CN103602143A - Transfer printing ink with release function - Google Patents
Transfer printing ink with release function Download PDFInfo
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- CN103602143A CN103602143A CN201310631909.2A CN201310631909A CN103602143A CN 103602143 A CN103602143 A CN 103602143A CN 201310631909 A CN201310631909 A CN 201310631909A CN 103602143 A CN103602143 A CN 103602143A
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Abstract
The invention relates to a transfer printing ink with a release function. The transfer printing ink comprises, by weight, 16 to 25% of a polymethacrylate resin, 1.5 to 2.5% of a cellulose acetate resin, 7 to 30% of a pigment, 50 to 62.5% of a mixed solvent, 0 to 2% of an auxiliary agent, 0 to 1% of matt powder and 0 to 2% of wax powder, wherein the mixed solvent is a mixture of two or more selected from the group consisting of ethyl acetate, n-propyl acetate, isopropyl acetate, n-butyl acetate, toluene, butanone, methyl isobutyl ketone, isopropanol, propylene glycol monomethyl ether and propylene glycol monomethyl ether acetate mixed at any ratio, the auxiliary agent is one or a mixture of more selected from the group consisting of a dispersant, an antistatic agent and an organosilicon leveling agent, the matt powder is gas phase silica, and the wax powder is polymer micro wax powder. The transfer printing ink provided by the invention has all the properties of a traditional transfer printing ink, e.g., pigment concentration, brilliance and good printability and heat resistance, further has excellent release performance and can be used as a release agent in a transfer printing process.
Description
Technical field
The present invention relates to a kind of ink, relate to specifically a kind of transfer ink with release function.
Background technology
Transfer technique refers to first that by ink printing (as polyethylene terephthalate (PET) film) makes transfer film on specific ground, then will print figuratum transfer film by certain temperature and pressure, pattern transfer is arrived to target ground (as buckle, photo frame, furniture facade, stationery plastic cement etc.) a kind of Technology on.Transfer printing process can be divided into cold transfer printing and hot transfer printing according to transfer printing temperature difference, traditional transfer film typography is PET film // parting agent // transfer ink // glue, parting agent plays the effect of peeling off with PET film after transfer printing, if there is no parting agent, adopt the technique of PET film // transfer ink // glue, when transfer printing, can occur ink layer and PET thin film layer peel off clean and ink layer and PET thin film layer attachment fastness very good and exert oneself when can not peeling off any more or peeling off excessive extremely.
Although present traditional transfer film typography comparative maturity, but it prints order slightly complicated, parting agent and the glue twice that just account for print order (some need to be gone up twice glue and must three roads print orders), general six-color printing press just can only leave four seal orders and do color chromatography, therefore complicated any pattern just need to be printed on the machine just and can complete through twice, simultaneously because transfer film manufacturer is numerous now, product competition is extremely fierce, so each transfer film manufacturer is very urgent to the requirement reducing costs.If but only cost-saving from traditional angle, can cause many bad quality problems: when the consumption of minimizing parting agent can cause transfer printing, peel off not smooth; The consumption of less ink can cause depth of shade and vividness inadequate, pattern printing is unintelligible; The consumption that reduces glue can cause transfer printing fastness variation.
Summary of the invention
The object of the invention is to solve the deficiencies in the prior art, a kind of transfer ink with release function is provided, the transfer film of " PET film // transfer ink // glue " structure is achieved, thereby simplifies transfer film print production technique, reduce its production cost.
The technical solution adopted for the present invention to solve the technical problems is:
A kind of transfer ink with release function, this ink is comprised of the component of following weight percent: polymethacrylate resin 16-25%, cellulose acetate resin 1.5-2.5%, pigment 7-30%, mixed solvent 50-62.5%, auxiliary agent 0-2%, mute powder 0-1%, wax powder 0-2%, described mixed solvent is vinyl acetic monomer, n-propyl acetate, Iso Butyl Acetate, N-BUTYL ACETATE, toluene, butanone, mibk, Virahol, the mixed solvent that the arbitrary proportion of two or more in propylene glycol monomethyl ether and propylene glycol monomethyl ether acetate combines, described auxiliary agent is dispersion agent, the mixture of one or more in static inhibitor and organosilicon flow agent, described mute powder is aerosil, described wax powder is polymkeric substance micro mist wax.
As preferably, in described polymethacrylate resin, polymethylmethacrylate and/or poly-n-butyl methacrylate account in ink total polymethacrylate resin quality more than 90%.Plexiglass is not good to PET adhesion of thin film, under transfer printing condition, be easy to depart from completely with PET film, but plexiglass hardness is higher, fragility is larger, easy stressed fracture after film forming, and polybutyl methacrylate resin can be improved the snappiness after ink film forming.
As preferably, in described auxiliary agent, to account for the weight percent of ink be 0-0.5% to dispersion agent, and the weight percent that flow agent accounts for ink is 0-1%, and the weight percent that static inhibitor accounts for ink is 0-0.5%.Dispersion agent can effectively help the colo(u)rant dispersion in ink; Flow agent can improve the levelling effect of ink picture and text in printing process; Static inhibitor can be eliminated the faults such as static burr in printing process.
As preferably, the molecular weight of described polymethacrylate resin is between 50000-120000, and second-order transition temperature (Tg) is between 60-120 ℃.The molecular weight of polymethacrylate resin is between 50000-120000, after the ink setting that can avoid causing because molecular weight is too little at this interval polymethacrylate resin, China ink layer is too crisp, can avoid again the ink viscosity that causes because molecular weight is excessive too high, impact is produced and printing process; The polymethacrylate resin of second-order transition temperature (Tg) between 60-120 ℃ can avoid the transfer film China ink layer causing because second-order transition temperature is too low to cross soft cause anti-sticky, can avoid again the resin dissolves difficulty causing because of too high second-order transition temperature.
As preferably, in ink formulations, the weight ratio of cellulose acetate resin and polymethacrylate resin is between 0.06-0.1.Cellulose acetate resin can play and improve levelling in ink, promotes solvent evaporates, reduces the effect of migration of plasticizer.
As preferably, described pigment is pigment dyestuff, and pigment dyestuff accounts for formulation weight than 7-15%, and one or more in red pigment, yellow ultramarine, blue pigments, veridian, orange pigments and violet pigment of this pigment dyestuff form.
As preferably, described pigment is mineral dye, and the weight percent of mineral dye is 15-30%, and one or more in black pigment, white pigment, red pigment, yellow ultramarine, blue pigments of this mineral dye form.
As preferably, described polymkeric substance micro mist wax is the mixture of one or more compositions in polyethylene wax, Poly Propylene Wax and tetrafluoroethylene wax.Polyethylene wax and tetrafluoroethylene wax can improve wear resistance and the anti-after-tack after ink film forming, and Poly Propylene Wax can effectively improve the smoothness of ink rete.
As preferably, described dispersion agent is a kind of in polyester type or polyether-type hyper-dispersant, and described static inhibitor is quaternary ammonium compound.
As preferably, the applicable transfer printing process of described ink is that cold transfer printing and temperature are not more than the hot transfer printing of 220 ℃, and pressure is 3-10kg/cm
2pressure.
The invention has the beneficial effects as follows:
(1) transfer ink of the present invention not only has traditional transfer ink properties as depth of shade, vividness, good printability and thermotolerance, but also there is excellent release, the parting agent that can serve as in transfer printing technique is used, and it can be for the production of the transfer film that is different from novel " PET film // transfer ink // glue " structure of traditional " PET film // parting agent // transfer ink // glue " structure.
(2) transfer ink of the present invention can substitute traditional transfer ink and parting agent, has effectively simplified the production typography of transfer film, has greatly saved the production cost of producing transfer film.
Embodiment
Below by specific embodiment, technical scheme of the present invention is described in further detail.
In embodiment, each raw material is all commercial conventional raw material.
Embodiment 1:
A transfer ink with release function, its composition is as shown in table 1:
Each component of the transfer ink of table 1. embodiment 1 and weight percent thereof
Wherein the molecular weight of polymethylmethacrylate is 90000, second-order transition temperature is 80 ℃, this transfer ink preparation method with release function is as follows: first resin and a part of solvent dispersion are dissolved into resin liquid, then pigment and auxiliary agent are put in resin liquid and be uniformly dispersed, then by sand mill, be ground to fineness qualified, then by residual solvent, mute powder and wax powder add, and high-speed stirring is disperseed 20 minutes and be get final product.
Embodiment 2:
A transfer ink with release function, its composition is as shown in table 2:
Each component of the transfer ink of table 2. embodiment 2 and weight percent thereof
Wherein the molecular weight of polymethylmethacrylate is 70000, and second-order transition temperature is 100 ℃; The molecular weight of poly-n-butyl methacrylate is 50000, and second-order transition temperature is 60 ℃.This transfer ink can be prepared in the following manner: first resin and a part of solvent dispersion are dissolved into resin liquid, then pigment and auxiliary agent are put in resin liquid and be uniformly dispersed, then by sand mill, be ground to fineness qualified, then residual solvent, mute powder and wax powder are added, high-speed stirring is disperseed 20 minutes and be get final product.
Embodiment 3
According to the transfer ink with release function of the present embodiment, it forms in Table 3.
Each component of the transfer ink of table 3. embodiment 3 and weight percent thereof
Wherein the molecular weight of polymethylmethacrylate is 90000, and second-order transition temperature is 120 ℃; The molecular weight of poly-n-butyl methacrylate is 70000, and second-order transition temperature is 75 ℃.This transfer ink can be prepared in the following manner: first resin and a part of solvent dispersion are dissolved into resin liquid, then pigment and auxiliary agent are put in resin liquid and be uniformly dispersed, then by sand mill, be ground to fineness qualified, then residual solvent, mute powder and wax powder are added, high-speed stirring is disperseed 20 minutes and be get final product.
Embodiment 4
According to the transfer ink with release function of the present embodiment, it forms in Table 4
Table 4. is executed each component of transfer ink and the weight percent thereof of example 4
Wherein the molecular weight of polymethylmethacrylate is 80000, and second-order transition temperature is 100 ℃; The molecular weight of poly-n-butyl methacrylate is 70000, and second-order transition temperature is 75 ℃; The molecular weight of polyisobutyl methacrylate is 55000, second-order transition temperature is 65 ℃. transfer ink can be prepared in the following manner: first resin and a part of solvent dispersion are dissolved into resin liquid, then pigment and auxiliary agent are put in resin liquid and be uniformly dispersed, then by sand mill, be ground to fineness qualified, then residual solvent and wax powder are added, high-speed stirring is disperseed 20 minutes and be get final product.
Embodiment 1 to embodiment 4 is made to transfer ink and carries out performance test, test assessment method:
1. fineness: carry out evaluation result YiμWei unit according to GB/T13217.3.
2. tinting strength: carry out according to GB/T13217.6, evaluation result be take % as unit.
3. release: first transfer ink is opened rarely to looking into grace 3# flow cup 16 seconds with opening rare solvent (vinyl acetic monomer: n-propyl acetate=7:3, massfraction ratio), then scrape sample with 5# scraper by parting agent // transfer ink // glue on PET film; Scraping sample is 180 ℃ in temperature, and pressure is 5kg/cm
2condition under carry out after transfer printing, PET film being peeled off.The residual degree that detects transfer ink on the PET film under whether peeling off smoothly and peel off, evaluation result is that 1-5 divides, 5 be divided into peel off smoothly and PET film on every 100cm
2ink residue point is no more than 3 points, and 1 is divided into and can not peels off smoothly, and every 100cm on PET film
2ink residue point surpasses 20 points.
4. transfer printing fastness: first transfer ink is opened rarely to looking into grace 3# flow cup 16 seconds with opening rare solvent (vinyl acetic monomer: n-propyl acetate=7:3, massfraction ratio), then scrape sample with 5# scraper by parting agent // transfer ink // glue on PET film; Scraping sample is 180 ℃ in temperature, and pressure is 5kg/cm
2condition under carry out after transfer printing, PET film being peeled off, then with 3M adhesive tape by the attachment fastness of hundred lattice method test ink layers (can with reference to GB/T13217.7), evaluation result is not for falling the lattice number of China ink layer except in 100.
5. rub-off resistance: first by transfer ink with opening rare solvent (vinyl acetic monomer: n-propyl acetate=7:3, massfraction ratio) open rare to looking into grace 3# flow cup 16 seconds, then on PET film, with 5# scraper, scrape continuously 3 layers, sample, then will scrape sample and with the hands rub 5 times, observe black layer of situation of breaking of ink.Evaluation result is that 1-5 divides, and 5 are divided into China ink layer does not break completely, and 1 is divided into China ink layer breaks completely and comes off.
Embodiment 1-4 is carried out to the test result of performance test and ask for an interview table 5.
The performance test of table 5. embodiment
| Test event | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
| Fineness | ＜18μ | ＜15μ | ＜15μ | ＜15μ |
| Tinting strength | 95-105% | 95-105% | 95-105% | 95-105% |
| Release | 5 | 5 | 5 | 5 |
| Transfer printing fastness | >95% | >95% | >95% | >95% |
| Rub-off resistance | 5 | 5 | 5- | 5 |
Above-described embodiment is a kind of preferably scheme of the present invention, not the present invention is done to any pro forma restriction, also has other variant and remodeling under the prerequisite that does not exceed the technical scheme that claim records.
Claims (10)
1. a transfer ink with release function, it is characterized in that: this ink is comprised of the component of following weight percent: polymethacrylate resin 16-25%, cellulose acetate resin 1.5-2.5%, pigment 7-30%, mixed solvent 50-62.5%, auxiliary agent 0-2%, mute powder 0-1%, wax powder 0-2%, described mixed solvent is vinyl acetic monomer, n-propyl acetate, Iso Butyl Acetate, N-BUTYL ACETATE, toluene, butanone, mibk, Virahol, the mixed solvent that the arbitrary proportion of two or more in propylene glycol monomethyl ether and propylene glycol monomethyl ether acetate combines, described auxiliary agent is dispersion agent, the mixture of one or more in static inhibitor and organosilicon flow agent, described mute powder is aerosil, described wax powder is polymkeric substance micro mist wax.
2. the transfer ink with release function according to claim 1, is characterized in that: in described polymethacrylate resin, polymethylmethacrylate and/or poly-n-butyl methacrylate account in ink total polymethacrylate resin quality more than 90%.
3. the transfer ink with release function according to claim 1, it is characterized in that: in described auxiliary agent, to account for the weight percent of ink be 0-0.5% to dispersion agent, the weight percent that flow agent accounts for ink is 0-1%, and the weight percent that static inhibitor accounts for ink is 0-0.5%.
4. according to the transfer ink with release function described in claim 1 or 2 or 3, it is characterized in that: the molecular weight of described polymethacrylate resin is between 50000-120000, and second-order transition temperature (Tg) is between 60-120 ℃.
5. according to the transfer ink with release function described in claim 1 or 2 or 3, it is characterized in that: in ink formulations, the weight ratio of cellulose acetate resin and polymethacrylate resin is between 0.06-0.1.
6. according to the transfer ink with release function described in claim 1 or 2 or 3, it is characterized in that: described pigment is pigment dyestuff, pigment dyestuff accounts for formulation weight than 7-15%, and one or more in red pigment, yellow ultramarine, blue pigments, veridian, orange pigments and violet pigment of this pigment dyestuff form.
7. according to the transfer ink with release function described in claim 1 or 2 or 3, it is characterized in that: described pigment is mineral dye, the weight percent of mineral dye is 15-30%, and one or more in black pigment, white pigment, red pigment, yellow ultramarine, blue pigments of this mineral dye form.
8. according to the transfer ink with release function described in claim 1 or 2 or 3, it is characterized in that: described polymkeric substance micro mist wax is the mixture of one or more compositions in polyethylene wax, Poly Propylene Wax and tetrafluoroethylene wax.
9. according to the transfer ink with release function described in claim 1 or 2 or 3, it is characterized in that: described dispersion agent is a kind of in polyester type or polyether-type hyper-dispersant, and described static inhibitor is quaternary ammonium compound.
10. according to the transfer ink with release function described in claim 1 or 2 or 3, it is characterized in that: the applicable transfer printing process of described ink is that cold transfer printing and temperature are not more than the hot transfer printing of 220 ℃, and pressure is 3-10kg/cm
2pressure.
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| CN201310631909.2A CN103602143A (en) | 2013-11-29 | 2013-11-29 | Transfer printing ink with release function |
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| CN201310631909.2A CN103602143A (en) | 2013-11-29 | 2013-11-29 | Transfer printing ink with release function |
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Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104804546A (en) * | 2015-04-13 | 2015-07-29 | 陈良伢 | Water-based hot-stamping ink |
| CN105419475A (en) * | 2014-09-11 | 2016-03-23 | 洋紫荆油墨（浙江）有限公司 | Gluing-free thermal transfer printing ink having release function |
| CN105542591A (en) * | 2016-01-08 | 2016-05-04 | 广东邦固化学科技有限公司 | Functional release agent and preparation and application method thereof |
| CN106221448A (en) * | 2016-07-28 | 2016-12-14 | 上海维凯光电新材料有限公司 | Low VOC easy offset printing cold wave releasing layer coating and preparation method thereof |
| CN106700727A (en) * | 2015-11-17 | 2017-05-24 | 洋紫荆油墨（浙江）有限公司 | Gluing-free thermal transfer printing ink with release function |
| CN107652760A (en) * | 2016-07-25 | 2018-02-02 | 洋紫荆油墨（浙江）有限公司 | A kind of environment-friendly polyurethane dual ink set and its manufacture method for being adapted to ultrahigh speed printing |
| CN108368365A (en) * | 2015-12-18 | 2018-08-03 | 惠普印迪戈股份公司 | Electrostatic ink composition |
| CN109385231A (en) * | 2017-08-04 | 2019-02-26 | 禹辉（上海）新材料科技股份有限公司 | A kind of thermal transfer glue for plate glass |
| CN109466195A (en) * | 2018-11-26 | 2019-03-15 | 安徽同和包装制品有限公司 | A kind of environmental protection and energy saving packing box printing technology |
| CN109897464A (en) * | 2019-03-11 | 2019-06-18 | 江苏斯迪克新材料科技股份有限公司 | A kind of printable transfer non-silicon separated type material |
| CN110746836A (en) * | 2019-11-06 | 2020-02-04 | 焦作卓立膜材料有限责任公司 | High-temperature steam resistant thermal transfer release agent and preparation method thereof |
| CN112280416A (en) * | 2020-10-27 | 2021-01-29 | 浙江龙游道明光学有限公司 | Manufacturing method of transfer film release agent |
| CN113370693A (en) * | 2021-07-13 | 2021-09-10 | 浙江英赛德数码科技有限公司 | High-efficiency curing transfer printing digital roller printing process and equipment |
| CN114083849A (en) * | 2021-10-13 | 2022-02-25 | 广东天进新材料有限公司 | Film with three-dimensional sense and preparation method and application thereof |
| CN116836599A (en) * | 2023-06-30 | 2023-10-03 | 北京梦之墨科技有限公司 | Micro-adhesion release agent and preparation method and application thereof |
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Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105419475A (en) * | 2014-09-11 | 2016-03-23 | 洋紫荆油墨（浙江）有限公司 | Gluing-free thermal transfer printing ink having release function |
| CN105419475B (en) * | 2014-09-11 | 2018-08-07 | 洋紫荆油墨（浙江）有限公司 | It is a kind of to exempt from gluing thermal transfer ink with release function |
| CN104804546A (en) * | 2015-04-13 | 2015-07-29 | 陈良伢 | Water-based hot-stamping ink |
| CN106700727A (en) * | 2015-11-17 | 2017-05-24 | 洋紫荆油墨（浙江）有限公司 | Gluing-free thermal transfer printing ink with release function |
| CN108368365B (en) * | 2015-12-18 | 2021-06-11 | 惠普印迪戈股份公司 | Electrostatic ink composition |
| CN108368365A (en) * | 2015-12-18 | 2018-08-03 | 惠普印迪戈股份公司 | Electrostatic ink composition |
| CN105542591A (en) * | 2016-01-08 | 2016-05-04 | 广东邦固化学科技有限公司 | Functional release agent and preparation and application method thereof |
| CN107652760A (en) * | 2016-07-25 | 2018-02-02 | 洋紫荆油墨（浙江）有限公司 | A kind of environment-friendly polyurethane dual ink set and its manufacture method for being adapted to ultrahigh speed printing |
| CN106221448A (en) * | 2016-07-28 | 2016-12-14 | 上海维凯光电新材料有限公司 | Low VOC easy offset printing cold wave releasing layer coating and preparation method thereof |
| CN109385231A (en) * | 2017-08-04 | 2019-02-26 | 禹辉（上海）新材料科技股份有限公司 | A kind of thermal transfer glue for plate glass |
| CN109466195A (en) * | 2018-11-26 | 2019-03-15 | 安徽同和包装制品有限公司 | A kind of environmental protection and energy saving packing box printing technology |
| CN109897464A (en) * | 2019-03-11 | 2019-06-18 | 江苏斯迪克新材料科技股份有限公司 | A kind of printable transfer non-silicon separated type material |
| CN110746836A (en) * | 2019-11-06 | 2020-02-04 | 焦作卓立膜材料有限责任公司 | High-temperature steam resistant thermal transfer release agent and preparation method thereof |
| CN112280416A (en) * | 2020-10-27 | 2021-01-29 | 浙江龙游道明光学有限公司 | Manufacturing method of transfer film release agent |
| CN112280416B (en) * | 2020-10-27 | 2021-12-24 | 浙江龙游道明光学有限公司 | Manufacturing method of transfer film release agent |
| CN113370693A (en) * | 2021-07-13 | 2021-09-10 | 浙江英赛德数码科技有限公司 | High-efficiency curing transfer printing digital roller printing process and equipment |
| CN114083849A (en) * | 2021-10-13 | 2022-02-25 | 广东天进新材料有限公司 | Film with three-dimensional sense and preparation method and application thereof |
| CN116836599A (en) * | 2023-06-30 | 2023-10-03 | 北京梦之墨科技有限公司 | Micro-adhesion release agent and preparation method and application thereof |
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Application publication date: 20140226 |