CN104369565B - A kind of environmentally friendly high glaze Weak solvent description medium and preparation method thereof - Google Patents
A kind of environmentally friendly high glaze Weak solvent description medium and preparation method thereof Download PDFInfo
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- CN104369565B CN104369565B CN201410126558.4A CN201410126558A CN104369565B CN 104369565 B CN104369565 B CN 104369565B CN 201410126558 A CN201410126558 A CN 201410126558A CN 104369565 B CN104369565 B CN 104369565B
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- weak solvent
- high glaze
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Abstract
The present invention relates to digital image field, discloses a kind of environmentally friendly high glaze Weak solvent description medium and preparation method thereof, environmentally friendly high glaze Weak solvent description medium includes：Base material, adhesion promoting layer, high glaze Weak solvent ink absorbing layer；The one side of the base material is provided with adhesion promoting layer, and the adhesion promoting layer is provided with high glaze Weak solvent ink absorbing layer away from the one side of base material；High glaze Weak solvent ink absorbing layer contains each component of following masses number：64 parts of urethane acrylate modified emulsions, 32 parts of emulsion acrylic resins, 3 parts of antistatic additive, 0.1 part of brightening agent, 0.5 part of levelling agent, 0.2 part of wetting agent, 0.2 part of defoamer.The present invention does not use the organic solvents such as ethanol, methanol, isopropanol in preparation process, eliminates VOC VOC emission；The poisonous and hazardous solvent discharges such as Ketohexamethylene, butanone are eliminated in use, without forced ventilation, solve the easy adhesion of high glaze Weak solvent description medium for using acrylic emulsion to prepare at present, it is impossible to the problem of uncoiling.
Description
Technical field
The present invention relates to digital image field, more particularly to a kind of environmentally friendly bloom for the output of digital image inkjet printing
Damp Weak solvent description medium and preparation method thereof, the description medium have high-resolution, high-weatherability, compatible Weak solvent ink
Water, solvent-based inks, UV solidification inks and Latex inks.
Background technology
Inkjet technology be widely used in culture and propaganda action, advertisement promotion portraiture photography, medical imaging, industrial image and
The fields such as military image.With the progress of digital ink-jet printing technique, the resolution, weatherability, resistance to purple to ink-jet printing media
Outer property, absorbency, ink dried rate request more and more higher, particularly to the volatile organic compound during production, use
The restriction of thing VOC emission is more and more stricter.
At present, the ink-jet printing media that open air uses is polrvinyl chloride spray painting cloth and Weak solvent ink-jet printing media.Polychlorostyrene
Ethylene spray painting cloth adopts polrvinyl chloride and substantial amounts of plasticizer to make, and this ink-jet printing material good weatherability, intensity are high, but beat
Print precision is not high, is only used for outdoor long sight distance advertisement；And polrvinyl chloride spray painting cloth is printed using solvent-based inks, in ink
Containing the poisonous organic solvent such as Ketohexamethylene, VOC VOC emission amount is big, production environment tanginess, must force
Ventilation, European Union have limited the use of this kind of ink-jet printing material；Additionally, polrvinyl chloride spray painting cloth is unable to reclaiming, at landfill
Reason is difficult natural degradation, and burning disposal can discharge substantial amounts of strong carcinogen bioxin.Weak solvent ink-jet printing media be
Weak solvent is coated on the materials such as PET film, PP synthetic papers, RC paper substrates and prints coating, the ink environment for using is friendly, without hexamethylene
The poisonous organic solvent such as ketone, and VOC VOC emission amount is extremely low, weather resistance is good, print resolution is high, can
1440dpi is reached, and overlay film is not necessary to for outdoor advertising.
Very widely used today Weak solvent ink-jet printing media, is divided into bloom Weak solvent ink-jet printing media and sub- light is weak molten
Agent ink-jet printing media, such as patent CN200510094318.1, CN201110311377.5,201210336950.2, describe
The method that polyvinyl butyral resin prepares Weak solvent ink-jet printing material, in a large number using ethanol, methanol, isopropanol, acetone as
The solvent of polyvinyl butyral resin, VOC VOC emission amount is very big in process of production, not only high cost, and
Explosive mixture is easily formed in process of production, there is potential safety hazard.Simultaneously as its polyvinyl alcohol used in formula
Butyral does ink-absorbed coated layer, bad to solvent-based inks compatibility, and blotting is poor, is dried slow.
So far, the high glaze Weak solvent description medium that prepared by water-based emulsion does not have product to appear on the market, and has no related report yet
Road.This is because being acrylic acid ester emulsion the emulsion used by environmentally friendly Weak solvent description dielectric coated is prepared, have the disadvantage cold short
It is hot sticky, easily return viscous when making high gloss coating, reel and product can be made to be sticked together, uncoiling resistance is greatly so as to affecting to print essence
Degree, or be unable to uncoiling and scrap.Sub- light Weak solvent ink-jet printing media, such as patent can only be prepared with water-based emulsion
CN201210181350.3, describes a kind of environmentally-frieweak weak solvent type inkjet carrier material of aqueous, environmental protective, although the light of undeclared coating
Damp degree, but due to adding SD-640 silica gel（Beijing Space Saden product, 8 microns of mean diameter）As ink absorbent, it is known that should
Coating is sub- light Weak solvent ink-jet printing media.It would therefore be highly desirable to a kind of environmentally friendly high glaze Weak solvent description medium and its preparation side
Method.
The content of the invention
The purpose of the present invention is：Viscous, shadow is easily returned when high glaze Weak solvent coating is made in order to solve existing water-based emulsion
Ring the technical problem that printing precision even results in product rejection, there is provided a kind of environmentally friendly high glaze Weak solvent description medium and its preparation
Method.
To reach above-mentioned purpose, the technical solution used in the present invention is：Disclose a kind of environmentally friendly high glaze Weak solvent description
Medium, including：Base material 3, adhesion promoting layer 2, high glaze Weak solvent ink absorbing layer 1；The one side of the base material 3 is provided with attachment and makes every effort to promote
Enter layer 2, the adhesion promoting layer 2 is provided with high glaze Weak solvent ink absorbing layer 1 away from the one side of base material 3；The high glaze is weak molten
Each component of the agent ink absorbing layer 1 containing following masses number：64 parts of urethane acrylate modified emulsions, 32 parts of acrylic resin breasts
Liquid, 3 parts of antistatic additive, 0.1 part of brightening agent, 0.5 part of levelling agent, 0.2 part of wetting agent, 0.2 part of defoamer.
Wherein, the urethane acrylate modified emulsion is：Blending and modifying emulsion or modification by copolymerization emulsion.Because blending changes
Property emulsion is sensitive to auxiliary agent, stability is poor, the urethane acrylate modified emulsion preferably modification by copolymerization emulsion.
Wherein, the emulsion acrylic resin is pure-acrylic emulsion or copolymer emulsion；The pure-acrylic emulsion be styrene-acrylic emulsion, institute
Copolymer emulsion is stated for acrylonitrile/acrylate copolymer emulsion.The glass temperature range of the emulsion acrylic resin is 23～
98 DEG C, preferably 50～70 DEG C.
Wherein, the antistatic additive is anion or non-ionic antistatic agent, specially fatty alcohol ether phosphate kalium salt, fat
Fat alcohol ether phosphate, polyoxyethylene, polyethylene glycol oxide Arrcostab, alkylbenzenesulfonate or sorbitol anhydride fatty acid
Ester.
Wherein, the brightening agent be water soluble fluorescers, preferably VBL.
Wherein, the levelling agent, wetting agent, defoamer are anion or nonionic common agent.
Wherein, the base material 3 is reel RC printing paper paper substrates, PET film, Dampler Ace, canvas cloth base, non-woven fabrics
Or Du Pont's cloth each web base material.
Wherein, to be coated in the coating formed on base material 3, its composition is polyaminoester emulsion group to the adhesion promoting layer 2
Compound, acrylic emulsion composition, Chlorinated Polypropylene Emulsions compositionss or aqueous titanic acid fat.Purpose is to increase high glaze ink absorbing layer
The adhesive force of 1 pair of various base material.
Wherein, when the adhesion promoting layer 2 is polyaminoester emulsion compositionss, each component containing following masses number：
50 parts of polyaminoester emulsions, 26.6 parts of deionized waters, 0.1 part of defoamer, 0.1 part of wetting agent.
The preparation method of medium the invention also discloses a kind of environmentally friendly high glaze Weak solvent is drawn a portrait, comprises the following steps：
Step 1：Corona impact is carried out to the cloth cover to be coated of base material 3, in the corona surface coating adhesion promoting layer 2 of base material 3,
Coating layer thickness is 3-5 μm, and after forming adhesion promoting layer, 2 are dried coating into baking oven；
Step 2：It is coated in dry 2 upper surface of adhesion promoting layer, forms high glaze Weak solvent ink absorbing layer 3；
Step 3：After the completion of high glaze Weak solvent ink absorbing layer 3 is coated with, into oven drying, build is obtained for 15～35
μm high glaze Weak solvent ink absorbing layer 1, then it is rolling, cut, be packaged to be high glaze Weak solvent description medium finished product.
Wherein, the coating method in step 1 is kiss painting, light scraper or anilox roll rubbing method, preferably optical wand rubbing method, this
Plant coating method and can obtain relatively thin and uniform coating, and be not likely to produce bubble；Coating method in step 2 is scraped for comma
Knife, silk rod, kiss are applied, dropping curtain or slope flow squeezing and pressing method, and preferred comma scraper coating method, which are full-bodied suitable for large arch dam
Coating, can improve speed with reducing energy consumption；In step 3, build is 23～28 μm, the image dried printed during less than 23 μm
Speed slows down, and higher than 28 μm, then the increase of image dried speed is not obvious, and increases cost.
The invention has the beneficial effects as follows：The present invention does not use ethanol, methanol, isopropanol, isobutanol etc. in preparation process
Organic solvent, eliminates VOC VOC emission, provides the environment of safety and environmental protection to production；Meanwhile, using process
The poisonous and hazardous solvent discharges such as middle elimination Ketohexamethylene, butanone, without forced ventilation, provide the work of health environment-friendly to operator
Environment, solve the easy adhesion of high glaze Weak solvent description medium for using at present acrylic emulsion to prepare, it is impossible to which uncoiling is asked
Topic.
Description of the drawings
Fig. 1 is a kind of structural representation of environmentally friendly high glaze Weak solvent description medium of the present invention.
Accompanying drawing is identified：1- high glaze Weak solvent ink absorbing layers, 2- adhesion promoting layer, 3- base materials.
Specific embodiment
The present invention is described in detail with reference to the accompanying drawings and examples.
A kind of environmentally friendly high glaze Weak solvent description medium of the present invention, including：Base material 3, adhesion promoting layer 2, high glaze are weak
Solvent ink absorbing layer 1；The one side of the base material 3 is provided with adhesion promoting layer 2, one side of the adhesion promoting layer 2 away from base material 3
It is provided with high glaze Weak solvent ink absorbing layer 1；1 each component containing following masses number of high glaze Weak solvent ink absorbing layer：64 parts
Urethane acrylate modified emulsion, 32 parts of emulsion acrylic resins, 3 parts of antistatic additive, 0.1 part of brightening agent, 0.5 part of levelling
Agent, 0.2 part of wetting agent, 0.2 part of defoamer.
The urethane acrylate modified emulsion is：Blending and modifying emulsion or modification by copolymerization emulsion.Because of blending and modifying breast
Liquid is sensitive to auxiliary agent, stability is poor, and the urethane acrylate modified emulsion is preferably modification by copolymerization emulsion.
The emulsion acrylic resin is pure-acrylic emulsion or copolymer emulsion；The pure-acrylic emulsion is styrene-acrylic emulsion, described common
Poly- emulsion is acrylonitrile/acrylate copolymer emulsion.The glass temperature range of the emulsion acrylic resin is 23～98 DEG C,
Preferably 50～70 DEG C.
The antistatic additive is anion or non-ionic antistatic agent, specially fatty alcohol ether phosphate kalium salt, fatty alcohol
Ether phosphate, polyoxyethylene, polyethylene glycol oxide Arrcostab, alkylbenzenesulfonate or sorbitan fatty acid ester.
The brightening agent be water soluble fluorescers, preferably VBL.
The levelling agent, wetting agent, defoamer are anion or nonionic common agent.
The base material 3 is reel RC printing paper paper substrates, PET film, Dampler Ace, canvas cloth base, non-woven fabrics or Du
Nation's cloth each web base material.
The adhesion promoting layer 2 to be coated in the coating formed on base material 3, its composition be polyaminoester emulsion compositionss,
Acrylic emulsion composition, Chlorinated Polypropylene Emulsions compositionss or aqueous titanic acid fat.It is each that purpose is to increase high glaze ink absorbing layer 1 pair
Plant the adhesive force of base material.
When the adhesion promoting layer 2 is polyaminoester emulsion compositionss, each component containing following masses number：50 parts are gathered
Urethane emulsion, 26.6 parts of deionized waters, 0.1 part of defoamer, 0.1 part of wetting agent.
Embodiment 1
A kind of preparation method of environmentally friendly high glaze Weak solvent description medium of the present invention, comprises the following steps：
Step 1：Base material 3 prepares；Using double light PP synthetic papers in South Asia, 140 μm of thickness, width 1.29m, length 3000m.
Step 2：2 coating preparation of adhesion promoting layer；Weigh 50kg polyaminoester emulsions, 26.6kg deionized waters, 0.1kg to disappear
Infusion, 0.1kg wetting agent, above-mentioned each component is sequentially added in the charging basket processed with stirring, starts agitator, stirs 0.5h,
Material mix homogeneously is made, is filtered with 200 mesh filter screens, loaded storage barrel interior sealing and preserve use to be coated.
Step 3：It is prepared by high glaze Weak solvent ink absorbing layer 3；64kg urethane acrylate modified emulsions are weighed first, are added
In mixer, agitator is started, revolution is set to into 400RPM（Can not be too fast, it is to avoid produce foam）；Then in order successively
Add following material：32kg acrylic emulsions, 3kg antistatic additive, 0.1kg brightening agents, 0.5kg levelling agents, 0.2kg wetting agent,
0.2kg defoamer, often adds a kind of component, adds next component after stirring 10min, and stirring mixing 40min, makes each component altogether
Mix homogeneously, then 300 mesh silk screen filters of Jing, sealing preserve use to be coated.
Step 4：Adhesion promoting layer coating 2；The coated face of base material 3 is carried out into sided corona treatment, then using on reverse roll
Material, obtains being coated with the attached of 3～5 μm of build with optical wand coating method coating adhesion promoting layer 2, Jing oven dryings is reversed
Put forth effort to promote layer 2.
Step 5：High glaze Weak solvent ink absorbing layer 1 is coated with：Using comma scraper coating method, adhesion promoting layer 2 it
Upper coating high glaze Weak solvent ink absorbing layer 1, Jing oven dryings obtain the high glaze Weak solvent ink absorbing layer of 20 μm of build, then Jing
Cross winding, cutting, rewinding and obtain high glaze Weak solvent description medium finished product.
Embodiment 2
A kind of preparation method of environmentally friendly high glaze Weak solvent description medium of the present invention, comprises the following steps：
Step 1：Base material 3 prepares；Using double light PP synthetic papers in South Asia, 140 μm of thickness, width 1.29m, length 3000m.
Step 2：2 coating preparation of adhesion promoting layer；Weigh 50kg polyaminoester emulsions, 26.6kg deionized waters, 0.1kg to disappear
Infusion, 0.1kg wetting agent, above-mentioned each component is sequentially added in the charging basket processed with stirring, starts agitator, stirs 0.5h,
Material mix homogeneously is made, is filtered with 200 mesh filter screens, loaded storage barrel interior sealing and preserve use to be coated.
Step 3：It is prepared by high glaze Weak solvent ink absorbing layer 3；64kg urethane acrylate modified emulsions are weighed first, are added
In mixer, agitator is started, revolution is set to into 400RPM（Can not be too fast, it is to avoid produce foam）；Then in order successively
Add following material：32kg acrylic emulsions, 3kg antistatic additive, 0.1kg brightening agents, 0.5kg levelling agents, 0.2kg wetting agent,
0.2kg defoamer, often adds a kind of component, adds next component after stirring 10min, and stirring mixing 40min, makes each component altogether
Mix homogeneously, then 300 mesh silk screen filters of Jing, sealing preserve use to be coated.
Step 4：Adhesion promoting layer coating 2；The coated face of base material 3 is carried out into sided corona treatment, then using on reverse roll
Material, obtains being coated with the attached of 3～5 μm of build with optical wand coating method coating adhesion promoting layer 2, Jing oven dryings is reversed
Put forth effort to promote layer 2.
Step 5：High glaze Weak solvent ink absorbing layer 1 is coated with：Using comma scraper coating method, adhesion promoting layer 2 it
Upper coating high glaze Weak solvent ink absorbing layer 1, Jing oven dryings obtain the high glaze Weak solvent ink absorbing layer of 30 μm of build, then Jing
Cross winding, cutting, rewinding and obtain high glaze Weak solvent description medium finished product.
The high glaze Weak solvent description medium of environmental protection of the invention, it is adaptable to Weak solvent ink, solvent-based inks, UV solidification inks
With latex inks.Using military rattan VJ-1204E description machine testings, printing precision can reach 1440dpi.
1 ink dried speedometer of table
The high glaze Weak solvent description medium of environmental protection of the invention, returns viscous experiment, laser heating 80 in 75 DEG C of baking oven
Hour, without sound during uncoiling, print uncoiling smoothly, have no adhesion.In 85 DEG C of baking ovens, laser heating 80 hours has during uncoiling
Extremely slight sound, coating surface gloss have no destruction, print uncoiling smoothly, have no adhesion.
Above content is the further description done to the present invention with reference to optimal technical scheme, it is impossible to assert invention
It is embodied as being only limitted to these explanations.For general technical staff of the technical field of the invention, without departing from the present invention
Design on the premise of, can also make it is simple deduce and replace, should all be considered as protection scope of the present invention.
Claims (6)
1. a kind of environmentally friendly high glaze Weak solvent is drawn a portrait medium, including：Base material (3), adhesion promoting layer (2), high glaze Weak solvent
Ink absorbing layer (1)；The one side of the base material (3) is provided with adhesion promoting layer (2), and the adhesion promoting layer (2) is away from base material (3)
One side be provided with high glaze Weak solvent ink absorbing layer (1)；Characterized in that, the high glaze Weak solvent ink absorbing layer (1) is containing following
The each component of mass fraction：64 parts of urethane acrylate modified emulsions, 32 parts of emulsion acrylic resins, 3 parts of antistatic additive,
0.1 part of brightening agent, 0.5 part of levelling agent, 0.2 part of wetting agent, 0.2 part of defoamer；
The adhesion promoting layer (2) is polyaminoester emulsion compositionss, each component containing following masses number：50 parts of polyurethane
Emulsion, 26.6 parts of deionized waters, 0.1 part of defoamer, 0.1 part of wetting agent.
2. environmentally friendly high glaze Weak solvent according to claim 1 is drawn a portrait medium, it is characterised in that the polyurethane acroleic acid
Ester modified emulsion is：Blending and modifying emulsion or modification by copolymerization emulsion.
3. environmentally friendly high glaze Weak solvent according to claim 1 is drawn a portrait medium, it is characterised in that the acrylic resin breast
Liquid is pure-acrylic emulsion or copolymer emulsion；The pure-acrylic emulsion be styrene-acrylic emulsion, the copolymer emulsion be acrylonitrile/acrylate be total to
Poly- emulsion.
4. environmentally friendly high glaze Weak solvent according to claim 1 is drawn a portrait medium, it is characterised in that the antistatic additive is cloudy
Ion or non-ionic antistatic agent, specially fatty alcohol ether phosphate kalium salt, fatty alcohol ether phosphate ester, polyoxyethylene allylic alkylation
Amine, polyethylene glycol oxide Arrcostab, alkylbenzenesulfonate or sorbitan fatty acid ester.
5. environmentally friendly high glaze Weak solvent according to claim 1 is drawn a portrait medium, it is characterised in that the brightening agent is water-soluble
Property fluorescent whitening agent.
6. environmentally friendly high glaze Weak solvent according to claim 1 is drawn a portrait medium, it is characterised in that the base material (3) is volume
Cylinder RC printing paper paper substrates, PET film, Dampler Ace, canvas cloth base, non-woven fabrics or Du Pont's cloth each web base material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410126558.4A CN104369565B (en) | 2014-03-31 | 2014-03-31 | A kind of environmentally friendly high glaze Weak solvent description medium and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410126558.4A CN104369565B (en) | 2014-03-31 | 2014-03-31 | A kind of environmentally friendly high glaze Weak solvent description medium and preparation method thereof |
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| Publication Number | Publication Date |
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| CN104369565A CN104369565A (en) | 2015-02-25 |
| CN104369565B true CN104369565B (en) | 2017-04-05 |
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| CN201410126558.4A Expired - Fee Related CN104369565B (en) | 2014-03-31 | 2014-03-31 | A kind of environmentally friendly high glaze Weak solvent description medium and preparation method thereof |
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Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105297437A (en) * | 2015-11-17 | 2016-02-03 | 无锡凤凰画材有限公司 | Rapid-drying canvas |
| CN108778765B (en) * | 2016-04-20 | 2021-02-19 | 惠普印迪戈股份公司 | Scraping structure |
| CN106117587A (en) * | 2016-08-19 | 2016-11-16 | 上海谷奇数码科技有限公司 | Erect image multi-functional Weak solvent printed material, the preparation method of printed material and card |
| CN106221468A (en) * | 2016-08-19 | 2016-12-14 | 上海谷奇数码科技有限公司 | Multi-functional Weak solvent prints coating and preparation method thereof |
| CN106117586A (en) * | 2016-08-19 | 2016-11-16 | 上海谷奇数码科技有限公司 | Mirror image multi-functional Weak solvent printed material, the preparation method of printed material and card |
| CN107325654B (en) * | 2017-07-04 | 2019-07-30 | 广东艺都科技股份有限公司 | A kind of air brushing coating and preparation method thereof adapting to Latex ink |
| CN108486904A (en) * | 2018-03-31 | 2018-09-04 | 江苏奥力广告材料股份有限公司 | A kind of advertising scroll cloth and its production method |
| CN109251596A (en) * | 2018-07-31 | 2019-01-22 | 安徽鼎兴纺织科技有限公司 | A kind of water-soluble coating material adapting to Latex ink |
| CN110904726B (en) * | 2019-12-06 | 2022-05-03 | 广东艺都科技有限公司 | High-gloss weak solvent composition, preparation method and application thereof |
| CN112356590B (en) * | 2020-11-09 | 2022-05-27 | 山东胜通光学材料科技有限公司 | Production method of special enhanced printing base film for electronic tag |
| CN115029076B (en) * | 2022-06-15 | 2023-06-20 | 广东艺都科技有限公司 | Non-substrate spray painting film and preparation method thereof |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3924913B2 (en) * | 1998-04-20 | 2007-06-06 | 凸版印刷株式会社 | Ink jet recording medium and manufacturing method thereof |
| CN1928710A (en) * | 2005-09-08 | 2007-03-14 | 李剑平 | Weak solvent digital colorful spray photographic paper |
| US8628833B2 (en) * | 2007-04-23 | 2014-01-14 | Hewlett-Packard Development Company, L.P. | Stackable ink-jet media |
| CN102501675A (en) * | 2011-10-14 | 2012-06-20 | 江苏格美高科技发展有限公司 | Matte polypropylene inkjet photo paper suitable for ECO-solvent ink |
| CN102658744A (en) * | 2012-06-05 | 2012-09-12 | 江苏泰特尔化工有限公司 | Water-based and environmentally-friendly weak solvent type inkjet carrier material |
| CN103045044B (en) * | 2012-12-12 | 2016-03-16 | 滁州市宏源喷涂有限公司 | Powder coating of a kind of energy-conserving and environment-protective and preparation method thereof |
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