CN105907207A - Environment-friendly low-temperature heat-set type transparent matte gloss oil - Google Patents

Environment-friendly low-temperature heat-set type transparent matte gloss oil Download PDF

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Publication number
CN105907207A
CN105907207A CN201610455624.1A CN201610455624A CN105907207A CN 105907207 A CN105907207 A CN 105907207A CN 201610455624 A CN201610455624 A CN 201610455624A CN 105907207 A CN105907207 A CN 105907207A
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China
Prior art keywords
parts
gloss oil
temperature heat
environment
vinyl chloride
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Pending
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CN201610455624.1A
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Chinese (zh)
Inventor
张东明
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Central Asia Suzhou Ink Co Ltd
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Central Asia Suzhou Ink Co Ltd
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Priority to CN201610455624.1A priority Critical patent/CN105907207A/en
Publication of CN105907207A publication Critical patent/CN105907207A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/20Diluents or solvents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/10Transparent films; Clear coatings; Transparent materials
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses environment-friendly low-temperature heat-set type transparent matte gloss oil. The oil is prepared from, by mass, 7-9 parts of vinyl chloride-vinyl acetate resin liquid, 16-20 parts of polyurethane resin liquid with mass percentage of 30%, 8-10 parts of matting agent, 0.5-2 parts of polyethylene wax, 25-35 parts of n-propyl acetate, 3-5 parts of isopropanol, 0.5-1.5 parts of adhesion promoter and 25-40 parts of acrylic resin. The mass percentage of vinyl chloride-vinyl acetate resin liquid is 20%. Vinyl chloride-vinyl acetate resin powder is dissolved in solvent to be stirred so that vinyl chloride-vinyl acetate resin liquid can be prepared. Solvent is formed by mixing n-propyl acetate with isopropanol according to the mass ratio of 8:2. The problem that gloss oil flexibility is poor when gloss oil is applied to a printed product at low temperature can be remarkably improved, adhesion of the gloss oil is improved, the matte effect required by the printed product is achieved, and weather resistance, waterproofing performance and wear resistance of the printed product are improved.

Description

Environmental protection is low The warm transparent matte gloss oil of curable type
Technical field
The present invention relates to gloss oil technical field, particularly relate to a kind of transparent matte gloss oil of environment-friendly low-temperature heat curing-type.
Background technology
On just print after finishing important means; mainly by being coated with (or spray, print) layer of transparent coating at printed matter surface; through levelling, it is dried, press polish, forms a kind of uniform and thin transparent optical bright layers at printed matter surface after solidification, play technique or the technology of the finish machining functions strengthening carrier surface smoothness, protection printing figure message.Glazing is possible not only to strengthen surface-brightening, protects printing figure message, and does not affect the recycling of paper.Therefore, the Surface Machining of the printings such as packing carton, books, picture album, pictorial poster it is widely used in.Existing transparent matte gloss oil, general thermosetting needs higher temperature, affects the quality of printed matter.
Summary of the invention
The technical problem that present invention mainly solves is to provide a kind of transparent matte gloss oil of environment-friendly low-temperature heat curing-type.
For solving above-mentioned technical problem, the technical scheme that the present invention uses is:
A kind of transparent matte gloss oil of environment-friendly low-temperature heat curing-type is provided, the composition of following mass fraction is prepared from: vinyl chloride-vinyl acetate resin liquid 7 ~ 9 parts, the polyurethane resin liquid 16 ~ 20 parts of 30% mass fraction, flatting silica 8 ~ 10 parts, Tissuemat E 0.5 ~ 2 part, n-propyl acetate 25 ~ 35 parts, isopropanol 3 ~ 5 parts, adhesion promoter 0.5 ~ 1.5 part and acrylic resin 25 ~ 40 parts;The mass fraction of described vinyl chloride-vinyl acetate resin liquid is 20%, uses vinyl chloride-vinyl acetate resin powder to be dissolved in solvent stirring and prepares, and described solvent is that n-propyl acetate mixes according to mass ratio 8:2 with isopropanol.
In a preferred embodiment of the present invention, vinyl chloride-vinyl acetate resin liquid 8 parts, the polyurethane resin liquid 18 parts of 30% mass fraction, flatting silica 9 parts, Tissuemat E 1 part, n-propyl acetate 30 parts, isopropanol 4.5 parts, adhesion promoter 1 part and acrylic resin 30 parts.
In a preferred embodiment of the present invention, the model of described vinyl chloride-vinyl acetate resin is VP-10.
In a preferred embodiment of the present invention, the model of described polyurethane resin is LP-950AL.
In a preferred embodiment of the present invention, the model of described flatting silica is OK-412, for silica.
In a preferred embodiment of the present invention, described Tissuemat E is 3620 polyethylene wax powder.
In a preferred embodiment of the present invention, the model of described adhesion promoter is TU-360.
In a preferred embodiment of the present invention, the model of described acrylic resin is T-212.
The invention has the beneficial effects as follows: the one transparent matte gloss oil of environment-friendly low-temperature heat curing-type of the present invention, the problem that when can significantly improve the printed matter oil polish when temperature is relatively low, gloss oil pliability is poor, improve the adherence of gloss oil simultaneously, meet the effect of dumb light needed for print product, improve the weatherability of printed matter, water proofing property and wearability.
Detailed description of the invention
Below presently preferred embodiments of the present invention is described in detail, so that advantages and features of the invention can be easier to be readily appreciated by one skilled in the art, thus protection scope of the present invention is made apparent clear and definite defining.
Embodiment 1:
A kind of transparent matte gloss oil of environment-friendly low-temperature heat curing-type, is prepared from by the composition of following mass fraction: vinyl chloride-vinyl acetate resin liquid 8 parts, the polyurethane resin liquid 18 parts of 30% mass fraction, flatting silica 9 parts, Tissuemat E 1 part, n-propyl acetate 30 parts, isopropanol 4.5 parts, adhesion promoter 1 part and acrylic resin 30 parts.
The mass fraction of described vinyl chloride-vinyl acetate resin liquid is 20%, uses vinyl chloride-vinyl acetate resin powder to be dissolved in solvent stirring and prepares, and described solvent is that n-propyl acetate mixes according to mass ratio 8:2 with isopropanol.The model of described vinyl chloride-vinyl acetate resin is VP-10, the model of described polyurethane resin is LP-950AL, the model of described flatting silica is OK-412, for silica, described Tissuemat E is 3620 polyethylene wax powder, the model of described adhesion promoter is TU-360, and the model of described acrylic resin is T-212.
Embodiment 2:
A kind of transparent matte gloss oil of environment-friendly low-temperature heat curing-type, is prepared from by the composition of following mass fraction: vinyl chloride-vinyl acetate resin liquid 7.5 parts, the polyurethane resin liquid 19 parts of 30% mass fraction, flatting silica 9.5 parts, Tissuemat E 1.5 parts, n-propyl acetate 32 parts, isopropanol 4 parts, adhesion promoter 1.2 parts and acrylic resin 30 parts.
The model of each composition is with embodiment 1.
Embodiment 3:
A kind of transparent matte gloss oil of environment-friendly low-temperature heat curing-type, is prepared from by the composition of following mass fraction: vinyl chloride-vinyl acetate resin liquid 8.8 parts, the polyurethane resin liquid 17 parts of 30% mass fraction, flatting silica 8.5 parts, Tissuemat E 1 part, n-propyl acetate 30 parts, isopropanol 4.2 parts, adhesion promoter 1 part and acrylic resin 32 parts.
The model of each composition is with embodiment 1.
The preparation method of above three embodiment is as follows:
1) get the raw materials ready, the constituent of formulation weight is weighed standby;
2) configuration vinyl chloride-vinyl acetate resin liquid, first mixes formation solvent by n-propyl acetate and isopropanol according to mass ratio 8:2, after vinyl chloride-vinyl acetate resin powder is mixed with solvent, obtain the vinyl chloride-vinyl acetate resin liquid that mass fraction is 20%;
3) stirring, is mixed and stirred for 2h by polyurethane resin liquid, flatting silica, Tissuemat E, n-propyl acetate, isopropanol and the acrylic resin of the vinyl chloride-vinyl acetate resin liquid of formulation weight number, 30% mass fraction;
4) add adjuvant, adhesion promoter is added in the material that step 3) is formed, continue stirring 30min, obtain finished product.
The foregoing is only embodiments of the invention; not thereby the scope of the claims of the present invention is limited; every equivalent structure utilizing description of the invention content to be made or equivalence flow process conversion; or directly or indirectly it is used in other relevant technical fields, the most in like manner it is included in the scope of patent protection of the present invention.

Claims (8)

1. the transparent matte gloss oil of environment-friendly low-temperature heat curing-type, it is characterized in that, the composition of following mass fraction be prepared from: vinyl chloride-vinyl acetate resin liquid 7 ~ 9 parts, the polyurethane resin liquid 16 ~ 20 parts of 30% mass fraction, flatting silica 8 ~ 10 parts, Tissuemat E 0.5 ~ 2 part, n-propyl acetate 25 ~ 35 parts, isopropanol 3 ~ 5 parts, adhesion promoter 0.5 ~ 1.5 part and acrylic resin 25 ~ 40 parts;The mass fraction of described vinyl chloride-vinyl acetate resin liquid is 20%, uses vinyl chloride-vinyl acetate resin powder to be dissolved in solvent stirring and prepares, and described solvent is that n-propyl acetate mixes according to mass ratio 8:2 with isopropanol.
The transparent matte gloss oil of environment-friendly low-temperature heat curing-type the most according to claim 1, it is characterized in that, vinyl chloride-vinyl acetate resin liquid 8 parts, the polyurethane resin liquid 18 parts of 30% mass fraction, flatting silica 9 parts, Tissuemat E 1 part, n-propyl acetate 30 parts, isopropanol 4.5 parts, adhesion promoter 1 part and acrylic resin 30 parts.
The transparent matte gloss oil of environment-friendly low-temperature heat curing-type the most according to claim 1 and 2, it is characterised in that the model of described vinyl chloride-vinyl acetate resin is VP-10.
The transparent matte gloss oil of environment-friendly low-temperature heat curing-type the most according to claim 1 and 2, it is characterised in that the model of described polyurethane resin is LP-950AL.
The transparent matte gloss oil of environment-friendly low-temperature heat curing-type the most according to claim 1 and 2, it is characterised in that the model of described flatting silica is OK-412, for silica.
The transparent matte gloss oil of environment-friendly low-temperature heat curing-type the most according to claim 1 and 2, it is characterised in that described Tissuemat E is 3620 polyethylene wax powder.
The transparent matte gloss oil of environment-friendly low-temperature heat curing-type the most according to claim 1 and 2, it is characterised in that the model of described adhesion promoter is TU-360.
The transparent matte gloss oil of environment-friendly low-temperature heat curing-type the most according to claim 1 and 2, it is characterised in that the model of described acrylic resin is T-212.
CN201610455624.1A 2016-06-22 2016-06-22 Environment-friendly low-temperature heat-set type transparent matte gloss oil Pending CN105907207A (en)

Priority Applications (1)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106883757A (en) * 2017-03-21 2017-06-23 南宁东印时代广告有限公司 Printed matter oil polish
CN107201121A (en) * 2017-07-04 2017-09-26 苏州中亚油墨有限公司 The anti-skidding matte gloss oil of elastic handfeel
CN107345114A (en) * 2017-08-15 2017-11-14 广西点图包装有限公司 A kind of vial printing oil polish and preparation method thereof
CN107384202A (en) * 2017-08-15 2017-11-24 南宁东印时代广告有限公司 A kind of metope beautification oil polish and preparation method thereof
CN110305528A (en) * 2018-03-20 2019-10-08 深圳正峰印刷有限公司 Surface treating agent and digital printing method for digital printing battery label
CN112552738A (en) * 2020-12-24 2021-03-26 昆山大世界油墨涂料有限公司 Fine flexo printing ink and preparation method thereof
CN116254028A (en) * 2023-03-29 2023-06-13 厦门金汇峰新型包装材料股份有限公司 Matt oils for low surface tension materials, articles and uses thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1807524A (en) * 2006-01-27 2006-07-26 陆中川 Thermosetting ink
CN103333550A (en) * 2013-07-09 2013-10-02 珠海市乐通化工股份有限公司 Novel laminated steel ink and preparation method thereof
CN103342920A (en) * 2013-07-15 2013-10-09 陈图壮 Surface printed solidified matte ink and preparation method thereof
CN104177914A (en) * 2014-07-30 2014-12-03 苏州中亚油墨有限公司 Benzene-free ketone-free single-solvent printing ink and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1807524A (en) * 2006-01-27 2006-07-26 陆中川 Thermosetting ink
CN103333550A (en) * 2013-07-09 2013-10-02 珠海市乐通化工股份有限公司 Novel laminated steel ink and preparation method thereof
CN103342920A (en) * 2013-07-15 2013-10-09 陈图壮 Surface printed solidified matte ink and preparation method thereof
CN104177914A (en) * 2014-07-30 2014-12-03 苏州中亚油墨有限公司 Benzene-free ketone-free single-solvent printing ink and preparation method thereof

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106883757A (en) * 2017-03-21 2017-06-23 南宁东印时代广告有限公司 Printed matter oil polish
CN107201121A (en) * 2017-07-04 2017-09-26 苏州中亚油墨有限公司 The anti-skidding matte gloss oil of elastic handfeel
CN107345114A (en) * 2017-08-15 2017-11-14 广西点图包装有限公司 A kind of vial printing oil polish and preparation method thereof
CN107384202A (en) * 2017-08-15 2017-11-24 南宁东印时代广告有限公司 A kind of metope beautification oil polish and preparation method thereof
CN110305528A (en) * 2018-03-20 2019-10-08 深圳正峰印刷有限公司 Surface treating agent and digital printing method for digital printing battery label
CN112552738A (en) * 2020-12-24 2021-03-26 昆山大世界油墨涂料有限公司 Fine flexo printing ink and preparation method thereof
CN116254028A (en) * 2023-03-29 2023-06-13 厦门金汇峰新型包装材料股份有限公司 Matt oils for low surface tension materials, articles and uses thereof

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Application publication date: 20160831