CN107325654A - A kind of air brushing coating of adaptation Latex inks and preparation method thereof - Google Patents
A kind of air brushing coating of adaptation Latex inks and preparation method thereof Download PDFInfo
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- CN107325654A CN107325654A CN201710538345.6A CN201710538345A CN107325654A CN 107325654 A CN107325654 A CN 107325654A CN 201710538345 A CN201710538345 A CN 201710538345A CN 107325654 A CN107325654 A CN 107325654A
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- 239000011248 coating agent Substances 0.000 title claims abstract description 61
- 238000000576 coating method Methods 0.000 title claims abstract description 61
- 239000000976 ink Substances 0.000 title claims abstract description 56
- 239000004816 latex Substances 0.000 title claims abstract description 37
- 229920000126 latex Polymers 0.000 title claims abstract description 36
- 230000001680 brushing effect Effects 0.000 title claims abstract description 32
- 230000006978 adaptation Effects 0.000 title claims abstract description 11
- 238000002360 preparation method Methods 0.000 title abstract description 5
- 239000000839 emulsion Substances 0.000 claims abstract description 49
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 40
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 29
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 29
- 239000000080 wetting agent Substances 0.000 claims abstract description 21
- 239000004005 microsphere Substances 0.000 claims abstract description 20
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 20
- 229920001909 styrene-acrylic polymer Polymers 0.000 claims abstract description 18
- 241001417490 Sillaginidae Species 0.000 claims abstract description 8
- 238000005703 Whiting synthesis reaction Methods 0.000 claims abstract description 8
- QQGISFDJEJMKIL-JAIQZWGSSA-N (5z)-5-[[3-(hydroxymethyl)thiophen-2-yl]methylidene]-10-methoxy-2,2,4-trimethyl-1h-chromeno[3,4-f]quinolin-9-ol Chemical compound C1=CC=2NC(C)(C)C=C(C)C=2C2=C1C=1C(OC)=C(O)C=CC=1O\C2=C/C=1SC=CC=1CO QQGISFDJEJMKIL-JAIQZWGSSA-N 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 30
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims description 28
- 229940068984 polyvinyl alcohol Drugs 0.000 claims description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 27
- 241000276489 Merlangius merlangus Species 0.000 claims description 12
- 229920000573 polyethylene Polymers 0.000 claims description 7
- 239000002245 particle Substances 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 4
- 238000001914 filtration Methods 0.000 claims description 4
- 239000011148 porous material Substances 0.000 claims description 4
- NECRQCBKTGZNMH-UHFFFAOYSA-N 3,5-dimethylhex-1-yn-3-ol Chemical compound CC(C)CC(C)(O)C#C NECRQCBKTGZNMH-UHFFFAOYSA-N 0.000 claims description 3
- 229910021529 ammonia Inorganic materials 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 238000009413 insulation Methods 0.000 claims description 2
- 240000007594 Oryza sativa Species 0.000 claims 1
- 235000007164 Oryza sativa Nutrition 0.000 claims 1
- FYHXNYLLNIKZMR-UHFFFAOYSA-N calcium;carbonic acid Chemical compound [Ca].OC(O)=O FYHXNYLLNIKZMR-UHFFFAOYSA-N 0.000 claims 1
- 235000013339 cereals Nutrition 0.000 claims 1
- 235000009566 rice Nutrition 0.000 claims 1
- 238000003384 imaging method Methods 0.000 abstract description 3
- 230000002045 lasting effect Effects 0.000 abstract description 3
- 239000003973 paint Substances 0.000 abstract description 3
- 230000003678 scratch resistant effect Effects 0.000 abstract description 2
- 239000003292 glue Substances 0.000 description 32
- 238000007639 printing Methods 0.000 description 22
- 239000002904 solvent Substances 0.000 description 14
- 239000000463 material Substances 0.000 description 11
- 239000007787 solid Substances 0.000 description 11
- 239000004698 Polyethylene Substances 0.000 description 9
- 230000000694 effects Effects 0.000 description 8
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 8
- 239000002994 raw material Substances 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 7
- -1 Polyethylene Polymers 0.000 description 5
- 230000007613 environmental effect Effects 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 239000000498 cooling water Substances 0.000 description 4
- 239000000693 micelle Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 238000009288 screen filtration Methods 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 238000005520 cutting process Methods 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 238000007790 scraping Methods 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 239000004925 Acrylic resin Substances 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 2
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 230000009477 glass transition Effects 0.000 description 2
- 238000005286 illumination Methods 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- CZFMLDUNXATLOW-XKZIYDEJSA-N (5z)-5-[[3-(2-hydroxyethoxymethyl)thiophen-2-yl]methylidene]-10-methoxy-2,2,4-trimethyl-1h-chromeno[3,4-f]quinolin-9-ol Chemical group C1=CC=2NC(C)(C)C=C(C)C=2C2=C1C=1C(OC)=C(O)C=CC=1O\C2=C/C=1SC=CC=1COCCO CZFMLDUNXATLOW-XKZIYDEJSA-N 0.000 description 1
- 229920002799 BoPET Polymers 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920005692 JONCRYL® Polymers 0.000 description 1
- 229910003978 SiClx Inorganic materials 0.000 description 1
- 229920002978 Vinylon Polymers 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 238000006136 alcoholysis reaction Methods 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000007641 inkjet printing Methods 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention belongs to paint field, disclose a kind of air brushing coating of adaptation Latex inks, including 20 ~ 25 parts of powdered whitings, 4 ~ 6 parts of silica, 20 ~ 40 parts of styrene-acrylic emulsions, 20 ~ 40 parts of polyaminoester emulsions, 0.3 ~ 0.8 part of polyvinyl alcohol, 8 ~ 12 parts of wear-resistance microspheres, 0.04~0.06 part of wetting agent.The invention also discloses the preparation method of air brushing coating.The air brushing coating of the present invention adapts to a variety of print media, and imaging is lasting, environmentally friendly, and it is good that scratch-resistant scratches performance.
Description
Technical field
The invention belongs to paint field, specifically a kind of air brushing coating of adaptation Latex inks and preparation method thereof.
Background technology
Main ink type on existing market has solvent-based inks, water-base ink, UV inks.Solvent-based inks can be right
Base material is corroded, and is suitable for many base materials, but due to containing solvent inside its ink, environment is had undesirable effect.It is aqueous
Ink is environmentally friendly, but weather resistance is not enough, generally makees outer indoor printing and uses, because inadequate waterproof is generally also needed to pair
Consumptive material carries out mounting film, adds process and cost.
LATEX inks are a kind of latex type inks, and colorant base material, resin and latex auxiliary agent based on its paint ink are matched somebody with somebody
Side, it has the advantages that solvent-based inks adapt to the diversity and image durability of print media, while having water-base ink again
The characteristics of low damage to equipment and the feature of environmental protection, be a functional ink for representing following printing inkjet direction.
Compared with UV inks, the advantage of Latex inks is mainly reflected in several aspects：
One：The sense of UV print screen ink droplets substantially, while depositing the UV spots of generally existing in industry, influences image quality.UV spot shapes
Into the reason for：The ink that UV is printed, it is desirable to have the time of an of short duration levelling, reuses UV lamp irradiation solidification.Because UV
Lamp is moved with printhead, while inkjet printing is all multiple-pass printing, so UV spots occur.By improving printing
Pass numbers can improve, but can sacrifice cost and efficiency.The problem of Latex inks are then no similar.
Two：Environmental protection：HP Latex use natural emulsion, and ink environmental protection obtains the states such as green guardian, Northern Europe white swan
The top environmental certification in border, can be widely applied among the high industry of the environmental requirement such as fitting-up, wallpaper mural painting.Either beat
During print, or the finished product that printing is completed, all without any peculiar smell.UV ink can all have the smell of comparison stimulus,
The picture that printing is completed in time also can persistently volatilize irritating smell.
Three：Printing effect
1st, HP Latex printheads（Heat foamable）Nozzle quantity is UV printheads（Minute-pressure electricity）More than 2 times；
2nd, HP Latex printheads are lighter than UV printhead（Inertia is small）, can move faster；
3rd, HP Latex printheads are not corrosion-resistant, it is impossible to in UV, Weak solvent, solvent-based inks；
4th, HP Latex ink cureds need heating, have heater and complicated algorithm control, and UV, Weak solvent, solvent inkjet ink
Wetting system does not possess such function.
Due to above reason, will determine HP Latex print speed can be faster than UV.
Latex inks are adapted to indoor and outdoor and used, environmentally friendly using water as ink solvent, for the adaptability of consumptive material
Extensively, good weatherability, combines the advantage of various inks, is welcome by market.This coating is provided simultaneously with into membrane structure and micropore
Structure, can quickly absorb ink, and for printing very dark-toned part, the stereovision that can also do well, image has
Very high vividness, image stabilization and definition, because coating material is very fine and smooth, can match high-precision printing.Due to
Coating also has good water resistance and scraping and wiping resistance performance, and this coating is outdoor indoors to be can be used, this painting wide using scope
Layer may apply to different media up, such as non-woven paper, printing paper, PP classes, PET classes, dry goods.
Since releasing Latex resin ink-jet printers from Hewlett-Packard, Latex can replace solvent-based inks and UV to solidify
Ink is used for exterior durability advertising and printing.Latex ink printeds have been applied on some media, such as art paper, PE
On material, PVC mantles, though its definition is not very high, market segment can receive.And be situated between for the higher printing of some requirements
Matter, such as stationery, PP, PET film, because no coating receives ink, printing effect is not good, and definition is not high, and color is not fresh enough
Gorgeous, demand can not be met.
Currently without the coating of the Latex inks specifically designed for HP, the patent of Application No. 201410126558.4 be
Compatibility Latex ink printeds on the basis of Weak solvent coating are developed, due to the composition and ink-jet of Weak solvent ink and Latex inks
Amount is different, the thickness needed for Weak solvent coating more than 20 microns, for Latex printings need not so thick coating,
It is a kind of waste of cost.
The content of the invention
It is an object of the invention to provide a kind of air brushing coating of adaptation Latex inks, this coating may apply to different
On base material, it is bright-coloured lasting to be showed by Latex ink printeds, rub resistance, the effect of waterproof.
It is a further object of the present invention to provide the preparation method of the air brushing coating.
To reach one of above-mentioned purpose, the present invention uses following technical scheme：
A kind of air brushing coating of adaptation Latex inks, according to parts by weight, including 20 ~ 25 parts of powdered whitings, 4 ~ 6 parts of dioxies
SiClx, 20 ~ 40 parts of styrene-acrylic emulsions, 20 ~ 40 parts of polyaminoester emulsions, 0.3 ~ 0.8 part of polyvinyl alcohol, 8 ~ 12 parts of wear-resistance microspheres, 0.04
~0.06 part of wetting agent.
Further, according to parts by weight, including 23 parts of powdered whitings, 5 parts of silica, 30 parts of styrene-acrylic emulsions, 30
Part polyaminoester emulsion, 0.5 part of polyvinyl alcohol, 10 parts of wear-resistance microspheres, 0.05 part of wetting agent.
Further, the powdered whiting requires that particle diameter accounts for more than 95% less than 2 microns.
Powdered whiting can play a part of absorbing ink, and powdered whiting has the performance of covering, forms coating
Opacity, while keeping high glaze, such Bulk coat is apparent to be opaque and maintains higher glossiness.Heavy carbon
Sour calcium must be 95 ranks（Particle diameter accounts for 95% less than 2 microns）More than, otherwise printing effect is not fine and smooth enough, has and bites phenomenon
Further, the pore volume of the silica is more than 1.8mL/g, and average grain diameter is below 3 microns.
Silica is a kind of loose porous material, and with big pore volume, its unique gap structure can absorb ink
Moisture in water, indiffusion is come, so that ink is quickly combined with coating.
Further, the Tg values of the styrene-acrylic emulsion are -18 DEG C.
Further, the Tg values of the polyaminoester emulsion are 25 DEG C.
Styrene-acrylic emulsion has splendid water-resistance at initial stage and excellent adhesive force, and coating can be promoted closely to be tied with base material
Close.
Polyaminoester emulsion has good filming performance, the film forming of coating when being conducive to being coated with, and stain resistance is strong, resists
Yellow, long-term indoor and outdoor is used, and keeps moisture, the impurity of picture not by environment to be influenceed.
Due to, than relatively low styrene-acrylic emulsion and polyaminoester emulsion, when Latex ink printeds, being printed using glass transition temperature
Machine is in warm-up mode, and the temperature of machine causes both emulsions that soft state is presented, is conducive to coating to be combined with ink, makes
Ink and coating adhesion-tight are obtained, is not easily disconnected from out.
Further, the polythene wax emulsion that the wear-resistance microspheres are 15 ~ 20 microns of particle diameter, fusing point is 140 DEG C（Polyethylene
Wax microballoon is dispersed in water）；Tissuemat E fusing point is general at 90 ~ 120 DEG C, is raised as molecular weight increases, and 140 DEG C belong to high
Fusing point.
Add wear-resistance microspheres, be in order to save cold lamination film, make coating waterproof, it is resistance to while have certain scraping and wiping resistance performance
Grind microspherulite diameter big, be conducive to picture exposed to outside scratch resistance, scrape, will not be also worn with 300 times pictures of brush brush.
Further, the wetting agent is BYK 333, TEGO wet KL 245, Tao Shi X405 or surfynol 440.
Wetting agent is to strengthen the overall flow and spreading property of coating.
Polyvinyl alcohol is that, in order to adjust the viscosity of glue, while strengthening the filming performance of coating, polyvinyl alcohol preferably is
PVA BM-1, can also use other types, alcoholysis degree more than 88%.
A kind of method for preparing above-mentioned air brushing coating, comprises the following steps：
Polyvinyl alcohol and water are mixed under S1, normal temperature, 85 DEG C of insulation 1h are then heated to, 40 DEG C are cooled to, filtering is quiet
Froth breaking is put, poly-vinyl alcohol solution is obtained；
Powdered whiting is added to the water under S2, stirring condition, silica is then added, styrene-acrylic emulsion and poly- ammonia is subsequently added into
Ester emulsion, adds S1 poly-vinyl alcohol solution, is eventually adding wear-resistance microspheres and wetting agent, filtering, stands froth breaking.
The invention has the advantages that：
1st, the diversity of print media is adapted to.Coating can be applied to different base materials up, such as PP, PET, PE, printing paper, nonwoven
Paper, dry goods.
2nd, image durability：Glass Transition Temperature of Latex used in the coating is low, and polymer segment is soft under normal temperature, can
Adhere to well with Latex inks；The emulsion ageing resistace that coating is used is strong, and the pigment and resin in ink are used for a long time
All have no problem, imaging frame stabilization persistently, outer can be used indoors.
3rd, environmentally friendly, air brushing figure layer of the invention does not have the smell of solvent when printing is matched with Latex inks, pair sets
It is standby not injure, either in print procedure, or the finished product that printing is completed, all without any peculiar smell.
4th, scratch-resistant scuffing performance is good, because coating uses the big wear-resistance microspheres of particle diameter, when scraping generation, its microballoon energy
Enough energy for absorbing impact, coating is not in scratch.
Embodiment
With reference to specific embodiment, the present invention is described further.
In following examples, number refers both to parts by weight；Powdered whiting is given birth to for Foshan City South Sea close friend's powder Co., Ltd
The MYJ-98 of production；Silica is the SD640 that Beijing Spaceflight Sai De Powder Material Technology Co., Ltd. produces；Styrene-acrylic emulsion is BASF
The Joncryl 2640 of production；Polyaminoester emulsion is the U57 that ShangHai SiSheng polymer Materials Co., Ltd produces；Polyvinyl alcohol is
The BM-1 of SINOPEC Sichuan Vinylon Factory production；Wear-resistance microspheres be this speciality chemical company of extra large name (ELEMENTIS
SPECIALTIES) the slip-ayd SL300 of production；Wetting agent is BYK 333, the wet KL 245 of TEGO companies production, pottery
The surfynol 440 of the X405 or Air products companies production of family name company production.
Embodiment 1
A kind of air brushing coating of adaptation Latex inks, dry glue ratio is：23 parts of powdered whitings, 5 parts of silica, 30 parts of benzene
Acrylic emulsion, 30 parts of polyaminoester emulsions, 0.5 part of polyvinyl alcohol, 10 parts of wear-resistance microspheres, 0.05 part of wetting agent.
The solid content of powdered whiting is 72%, and the solid content of silica is 100%, and the solid content of styrene-acrylic emulsion is
48.50%, the solid content of polyaminoester emulsion is 50%, and the solid content of poly-vinyl alcohol solution is 15%, and wear-resistance microspheres solid content is 30%,
The solid content of wetting agent is 100%.
According to above solid content, dry glue each component is converted into raw material dosage when S2 feeds intake：30 parts of water, 31.94 parts of weights
Matter calcium carbonate, 5 parts of silica, 61.86 parts of styrene-acrylic emulsions, 60 parts of polyaminoester emulsions, 3.333 parts of polyvinyl alcohol, 33.33 parts it is resistance to
Grind microballoon, 0.05 part of wetting agent.
Air brushing coating glue is prepared according to following steps：
S1, configuration poly-vinyl alcohol solution：Weigh polyethylene alcohol and water（The consumption of water with obtain admittedly contain 15% poly-vinyl alcohol solution
It is advisable）, first add water under normal temperature in glue pot, slow turn on agitator, mixing speed reaches 200r/min, then slowly will
BM-1 micelles are added in glue pot, are kept stirring for and are started to warm up, and be incubated 1 hour until being raised to after 85 DEG C, cooling water is led to afterwards
40 DEG C are cooled to, 200 mesh filter screen filtrations stand froth breaking standby after 24 hours；
S2, raw material being weighed in proportion, first adding water in glue pot, open mixer, it is 700 ~ 800r/min, side to make its rotating speed
Stir side and add powdered whiting, stir 10min, add silica, stir 10min, reduce afterwards rotating speed to 400 ~
500r/min, adds styrene-acrylic emulsion and polyaminoester emulsion while stirring, stirs 20min, is slow added into the poly- second prepared by S1
Enolate solution, stirs 20min, adds wear-resistance microspheres and wetting agent, 30min is stirred together, afterwards with 300 mesh screen pack mistakes
Filter, stands froth breaking standby after 24 hours.
Embodiment 2
A kind of air brushing coating of adaptation Latex inks, dry glue ratio is：20 parts of powdered whitings, 4 parts of silica, 21 parts of benzene
Acrylic emulsion, 22 parts of polyaminoester emulsions, 0.3 part of polyvinyl alcohol, 8 parts of wear-resistance microspheres, 0.04 part of wetting agent.
According to the solid content of embodiment 1, dry glue each component is converted into raw material dosage when S2 feeds intake.
Air brushing coating glue is prepared according to following steps：
S1, configuration poly-vinyl alcohol solution：Weigh polyethylene alcohol and water（The consumption of water with obtain admittedly contain 15% poly-vinyl alcohol solution
It is advisable）, first add water under normal temperature in glue pot, slow turn on agitator, mixing speed reaches 200r/min, then slowly will
BM-1 micelles are added in glue pot, are kept stirring for and are started to warm up, and be incubated 1 hour until being raised to after 85 DEG C, cooling water is led to afterwards
40 DEG C are cooled to, 200 mesh filter screen filtrations stand froth breaking standby after 24 hours；
S2, raw material being weighed in proportion, first adding water in glue pot, open mixer, it is 700 ~ 800r/min, side to make its rotating speed
Stir side and add powdered whiting, stir 10min, add silica, stir 10min, reduce afterwards rotating speed to 400 ~
500r/min, adds styrene-acrylic emulsion and polyaminoester emulsion while stirring, stirs 20min, is slow added into the poly- second prepared by S1
Enolate solution, stirs 20min, adds wear-resistance microspheres and wetting agent, 30min is stirred together, afterwards with 300 mesh screen pack mistakes
Filter, stands froth breaking standby after 24 hours.
Embodiment 3
A kind of air brushing coating of adaptation Latex inks, dry glue ratio is：25 parts of powdered whitings, 6 parts of silica, 40 parts of benzene
Acrylic emulsion, 39 parts of polyaminoester emulsions, 0.7 part of polyvinyl alcohol, 11 parts of wear-resistance microspheres, 0.06 part of wetting agent.
According to the solid content of embodiment 1, dry glue each component is converted into raw material dosage when S2 feeds intake.
Air brushing coating glue is prepared according to following steps：
S1, configuration poly-vinyl alcohol solution：Weigh polyethylene alcohol and water（The consumption of water with obtain admittedly contain 15% poly-vinyl alcohol solution
It is advisable）, first add water under normal temperature in glue pot, slow turn on agitator, mixing speed reaches 200r/min, then slowly will
BM-1 micelles are added in glue pot, are kept stirring for and are started to warm up, and be incubated 1 hour until being raised to after 85 DEG C, cooling water is led to afterwards
40 DEG C are cooled to, 200 mesh filter screen filtrations stand froth breaking standby after 24 hours；
S2, raw material being weighed in proportion, first adding water in glue pot, open mixer, it is 700 ~ 800r/min, side to make its rotating speed
Stir side and add powdered whiting, stir 10min, add silica, stir 10min, reduce afterwards rotating speed to 400 ~
500r/min, adds styrene-acrylic emulsion and polyaminoester emulsion while stirring, stirs 20min, is slow added into the poly- second prepared by S1
Enolate solution, stirs 20min, adds wear-resistance microspheres and wetting agent, 30min is stirred together, afterwards with 300 mesh screen pack mistakes
Filter, stands froth breaking standby after 24 hours.
Embodiment 4
A kind of air brushing coating of adaptation Latex inks, dry glue ratio is：22 parts of powdered whitings, 5 parts of silica, 28 parts of benzene
Acrylic emulsion, 32 parts of polyaminoester emulsions, 0.6 part of polyvinyl alcohol, 9 parts of wear-resistance microspheres, 0.05 part of wetting agent.
According to the solid content of embodiment 1, dry glue each component is converted into raw material dosage when S2 feeds intake.
Air brushing coating glue is prepared according to following steps：
S1, configuration poly-vinyl alcohol solution：Weigh polyethylene alcohol and water（The consumption of water with obtain admittedly contain 15% poly-vinyl alcohol solution
It is advisable）, first add water under normal temperature in glue pot, slow turn on agitator, mixing speed reaches 200r/min, then slowly will
BM-1 micelles are added in glue pot, are kept stirring for and are started to warm up, and be incubated 1 hour until being raised to after 85 DEG C, cooling water is led to afterwards
40 DEG C are cooled to, 200 mesh filter screen filtrations stand froth breaking standby after 24 hours；
S2, raw material being weighed in proportion, first adding water in glue pot, open mixer, it is 700 ~ 800r/min, side to make its rotating speed
Stir side and add powdered whiting, stir 10min, add silica, stir 10min, reduce afterwards rotating speed to 400 ~
500r/min, adds styrene-acrylic emulsion and polyaminoester emulsion while stirring, stirs 20min, is slow added into the poly- second prepared by S1
Enolate solution, stirs 20min, adds wear-resistance microspheres and wetting agent, 30min is stirred together, afterwards with 300 mesh screen pack mistakes
Filter, stands froth breaking standby after 24 hours.
Performance test
Emboss wallpaper：The paper substrate of wallpaper is non-woven paper, and first both are combined with composite glue with cloth with non-woven paper, Ran Houjin
Row surface embossed, then with the air brushing coating glue of 20# bars coating Examples 1, coating weight is in 20 ~ 25g/M2, and machine speed is in 30M/
Min, dry glue is packed in 11G or so, afterwards cutting.
Two generation wallpapers：The difference of two generation wallpapers and embossing wallpaper is not emboss this procedure.The paper substrate of wallpaper is nonwoven
Paper, is first combined both with composite glue with cloth with non-woven paper, then with the air brushing coating adhesive of 20# bars coating Examples 2
Water, coating weight is packed in 20 ~ 25g/M2, machine speed in 30M/min, dry glue in 10G or so, afterwards cutting.
Latex printing paper：There is film PE on printing paper paper substrate, in air brushing coating adhesive of the PE faces with 20# bars coating Examples 3
Water, coating weight is packed in 20 ~ 25g/M2, machine speed in 30M/min, afterwards cutting.
Composite glue is by acrylic resin（Tg：-7℃）Mixed with aluminium hydroxide, acrylic resin plays bonded fabric
With the effect of non-woven paper, aluminium hydroxide plays fireproof effect, and both dry glue ratios are 70：30~60：Between 40.
Printed using HP L26500, effect is as shown in the table：
Lab colour models are by illumination（L）Constituted with tri- key elements of a, b about color.L represents illumination, equivalent to brightness, a
The scope from carmetta to green is represented, b represents the scope from yellow to blueness.L codomain by 0 to 100, L=50 when, with regard to phase
When in 50% it is black；A and b codomain is all, by+127 to -128, wherein+127a is exactly carmetta, to be transitioned into -128a's gradually
When reform into green；Same principle ,+127b is yellow, and -128b is blueness.All colors are just interacted with these three values to be become
Change is constituted, for example, the Lab values of one piece of color are L=100, a=30, b=0, this block color is exactly pink.
As can be known from the above table, the property indices after the printing of air brushing coating（Glossiness, whiteness, color density, LAB values etc.）
It is excellent.
Wallpaper, two generation wallpapers, Latex printing paper is embossed to toast 10 days in 70 DEG C of baking ovens respectively（Equivalent to out of doors use 2
Year）, after tested, glossiness, LAB values, colour gamut etc. are without significant changes, it was demonstrated that imaging is lasting.
The foregoing is only a specific embodiment of the invention, but protection scope of the present invention is not limited thereto, any
Belong to those skilled in the art the invention discloses technical scope in, the change or replacement that can be readily occurred in, all should
It is included within the scope of the present invention.Therefore, protection scope of the present invention should be defined by scope of the claims.
Claims (9)
1. a kind of air brushing coating of adaptation Latex inks, it is characterised in that according to parts by weight, including 20 ~ 25 parts of heavy carbonic acid
Calcium, 4 ~ 6 parts of silica, 20 ~ 40 parts of styrene-acrylic emulsions, 20 ~ 40 parts of polyaminoester emulsions, 0.3 ~ 0.8 part of polyvinyl alcohol, 8 ~ 12 parts it is resistance to
Grind microballoon, 0.04~0.06 part of wetting agent.
2. air brushing coating according to claim 1, it is characterised in that according to parts by weight, including 23 parts of powdered whitings,
5 parts of silica, 30 parts of styrene-acrylic emulsions, 30 parts of polyaminoester emulsions, 0.5 part of polyvinyl alcohol, 10 parts of wear-resistance microspheres, 0.05 part of wetting
Agent.
3. air brushing coating according to claim 1 or 2, it is characterised in that it is micro- that the powdered whiting requires that particle diameter is less than 2
Rice account for more than 95%.
4. air brushing coating according to claim 1 or 2, it is characterised in that the pore volume of the silica is more than 1.8mL/
G, average grain diameter is below 3 microns.
5. air brushing coating according to claim 1 or 2, it is characterised in that the Tg values of the styrene-acrylic emulsion are -18 DEG C.
6. air brushing coating according to claim 1 or 2, it is characterised in that the Tg values of the polyaminoester emulsion are 25 DEG C.
7. air brushing coating according to claim 1 or 2, it is characterised in that the wear-resistance microspheres be 15 ~ 20 microns of particle diameter,
Fusing point is 140 DEG C of polythene wax emulsion.
8. air brushing coating according to claim 1 or 2, it is characterised in that the wetting agent is BYK 333, TEGO wet
KL 245, Tao Shi X405 or surfynol 440.
9. a kind of method of the air brushing coating prepared described in claim 1 or 2, it is characterised in that comprise the following steps：
Polyvinyl alcohol and water are mixed under S1, normal temperature, 85 DEG C of insulation 1h are then heated to, 40 DEG C are cooled to, filtering is quiet
Froth breaking is put, poly-vinyl alcohol solution is obtained；
Powdered whiting is added to the water under S2, stirring condition, silica is then added, styrene-acrylic emulsion and poly- ammonia is subsequently added into
Ester emulsion, adds S1 poly-vinyl alcohol solution, is eventually adding wear-resistance microspheres and wetting agent, filtering, stands froth breaking.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710538345.6A CN107325654B (en) | 2017-07-04 | 2017-07-04 | A kind of air brushing coating and preparation method thereof adapting to Latex ink |
| PCT/CN2017/094300 WO2019006786A1 (en) | 2017-07-04 | 2017-07-25 | Inkjet coating for adapting to latex ink and preparation method therefor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710538345.6A CN107325654B (en) | 2017-07-04 | 2017-07-04 | A kind of air brushing coating and preparation method thereof adapting to Latex ink |
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| CN107325654A true CN107325654A (en) | 2017-11-07 |
| CN107325654B CN107325654B (en) | 2019-07-30 |
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| CN201710538345.6A Withdrawn - After Issue CN107325654B (en) | 2017-07-04 | 2017-07-04 | A kind of air brushing coating and preparation method thereof adapting to Latex ink |
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| WO (1) | WO2019006786A1 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108948908A (en) * | 2018-05-30 | 2018-12-07 | 惠州艺都影像科技有限公司 | A kind of foaming jet drawing material and preparation method thereof |
| CN109251596A (en) * | 2018-07-31 | 2019-01-22 | 安徽鼎兴纺织科技有限公司 | A kind of water-soluble coating material adapting to Latex ink |
| CN113389084A (en) * | 2021-06-17 | 2021-09-14 | 广东希贵光固化材料有限公司 | Melamine impregnated paper body paper printing ink-absorbing coating and preparation method thereof |
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| CN1727203A (en) * | 2004-07-26 | 2006-02-01 | 富士胶片株式会社 | Recording medium, ink composition and recording method using the same |
| CN102796431A (en) * | 2012-09-13 | 2012-11-28 | 惠州艺都影像科技有限公司 | Label film paint and manufacturing method thereof |
| CN104191852A (en) * | 2014-09-01 | 2014-12-10 | 江苏格美高科技发展有限公司 | Ink-jet oil painting canvas and manufacturing method thereof |
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| EP1714792A1 (en) * | 2005-03-28 | 2006-10-25 | Konica Minolta Holdings, Inc. | Inkjet recording medium and method for producing the same |
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| US8361572B2 (en) * | 2009-10-30 | 2013-01-29 | Hewlett-Packard Development Company, L.P. | Coated medium for inkjet printing |
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| CN1727203A (en) * | 2004-07-26 | 2006-02-01 | 富士胶片株式会社 | Recording medium, ink composition and recording method using the same |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108948908A (en) * | 2018-05-30 | 2018-12-07 | 惠州艺都影像科技有限公司 | A kind of foaming jet drawing material and preparation method thereof |
| CN108948908B (en) * | 2018-05-30 | 2020-06-19 | 广东艺都科技有限公司 | Foaming spray-painting material and preparation method thereof |
| CN109251596A (en) * | 2018-07-31 | 2019-01-22 | 安徽鼎兴纺织科技有限公司 | A kind of water-soluble coating material adapting to Latex ink |
| CN113389084A (en) * | 2021-06-17 | 2021-09-14 | 广东希贵光固化材料有限公司 | Melamine impregnated paper body paper printing ink-absorbing coating and preparation method thereof |
Also Published As
| Publication number | Publication date |
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| WO2019006786A1 (en) | 2019-01-10 |
| CN107325654B (en) | 2019-07-30 |
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