CN101633826A - Toy glue and method for preparing same - Google Patents
Toy glue and method for preparing same Download PDFInfo
- Publication number
- CN101633826A CN101633826A CN200810063717A CN200810063717A CN101633826A CN 101633826 A CN101633826 A CN 101633826A CN 200810063717 A CN200810063717 A CN 200810063717A CN 200810063717 A CN200810063717 A CN 200810063717A CN 101633826 A CN101633826 A CN 101633826A
- Authority
- CN
- China
- Prior art keywords
- emulsion
- film forming
- toy glue
- toy
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
The invention discloses toy glue and a method for preparing the same. The toy glue comprises the following components in portion by mass: 75 to 98 portions of thermoplastic polymer film forming material, 1 to 5 portions of plasticizer, 0.1 to 2 portions of coloring agent, 1 to 5 portions of moisturizer and 0 to 20 portions of dispersion medium, wherein the film forming material is an poly(methyl) acrylate copolymer emulsion, an styrene-acrylate copolymer emulsion, a polyurethane emulsion, a polyvinyl acetate emulsion and the like; the coloring agent is dye or aqueous dye; and the dispersion medium is water. The method comprises the following steps of: according to the formula, adding the metered water serving as a dispersant in a reaction kettle and starting stirring; adding the metered high polymer emulsion serving as the film forming material and evenly stirring the mixture; adding the metered plasticizer, moisturizer and coloring agent in sequence, adding small amount of auxiliary agent and antiseptic; and evenly stirring the mixed solution, and obtaining the toy glue after discharging and packaging. The colorful toy glue is painted on the smooth surfaces of glass, ceramics, plastics and the like to from bright, three-dimensional, full and vivid patterns which can be stripped and repeatedly painted and is particularly suitable to draw patterns on plastic films that can be transferred to places such as a place before window glass after being dried and re-stuck and are beautiful and interesting.
Description
Technical field
The present invention relates to a kind of toy glue is a kind of hydrate colour ink component and relevant preparation method.
Background technology
The greasepaint of watercolor painting is with water compositing dispersion medium, and binder mixture and various pigment are made.Watercolor painting is widely used and develops by leaps and bounds in China, and (Wang Haitao, watercolor painting is taken root in and develop China.Linyi Normal University's journal, 2002,04).The main component of watercolor painting greasepaint is a water, tackiness agent and tinting pigment.For example, early stage watercolor painting greasepaint uses egg white mediation natural pigment to make, and shortcoming is that cohesive force is poor, and color is not bright-coloured, and advantage is that the feature of environmental protection is good.Applied range, the watercolor that usage quantity is big surely belongs to the advertisement watercolor, and its main component is a water, natural polymer and pigment.So-called natural polymer comprises peach gum, gum arabic and gelatin etc., and its shortcoming is a poor water resistance, quality is low.Now, the watercolor painting greasepaint of better quality makes water, and synthetic water-based polymer and pigment are formed.Synthetic water-based polymer comprises polyvinyl alcohol, polyvinylpyrrolidone, aqurous ployurethane and various emulsion.Its advantage is that cohesive force is good, and water-tolerant especially is suitable for children and learns drawing and recreation use.For example a kind of water-base drawing adhesive (CN1740241A, Huang Xiaoxi, a kind of water-base drawing adhesive) just belongs to this watercolor painting greasepaint.But relate to some composition that should not use in the prescription at articles for children.
Comprehensively above-mentioned, require further improvement.
Summary of the invention
Primary technical problem to be solved by this invention provides a kind of toy glue, and be coated with and be drawn in glass, pottery, on the smooth surfaces such as plastics, it is bright-coloured to form colour, has stereoscopic sensation, and full lively picture can be peeled off and repeat to paste, and especially is fit to children and uses.
Another technical problem to be solved by this invention provides a kind of preparation method of simple and practical toy glue.
The present invention solves the technical scheme that above-mentioned primary technical problem adopts: a kind of toy glue, be that hydrate colour printing ink is to include 75～98 mass fraction thermoplastic polymer film forming matters, 1～5 mass fraction softening agent, 0.1～2 mass fraction tinting materials, 1～5 mass fraction wetting Agent for Printing Inks and 0～20 mass fraction dispersion medium.
The present invention solves the technical scheme that above-mentioned another technical problem adopts: a kind of preparation method of toy glue, it is characterized in that in the preparation still, adding metering dispersion agent water by prescription, open and stir, the polymer emulsion that adds metering as film forming matter, stir, add the softening agent of metering more successively, wetting Agent for Printing Inks and tinting material, drop into a little auxiliary sanitas at last, back discharging packing stirs;
Wherein dispersion medium is a water, and softening agent can be general ester plasticizer, but phthalate should be foreclosed, because of it can have a negative impact to children's health.Here select environment-friendly type citrate derivative, tinting material is pigment or water soluble dyestuffs mill base, wetting Agent for Printing Inks is a glycerine, glycol ether, low molecular poly etc., film forming matter is poly-(methyl) acrylate copolymer emulsion, latex of copolymer in cinnamic acrylic ester, polyurethane(s) emulsion, aqueous polyvinyl acetate emulsion etc., can be wherein a kind of, also can be two or more mixture.
Can further include the essence or/and the sanitas of an amount of umber.
Compared with prior art, the invention has the advantages that: it is coated with and is drawn in glass, and pottery is perhaps on the smooth surface such as plastics, it is bright-coloured to form colour, has stereoscopic sensation, and full lively picture can be peeled off and repeat to paste, the toxicological harmless component especially is fit to children and uses, and method is simple and practical.
Embodiment
Below in conjunction with embodiment the present invention is described in further detail.
Embodiment 1
By prescription 15 kg of water in the preparation still, open and stir, add 78 kilograms of aqueous polyvinyl acetate emulsion (white glues, 55% solid content), stir, add 1 kilogram softening agent tributyl acetylcitrate more successively, 5 kilograms of wetting Agent for Printing Inks glycerine and 0.8 kilogram of red mill base, drop into a little auxiliary (as sanitas) at last, back discharging packing stirs.
Embodiment 2
By prescription 5 kg of water in the preparation still, open and stir, add 95 kilograms of interpolymer latex of polystyrene and acrylic ester (47% solid content), stir, the softening agent tributyl acetylcitrate that adds 1 kilogram more successively, 3 kilograms of wetting Agent for Printing Inks glycerine and 2 kilograms of propylene glycol, 1.5 kilograms of titanium white mill bases, drop into a little auxiliary (as sanitas) at last, back discharging packing stirs.
Embodiment 3
By prescription 10 kg of water in the preparation still, open and stir, add 95 kilograms of interpolymer latex of polystyrene and acrylic ester (47% solid content), stir, the softening agent tributyl acetylcitrate that adds 1 kilogram more successively, 3 kilograms of wetting Agent for Printing Inks glycerine and 2 kilograms of propylene glycol, 1.5 kilograms of titanium white mill bases, drop into a little auxiliary (as sanitas and essence) at last, back discharging packing stirs.
Embodiment 4
By prescription 15 kg of water in the preparation still, open and stir, add 85 kilograms of interpolymer latex of polystyrene and acrylic ester (47% solid content), stir, the softening agent tributyl acetylcitrate that adds 2 kilograms more successively, 3 kilograms of wetting Agent for Printing Inks glycerine, 1.5 kilograms of titanium white mill bases, drop into a little auxiliary (as sanitas and essence) at last, back discharging packing stirs.
Embodiment 5
By prescription 20 kg of water in the preparation still, open and stir, add 75 kilograms of interpolymer latex of polystyrene and acrylic ester (47% solid content), stir, the softening agent tributyl acetylcitrate that adds 5 kilograms more successively, 5 kilograms of wetting Agent for Printing Inks glycerine, 2 kilograms of titanium white mill bases, drop into a little auxiliary (as sanitas and essence) at last, back discharging packing stirs.
Above examples of implementation, toy glue with the present technique preparation, lovely luster has stereoscopic sensation, clean on glass repeat to paste peel off more than 30 times, can be by subzero 10 ℃, 3 hours/room temperature, 3 hours, three round-robin freezing and thawing test, big fire retaining time of drying≤10 minute in the microwave oven, security meets " GB 6675-2003 country toy safety technical specifications ".
Claims (10)
1, a kind of toy glue is characterized in that component includes
75～98 parts of thermoplastic polymer film forming matters;
1～5 part of softening agent;
0.1～2 parts of tinting materials;
1～5 part of wetting Agent for Printing Inks;
0～20 part of dispersion medium;
Above umber is a mass fraction.
2, toy glue according to claim 1, it is characterized in that described film forming matter is poly-(methyl) acrylate copolymer emulsion, latex of copolymer in cinnamic acrylic ester, the polyurethane(s) emulsion, perhaps aqueous polyvinyl acetate emulsion, can be wherein a kind of, also can be two or more mixture.
3, toy glue according to claim 1 is characterized in that described softening agent is general ester plasticizer.
4, toy glue according to claim 1 is characterized in that described tinting material is pigment or water soluble dyestuffs mill base.
5, toy glue according to claim 1 is characterized in that described wetting Agent for Printing Inks is a glycerine, glycol ether, the perhaps polyoxyethylene glycol of lower molecular weight 200～2000.
6, toy glue according to claim 1 is characterized in that described dispersion medium is a water.
7, toy glue according to claim 1 is characterized in that described component also includes the essence or the sanitas of an amount of umber.
8, a kind of preparation method of toy glue, it is characterized in that in the preparation still, adding metering dispersion agent water by prescription, open and stir, the polymer emulsion that adds metering as film forming matter, stir, add the softening agent of metering more successively, wetting Agent for Printing Inks and tinting material, drop into a little auxiliary sanitas at last, back discharging packing stirs;
Each component is:
75～98 parts of thermoplastic polymer film forming matters;
1～5 part of softening agent;
0.1～2 parts of tinting materials;
1～5 part of wetting Agent for Printing Inks;
0～20 part of dispersion medium;
Above umber is a mass fraction.
9, preparation method according to claim 8 is characterized in that described auxiliary agent also includes the essence of an amount of umber.
10, preparation method according to claim 8, it is characterized in that described film forming matter is poly-(methyl) acrylate copolymer emulsion, latex of copolymer in cinnamic acrylic ester, the polyurethane(s) emulsion, perhaps aqueous polyvinyl acetate emulsion, can be wherein a kind of, also can be two or more mixture; Described softening agent is general ester plasticizer; Described tinting material is pigment or water soluble dyestuffs mill base; Described wetting Agent for Printing Inks is a glycerine, glycol ether, the perhaps polyoxyethylene glycol of lower molecular weight 200～2000; Described dispersion medium is a water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200810063717A CN101633826A (en) | 2008-07-25 | 2008-07-25 | Toy glue and method for preparing same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200810063717A CN101633826A (en) | 2008-07-25 | 2008-07-25 | Toy glue and method for preparing same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101633826A true CN101633826A (en) | 2010-01-27 |
Family
ID=41593168
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200810063717A Pending CN101633826A (en) | 2008-07-25 | 2008-07-25 | Toy glue and method for preparing same |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101633826A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102559093A (en) * | 2011-12-23 | 2012-07-11 | 吴江德邦科技化工有限公司 | Binder and production method |
| CN104592912A (en) * | 2015-02-03 | 2015-05-06 | 北京百世邦高科技有限公司 | Modified adhesive for manufacturing formaldehyde-free artificial boards |
| CN105670398A (en) * | 2016-04-14 | 2016-06-15 | 陕西科技大学 | Art masking fluid and preparation method thereof |
| CN108239496A (en) * | 2016-12-23 | 2018-07-03 | 张家港康得新光电材料有限公司 | Maleic anhydride of styrene prepares preparation method, aqueous peelable glue composition and the aqueous peelable glue of amic acid |
| CN108410394A (en) * | 2018-04-02 | 2018-08-17 | 浙江凯达文具用品有限公司 | A kind of water-soluble multifunctional liquid glue and preparation method thereof |
-
2008
- 2008-07-25 CN CN200810063717A patent/CN101633826A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102559093A (en) * | 2011-12-23 | 2012-07-11 | 吴江德邦科技化工有限公司 | Binder and production method |
| CN104592912A (en) * | 2015-02-03 | 2015-05-06 | 北京百世邦高科技有限公司 | Modified adhesive for manufacturing formaldehyde-free artificial boards |
| CN105670398A (en) * | 2016-04-14 | 2016-06-15 | 陕西科技大学 | Art masking fluid and preparation method thereof |
| CN108239496A (en) * | 2016-12-23 | 2018-07-03 | 张家港康得新光电材料有限公司 | Maleic anhydride of styrene prepares preparation method, aqueous peelable glue composition and the aqueous peelable glue of amic acid |
| CN108410394A (en) * | 2018-04-02 | 2018-08-17 | 浙江凯达文具用品有限公司 | A kind of water-soluble multifunctional liquid glue and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101870793B (en) | Self-crosslinking polyacrylate rubber latex, preparation method thereof and water-based paper printing ink | |
| CN105419475B (en) | It is a kind of to exempt from gluing thermal transfer ink with release function | |
| CN102304262B (en) | Self-crosslinked polyacrylate latex and preparation method thereof, and water-based paper ink | |
| CN102718916B (en) | Alcohol-water-soluble vinyl versatate modified vinegar C system acrylic resin and preparation method thereof | |
| CN103602143A (en) | Transfer printing ink with release function | |
| CN101633826A (en) | Toy glue and method for preparing same | |
| CN109825126B (en) | Fluorine-silicon-epoxy modified water-based acrylate emulsion ink special for PVC (polyvinyl chloride) film and preparation method thereof | |
| CN102464938B (en) | Plastic cement list is coated with painted UV radiation curable coating and production thereof, using method | |
| CN102051115A (en) | Ultraviolet light curing colored paint and preparation method thereof | |
| CN103254687B (en) | High-temperature resistant ester-soluble printing ink | |
| CN106349811A (en) | Six-color full-color soft printing ink and preparation method thereof | |
| CN104710717B (en) | Macromolecule clay material | |
| WO2011035522A1 (en) | Resin composition used for peelable coating and compounding process thereof | |
| CN115141512B (en) | Water-based ink for pre-impregnated paper gravure printing and synthesis process thereof | |
| CN106170519A (en) | Black ink composition | |
| CN103254854B (en) | Colored laminating adhesive | |
| CN101511954A (en) | Crayon and method for producing the same | |
| CN103666027A (en) | Blended waterborne photocurable resin material and preparation method thereof | |
| CN111117354A (en) | Water-based propylene marker ink and preparation method thereof | |
| CN112322127A (en) | Water-based paint and application thereof | |
| CN106726694B (en) | Temperature-variable nail film and preparation method thereof | |
| CN102093766B (en) | Crystal picture palettes and preparation method thereof | |
| CN112210316B (en) | Environment-friendly dual-purpose color-changing solid glue stick and preparation method thereof | |
| JPS6040395B2 (en) | Peelable transfer resin composition and transfer painting method | |
| JP2001172540A (en) | Water base printing ink composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Open date: 20100127 |