CN104946005A - Gray sparkle silver printing ink - Google Patents
Gray sparkle silver printing ink Download PDFInfo
- Publication number
- CN104946005A CN104946005A CN201510349056.2A CN201510349056A CN104946005A CN 104946005 A CN104946005 A CN 104946005A CN 201510349056 A CN201510349056 A CN 201510349056A CN 104946005 A CN104946005 A CN 104946005A
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- Prior art keywords
- hcp
- printing ink
- ink
- gray
- silver
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
Abstract
The invention relates to a gray sparkle silver printing ink, and belongs to the technical field of printing ink. The gray sparkle silver printing ink comprises 8.5-8.8 wt% of black pigment, 0.53-0.55 wt% of transparent yellow pigment, 0.61-0.65 wt% of transparent blue pigment, 18.0-32.0 wt% of gloss oil, 0.80-1.0 wt% of aluminum powders, 2.2-2.5 wt% of phosphoglyceride compound, 1.2-1.5 wt% of glycerol carbonate allyl ether and residual fine-workmanship T-926 diluent. The gray sparkle silver printing has no stimulation on skin and is green and environmental-friendly, and a good storage stability and good film-forming property are achieved. The gray sparkle silver printing ink applies to printing on PET, PMMA and the surface of glass substrate, a good adhesiveness and abrasive resistance are archived when the printing ink is dried totally, and bleeding phenomenon does not occur basically.
Description
Technical field
The invention belongs to the technical field of printing-ink, in particular, the present invention relates to a kind of grey and dodge silver-colored ink and preparation method thereof.
Background technology
Ink is the important materials for wrapping material printing, and pattern, the present stock curing ink of literal table are comprised main component and ancillary component by printing by it, and they mix equably and form the gluey fluid of a kind of viscosity through repeat-rolling.Printing-ink is by the pulpous state colloid of colorant, low-melting ink vehicle and the homogenize material such as auxiliary agent and solvent dispersing and mixing.The binder of solvent type ink is made up of solid resin and a large amount of volatile organic solvent.Solid resin is dissolved in after in solvent, is dispersed in by colorant in binder, and ink is printed to printed medium, the rapid volatile dry conjunctiva of solvent.
For ink, general expectation uses the aesthetic effect and the permanent printing characteristic kept that can produce on printed medium and show pleasant simultaneously.The example of these printing characteristics comprises press quality, as optical density (OD), colourity etc.; And weather resistance, as water tolerance, fade resistance, persistence, acidproof and alkaline-resisting etc.Plastisol ink composite is often referred to as plastisol ink, because the mode applied utilizes plastisol fluid properties before heating, causes the base resin in plastisol to be solidified into solid by baking or thermofixation.In prior art, most plastisol is dispersed in the softening agent based on phthalic ester and is occurred in the composition of swelling polyvinyl chloride (PVC) RESINS by it.Polyvinyl chloride (PVC) RESINS plastisol ink is widely used for screen printing operation.But due to the consideration of environment, health and safety, the use of these ink is subject to strict restriction just day by day.
Summary of the invention
In order to solve above-mentioned technical problem of the prior art, a kind of grey is the object of the present invention is to provide to dodge silver-colored ink.
In order to realize foregoing invention object, present invention employs following technical scheme:
The present invention relates to a kind of grey and dodge silver-colored ink, it comprises black pigment, the transparent yellow pigments of 0.53 ~ 0.55wt%, the transparent blue pigment of 0.61 ~ 0.65wt%, the gloss oil of 28.0 ~ 32.0wt%, the silver powder of 0.80 ~ 1.0wt%, the phosphoglyceride compound of 2.2 ~ 2.5wt%, the glycerol carbonate propenyl ether of 1.2 ~ 1.5wt% of 8.5 ~ 8.8wt%, and the Seiko T-926 thinner of surplus.
Wherein, described phosphoglyceride compound is selected from phosphatidyl serine (PS), phosphatidyl ethanolamine (PE), or at least one in phosphatldylcholine (PC).
Wherein, described black pigment is HCP-213 black pigment, and described transparent yellow pigments is HCP-214 transparent yellow pigments, and described transparent blue pigment is HCP-216 transparent blue pigment.
Wherein, described gloss oil is HF1000-800 gloss oil.
Wherein, described silver powder is 607S silver powder, 606Y silver powder, or the combination of the two.
Compared with prior art, grey of the present invention is dodged silver-colored ink and is had following beneficial effect:
Ink of the present invention is non-stimulated to skin, environmental protection; And there is good preservation stability and good film-forming properties.Ink of the present invention is applicable to the printing of PET, PMMA and glass substrate surface, and after ink complete drying, tack is good, wear resistance good, substantially without oozing out phenomenon.
Embodiment
Dodge silver-colored ink and preparation method thereof below with reference to specific embodiment to grey of the present invention to be described further, have more complete, accurate and deep understanding to help those skilled in the art to inventive concept of the present invention, technical scheme.What applicant needed to declare is the description of related materials in embodiment, performance and technique etc. is all exemplary, and does not refer to the restriction to invention protection domain.
Grey of the present invention dodges silver-colored ink, comprise the HCP-213 black pigment of 8.5 ~ 8.8wt%, the HCP-214 transparent yellow pigments of 0.53 ~ 0.55wt%, the HCP-216 transparent blue pigment of 0.61 ~ 0.65wt%, the HF1000-800 gloss oil of 28.0 ~ 32.0wt%, the silver powder of 0.80 ~ 1.0wt%, the phosphoglyceride compound of 2.2 ~ 2.5wt%, the glycerol carbonate propenyl ether of 1.2 ~ 1.5wt%, and the Seiko T-926 thinner of surplus.Described phosphoglyceride compound is selected from phosphatidyl serine (PS), phosphatidyl ethanolamine (PE), or at least one in phosphatldylcholine (PC).
Embodiment 1
The grey of the present embodiment dodges HCP-213 black pigment, the HCP-214 transparent yellow pigments of 0.53wt%, the HCP-216 transparent blue pigment of 0.61wt%, the HF1000-800 gloss oil of 32.0wt%, the 607S silver powder of 0.52wt%, the 606Y silver powder of 0.31wt%, the phosphatidyl serine of 2.2wt%, the glycerol carbonate propenyl ether of 1.5wt% that silver-colored ink contains 8.8wt%, and the Seiko T-926 thinner of surplus.Described ink preparation technology is as follows: (1), by the HF1000-800 gloss oil of 8wt%, the Seiko T-926 thinner of 10wt% fully mixes with alr mode and dissolves, obtained dispersion soln; (2) by the dispersion soln that described HCP-213 black pigment, HCP-214 transparent yellow pigments, HCP-216 transparent blue pigment and step (1) prepare, obtained first mixed solution is fully mixed with alr mode; (3) by described glycerol carbonate propenyl ether, phosphatidyl serine, 607S silver powder, and 606Y silver powder and remaining HF1000-800 gloss oil fully mix with alr mode and dissolve, obtained second mixed solution; (4) the second mixed solution that the first mixed solution step (2) obtained, step (3) obtain and remaining Seiko T-926 thinner are fully mixed to get mixed liquor with alr mode; (5) mixed liquor that step (4) obtained adopts sand mill to grind, and obtains the ink that fineness is less than 5 μm.
Embodiment 2
The grey of the present embodiment dodges HCP-213 black pigment, the HCP-214 transparent yellow pigments of 0.55wt%, the HCP-216 transparent blue pigment of 0.65wt%, the HF1000-800 gloss oil of 28.0wt%, the 607S silver powder of 0.52wt%, the 606Y silver powder of 0.31wt%, the phosphatidyl ethanolamine of 2.5wt%, the glycerol carbonate propenyl ether of 1.2wt% that silver-colored ink contains 8.5wt%, and the Seiko T-926 thinner of surplus.Described ink preparation technology is as follows: (1), by the HF1000-800 gloss oil of 8wt%, the Seiko T-926 thinner of 10wt% fully mixes with alr mode and dissolves, obtained dispersion soln; (2) by the dispersion soln that described HCP-213 black pigment, HCP-214 transparent yellow pigments, HCP-216 transparent blue pigment and step (1) prepare, obtained first mixed solution is fully mixed with alr mode; (3) by described glycerol carbonate propenyl ether, phosphatidyl ethanolamine, 607S silver powder, and 606Y silver powder and remaining HF1000-800 gloss oil fully mix with alr mode and dissolve, obtained second mixed solution; (4) the second mixed solution that the first mixed solution step (2) obtained, step (3) obtain and remaining Seiko T-926 thinner are fully mixed to get mixed liquor with alr mode; (5) mixed liquor that step (4) obtained adopts sand mill to grind, and obtains the ink that fineness is less than 5 μm.
Embodiment 3
The grey of the present embodiment dodges HCP-213 black pigment, the HCP-214 transparent yellow pigments of 0.55wt%, the HCP-216 transparent blue pigment of 0.63wt%, the HF1000-800 gloss oil of 30wt%, the 607S silver powder of 0.52wt%, the 606Y silver powder of 0.31wt%, the phosphatldylcholine of 2.3wt%, the glycerol carbonate propenyl ether of 1.5wt% that silver-colored ink contains 8.6wt%, and the Seiko T-926 thinner of surplus.Described ink preparation technology is as follows: (1), by the HF1000-800 gloss oil of 8wt%, the Seiko T-926 thinner of 10wt% fully mixes with alr mode and dissolves, obtained dispersion soln; (2) by the dispersion soln that described HCP-213 black pigment, HCP-214 transparent yellow pigments, HCP-216 transparent blue pigment and step (1) prepare, obtained first mixed solution is fully mixed with alr mode; (3) by described glycerol carbonate propenyl ether, phosphatldylcholine, 607S silver powder, and 606Y silver powder and remaining HF1000-800 gloss oil fully mix with alr mode and dissolve, obtained second mixed solution; (4) the second mixed solution that the first mixed solution step (2) obtained, step (3) obtain and remaining Seiko T-926 thinner are fully mixed to get mixed liquor with alr mode; (5) mixed liquor that step (4) obtained adopts sand mill to grind, and obtains the ink that fineness is less than 5 μm.
Comparative example 1
The grey of this comparative example dodges HCP-213 black pigment, the HCP-214 transparent yellow pigments of 0.55wt%, the HCP-216 transparent blue pigment of 0.63wt%, the HF1000-800 gloss oil of 30wt%, the 607S silver powder of 0.52wt%, the 606Y silver powder of 0.31wt% that silver-colored ink contains 8.6wt%, and the Seiko T-926 thinner of surplus.Described ink preparation technology is as follows: (1), by the HF1000-800 gloss oil of 8wt%, the Seiko T-926 thinner of 10wt% fully mixes with alr mode and dissolves, obtained dispersion soln; (2) by the dispersion soln that described HCP-213 black pigment, HCP-214 transparent yellow pigments, HCP-216 transparent blue pigment and step (1) prepare, obtained first mixed solution is fully mixed with alr mode; (3) by 607S silver powder, and 606Y silver powder and remaining HF1000-800 gloss oil fully mix with alr mode and dissolve, obtained second mixed solution; (4) the second mixed solution that the first mixed solution step (2) obtained, step (3) obtain and remaining Seiko T-926 thinner are fully mixed to get mixed liquor with alr mode; (5) mixed liquor that step (4) obtained adopts sand mill to grind, and obtains the ink that fineness is less than 5 μm.
Comparative example 2
The grey of this comparative example dodges HCP-213 black pigment, the HCP-214 transparent yellow pigments of 0.55wt%, the HCP-216 transparent blue pigment of 0.63wt%, the HF1000-800 gloss oil of 30wt%, the 607S silver powder of 0.52wt%, the 606Y silver powder of 0.31wt%, the phosphatldylcholine of 2.3wt% that silver-colored ink contains 8.6wt%, and the Seiko T-926 thinner of surplus.Described ink preparation technology is as follows: (1), by the HF1000-800 gloss oil of 8wt%, the Seiko T-926 thinner of 10wt% fully mixes with alr mode and dissolves, obtained dispersion soln; (2) by the dispersion soln that described HCP-213 black pigment, HCP-214 transparent yellow pigments, HCP-216 transparent blue pigment and step (1) prepare, obtained first mixed solution is fully mixed with alr mode; (3) by described phosphatldylcholine, 607S silver powder, and 606Y silver powder and remaining HF1000-800 gloss oil fully mix with alr mode and dissolve, obtained second mixed solution; (4) the second mixed solution that the first mixed solution step (2) obtained, step (3) obtain and remaining Seiko T-926 thinner are fully mixed to get mixed liquor with alr mode; (5) mixed liquor that step (4) obtained adopts sand mill to grind, and obtains the ink that fineness is less than 5 μm.
Comparative example 3
The grey of this comparative example dodges HCP-213 black pigment, the HCP-214 transparent yellow pigments of 0.55wt%, the HCP-216 transparent blue pigment of 0.63wt%, the HF1000-800 gloss oil of 30wt%, the 607S silver powder of 0.52wt%, the 606Y silver powder of 0.31wt%, the glycerol carbonate propenyl ether of 1.5wt% that silver-colored ink contains 8.6wt%, and the Seiko T-926 thinner of surplus.Described ink preparation technology is as follows: (1), by the HF1000-800 gloss oil of 8wt%, the Seiko T-926 thinner of 10wt% fully mixes with alr mode and dissolves, obtained dispersion soln; (2) by the dispersion soln that described HCP-213 black pigment, HCP-214 transparent yellow pigments, HCP-216 transparent blue pigment and step (1) prepare, obtained first mixed solution is fully mixed with alr mode; (3) by described glycerol carbonate propenyl ether, 607S silver powder, and 606Y silver powder and remaining HF1000-800 gloss oil fully mix with alr mode and dissolve, obtained second mixed solution; (4) the second mixed solution that the first mixed solution step (2) obtained, step (3) obtain and remaining Seiko T-926 thinner are fully mixed to get mixed liquor with alr mode; (5) mixed liquor that step (4) obtained adopts sand mill to grind, and obtains the ink that fineness is less than 5 μm.
The each 10g of ink sample of Example 1-3 is placed in the thermostat container of 40 DEG C, detects ink sample stability in storage at elevated temperatures; Utilized probe to detect sample at interval of 12 hours, the time of silk screen printing cannot be carried out to determine sample to become enough thick, characterize the time of stability in storage.Result shows: the ink sample storage stability at an elevated temperature of embodiment of the present invention can reach 30-40 days, has good preservation stability.
Spin coating method is adopted to be printed on glass by the ink described in embodiment 1-3 and comparative example 1-3; Then toast at the temperature of 65 ± 1 DEG C; Baking time is 50 minutes.As a child carried out the tests such as tack, scratch resistance, solvent-resisting through 24, its result is as shown in table 1.
Table 1
In the present invention; for the ordinary skill in the art described; specific embodiment is just to invention has been exemplary description; obvious specific implementation of the present invention is not subject to the restrictions described above; as long as have employed the improvement of the various unsubstantialities that method of the present invention is conceived and technical scheme is carried out; or design of the present invention and technical scheme directly applied to other occasion, all within protection scope of the present invention without to improve.
Claims (5)
1. a grey dodges silver-colored ink, it comprises black pigment, the transparent yellow pigments of 0.53 ~ 0.55wt%, the transparent blue pigment of 0.61 ~ 0.65wt%, the gloss oil of 28.0 ~ 32.0wt%, the silver powder of 0.80 ~ 1.0wt%, the phosphoglyceride compound of 2.2 ~ 2.5wt%, the glycerol carbonate propenyl ether of 1.2 ~ 1.5wt% of 8.5 ~ 8.8wt%, and the Seiko T-926 thinner of surplus.
2. grey according to claim 1 dodges silver-colored ink, it is characterized in that: described phosphoglyceride compound is selected from phosphatidyl serine (PS), phosphatidyl ethanolamine (PE), or at least one in phosphatldylcholine (PC).
3. grey according to claim 1 dodges silver-colored ink, it is characterized in that: described black pigment is HCP-213 black pigment, and described transparent yellow pigments is HCP-214 transparent yellow pigments, and described transparent blue pigment is HCP-216 transparent blue pigment.
4. grey according to claim 1 dodges silver-colored ink, it is characterized in that: described gloss oil is HF1000-800 gloss oil.
5. grey according to claim 1 dodges silver-colored ink, it is characterized in that: described silver powder is 607S silver powder, 606Y silver powder, or the combination of the two.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510349056.2A CN104946005A (en) | 2015-06-23 | 2015-06-23 | Gray sparkle silver printing ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510349056.2A CN104946005A (en) | 2015-06-23 | 2015-06-23 | Gray sparkle silver printing ink |
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| Publication Number | Publication Date |
|---|---|
| CN104946005A true CN104946005A (en) | 2015-09-30 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510349056.2A Pending CN104946005A (en) | 2015-06-23 | 2015-06-23 | Gray sparkle silver printing ink |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108839504A (en) * | 2018-08-03 | 2018-11-20 | 合肥联宝信息技术有限公司 | A kind of shell and surface treatment method and the electronic equipment for including the shell |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008088262A (en) * | 2006-09-29 | 2008-04-17 | Toyo Ink Mfg Co Ltd | Offset ink composition |
| CN102369157A (en) * | 2008-12-19 | 2012-03-07 | 沃尔贝克材料有限公司 | Inks and coatings containing multi-chain lipids |
| CN102876123A (en) * | 2012-09-29 | 2013-01-16 | 苏州安洁科技股份有限公司 | Shiny silver printing ink |
| CN103911037A (en) * | 2014-04-30 | 2014-07-09 | 苏州安洁科技股份有限公司 | Matte black printing ink for silk-screen printing |
| CN103923521A (en) * | 2014-04-30 | 2014-07-16 | 苏州安洁科技股份有限公司 | Preparation method of semitransparent grey environment-friendly ink |
-
2015
- 2015-06-23 CN CN201510349056.2A patent/CN104946005A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008088262A (en) * | 2006-09-29 | 2008-04-17 | Toyo Ink Mfg Co Ltd | Offset ink composition |
| CN102369157A (en) * | 2008-12-19 | 2012-03-07 | 沃尔贝克材料有限公司 | Inks and coatings containing multi-chain lipids |
| CN102876123A (en) * | 2012-09-29 | 2013-01-16 | 苏州安洁科技股份有限公司 | Shiny silver printing ink |
| CN103911037A (en) * | 2014-04-30 | 2014-07-09 | 苏州安洁科技股份有限公司 | Matte black printing ink for silk-screen printing |
| CN103923521A (en) * | 2014-04-30 | 2014-07-16 | 苏州安洁科技股份有限公司 | Preparation method of semitransparent grey environment-friendly ink |
Non-Patent Citations (1)
| Title |
|---|
| 朱洪法: "《精细化工常用原材料手册》", 31 December 2003 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108839504A (en) * | 2018-08-03 | 2018-11-20 | 合肥联宝信息技术有限公司 | A kind of shell and surface treatment method and the electronic equipment for including the shell |
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Application publication date: 20150930 |
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