CN107652761A - It is a kind of to exempt from gluing flexible thermal transfer ink composition and its manufacture method with the viscous function of anti-reflective - Google Patents
It is a kind of to exempt from gluing flexible thermal transfer ink composition and its manufacture method with the viscous function of anti-reflective Download PDFInfo
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- CN107652761A CN107652761A CN201610595960.6A CN201610595960A CN107652761A CN 107652761 A CN107652761 A CN 107652761A CN 201610595960 A CN201610595960 A CN 201610595960A CN 107652761 A CN107652761 A CN 107652761A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
Abstract
Exempt from gluing flexible thermal transfer ink composition with the viscous function of anti-reflective the invention discloses a kind of, include following raw material：40 parts of flexible resin 25 part, 5 parts of vinyl chloride-vinyl acetate resin 1 part, 30 parts of pigment 7 part, 55 parts of mixed solvent 36 part, 2 parts of auxiliary agent 0 part, mute 1 part of powder 0 part, 2 parts of wax powder 0 part, 2 parts of filler 1 part.This exempts to glue flexible thermal transfer ink composition with to leather with the viscous function of anti-reflective, the outstanding cohesive of the flexible macromolecule material such as fabric, it can be effectively simplified the production typography of transfer film, greatly save the production cost of production transfer film, improve the efficiency of printing transfer film, with the pliability not available for other polyacrylic resin system thermal transfer ink, so that the production of multilayer ink transfer film, because the loss of ink film layer rupture is greatly reduced during transport and use, avoid the anti-viscous phenomenon in the printing of polyurethane flexible thermal transfer ink, reduce printing secondary frequencies and loss, improve the production efficiency and benefit of print film.
Description
Technical field
It is more particularly to a kind of to exempt to glue flexible thermal transfer oil with the viscous function of anti-reflective the present invention relates to technical field of ink
Ink composition and its manufacture method.
Background technology
Thermal-printing Technology refer to first by ink by press printing in specific ground (such as polyethylene terephthalate
(PET) film) on transfer film is made, then will print figuratum transfer film by certain temperature and pressure, pattern transferred
A kind of technology onto target ground (such as furniture facade, leather, fabric, macromolecule sheet material, stationery plastic cement etc.).Clamper
Skill can be divided into cold transfer and thermal transfer according to transfer temperature difference, traditional transfer membrane printing process for " PET film/mould release/
Transfer ink/glue " structure, mould release play a part of peeling off with PET film after transfer, if without mould release, use
The technique of PET film/transfer ink/glue, ink layer can occur in transfer and peel off unclean and ink layer with PET film layer
It is very good with PET film layer attachment fastness and peel off do not get off or exerted oneself when peeling off it is excessive cause PET film fracture situations such as.
The various printed patterns of ink layer main composition transfer film.Glue layer then plays the work of cohesive ink layer and final transfer ground
With so that ink logo is firmly attached on ground after transfer.
Although present conventional transfer membrane printing process comparative maturity, its printing process slightly complicated, mould release and glue
Twice print sequence (some need twice glue three must print sequences) is just accounted for, in general six-color printing press can only just leave four
Print sequence does color chromatography, therefore the complicated pattern of any just needs to complete by being printed on the machine twice, compares influence production
Efficiency.Simultaneously because transfer film manufacturer is numerous now, product competition is extremely fierce, therefore each transfer film manufacturer is to drop
The requirement of low cost is very urgent.But if only cost-effective from conventional angle, many bad quality problems can be caused：Subtract
The dosage of few mould release is peeled off not smooth when can cause to transfer；The dosage of less ink can cause colour saturation and vividness inadequate, figure
Case printing is unintelligible；Reducing the dosage of glue can cause to transfer fastness variation.
It is applied to that the product of caloric transfer printing technology is many in the market, but most transfer ground is all the plate of hard
Material, such as various density boards, plastic plate, metallic plate etc., to this, the acrylic resin transfer ink of main flow can great Zhan bodies on the market
Hand.But for some flexible materials, such as leather, fabric, soft rubber etc., after the fragility of acrylic resin in itself can cause transfer
Pattern layer of ink ground bend or rub when ftracture, so as to influence the quality of final products.Therefore for these flexible substrates,
The ink manufactured by flexible resin must be used.
But thermal transfer ink of the conventional flexible resin as manufactured by polyurethane (PU) resin is used, although can be well
Solve the flexible problem being transferred on flexible substrates, but in printing process, due to the presence of mould release, plus poly- ammonia
The viscosity of ester resin in itself, it is easy to make layer of ink be come off with mould release from PET film printing surface when printing and winding, adhere to
On the reverse side of PET film, the adhesion phenomenon of heat transfer film printed is caused, serious meeting makes entire volume print film all scrap.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of exempts to glue flexible thermal transfer oil with what anti-reflective glued function
Ink composition and its manufacture method.
Technical scheme is used by the present invention solves above-mentioned technical problem：
It is a kind of to exempt from gluing flexible thermal transfer ink composition with the viscous function of anti-reflective, include following raw material：Flexible resin
25 parts -40 parts, 1 part -5 parts of vinyl chloride-vinyl acetate resin, 30 parts of pigment 7- parts, 36 parts -55 parts of mixed solvent, 0 part -2 parts of auxiliary agent, mute 0 part of powder -
1 part, 0 part -2 parts of wax powder, 1 part -2 parts of filler.The formula of described thermal transfer ink is due to from excellent to substrate adhesion
Flexible resin, so its applicable heat transfer film print structure is non-traditional for " polyester film/mould release/transfer ink " structure
" polyester film/mould release/transfer ink/glue " structure, so its typography and production cost and efficiency are significantly excellent
In the heat transfer film of traditional structure.
Preferably, described vinyl chloride-vinyl acetate resin is one kind in binary vinyl chloride-vinyl acetate resin and trihydroxylic modification vinyl chloride-vinyl acetate resin
Or two kinds of mixtures, vinyl chloride-vinyl acetate resin all have good compatibility to PU and TPU resins, its preferable hardness can effectively reduce PU
With the viscosity of TPU resins, while chlorine vinegar also have reduce some transfer grounds such as dermatine in plasticizer in ink layer
Migration effect.
It is particularly preferred, include following raw material：25 parts -40 parts of flexible resin, 1 part -5 parts of vinyl chloride-vinyl acetate resin, pigment 7- parts 30
Part, 36 parts -55 parts of mixed solvent, 0 part -2 parts of auxiliary agent, mute 0 part -1 part of powder, 0 part -2 parts of wax powder, 1 part -2 parts of filler.
Particularly preferred, described flexible resin includes polyurethane resin and/or TPUE resin.
Particularly preferred, described flexible resin includes following raw material：Polyurethane resin accounts for 0 part -75 parts, thermoplastic poly ammonia
25 parts -100 parts of ester elastomer resin.
Preferably, in described flexible resin, polyurethane (PU) resin accounts for 0 part -80 parts, TPUE
(TPU) resin accounts for 20 parts -100 parts.PU resins and TPU resins not only have preferable pliability and higher elongation at break,
And soft ground has excellent adhesive force to leather, fabric etc., therefore glue is not needed, the only transfer in HTHP
Under the conditions of can melt and be transferred on ground, layer of ink is just firmly adhered on ground after cooling.But PU resins is anti-stick
Even poor-performing, in ink formulations be used alone can cause printing after layer of ink instead glue phenomenon, so need in formula with TPU
Resin complex uses.The elongation at break and pliability of TPU resins can match in excellence or beauty with PU resins, and most critical is that TPU resins are one
Elastomeric material kind between rubber and plastics, hardness is higher, have PU resins without resistance to blocking.
Preferably, the elongation at break (%) of the polyurethane resin, between 200-800, viscosity is in 800-
Between 6000mPa.s (25 DEG C)；The elongation at break (%) of described TPUE resin 200-700 it
Between, molecular weight is between 30000-300000.The flexible resin of so compounding gained can keep good pliability, again can be with
Take into account anti-reflective viscosity energy.
Particularly preferred, described mixed solvent is ethyl acetate, n-propyl acetate, isopropyl acetate, butyl acetate, first
Two kinds in benzene, butanone, methylisobutylketone, isopropanol, ethanol, propylene glycol monomethyl ether and propylene glycol monomethyl ether acetate or two kinds
Arbitrary proportion above combines.
Particularly preferred, described auxiliary agent is a kind of or more in dispersant, antistatic additive and organosilicon levelling agent
The mixture of kind.
Preferably, 0 part -0.5 part of ink formulations of dispersant addition in the auxiliary agent, 0 part of ink formulations of levelling agent addition -
1 part, antistatic additive adds 0 part -0.5 part of ink formulations.Dispersant can effectively help the pigment in ink to disperse；Levelling agent can be with
Improve the levelling effect of ink picture and text in printing process；Antistatic additive can eliminate the printing event such as electrostatic burr in printing process
Barrier.
Preferably, the dispersant is one kind in polyester-type or polyether-type hyper-dispersant, the antistatic additive is season
Ammonium salt compounds.
Particularly preferred, described mute powder is aerosil.
Particularly preferred, described wax powder is polymer micro mist.
Preferably, the polymer micro mist wax be Tissuemat E, polypropylene wax and polytetrafluoroethylwax wax in one kind or
The mixture of several compositions.Tissuemat E and polytetrafluoroethylwax wax can improve the wearability and anti-reflective viscosity after ink film forming,
Polypropylene wax can be efficiently modified the smoothness of ink film layer.
Particularly preferred, described calcium carbonate, barium sulfate, talcum powder, one or more mixtures in kaolin.
Preferably, described filler is calcium carbonate, barium sulfate, talcum powder, one or more mixtures in kaolin.
Filler, which is dispersed in resin, can play strengthening action, can effectively improve the mechanical strength of ink layer, improve the thixotropy of ink
And printability, while the adhesive of ink also can be effectively reduced, reduction instead glues phenomenon.
Preferably, the pigment includes organic pigment and/or inorganic pigment, the organic pigment is by red pigment, Huang
One or more of compositions in color pigment, blue pigment, viridine green, orange pigment and violet pigment；The inorganic pigment by
One or more of compositions in black pigment, Chinese white, red pigment, yellow uitramarine, blue pigment.
A kind of manufacture method for exempting to glue flexible thermal transfer ink composition that function is glued with anti-reflective, including following step
Suddenly：
Step 1: first by resin and a part of solvent dispersing and dissolving resin liquid；
It is uniformly dispersed Step 2: pigment, auxiliary agent and filler are put into resin liquid；
Step 3: be ground by sand mill it is qualified to fineness；
Step 4: residual solvent, mute powder, wax powder and filler are added, high-speed stirred produces for scattered 20 minutes.
Preferably, the caloric transfer printing technology that the ink is applicable is not more than 220 DEG C of thermal transfer for cold transfer and temperature,
Pressure is 3-10kg/cm2Pressure.
Preferably, it is described as with anti-reflective glue function exempt from glue flexible thermal transfer ink printed by obtained transfer film
Transfer ground be mainly leather, artificial leather, textile cloth, the flexible polymeric material such as rubber and plastic cloth.
Compared with prior art, the present invention has following beneficial effect：
(1) thermal transfer ink of the present invention not only has a conventional transfer ink properties such as colour saturation, vividness,
Excellent printability and heat resistance, but also there is the outstanding cohesive to the flexible macromolecule material such as leather, fabric, it
New " the polyester film/release that production is different from traditional " polyester film/mould release/transfer ink/glue " structure can be used for
The transfer film of agent/transfer ink " structure, the production typography of transfer film is effectively simplified, greatlys save production transfer film
Production cost, improve printing transfer film efficiency.
(2) thermal transfer ink of the present invention has not available for other polyacrylic resin system thermal transfer ink
Pliability so that because the loss of ink film layer rupture is greatly reduced during production, transport and the use of multilayer ink transfer film.
(3) thermal transfer ink of the present invention introduces TPUE resin, and it is soft to avoid polyurethane
Property the printing of thermal transfer ink in anti-viscous phenomenon, reduce printing secondary frequencies and loss, improve print film production efficiency and
Benefit.
Embodiment
The present invention clearly will completely be described below, described embodiment is only the part implementation of the present invention
Example, rather than whole embodiments, based on the embodiment in the present invention, those of ordinary skill in the art are not making creative labor
Other all embodiments obtained under the premise of dynamic, belong to protection scope of the present invention.Agents useful for same or the unreceipted life of instrument
Manufacturer person is produced, can pass through acquisition purchased in market.
The present invention is described in further detail below by specific embodiment.
Embodiment 1
It is a kind of to exempt from gluing flexible thermal transfer ink composition with the viscous function of anti-reflective, include following raw material：Thermoplastic poly
5 parts of urethane elastomer resin, 20 parts of polyurethane resin, 1 part of hydroxyl ternary chlorine vinegar resin, 35 parts of titanium dioxide, alkyl sulfonic acid quaternary ammonium
0.2 part of salt, 0.3 part of organic silicon modified by polyether levelling agent, 1 part of Tissuemat E, 0.5 part of aerosil, 1 part of calcium carbonate, fourth
10 parts of ketone, 6 parts of ethyl acetate, 8 parts of n-propyl acetate, 2 parts of isopropyl acetate, 5 parts of isopropanol, propylene glycol monomethyl ether acetate 5
Part.
This have anti-reflective glue function exempt from glue flexible thermal transfer ink preparation method it is as follows：First by resin and a part
Solvent dispersing and dissolving resin liquid, then pigment, auxiliary agent and filler are put into resin liquid and are uniformly dispersed, then pass through sand milling
It is qualified to fineness that machine is ground, and then adds residual solvent, mute powder, wax powder and filler, and high-speed stirred disperses 20 minutes i.e.
.
Embodiment 2
It is a kind of to exempt from gluing flexible thermal transfer ink composition with the viscous function of anti-reflective, include following raw material：Thermoplastic poly
15 parts of urethane elastomer resin, 25 parts of polyurethane resin, 1 part of hydroxyl ternary chlorine vinegar resin, 1 part of binary chlorine vinegar, pigment Yellow 14 #
7 parts of (organic pigment), 0.5 part of alkyl sulfonic acid quaternary ammonium salt, 0.5 part of polyester type ultra-dispersant agent, 1.5 parts of Tissuemat E, polypropylene wax
0.5 part, 1 part of aerosil, 1 part of barium sulfate, 1 part of kaolin, 10 parts of butanone, 12 parts of ethyl acetate, 11 parts of butyl acetate,
5 parts of ethanol, 3 parts of isopropanol, 4 parts of propylene glycol monomethyl ether.
This have anti-reflective glue function exempt from glue flexible thermal transfer ink preparation method it is as follows：First by resin and a part
Solvent dispersing and dissolving resin liquid, then pigment, auxiliary agent and filler are put into resin liquid and are uniformly dispersed, then pass through sand milling
It is qualified to fineness that machine is ground, and then adds residual solvent, mute powder, wax powder and filler, and high-speed stirred disperses 20 minutes i.e.
.
Embodiment 3
It is a kind of to exempt from gluing flexible thermal transfer ink composition with the viscous function of anti-reflective, include following raw material：Thermoplastic poly
It is 25 parts of urethane elastomer resin, 4 parts of hydroxyl ternary chlorine vinegar resin, 1 part of binary chlorine vinegar, 1 part of paratonere 185# (inorganic pigment), poly-
1 part of ether modified organic silicon levelling agent, 0.5 part of polyether-type hyper-dispersant, 1 part of polytetrafluoroethylwax wax, 0.5 part of aerosil,
1 part of calcium carbonate, 1 part of kaolin, 15 parts of butanone, 15 parts of ethyl acetate, 9 parts of butyl acetate, 10 parts of n-propyl acetate, methyl tert-butyl
6.5 parts of base ketone, 6.5 parts of isopropanol, 3 parts of propylene glycol monomethyl ether acetate.
This have anti-reflective glue function exempt from glue flexible thermal transfer ink preparation method it is as follows：First by resin and a part
Solvent dispersing and dissolving resin liquid, then pigment, auxiliary agent and filler are put into resin liquid and are uniformly dispersed, then pass through sand milling
It is qualified to fineness that machine is ground, and then adds residual solvent, mute powder, wax powder and filler, and high-speed stirred disperses 20 minutes i.e.
.
Embodiment 4
It is a kind of to exempt from gluing flexible thermal transfer ink composition with the viscous function of anti-reflective, include following raw material：Thermoplastic poly
20 parts of urethane elastomer resin, 10 parts of polyurethane resin, 3 parts of hydroxyl ternary chlorine vinegar resin, pigment blue 15:4 (inorganic pigments) 15
Part, 0.5 part of polyester type ultra-dispersant agent, 0.5 part of organic silicon modified by polyether levelling agent, 1 part of Tissuemat E, 1 part of calcium carbonate, talcum powder
0.5 part, 15 parts of butanone, 3 parts of ethanol, 6 parts of ethyl acetate, 7.5 parts of butyl acetate, 15 parts of toluene, propylene glycol monomethyl ether acetate 3
Part.
This have anti-reflective glue function exempt from glue flexible thermal transfer ink preparation method it is as follows：First by resin and a part
Solvent dispersing and dissolving resin liquid, then pigment, auxiliary agent and filler are put into resin liquid and are uniformly dispersed, then pass through sand milling
It is qualified to fineness that machine is ground, and then adds residual solvent, mute powder, wax powder and filler, and high-speed stirred disperses 20 minutes i.e.
.
Thermal transfer ink is made to embodiment 1 to embodiment 4 and carries out performance test, tests assessment method：
1. fineness：Performed according to GB/T13217.3, evaluation result is in units of μ.
2. tinting strength, tinting power：Performed according to GB/T13217.6, evaluation result is in units of %.
3. release：First by transfer ink with opening dilute solvent (ethyl acetate：N-propyl acetate=7:3, mass fraction ratio)
Open dilute to grace 3# flow cups are looked into 16 seconds, then scraped on PET film non-process face with 5# scrapers by from by thermal transfer ink
Sample；It is 180 DEG C that sample, which is scraped, in temperature, and pressure peels off PET film after being transferred under conditions of being 5kg/cm2 in PVC board.Detection
The residual degree of transfer ink in PET film under whether smoothly peeling off and peel off, evaluation result are 1-5 points, and 5 points are smoothly stripping
From and PET film on per 100cm2 ink residues point be no more than 3 points, 1 point can not smoothly to peel off, and often 100cm2 in PET film
More than 20 points of ink residue o'clock.
4. transfer fastness：First by transfer ink with opening dilute solvent (ethyl acetate：N-propyl acetate=7:3, mass fraction
Than) open dilute to grace 3# flow cups are looked into 16 seconds, then carried out on PET film non-process face with 5# scrapers by from by thermal transfer ink
Scrape sample；It is 180 DEG C that sample, which is scraped, in temperature, and pressure peels off PET film after being transferred under conditions of being 5kg/cm2 in PVC board.So
Attachment fastness (referring to GB/T13217.7) with 3M adhesive tapes by cross-cut methods test oil layer of ink afterwards, evaluation result are not fall the effect of ink layer
Lattice number remove in 100.
5. pliability：First by transfer ink with opening dilute solvent (ethyl acetate：N-propyl acetate=7:3, mass fraction ratio)
Open it is dilute then continuously scrape 3 layers of sample with 5# scrapers in PET film to grace 3# flow cups are looked into 16 seconds, then will scrape sample and with the hands rub
Rub with the hands 5 times, observe ink layer of ink rupture event.Evaluation result is 1-5 points, and 5 points are that layer of ink does not rupture completely, and 1 point is that layer of ink is complete
Rupture and come off.
The test result of performance test is carried out to embodiment 1-4 see table 1.
The performance test of the embodiment of table 1.
| Test event | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
| Fineness | The μ of ＜ 18 | The μ of ＜ 15 | The μ of ＜ 15 | The μ of ＜ 15 |
| Tinting strength, tinting power | 95-105% | 95-105% | 95-105% | 95-105% |
| Release | 5 | 5 | 5 | 5 |
| Transfer fastness | >95% | >95% | >95% | >95% |
| Pliability | 5- | 5 | 5 | 5+ |
The present invention is described in detail according to embodiment and comparative example above, but the present invention is not limited to above-mentioned reality
Example and comparative example are applied, in the knowledge that those skilled in the art possess, the premise of present inventive concept can also not departed from
Under make a variety of changes.
Claims (10)
1. a kind of exempt from gluing flexible thermal transfer ink composition with the viscous function of anti-reflective, it is characterised in that includes following raw material：
25 parts -40 parts of flexible resin, 1 part -5 parts of vinyl chloride-vinyl acetate resin, 35 parts of 7 part-part of pigment, 36 parts -55 parts of mixed solvent, 0 part -2 of auxiliary agent
Part, mute 0 part -1 part of powder, 0 part -2 parts of wax powder, 1 part -2 parts of filler.
2. according to claim 1 exempt from gluing flexible thermal transfer ink composition with the viscous function of anti-reflective, its feature exists
In including following raw material：25 parts -40 parts of flexible resin, 1 part -5 parts of vinyl chloride-vinyl acetate resin, 30 parts of pigment 7- parts, 36 parts of mixed solvent -
55 parts, 0 part -2 parts of auxiliary agent, mute 0 part -1 part of powder, 0 part -2 parts of wax powder, 1 part -2 parts of filler.
3. according to claim 1 or 2 exempt from gluing flexible thermal transfer ink composition, its feature with the viscous function of anti-reflective
It is：Described flexible resin includes polyurethane resin and/or TPUE resin.
4. according to claim 3 exempt from gluing flexible thermal transfer ink composition with the viscous function of anti-reflective, its feature exists
In described flexible resin includes following raw material：Polyurethane resin accounts for 0 part -75 parts, TPUE resin 25
- 100 parts of part.
5. according to claim 1 or 2 exempt from gluing flexible thermal transfer ink composition, its feature with the viscous function of anti-reflective
It is：Described mixed solvent is that ethyl acetate, n-propyl acetate, isopropyl acetate, butyl acetate, toluene, butanone, methyl are different
Two or more arbitrary proportion in butanone, isopropanol, ethanol, propylene glycol monomethyl ether and propylene glycol monomethyl ether acetate
Combine.
6. according to claim 1 or 2 exempt from gluing flexible thermal transfer ink composition, its feature with the viscous function of anti-reflective
It is, described auxiliary agent is one or more kinds of mixtures in dispersant, antistatic additive and organosilicon levelling agent.
7. according to claim 1 or 2 exempt from gluing flexible thermal transfer ink composition, its feature with the viscous function of anti-reflective
It is：Described mute powder is aerosil.
8. according to claim 1 or 2 exempt from gluing flexible thermal transfer ink composition, its feature with the viscous function of anti-reflective
It is：Described wax powder is polymer micro mist.
9. according to claim 1 or 2 exempt from gluing flexible thermal transfer ink composition, its feature with the viscous function of anti-reflective
It is：Described calcium carbonate, barium sulfate, talcum powder, one or more mixtures in kaolin.
A kind of 10. system according to claim 3 that exempt to glue flexible thermal transfer ink composition that function is glued with anti-reflective
Make method, it is characterised in that comprise the following steps：
Step 1: first by resin and a part of solvent dispersing and dissolving resin liquid；
It is uniformly dispersed Step 2: pigment, auxiliary agent and filler are put into resin liquid；
Step 3: be ground by sand mill it is qualified to fineness；
Step 4: residual solvent, mute powder, wax powder and filler are added, high-speed stirred produces for scattered 20 minutes.
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|---|---|---|---|
| CN201610595960.6A CN107652761A (en) | 2016-07-25 | 2016-07-25 | It is a kind of to exempt from gluing flexible thermal transfer ink composition and its manufacture method with the viscous function of anti-reflective |
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|---|---|---|---|
| CN201610595960.6A CN107652761A (en) | 2016-07-25 | 2016-07-25 | It is a kind of to exempt from gluing flexible thermal transfer ink composition and its manufacture method with the viscous function of anti-reflective |
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| CN109810575B (en) * | 2018-12-25 | 2021-08-03 | 上海图赢科技发展有限公司 | Washable digital printing inkjet ink for leather, and preparation method and application thereof |
| CN110437674A (en) * | 2019-08-13 | 2019-11-12 | 梁宜信 | A kind of ink and its ink preparation method |
| CN111253797A (en) * | 2020-03-31 | 2020-06-09 | 英科﹒卡乐油墨（苏州）有限公司 | OPP water mark alkali-resistant environment-friendly printing ink |
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