CN104530868B - A kind of aqueous, environmental protective glass lacquer and preparation method thereof - Google Patents
A kind of aqueous, environmental protective glass lacquer and preparation method thereof Download PDFInfo
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- CN104530868B CN104530868B CN201410830791.0A CN201410830791A CN104530868B CN 104530868 B CN104530868 B CN 104530868B CN 201410830791 A CN201410830791 A CN 201410830791A CN 104530868 B CN104530868 B CN 104530868B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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Abstract
The present invention relates to technical field of coatings, specifically related to a kind of aqueous, environmental protective glass lacquer and preparation method thereof, aqueous, environmental protective glass lacquer of the invention, not only have paint film plentiful, drying time is fast, repainting time is short, excellent chemical-resistant, excellent resistance to blocking, resistance to marring, superpower hardness, it is nonflammable, it is non-explosive, nontoxic free from extraneous odour, excellent adhesive force, the advantages of superpower water resistance, and with good insulation, it is heat-insulated, power saving function, it is applied to building curtain wall, glass etc. can effectively improve the heat-insulation and heat-preservation ability of building, reduce the consumption of the energy;The preparation method of aqueous, environmental protective glass lacquer of the invention, process is simple can directly be diluted with water, convenient and quick construction during use, can effectively improve efficiency of construction.
Description
Technical field
The present invention relates to technical field of coatings, and in particular to a kind of aqueous, environmental protective glass lacquer and preparation method thereof.
Background technology
Glass lacquer is a kind of to be widely used in various glasswares and can play the suitable of the effects such as decoration, waterproof, anti-corrosion
Used in the paint of glass surface application, in recent years, with the development of national economy, various glass lacquer products appear in the life of people
In the middle of living, family housing finishing, StoreFront finishing, sliding door, furniture item, sanitaryware, Glass Craft are processed etc. nowhere without
Glass lacquer, allows glass lacquer industry to be flourished.
The defect, meeting such as but traditional glass lacquer product is present, and the feature of environmental protection is poor, volatile materials is more, smell is larger in solvent
Health is damaged, therefore, in environmental requirement house decoration higher (including desktop, bathroom, windowpane etc.), office
The application such as building, Glass Craft is limited by larger, in addition, existing glass lacquer product is without the function of insulation, should
The purpose of heat preservation energy-saving is unable to reach during for building curtain wall.
Therefore, need a kind of not only high and low smell of health environment-friendly performance and safety and Health badly, and with good insulation,
Heat-insulated, power saving function aqueous, environmental protective glass lacquer.
The content of the invention
First purpose of the present invention is directed to the deficiencies in the prior art and provides a kind of not only high and low smell of environmental-protecting performance and peace
Full health, and with good insulation, heat-insulated, power saving function aqueous, environmental protective glass lacquer.
It is a further object to provide a kind of preparation method of aqueous, environmental protective glass lacquer.
In order to realize the above object the present invention provides following technical scheme:
A kind of aqueous, environmental protective glass lacquer, including two kinds of components of A, B, wherein, component A includes the composition of following weight portion:
The B component includes the composition of following weight portion:
400~500 parts of propandiol butyl ether
400~500 parts of dipropylene
5~15 parts of silane coupler;
Wherein, the aqueous, environmental protective glass lacquer by component A, B component, water according to 9:1:1~2 ratio be mixed with and
Into.
Wherein, the coalescents include 10~50 parts of propandiol butyl ether and 30~80 parts of dipropylene.
Wherein, the thickener includes 1~10 part of thickener 288 and 1~10 part of thickener 278.
Wherein, the defoamer includes 1~2 part of the defoamer 902W of 822,1~2 part of defoamer and 0.5~2 part disappear
Infusion 805.
Wherein, the wetting agent is wetting agent 270, and the feel auxiliary agent is feel auxiliary agent 738, and the aqueous wax emulsion is
Aqueous wax emulsion D-816.
A kind of preparation method of aqueous, environmental protective glass lacquer, including component A, B component preparation and component A, B component, water
Blend step, wherein, the preparation of component A is comprised the following steps:
(1) by the water of above-mentioned weight portion, water-based acrylic resin, waterborne polyurethane resin, aqueous wax emulsion, wetting agent,
Defoamer 822 is fed intake cylinder successively, and mixing at least 15 minutes is continuously stirred under the rotating speed of 400~600r/min;
(2) feel auxiliary agent, the propane diols of above-mentioned weight portion are added under the rotating speed of 800~1200r/min to the cylinder that feeds intake
Butyl ether, dipropylene, continuously stir mixing at least 20 minutes;
(3) the defoamer 902W and froth breaking of above-mentioned weight portion are added under the rotating speed of 800~1200r/min to the cylinder that feeds intake
Agent 805, the thickener 288 and thickener 278 for adding above-mentioned weight portion adjusts viscosity to 100~120pa.s;
(4) continue to stir mixing at least 15 minutes under the rotating speed of 800~1200r/min, it is standby;
The preparation of B component:The propandiol butyl ether of above-mentioned weight portion, dipropylene, silane coupler are fed intake
Cylinder, and mixing is continuously stirred under the rotating speed of 400~600r/min 15~20 minutes to well mixed, it is standby;
The preparation of aqueous, environmental protective glass lacquer:Component A, B component, the water that will be prepared are according to 9:1:1~2 ratio is well mixed
The aqueous, environmental protective glass lacquer is obtained.
Compared with prior art, the device have the advantages that being:Aqueous, environmental protective glass lacquer of the invention, not only has
Paint film is plentiful, drying time is fast, repainting time is short, excellent chemical-resistant, excellent resistance to blocking, resistance to marring, superpower
Hardness, nonflammable, non-explosive, nontoxic free from extraneous odour, excellent adhesive force, superpower water resistance the advantages of, and with good
Insulation, heat-insulated, power saving function, being applied to building curtain wall, glass etc. can effectively improve the heat-insulation and heat-preservation ability of building,
Reduce the consumption of the energy;The preparation method of aqueous, environmental protective glass lacquer of the invention, process is simple can be direct during use
Be diluted with water, convenient and quick construction, efficiency of construction can be effectively improved.
Specific embodiment
With reference to specific embodiment, the present invention is described in further detail, but do not constitute to of the invention any
Limitation.
Embodiment 1.
The aqueous, environmental protective glass lacquer of the present embodiment, including component A and B component, wherein component A include following weight portion into
Point:400 parts of water-based acrylic resin, 50 parts of waterborne polyurethane resin, 10 parts of propandiol butyl ether, 30 parts of dipropylene, hand
1 part of auxiliary agent of sense, 10 parts of aqueous wax emulsion, 1 part of wetting agent, the defoamer of 278,1 part of the thickener of 1 part of 288,1 part of thickener
822nd, 1 part of defoamer 902W, 0.5 part of defoamer 805,50 parts of dispersible pigment color paste, 100 parts of water;
The B component includes the composition of following weight portion:400 parts of propandiol butyl ether, 400 parts of dipropylene, silane
5 parts of coupling agent.
The aqueous, environmental protective glass lacquer of the present embodiment is by component A, B component, water according to 9:1:1 ratio is mixed with and forms.
The preparation method of component A:
(1) by the water of above-mentioned weight portion, water-based acrylic resin, waterborne polyurethane resin, aqueous wax emulsion, wetting agent,
Defoamer 822 is fed intake cylinder successively, and mixing at least 15 minutes is continuously stirred under the rotating speed of 400~600r/min;
(2) feel auxiliary agent, the propane diols of above-mentioned weight portion are added under the rotating speed of 800~1200r/min to the cylinder that feeds intake
Butyl ether, dipropylene, continuously stir mixing at least 20 minutes;
(3) the defoamer 902W and froth breaking of above-mentioned weight portion are added under the rotating speed of 800~1200r/min to the cylinder that feeds intake
Agent 805, the thickener 288 and thickener 278 for adding above-mentioned weight portion adjusts viscosity to 100~120pa.s;
(4) continue to stir mixing at least 15 minutes under the rotating speed of 800~1200r/min, it is standby;
The preparation method of B component:By the propandiol butyl ether of above-mentioned weight portion, dipropylene, silane coupler input
Feed intake cylinder, and mixing is continuously stirred under the rotating speed of 400~600r/min 15~20 minutes to well mixed, standby;
The preparation of aqueous, environmental protective glass lacquer:Component A, B component, the water that will be prepared are according to 9:1:The well mixed system of 1 ratio
Obtain the aqueous, environmental protective glass lacquer.
Embodiment 2.
The aqueous, environmental protective glass lacquer of the present embodiment, including component A and B component, wherein component A include following weight portion into
Point:420 parts of water-based acrylic resin, 70 parts of waterborne polyurethane resin, 20 parts of propandiol butyl ether, 40 parts of dipropylene, hand
3 parts of auxiliary agent of sense, 15 parts of aqueous wax emulsion, 1.5 parts of wetting agent, 278,1.3 parts of the thickener of 3 parts of 288,3 parts of thickener disappear
Defoamer 902W, 0.8 part of defoamer 805,70 parts of dispersible pigment color paste, 110 parts of the water that 822,1.3 part of infusion;
The B component includes the composition of following weight portion:420 parts of propandiol butyl ether, 420 parts of dipropylene, silane
7 parts of coupling agent.
The aqueous, environmental protective glass lacquer of the present embodiment is by component A, B component, water according to 9:1:2 ratio is mixed with and forms,
Preparation method is no longer repeated herein with embodiment 1.
Embodiment 3.
The aqueous, environmental protective glass lacquer of the present embodiment, including component A and B component, wherein component A include following weight portion into
Point:450 parts of water-based acrylic resin, 100 parts of waterborne polyurethane resin, 30 parts of propandiol butyl ether, 50 parts of dipropylene, hand
5 parts of auxiliary agent of sense, 20 parts of aqueous wax emulsion, 2 parts of wetting agent, the froth breaking of 278,1.5 parts of the thickener of 5 parts of 288,5 parts of thickener
Defoamer 902W, 1 part of defoamer 805,90 parts of dispersible pigment color paste, 120 parts of the water that 822,1.5 part of agent;
The B component includes the composition of following weight portion:450 parts of propandiol butyl ether, 450 parts of dipropylene, silane
10 parts of coupling agent.
The aqueous, environmental protective glass lacquer of the present embodiment is by component A, B component, water according to 9:1:1 ratio is mixed with and forms,
Preparation method is no longer repeated herein with embodiment 1.
Embodiment 4.
The aqueous, environmental protective glass lacquer of the present embodiment, including component A and B component, wherein component A include following weight portion into
Point:480 parts of water-based acrylic resin, 130 parts of waterborne polyurethane resin, 40 parts of propandiol butyl ether, 70 parts of dipropylene, hand
8 parts of auxiliary agent of sense, 25 parts of aqueous wax emulsion, 2.5 parts of wetting agent, 278,1.8 parts of the thickener of 8 parts of 288,8 parts of thickener disappear
Defoamer 902W, 1.5 parts of defoamer 805,95 parts of dispersible pigment color paste, 140 parts of the water that 822,1.8 part of infusion;
The B component includes the composition of following weight portion:480 parts of propandiol butyl ether, 470 parts of dipropylene, silane
12 parts of coupling agent.
The aqueous, environmental protective glass lacquer of the present embodiment is by component A, B component, water according to 9:1:2 ratio is mixed with and forms,
Preparation method is no longer repeated herein with embodiment 1.
Embodiment 5.
The aqueous, environmental protective glass lacquer of the present embodiment, including component A and B component, wherein component A include following weight portion into
Point:460 parts of water-based acrylic resin, 100 parts of waterborne polyurethane resin, 30 parts of propandiol butyl ether, 50 parts of dipropylene, hand
5 parts of auxiliary agent of sense, 20 parts of aqueous wax emulsion, 2 parts of wetting agent, the froth breaking of 278,1.5 parts of the thickener of 6 parts of 288,6 parts of thickener
Defoamer 902W, 1 part of defoamer 805,90 parts of dispersible pigment color paste, 127 parts of the water that 822,1.5 part of agent;
The B component includes the composition of following weight portion:470 parts of propandiol butyl ether, 480 parts of dipropylene, silane
14 parts of coupling agent.
The aqueous, environmental protective glass lacquer of the present embodiment is by component A, B component, water according to 9:1:2 ratio is mixed with and forms,
Preparation method is no longer repeated herein with embodiment 1.
Embodiment 6.
The aqueous, environmental protective glass lacquer of the present embodiment, including component A and B component, wherein component A include following weight portion into
Point:500 parts of water-based acrylic resin, 150 parts of waterborne polyurethane resin, 50 parts of propandiol butyl ether, 80 parts of dipropylene, hand
10 parts of auxiliary agent of sense, 30 parts of aqueous wax emulsion, 3 parts of wetting agent, the froth breaking of 278,2 parts of the thickener of 10 parts of 288,10 parts of thickener
Defoamer 902W, 2 parts of defoamer 805,100 parts of dispersible pigment color paste, 150 parts of the water that 822,2 part of agent;
The B component includes the composition of following weight portion:500 parts of propandiol butyl ether, 500 parts of dipropylene, silane
15 parts of coupling agent.
The aqueous, environmental protective glass lacquer of the present embodiment is by component A, B component, water according to 9:1:1 ratio is mixed with and forms,
Preparation method is no longer repeated herein with embodiment 1.
The performance test data of aqueous, environmental protective glass lacquer prepared by embodiment 1~6 are as shown in the table:
In sum, aqueous, environmental protective glass lacquer of the invention, not only with paint film is plentiful, drying time fast, repainting time
Short, excellent chemical-resistant, excellent resistance to blocking, resistance to marring, superpower hardness, nonflammable, non-explosive, nontoxic it is as good as
The advantages of taste, excellent adhesive force, superpower water resistance, and with good insulation, heat-insulated, power saving function, be applied to build
Building curtain wall, glass etc. can effectively improve the heat-insulation and heat-preservation ability of building, reduce the consumption of the energy;Aqueous ring of the invention
The preparation method of glass lacquer is protected, process is simple can directly be diluted with water, convenient and quick construction, Neng Gouyou during use
Effect improves efficiency of construction.
The above embodiments are only the preferred embodiments of the present invention, it is impossible to interest field of the invention is limited with this, because
This, the equivalent variations made according to scope of the present invention patent still belong to the scope that the present invention is covered.
Claims (2)
1. a kind of aqueous, environmental protective glass lacquer, it is characterised in that:Including two kinds of components of A, B, wherein, component A includes following weight portion
Composition:
The B component includes the composition of following weight portion:
400~500 parts of propandiol butyl ether
400~500 parts of dipropylene
5~15 parts of silane coupler;
Wherein, the aqueous, environmental protective glass lacquer by component A, B component, water according to 9:1:1~2 ratio is mixed with and forms.
2. a kind of preparation method of aqueous, environmental protective glass lacquer as claimed in claim 1, it is characterised in that including component A, B groups
The preparation for dividing and component A, B component, the blend step of water, wherein, the preparation of component A is comprised the following steps:
(1) by the water of above-mentioned weight portion, water-based acrylic resin, waterborne polyurethane resin, aqueous wax emulsion, wetting agent, froth breaking
Agent 822 is fed intake cylinder successively, and mixing at least 15 minutes is continuously stirred under the rotating speed of 400~600r/min;
(2) added under the rotating speed of 800~1200r/min to the cylinder that feeds intake the feel auxiliary agent of above-mentioned weight portion, propandiol butyl ether,
Dipropylene, continuously stirs mixing at least 20 minutes;
(3) the defoamer 902W and defoamer of above-mentioned weight portion are added under the rotating speed of 800~1200r/min to the cylinder that feeds intake
805, the thickener 288 and thickener 278 for adding above-mentioned weight portion adjust viscosity to 100~120pa.s;
(4) continue to stir mixing at least 15 minutes under the rotating speed of 800~1200r/min, it is standby;
The preparation of B component:The propandiol butyl ether of above-mentioned weight portion, dipropylene, silane coupler are fed intake cylinder, and
Mixing is continuously stirred under the rotating speed of 400~600r/min 15~20 minutes to well mixed, it is standby;
The preparation of aqueous, environmental protective glass lacquer:Component A, B component, the water that will be prepared are according to 9:1:1~2 ratio is well mixed to be obtained
The aqueous, environmental protective glass lacquer.
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CN104962154B (en) * | 2015-07-06 | 2018-07-20 | 香山红叶建设有限公司 | A kind of curtain wall flame-retardant insulating paint and preparation method thereof |
CN107446487B (en) * | 2017-08-16 | 2019-10-15 | 河北惠驰装饰材料有限公司 | A kind of glass lacquer and preparation method thereof and a kind of glass sealing wax |
CN107629654A (en) * | 2017-09-29 | 2018-01-26 | 天长市墨缘玻璃建材有限公司 | A kind of base coat and its processing technology for coromandel laquer glass |
CN107629506A (en) * | 2017-09-29 | 2018-01-26 | 天长市墨缘玻璃建材有限公司 | A kind of outdoor glass color-painting pigment and preparation method thereof |
CN108129953A (en) * | 2017-12-28 | 2018-06-08 | 苏州德达特种涂料有限公司 | A kind of bi-component waterborne glass lacquer and preparation method thereof |
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CN101851461B (en) * | 2010-06-08 | 2013-08-28 | 中华制漆(深圳)有限公司 | Double-component waterborne polyurethane glass transparent insulating coating |
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