CN103694788B - Special-purpose aqueous foam ink of a kind of wallpaper intaglio printing and preparation method thereof - Google Patents
Special-purpose aqueous foam ink of a kind of wallpaper intaglio printing and preparation method thereof Download PDFInfo
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- CN103694788B CN103694788B CN201310625096.6A CN201310625096A CN103694788B CN 103694788 B CN103694788 B CN 103694788B CN 201310625096 A CN201310625096 A CN 201310625096A CN 103694788 B CN103694788 B CN 103694788B
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Abstract
The present invention relates to special-purpose aqueous foam ink of a kind of foaming wallpaper and preparation method thereof. Described formula comprises following component and mass fraction: waterborne film-forming emulsion 30-40%; Distilled water 40-50%; Moistening flatting agent 0.5-5%; Defoamer 0.1-1%; Pigment 5-10%; Blowing agent 1-5%; Dispersant 1-5%; Thickener 1-5%; Its processing technology, for to get raw material according to described parts by weight, adds described waterborne film-forming emulsion in agitator and stirs, and described pigment, dispersant, blowing agent are added in waterborne film-forming emulsion, stirs; Mixture in agitator is carried out to speed lapping with milling apparatus; After grinding finishes, more described distilled water, moistening flatting agent, defoamer, thickener are added in agitator, stir; Finally filter, obtain aqueous foaming ink. The present invention adopts aqueous solvent, pollution-free to air, and realizes three-dimensional foaming effect after can allowing common wallpaper print this aqueous foaming ink, not only good permeability, and wallpaper surface scrubbing resistance, and also resistance to extruding is indeformable.
Description
Technical field
The present invention relates to special aqueous foaming ink of a kind of wallpaper intaglio printing and preparation method thereof.
Background technology
Along with the development of national economy and the raising of living standards of the people, shiploads of merchandise house and hotel, exhibitionLook at the emerging in large numbers of shop, people improve constantly the requirement of house decorative material, and foaming wallpaper is as the weight of Modern Interior Decoration materialWant part to be more and more subject to people's attention. Because foaming wallpaper has good decorative effect, the convenient and environmental protection of constructingFeature obtain applying more and more widely. From at first in hotel, the public arena such as office building, show room, come by nowBe applied to more in large quantities ordinarily resident's house. But traditional wallpaper use foam ink adopts physical blowing principle, useMicroballoon blowing agent is realized foaming effect, has resistance to soiling, the poor problem of scratch resistance. And the goods of employing CBACan address these problems, existingly in the industry adopt chemical blowing ink printing that polyvinyl chloride paste is carrier on wallpaper, butBe because needs adopt a large amount of plasticizer and toxic solvent, application is restricted. Therefore, solve CBA withThe compatibility of water color ink is the focus of sector application always.
Summary of the invention
In order to realize above-mentioned effect, the invention provides a kind of wallpaper intaglio printing special aqueous foaming ink and system thereofPreparation Method. This ink adopts CBA TSH, and abscess is trickle seal, and shrinkage factor is little, and printing fashion is to version, resistance toWater-based is good, and it is low to compare AC blowing agent blowing temperature, energy-conserving and environment-protective, and goods are difficult for jaundice.
The present invention solves the scheme that its technical problem adopts: the aqueous foaming oil that a kind of wallpaper intaglio printing is specialChina ink, it by the raw material of following parts by weight add in agitator through mixing, stirring obtains:
Excellent preferred, described waterborne film-forming emulsion is aqueous acrylic emulsion, solid content 45～48%, and acid number 30～60mgKOH/g, 20～40 DEG C of vitrification points, pH value approximately 7.5～9.5, viscosity 500～1000mPa.s.
Preferably, described moistening flatting agent is polyether siloxane copolymer, effective content 100%, and viscosity is approximately100mPa.s。
Preferably, described defoamer is the mixture of fatty family mineral oil, effective content 100%, and viscosity is approximately100mPa.s。
Preferably, described blowing agent is TSH blowing agent, particle diameter≤10 μ m. TSH blowing agent Chinese name: rightToluene sulfonyl hydrazide (P-Toiuenesulfonylhydrozide) molecular formula: C7H10NO2S, physical property: white is to ashWhite crystalline powder. Relative density 1.40-1.42, molten some 100-110 DEG C, is soluble in alkali, methyl alcohol. ethanol. and MEK.Be slightly soluble in water, aldehydes, be insoluble to benzene and toluene. Decomposition temperature 100-110 DEG C, emits nitrogen and a small amount of water, gas forming amount110-125ml/g. In hot water, hydrolysis produces sulfonic acid, puts nitrogen, and under normal temperature, without moisture absorption phenomenon, inflammable substance, meets acidMissing of ignition. Be generally used for the multiple plastics such as polyvinyl chloride and natural elastomeric blowing agent. Catabolite is colourless-nontoxic-Odorless-do not pollute; Decompose quite slow; Shrink of product rate is little, and tearing strength is large, and for closed pores such as sport footwear-adhesive plastersFoamed plastics and sandwich rubber.
Preferably, described thickener is association type polyurethane thickener, effective content 50～60%, and viscosity 2000～3000mPa.s。
Preferably, described dispersant is polycarboxylate sodium's dispersant, PH=7.0 ± 1, and effective content 50%, stickyDegree 500～1000mPa.s.
A preparation method for the special aqueous foaming ink of wallpaper intaglio printing, gets former according to described parts by weightMaterial, adds described waterborne film-forming emulsion in agitator and stirs, and described pigment, dispersant, blowing agent are added to waterborne film-formingIn emulsion, stir; Mixture in agitator is carried out to speed lapping with milling apparatus; After grinding finishes, then by instituteState distilled water, moistening flatting agent, defoamer, thickener and add in agitator, stir; Finally, use 200-300Eye mesh screen filters, and obtains aqueous foaming ink.
Beneficial effect of the present invention: (1) traditional foam ink is to adopt the heat-set ink that polyvinyl chloride paste is carrier, containsA large amount of poisonous plasticizer and other organic solvents. It is solvent that the present invention adopts water, without the volatilization of poisonous organic solvent, to skyGas is pollution-free; (2) TSH blowing agent is insoluble in water, and the present invention uses special polycarboxylate sodium's dispersant to realize TSH foamingAgent is dispersed in water-based system; (3) the present invention can allow common wallpaper print to realize after this aqueous foaming ink three-dimensionalFoaming effect, and good permeability, wallpaper surface scrubbing resistance, resistance to extruding are indeformable.
Detailed description of the invention
The present invention is further detailed explanation to use an embodiment below, is not enforcement model of the present inventionEnclose and be confined to this.
Embodiment 1, the special aqueous foaming ink of a kind of wallpaper intaglio printing described in the present embodiment, it be by underThe raw material of row parts by weight adds in agitator and obtains through mixing, grind, stirring:
Described in present case, waterborne film-forming emulsion is the water that Green spring (Xiamen) environmental protection science and technology Materials Co., Ltd producesProperty acrylic emulsion, solid content 47%, acid number 55,30 DEG C of vitrification points, pH value approximately 8.5, viscosity 800mPa.s;Moistening flatting agent isFlow425, polyether siloxane copolymer, effective content 100%, the about 100mPa.s of viscosity;Defoamer isFoamexK8, the mixture of aliphatic mineral oil, effective content 100%, the about 100mPa.s of viscosity;Pigment is the C311 colour carbon black of Shanghai Jiaohua Co., Ltd; Blowing agent is the TSH blowing agent of Hangzhou marine rainbow chemical industry, averageParticle diameter 10 μ m; Dispersant is the SN-DISPERSANT5040 of Japanese Nuo Puke, PH=7.0 ± 1, and effective content 50%,Viscosity 800mPa.s; Thickener isViscoPlus3030, association type polyurethane thickener, effective content 55%,Viscosity 2500mPa.s. Preparation method is, gets raw material according to described parts by weight, and described waterborne film-forming emulsion is added to stirringBucket high-speed stirred (mixing speed 800rpm) adds described pigment, dispersant, blowing agent in waterborne film-forming emulsion simultaneously,Stir; Mixture in agitator is carried out to speed lapping with milling apparatus; After grinding finishes, then by described distilled water,Moistening flatting agent, defoamer, thickener add agitator stirring at low speed (mixing speed 400rpm), stir; Finally,With 260 eye mesh screens filtrations, obtain aqueous foaming ink. According to standard GB/T/T9756-2001 to using present case inkPrinting sample carry out scrubbing resistance test, scrubbing resistance number of times >=800 time, far above using the resistance to wiping of traditional aqueous foaming inkWash effect (≤100 times).
Embodiment 2, the special aqueous foaming ink of a kind of wallpaper intaglio printing described in the present embodiment, it be by underThe raw material of row parts by weight adds in agitator and obtains through mixing, grind, stirring:
Described in present case, waterborne film-forming emulsion is the water that Green spring (Xiamen) environmental protection science and technology Materials Co., Ltd producesProperty acrylic emulsion, solid content 47%, acid number 55,30 DEG C of vitrification points, pH value approximately 8.5, viscosity 800mPa.s;Moistening flatting agent isFlow425, polyether siloxane copolymer, effective content 100%, the about 100mPa.s of viscosity;Defoamer isFoamexK8, the mixture of aliphatic mineral oil, effective content 100%, the about 100mPa.s of viscosity;Pigment is the C311 colour carbon black of Shanghai Jiaohua Co., Ltd; Blowing agent is the TSH blowing agent of Hangzhou marine rainbow chemical industry, averageParticle diameter 10 μ m; Dispersant is the SN-DISPERSANT5040 of Japanese Nuo Puke, PH=7.0 ± 1, and effective content 50%,Viscosity 800mPa.s; Thickener isViscoPlus3030, association type polyurethane thickener, effective content 55%,Viscosity 2500mPa.s. Preparation method is, gets raw material according to described parts by weight, and described waterborne film-forming emulsion is added to stirringBucket high-speed stirred (mixing speed 800rpm) adds described pigment, dispersant, blowing agent in waterborne film-forming emulsion simultaneously,Stir; Mixture in agitator is carried out to speed lapping with milling apparatus; After grinding finishes, then by described distilled water,Moistening flatting agent, defoamer, thickener add agitator stirring at low speed (mixing speed 400rpm), stir; Finally,With 260 eye mesh screens filtrations, obtain aqueous foaming ink. According to standard GB/T/T9756-2001 to using present case inkPrinting sample carry out scrubbing resistance test, scrubbing resistance number of times >=1500 time, far above using traditional aqueous foaming ink resistance toScrub effect (≤100 times).
The above is only a preferred embodiment of the present invention, just for help to understand method of the present invention andIts core concept. It should be pointed out that for those skilled in the art, under the premise of not departing from the present invention,Can also carry out some improvement and modification to the present invention, these modifications and modification also fall into the protection model of the claims in the present inventionIn enclosing.
Claims (2)
1. the special aqueous foaming ink of wallpaper intaglio printing, is characterized in that: it comprises the raw material of following weight ratio:
Described waterborne film-forming emulsion is aqueous acrylic emulsion, solid content 45～48%, acid number 30～60mgKOH/g, glass20～40 DEG C of glass temperature, pH value 7.5～9.5, viscosity 500～1000mPa.s;
Described moistening flatting agent is polyether siloxane copolymer, effective content 100%, viscosity 50～300mPa.s;
Described defoamer is the mixture of fatty family mineral oil, effective content 100%, viscosity 50～300mPa.s;
Described blowing agent is TSH blowing agent, particle diameter≤10 μ m;
Described thickener is association type polyurethane thickener, effective content 50～60%, viscosity 2000～3000mPa.s;
Described dispersant is polycarboxylate sodium's dispersant, pH=7.0 ± 1, effective content 50%, viscosity 500～1000mPa.s.
2. a preparation method for the special aqueous foaming ink of wallpaper intaglio printing, comprises the steps: according to claim 1Described in weight ratio get raw material, described waterborne film-forming emulsion is added in agitator and is stirred, by described pigment, dispersant,Blowing agent adds in waterborne film-forming emulsion, stirs; With milling apparatus, the mixture in agitator being carried out to high speed grindsMill; After grinding finishes, more described distilled water, moistening flatting agent, defoamer, thickener are added in agitator, stirMix evenly; Finally, with the filtration of 200-300 eye mesh screen, obtain aqueous foaming ink.
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104164077B (en) * | 2014-07-02 | 2016-08-17 | 河南奥图喷绘有限公司 | A kind of aqueous chamois leather effect slurry and the production technology utilizing this slurry to prepare chamois leather effect non-woven paper wallpaper |
| CN104231464A (en) * | 2014-09-30 | 2014-12-24 | 郑州威尔森壁纸有限公司 | Water-based transparent alluvial gold paint sizing agent for wallpaper and preparation method thereof |
| CN105348911B (en) * | 2015-11-12 | 2018-01-23 | 成都普瑞斯特新材料有限公司 | Intaglio plate environment-friendly foaming ink and preparation method thereof |
| CN105968960A (en) * | 2016-05-27 | 2016-09-28 | 安徽胜利精密制造科技有限公司 | Water-based anti-precipitation fluorescent ink and processing method thereof |
| CN109337440A (en) * | 2018-09-26 | 2019-02-15 | 浙江美浓世纪集团有限公司 | A kind of environment-friendly water-based gravure printing ink and preparation method thereof |
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| CN102153910A (en) * | 2011-01-19 | 2011-08-17 | 厦门格林春天环保科技材料有限公司 | Composite special water-based ink for plastic inner printing |
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| JPS5962680A (en) * | 1982-10-02 | 1984-04-10 | 「よし」見 直喜 | Foamable ink composition |
| CN2396985Y (en) * | 1999-06-29 | 2000-09-20 | 程刚 | Stereoscopic relief sand picture card |
| CN101349032A (en) * | 2007-07-16 | 2009-01-21 | 捷安特(中国)有限公司 | Marking paper with coating stereoscopic light extinction effect and preparation method and coating method thereof |
| KR101405872B1 (en) * | 2012-01-13 | 2014-06-18 | 한양잉크 주식회사 | Manufacturing method of non-woven fabrics wallpaper using the water based foaming-ink composite for gravure printing |
| CN102775852A (en) * | 2012-08-13 | 2012-11-14 | 东莞市允诚涂料有限公司 | Waterborne foaming printing ink and preparation method thereof |
| CN102978997B (en) * | 2012-11-22 | 2014-10-08 | 浙江维涅斯装饰材料有限公司 | Production process for gravure embossed wallpaper |
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|---|---|---|---|---|
| CN101284965A (en) * | 2007-04-10 | 2008-10-15 | 樊官保 | Water-based intaglio ink equal to plate engraving ink and uses thereof |
| CN102153910A (en) * | 2011-01-19 | 2011-08-17 | 厦门格林春天环保科技材料有限公司 | Composite special water-based ink for plastic inner printing |
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Effective date of registration: 20160408 Address after: 363000 G building, No. 18 Zhen Xing Road, Longhai Town, Fujian, China Applicant after: Zhangzhou Green Spring Science and Technology Co., LTD. Address before: Tongan District of Xiamen City, Fujian province 361000 District Siming Park Central East Sea industrial plant No. 90 3 floor Green spring (Xiamen) environmental Greenway Technology Materials Co Applicant before: Lin Guoliang |
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Effective date of registration: 20180611 Address after: 361000 South 101A room, Chuang Chuang business park, torch high tech Zone, Xiamen, Fujian Patentee after: Fujian Green spring new material Limited by Share Ltd Address before: 363000 G, 18 Zhenxing Road, Fu Gong town, Longhai, Fujian. Patentee before: Zhangzhou Green Spring Science and Technology Co., LTD. |
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Effective date of registration: 20201228 Address after: 363000 building g, No.18 Zhenxing Road, Fugong Town, Longhai City, Zhangzhou City, Fujian Province Patentee after: Zhangzhou Green Spring Science and Technology Co.,Ltd. Address before: 361000 South 101A room, Chuang Chuang business park, torch high tech Zone, Xiamen, Fujian Patentee before: FUJIAN GREEN SPRING NEW MATERIAL Co.,Ltd. |
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