodiment 1 | 220 | 2H | 8 times |
| Embodiment 2 | 210 | 2H | 8 times |
| Embodiment 3 | 213 | 2H | 8 times |
| Embodiment 4 | 214 | 2H | 8 times |
| Embodiment 5 | 215 | 2H | 8 times |
| Embodiment 6 | 208 | 2H | 8 times |
| Embodiment 7 | 206 | 2H | 8 times |
| Embodiment 8 | 207 | 2H | 8 times |
| Embodiment 9 | 204 | 2H | 8 times |
As shown in Table 4, the ethanol-tolerant performance of general ink provided by the invention, hardness and high-low temperature resistant impact are good, all meet industry regulation, can meet customer need.
Above specific embodiments of the invention be have been described in detail, but it is just as example, the present invention is not restricted to specific embodiment described above.To those skilled in the art, any equivalent modifications that the present invention is carried out and alternative also all among category of the present invention.Therefore, equalization conversion and the amendment done without departing from the spirit and scope of the invention, all should contain within the scope of the invention.
Claims (10)
1. a general ink, it is characterized in that, formed by host and solidifying agent, the mass ratio of host and solidifying agent is (15-45): (5-12), described in every 100g, in host, comprise: Hydroxylated acrylic resin 28-45g, adhesion promoter 4-9g, color paste composition 30-50g, wilkinite 2-8g, flow agent 0.1-1g and solvent orange 2 A 5-15g, wherein
In described color paste composition, comprise: Hydroxylated acrylic resin, defoamer, dispersion agent, wetting agent, toner and solvent B, and the mass ratio of Hydroxylated acrylic resin, defoamer, dispersion agent, wetting agent, toner and solvent B is (5-15): (0.1-1): (1-5): (0.1-1): (5-15): (20-30).
2. general ink according to claim 1, it is characterized in that, in host, comprise described in every 100g:: Hydroxylated acrylic resin 35-45g, adhesion promoter 3-6g, color paste composition 35-45g, wilkinite 3-6g, flow agent 0.3-0.8g, solvent orange 2 A 8-12g.
3. general ink according to claim 2, is characterized in that, in every 100g universal lacquer, comprises: Hydroxylated acrylic resin 38g, adhesion promoter 5g, color paste composition 41.5g, wilkinite 5g, flow agent 0.5g, solvent orange 2 A 10g.
4. general ink according to claim 1, it is characterized in that, in described color paste composition, the mass ratio of Hydroxylated acrylic resin, defoamer, dispersion agent, wetting agent, toner and solvent B is (8-12): (0.3-0.8): (2-4): (0.3-0.8): (8-12): (24-28).
5. general ink according to claim 4, is characterized in that, in described color paste composition, the mass ratio of Hydroxylated acrylic resin, defoamer, dispersion agent, wetting agent, toner and solvent B is 10:0.5:3:0.5:10:26.
6. according to the general ink described in any one in claim 1-5, it is characterized in that, described solvent orange 2 A is isophorone, and described solvent B is pimelinketone.
7. general ink according to claim 1, is characterized in that, the mass ratio of host and solidifying agent is (20-40): (8-11).
8. a preparation method for universal lacquer claimed in claim 1, is characterized in that, each component of universal lacquer described in claim 1 was both mixed and obtained, and wherein said color paste composition is mixed to get by its each component.
9. preparation method according to claim 8, is characterized in that, specifically comprises the following steps:
Step 1, puts into Hydroxylated acrylic resin and adhesion promoter in stirrer and is uniformly mixed;
Step 2, joins color paste composition in stirrer and is uniformly mixed;
Step 3, slowly joins wilkinite and flow agent in stirrer, is uniformly mixed;
Step 4, adds the solvent orange 2 A to stir until both mixed;
Wherein, described color paste composition is prepared from by the following method:
A, Hydroxylated acrylic resin, defoamer, dispersion agent and wetting agent are put into and produced in container; B, toner is slowly added to then rapid stirring under low rate mixing; C, add solvent B, rapid stirring mixes; D, mixture is milled until fineness≤5 μ m.
10. a using method for general ink claimed in claim 1, is characterized in that, the host in general ink claimed in claim 1 and solidifying agent are used with after appropriate pimelinketone mixing 10min, mixes in latter 4 hours and is finished.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410175666.0A CN103952033B (en) | 2014-04-28 | 2014-04-28 | A kind of general ink and preparation method thereof and using method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410175666.0A CN103952033B (en) | 2014-04-28 | 2014-04-28 | A kind of general ink and preparation method thereof and using method |
Publications (2)
| Publication Number | Publication Date |
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| CN103952033A true CN103952033A (en) | 2014-07-30 |
| CN103952033B CN103952033B (en) | 2016-06-08 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108624126A (en) * | 2018-05-25 | 2018-10-09 | 佛山市高明绿色德化工有限公司 | A kind of bi-component silk-screen glass ink and its preparation, application method |
| CN112708031A (en) * | 2020-12-25 | 2021-04-27 | 嘉宝莉化工集团股份有限公司 | Water-based hydroxyl acrylic emulsion and preparation method and application thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11189742A (en) * | 1997-12-26 | 1999-07-13 | Nippon Paper Industries Co Ltd | Curing type binder resin composition and its use |
| CN103627308A (en) * | 2012-08-23 | 2014-03-12 | 展辰涂料集团股份有限公司 | Polyurethane coating used on surfaces of polypropylene materials |
-
2014
- 2014-04-28 CN CN201410175666.0A patent/CN103952033B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11189742A (en) * | 1997-12-26 | 1999-07-13 | Nippon Paper Industries Co Ltd | Curing type binder resin composition and its use |
| CN103627308A (en) * | 2012-08-23 | 2014-03-12 | 展辰涂料集团股份有限公司 | Polyurethane coating used on surfaces of polypropylene materials |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108624126A (en) * | 2018-05-25 | 2018-10-09 | 佛山市高明绿色德化工有限公司 | A kind of bi-component silk-screen glass ink and its preparation, application method |
| CN112708031A (en) * | 2020-12-25 | 2021-04-27 | 嘉宝莉化工集团股份有限公司 | Water-based hydroxyl acrylic emulsion and preparation method and application thereof |
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| CN103952033B (en) | 2016-06-08 |
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Effective date of registration: 20170516 Address after: 516000 Guangdong District of Huiyang city in Huizhou Province town of Wai long autumn white cave Patentee after: HUIZHOU QIYOU CHEMICAL CO.,LTD. Address before: 516200, Nanhu street, freshwater lake village, Huiyang District, Guangdong, Huizhou Patentee before: Shen Jianguo |
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Granted publication date: 20160608 |