CN103694787B - Aqueous 3D accumulation ink that a kind of wallpaper intaglio printing is special and preparation method thereof - Google Patents

Aqueous 3D accumulation ink that a kind of wallpaper intaglio printing is special and preparation method thereof Download PDF

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CN103694787B
CN103694787B CN201310625067.XA CN201310625067A CN103694787B CN 103694787 B CN103694787 B CN 103694787B CN 201310625067 A CN201310625067 A CN 201310625067A CN 103694787 B CN103694787 B CN 103694787B
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aqueous
ink
agitator
viscosity
piles
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CN103694787A (en
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林国良
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Zhangzhou Green Spring Science and Technology Co.,Ltd.
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Zhangzhou Green Spring Science And Technology Co Ltd
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Abstract

The present invention relates to a kind of special-purpose aqueous 3D of foam wallpaper and pile up ink and preparation method thereof.Described formula includes following components and mass fraction: distilled water 18-22%;Ethylene glycol 1-2%;Dispersant 0.1-1%;Moistening flatting agent 0.1-1%;Defoamer 0.1-1%;Lithopone 18-25%;Triple superphosphate 3-8%;Fine particle calcium carbonate 10-15%;Pulvis Talci 5-15%;Kaolin 5-15%;Waterborne film-forming emulsion 15-27%;Thickening agent 0.5-1.5%;PH regulator 0.1-0.5%.Its processing technique, for take raw material according to described parts by weight, is progressively dividedly in some parts in agitator, stirs;Finally, filter with 200-300 eye mesh screen, it is thus achieved that aqueous 3D piles up ink.The present invention adopts water as solvent, to free of air pollution, and common wallpaper can be allowed to print the 3D realizing solid after this aqueous 3D piles up ink and pile up effect, all be obviously improved relative to aqueous foaming ink, scrub resistance and fastness.

Description

Aqueous 3D accumulation ink that a kind of wallpaper intaglio printing is special and preparation method thereof
Technical field
The present invention relates to the special aqueous 3D of a kind of wallpaper intaglio printing and pile up ink and preparation method thereof.
Background technology
Raising along with the development of national economy and living standards of the people, shiploads of merchandise house and hotel, the emerging in large numbers of exhibition center, the requirement of house decorative material is improved constantly by people, and foam wallpaper is increasingly subject to people's attention as the important component part of Modern Interior Decoration material.Because foam wallpaper has good decorative effect, convenient and environmental protection feature of constructing increasingly is widely applied.From initial in hotel, the public arena such as office building, show room, be applied to ordinarily resident's house by now more and more in large quantities.But although it is strong to adopt the aqueous 3D foam wallpaper piling up ink printing to have third dimension, saves the features such as consumption, but owing to layer of ink is that hollow-core construction causes that scrub resistance, attachment fastness are poor so that application is subject to a definite limitation.
Summary of the invention
In order to solve the problems referred to above, the aqueous 3D that the present invention provides a kind of wallpaper intaglio printing special piles up ink and preparation method thereof.This ink adopts mass filler to realize the piling height of layer of ink, and by having special 3D stereoscopic visual effect after intaglio printing, and fastness and scrubbing resistance row are superior to aqueous foaming ink.
This invention address that the scheme that its technical problem adopts: the special aqueous 3D of a kind of wallpaper intaglio printing piles up ink, it be by the raw material of following parts by weight add in agitator blended, stir and obtain:
Preferably, described waterborne film-forming emulsion is aqueous acrylic emulsion, solid content 45~48%, acid number 30~60mgKOH/g, vitrification point 20~40 DEG C, pH value about 7.5~9.5, viscosity 500~1000mPa.s.
Preferably, described moistening flatting agent is polyether siloxane copolymer, and effective content 100%, viscosity is about 100mPa.s.
Preferably, described defoamer is the mixture of fatty race mineral oil, and effective content 100%, viscosity is about 100mPa.s.
Preferably, described PH regulator is 2-amino-2-methyl-1-propanol, trade name AMP-95.
Preferably, described thickening agent is association type polyurethane thickener, effective content 50~60%, viscosity 2000~3000mPa.s.
Preferably, described dispersant is polycarboxylate sodium's dispersant, PH=7.0 ± 1, effective content 50%, viscosity 500~1000mPa.s.
Preferably, described lithopone is total zinc amount >=30%, particle diameter≤5 μm.
Preferably, described triple superphosphate is 1250 orders, whiteness >=95%.
Preferably, described fine particle calcium carbonate is 400 orders, whiteness >=95%.
Preferably, described Pulvis Talci is 325 orders, SiO2 content >=60%.
Preferably, described Kaolin is water-washed kaoline, 800 orders, content >=90%.
The preparation method of the aqueous 3D accumulation ink that a kind of wallpaper intaglio printing is special, raw material is taken according to described parts by weight, described distilled water is added agitator high-speed stirred, described ethylene glycol, dispersant, moistening flatting agent, defoamer, lithopone, triple superphosphate, fine particle calcium carbonate, Pulvis Talci, Kaolin are added in agitator simultaneously, stir;With milling apparatus, the mixture in agitator is carried out speed lapping;After grinding terminates, more described waterborne film-forming emulsion, thickening agent, PH regulator are added in agitator, stir;Finally, filter with 200-300 eye mesh screen, it is thus achieved that aqueous 3D piles up ink.
Beneficial effects of the present invention: (1) present invention adopts water as solvent, without the volatilization of toxic organic solvents, to free of air pollution;(2) special formula design and dispersing technology is used to realize high amount of inorganic filler dispersed in water-based system;(3) present invention can allow common wallpaper print the 3D accumulation effect realizing solid after this aqueous 3D piles up ink, is all obviously improved relative to aqueous foaming ink, scrub resistance and fastness.
Detailed description of the invention
By an embodiment, the present invention is further detailed explanation below, is not that the practical range of the present invention is limited thereto.
Embodiment 1, the special aqueous 3D of a kind of wallpaper intaglio printing described in the present embodiment piles up ink, it be by the raw material of following parts by weight add in agitator blended, grind, stir and obtain:
Waterborne film-forming emulsion described in present case is the aqueous acrylic emulsion that Green spring (Xiamen) environmental protection tech materials company limited produces, solid content 47%, acid number 55, vitrification point 30 DEG C, pH value about 8.5, viscosity 800mPa.s;Moistening flatting agent is425, polyether siloxane copolymer, effective content 100%, viscosity is about 100mPa.s;Defoamer isFoamexK8, the mixture of Aliphatic mineral oils, effective content 100%, viscosity is about 100mPa.s;Dispersant is SN-DISPERSANT5040, the PH=7.0 ± 1 of Japan Nuo Puke, effective content 50%, viscosity 800mPa.s;Thickening agent isViscoPlus3030, association type polyurethane thickener, effective content 55%, viscosity 2500mPa.s.PH regulator is the AMP-95 of Dow Chemical.Lithopone is the B301 of Liuzhou Musa basjoo Sieb. Et Zucc. factory, total zinc amount >=30%, particle diameter≤5 μm.Triple superphosphate is 1250 orders of Heshan chemical industry, whiteness >=95%.Fine particle calcium carbonate is 400 orders of Yongfeng In Jiangxi Province, whiteness >=95%.Pulvis Talci is 325 orders that Chengdu is carefully precious, SiO2 content >=60%.Kaolin is the TSP-88 of Zhanjiang natural sciences, 800 orders, content >=90%.Preparation method is, raw material is taken according to described parts by weight, described distilled water is added agitator high-speed stirred (mixing speed 800rpm), described ethylene glycol, dispersant, moistening flatting agent, defoamer, lithopone, triple superphosphate, fine particle calcium carbonate, Pulvis Talci, Kaolin are added in agitator simultaneously, stir;With milling apparatus, the mixture in agitator is carried out speed lapping;After grinding terminates, more described waterborne film-forming emulsion, thickening agent, PH regulator are added agitator stirring at low speed (mixing speed 400rpm), stir;Finally, filter with 260 eye mesh screens, it is thus achieved that aqueous 3D piles up ink.According to standard GB/T/T9756-2001, the printing sample using present case ink being carried out scrubbing resistance test, scrubbing resistance number of times >=2000 time, far above the scrubbing resistance effect (≤100 times) using tradition aqueous foaming ink.
Embodiment 2, the special aqueous 3D of a kind of wallpaper intaglio printing described in the present embodiment piles up ink, it be by the raw material of following parts by weight add in agitator blended, grind, stir and obtain:
Waterborne film-forming emulsion described in present case is the aqueous acrylic emulsion that Green spring (Xiamen) environmental protection tech materials company limited produces, solid content 47%, acid number 55, vitrification point 30 DEG C, pH value about 8.5, viscosity 800mPa.s;Moistening flatting agent is425, polyether siloxane copolymer, effective content 100%, viscosity is about 100mPa.s;Defoamer isFoamexK8, the mixture of Aliphatic mineral oils, effective content 100%, viscosity is about 100mPa.s;Dispersant is SN-DISPERSANT5040, the PH=7.0 ± 1 of Japan Nuo Puke, effective content 50%, viscosity 800mPa.s;Thickening agent isViscoPlus3030, association type polyurethane thickener, effective content 55%, viscosity 2500mPa.s.PH regulator is the AMP-95 of Dow Chemical.Lithopone is the B301 of Liuzhou Musa basjoo Sieb. Et Zucc. factory, total zinc amount >=30%, particle diameter≤5 μm.Triple superphosphate is 1250 orders of Heshan chemical industry, whiteness >=95%.Fine particle calcium carbonate is 400 orders of Yongfeng In Jiangxi Province, whiteness >=95%.Pulvis Talci is 325 orders that Chengdu is carefully precious, SiO2 content >=60%.Kaolin is the TSP-88 of Zhanjiang natural sciences, 800 orders, content >=90%.Preparation method is, raw material is taken according to described parts by weight, described distilled water is added agitator high-speed stirred (mixing speed 800rpm), described ethylene glycol, dispersant, moistening flatting agent, defoamer, lithopone, triple superphosphate, fine particle calcium carbonate, Pulvis Talci, Kaolin are added in agitator simultaneously, stir;With milling apparatus, the mixture in agitator is carried out speed lapping;After grinding terminates, more described waterborne film-forming emulsion, thickening agent, PH regulator are added agitator stirring at low speed (mixing speed 400rpm), stir;Finally, filter with 260 eye mesh screens, it is thus achieved that aqueous 3D piles up ink.According to standard GB/T/T9756-2001, the printing sample using present case ink being carried out scrubbing resistance test, scrubbing resistance number of times >=1000 time, far above the scrubbing resistance effect (≤100 times) using tradition aqueous foaming ink.
The above is only a preferred embodiment of the present invention, is only intended to help to understand method and the core concept thereof of the present invention.It should be pointed out that, for those skilled in the art, under the premise of not departing from the present invention, it is also possible to the present invention carries out some improvement and modification, these are modified and modify in the protection domain also falling into the claims in the present invention.

Claims (2)

1. the aqueous 3D that a wallpaper intaglio printing is special piles up ink, it is characterised in that: it be by the raw material of following weight percents add in agitator blended, stir and obtain:
Described lithopone is total zinc amount >=30%, particle diameter≤5 μm;Described triple superphosphate is 1250 orders, whiteness >=95%;
Described fine particle calcium carbonate is 400 orders, whiteness >=95%;Described Pulvis Talci is 325 orders, SiO2Content >=60%;Described Kaolin is water-washed kaoline, 800 orders, content >=90%;
Described waterborne film-forming emulsion is aqueous acrylic emulsion, solid content 45~48%, acid number 30~60mgKOH/g, vitrification point 20~40 DEG C, pH value 7.5~9.5, viscosity 500~1000mPa.s;
Described moistening flatting agent is polyether siloxane copolymer, effective content 100%, viscosity 50~300mPa.s;
Described defoamer is the mixture of fatty race mineral oil, effective content 100%, viscosity 50~300mPa.s;
Described pH adjusting agent is 2-amino-2-methyl-1-propanol, trade name AMP-95;
Described thickening agent is association type polyurethane thickener, effective content 50~60%, viscosity 2000~3000mPa.s;Described dispersant is polycarboxylate sodium's dispersant, pH=7.0 ± 1, effective content 50%, viscosity 500~1000mPa.s.
2. the preparation method that the aqueous 3D that a kind of wallpaper intaglio printing as claimed in claim 1 is special piles up ink, comprise the steps: that percentage by weight takes raw material described in claim 1, described distilled water is added agitator high-speed stirred, described ethylene glycol, dispersant, moistening flatting agent, defoamer, lithopone, triple superphosphate, fine particle calcium carbonate, Pulvis Talci, Kaolin are added in agitator simultaneously, stir;With milling apparatus, the mixture in agitator is carried out speed lapping;After grinding terminates, more described waterborne film-forming emulsion, thickening agent, pH adjusting agent are added in agitator, stir;Finally, filter with 200-300 eye mesh screen, it is thus achieved that aqueous 3D piles up ink.
CN201310625067.XA 2013-11-28 2013-11-28 Aqueous 3D accumulation ink that a kind of wallpaper intaglio printing is special and preparation method thereof Active CN103694787B (en)

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CN107163671A (en) * 2017-07-18 2017-09-15 河南顺美国际家居股份有限公司 A kind of aqueous suppression gloss oil and preparation method thereof
CN109610219B (en) * 2018-10-29 2021-04-13 浙江凯丰新材料股份有限公司 Beating and stirring device for preparing high-grade matte pure paper wallpaper

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102153910A (en) * 2011-01-19 2011-08-17 厦门格林春天环保科技材料有限公司 Composite special water-based ink for plastic inner printing
CN103334563A (en) * 2013-07-10 2013-10-02 广东玉兰装饰材料有限公司 Wallpaper with surface patterns having accumulation effect and manufacturing method thereof
CN103351717A (en) * 2013-07-10 2013-10-16 广东玉兰装饰材料有限公司 Water-based resin with accumulative and heaping effect for wallpaper and preparation method thereof

Family Cites Families (4)

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Publication number Priority date Publication date Assignee Title
FR2508383B1 (en) * 1981-06-27 1987-04-17 Pelikan Ag Ink tape which can be overloaded in overlay
JPS63273672A (en) * 1987-05-01 1988-11-10 Plus Kk Stereoscopic ink
JP5155933B2 (en) * 2009-04-21 2013-03-06 株式会社サクラクレパス Bright water-based ink composition for ballpoint pens
CN102702854A (en) * 2012-06-29 2012-10-03 惠州市君道实业有限公司 Super-weatherable external color water-based ink

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102153910A (en) * 2011-01-19 2011-08-17 厦门格林春天环保科技材料有限公司 Composite special water-based ink for plastic inner printing
CN103334563A (en) * 2013-07-10 2013-10-02 广东玉兰装饰材料有限公司 Wallpaper with surface patterns having accumulation effect and manufacturing method thereof
CN103351717A (en) * 2013-07-10 2013-10-16 广东玉兰装饰材料有限公司 Water-based resin with accumulative and heaping effect for wallpaper and preparation method thereof

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