CN107955494A - A kind of water-base epoxy hammer paint and preparation method thereof - Google Patents
A kind of water-base epoxy hammer paint and preparation method thereof Download PDFInfo
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- CN107955494A CN107955494A CN201711215634.9A CN201711215634A CN107955494A CN 107955494 A CN107955494 A CN 107955494A CN 201711215634 A CN201711215634 A CN 201711215634A CN 107955494 A CN107955494 A CN 107955494A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/10—Anti-corrosive paints containing metal dust
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/28—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for wrinkle, crackle, orange-peel, or similar decorative effects
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
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Abstract
The invention discloses a kind of water-base epoxy hammer paint and preparation method thereof, and specifically disclose component A and be：Aqueous epoxy resins, deionized water, cosolvent, wetting aid, mallear stria agent, thixotropic agent, thickener, dispersant, silver powder, mill base, defoamer；B component is：Aqueous epoxy curing agent, deionized water, and aqueous epoxy resins are added in paint mixing cylinder, add dispersant, wetting aid and deionized water, cosolvent and thixotropic agent are added under high-speed stirred state, then the color needed for mill base is modulated, adds thickener and silver powder, it is to be mixed uniform, mixing speed is reduced, mallear stria agent and defoamer is being added under stirring at low speed, component A is made；Aqueous epoxy curing agent is uniformly mixed with deionized water again, B component is made；The component A prepared is uniformly mixed with B component, up to water-base epoxy hammer paint.Water-base epoxy hammer paint prepared by the present invention has the advantages that appearance looks elegant, hardness of paint film are high, anti-corrosive properties are good and gloss is high.
Description
Technical field
The present invention relates to paint field, more particularly to a kind of water-base epoxy hammer paint and preparation method thereof.
Background technology
Hammer paint is a kind of common industrial art paint, it can form one layer of similar iron hammer in the body surface being coated and strike
Forge iron the paint film of left mallear stria style after piece, therefore referred to as hammer paint.It can both cover ground out-of-flatness or other
Defect, and without wrinkle finish the easy dust stratification dustiness of wrinkle it is dirty the shortcomings that, there is excellent protected decoration to act on.Its application neck
Domain is from being mainly used for the metal surfaces such as instrument, instrument, hardware, medical instrument, metal filing cabinet, safety cabinet, antitheft door
Decoration.
At present, with the steady growth of China's economic, environmental pressure is also increasing, especially starts in recent years " prevalence "
Haze, make all orders of society and everyone will appreciate that the importance of good environment, therefore, environment-friendly products are increasingly subject to people
Favor, the especially development of water-based industrial paint in recent years.At present, water-based industrial paint be successfully applied to engineering machinery,
Baking vanish, furniture lacquer even automobile lacker, however, in hammer paint field, its comprehensive performance of water paint is still difficult to meet demand, such as
The workability of dual-component polyurethane series is poor, decorative pattern be not as poor as the beauty of paint, difference of hardness, gloss difference, paint film weatherability, especially
It is that corrosion resistance is poor.
Therefore, how to provide it is a kind of it is easy for construction, anti-corrosive properties are good, paint film is beautiful and environmentally protective aqueous hammer paint into
Problem is obtained for those skilled in the art's urgent need to resolve.
The content of the invention
In view of this, the present invention provides a kind of easy to operate, appearance looks elegant, that hardness of paint film is high, anti-corrosive properties are good is water-based
Hammer paint, and paint film firmly without it is crisp, richness is good, gloss is high, oil resistant and chemicals are excellent.
To achieve these goals, the present invention adopts the following technical scheme that：
A kind of water-base epoxy hammer paint, includes the raw material of following parts by weight：
Component A is：50-60 parts of aqueous epoxy resins, 20-32 parts of deionized water, 3-5 parts of cosolvent, wetting aid 0.3-
0.8 part, 5-8 parts of mallear stria agent, 0.3-0.8 parts of thixotropic agent, 1-2 parts of thickener, 0.8-1.5 parts of dispersant, 3-5 parts of silver powder, mill base
0.8-1.5 parts, 0.3-0.8 parts of defoamer；
B component is：65-75 parts of aqueous epoxy curing agent, 25-35 parts of deionized water.
Preferably, a kind of water-base epoxy hammer paint, includes the raw material of following parts by weight：
Component A is：53-57 parts of aqueous epoxy resins, 25-28 parts of deionized water, 3.5-4.5 parts of cosolvent, wetting aid
0.4-0.7 parts, 5.5-7.5 parts of mallear stria agent, 0.4-0.7 parts of thixotropic agent, 1.2-1.8 parts of thickener, 1-1.3 parts of dispersant, silver powder
3.5-4.5 parts, 1-1.2 parts of mill base, 0.4-0.6 parts of defoamer；
B component is：67-72 parts of aqueous epoxy curing agent, 28-32 parts of deionized water.
Preferably, a kind of water-base epoxy hammer paint, includes the raw material of following parts by weight：
Component A is：55 parts of aqueous epoxy resins, 27 parts of deionized water, 4 parts of cosolvent, 0.5 part of wetting aid, mallear stria agent 6
Part, 0.5 part of thixotropic agent, 1.5 parts of thickener, 1 part of dispersant, 4 parts of silver powder, 1 part of mill base, 0.5 part of defoamer；
B component is：70 parts of aqueous epoxy curing agent, 30 parts of deionized water.
Preferably, the aqueous epoxy resins are resin SWT703A.
Preferably, the cosolvent includes butyl glycol ether and alcohol ester, and its ratio be 3：2.
Preferably, the wetting aid is the one or more in Tego4000, Tego4100, Tego270；The mallear stria
Agent is mallear stria agent 68；The thixotropic agent is BENTONE DE；The thickener is RHEOLATE299, RM-8W, Borchi
One or more in Gel0620.
Preferably, the dispersant is the one or more in BYK190, BYK194；The silver powder is non-leafing aluminum paste
967；The mill base is aqueous color paste；The defoamer is one in BYK024, BYK028, BYK020, Tego825, Tego810
Kind is a variety of；The aqueous epoxy curing agent is Aradur3986.
A kind of preparation method of water-base epoxy hammer paint, includes the following steps：
(1) each raw material is weighed by a kind of above-mentioned water-base epoxy hammer paint；
(2) aqueous epoxy resins weighed in step (1) are added in paint mixing cylinder, sequentially add dispersant, profit
Wet auxiliary agent and deionized water, then high-speed stirred, adds cosolvent under high-speed stirred state and thixotropic agent, high speed dispersion is opened,
Then the color needed for mill base is modulated, adds thickener and silver powder, to be mixed uniform, reduction mixing speed, under stirring at low speed
Mallear stria agent and defoamer are being added, up to component A；
(3) aqueous epoxy curing agent that step (1) has weighed is uniformly mixed with deionized water, up to B component；
(4) component A prepared in step (2) is uniformly mixed with the B component prepared in step (3), up to water-based
Epoxy hammer paint.
Preferably, the ratio of the component A and the B component is 4：1 or 3：1.
It can be seen via above technical scheme that compared with prior art, beneficial effect is：1) present invention is prepared water-based
Epoxy hammer paint glossiness is high, hardness of paint film is high, anti-corrosive properties are good, oil resistivity is good, richness is good and weatherability is strong；2) it is of the invention
The water-base epoxy hammer paint of preparation can not make priming paint, you can bottom surface is general, suitable for being used under various complex environments, and constructs
It is convenient；3) the water-base epoxy hammer paint A of the invention prepared, B component mixing are convenient, and spraying is convenient, and pot-life is grown, and is less prone to not
Good disadvantage；4) product is without the harmful substances such as heavy metal, triphen, environmentally protective, harmless, industrial applications prospect
It is good；5) raw material needed for the product is easily bought, and cost is low, and its preparation method is simple, easy to operate, can be produced in enormous quantities.
Embodiment
Below in conjunction with specific embodiment, complete, clearly description is carried out to technical scheme.
Aqueous epoxy resins used are resin SWT703A in the embodiment of the present invention；Cosolvent is by ethylene glycol and alcohol ester
3：2 are formulated；The mallear stria agent 68 of paint company production is contained in mallear stria agent for good fortune；For hamming, this BENTONE DE (are gone thixotropic agent
Ionized water：DE=86/14)；Silver powder is non-leafing aluminum paste 967；Mill base is the bright serial aqueous color paste of generation；Aqueous epoxy curing agent
The Aradur3986 stepped for Hensel.
Embodiment 1
Weigh component A：50 parts of aqueous epoxy resins, 20 parts of deionized water, 3 parts of cosolvent, wetting aid Tego4000
0.3 part, 5 parts of mallear stria agent, 0.3 part of thixotropic agent, 0.8 part of 1 part of thickener RM-8W, dispersant B YK190,3 parts of silver powder, mill base
0.8 part, 0.3 part of defoamer BYK028；B component：65 parts of aqueous epoxy curing agent, 25 parts of deionized water；Then by water-base epoxy
Resin is added in paint mixing cylinder, dispersant, wetting aid and deionized water is sequentially added, then high-speed stirred, in high-speed stirring
Mix addition cosolvent and thixotropic agent, high speed dispersion under state to open, then the color needed for mill base is modulated, adds thickener and silver
Powder, it is to be mixed uniform, mixing speed is reduced, mallear stria agent and defoamer are being added under stirring at low speed, up to component A；Again will be water-based
Epoxy hardener is uniformly mixed with deionized water, up to B component；By component A and B component it is finally 4 in proportion：1 mixing is equal
It is even, up to water-base epoxy hammer paint.
Embodiment 2
Weigh component A：60 parts of aqueous epoxy resins, 32 parts of deionized water, 5 parts of cosolvent, wetting aid Tego4100
0.8 part, 8 parts of mallear stria agent, 0.8 part of thixotropic agent, 1.5 parts of 2 parts of thickener RHEOLATE299, dispersant B YK194,5 parts of silver powder,
1.5 parts of mill base, 0.8 part of defoamer BYK024；B component：75 parts of aqueous epoxy curing agent, 35 parts of deionized water；Then will be water-based
Epoxy resin is added in paint mixing cylinder, dispersant, wetting aid and deionized water is sequentially added, then high-speed stirred, in height
Cosolvent is added under fast stirring and thixotropic agent, high speed dispersion are opened, and then the color needed for mill base is modulated, adds thickener
And silver powder, it is to be mixed uniform, mixing speed is reduced, mallear stria agent and defoamer are being added under stirring at low speed, up to component A；Again will
Aqueous epoxy curing agent is uniformly mixed with deionized water, up to B component；By component A and B component it is finally 3 in proportion：1 is mixed
Close uniformly, up to water-base epoxy hammer paint.
Embodiment 3
Weigh component A：50 parts of aqueous epoxy resins, 31.7 parts of deionized water, 3 parts of cosolvent, wetting aid Tego4000
0.5 part, 5 parts of mallear stria agent, 0.3 part of thixotropic agent, 1 part of 2 parts of thickener RM-8W, dispersant B YK190,5 parts of silver powder, 1 part of mill base,
0.5 part of defoamer BYK028；B component：70 parts of aqueous epoxy curing agent, 30 parts of deionized water；Then aqueous epoxy resins are added
Enter into paint mixing cylinder, sequentially add dispersant, wetting aid and deionized water, then high-speed stirred, in high-speed stirred state
Lower addition cosolvent and thixotropic agent, high speed dispersion are opened, and then the color needed for mill base is modulated, adds thickener and silver powder, treat
Stir evenly, reduce mixing speed, mallear stria agent and defoamer are being added under stirring at low speed, up to component A；Water-base epoxy is consolidated again
Agent is uniformly mixed with deionized water, up to B component；By component A and B component it is finally 4 in proportion：1 is uniformly mixed, to obtain the final product
Water-base epoxy hammer paint.
Embodiment 4
Weigh component A：60 parts of aqueous epoxy resins, 20 parts of deionized water, 5 parts of cosolvent, wetting aid Tego4100
0.5 part, 6.2 parts of mallear stria agent, 0.8 part of thixotropic agent, 1 part of 1 part of thickener RHEOLATE299, dispersant B YK194,3 parts of silver powder,
1 part of mill base, 0.5 part of defoamer BYK020；B component：70 parts of aqueous epoxy curing agent, 30 parts of deionized water；Then by water-based ring
Oxygen tree fat is added in paint mixing cylinder, sequentially adds dispersant, wetting aid and deionized water, then high-speed stirred, at a high speed
Add cosolvent and thixotropic agent, high speed dispersion under stirring to open, then the color needed for mill base is modulated, add thickener and
Silver powder, it is to be mixed uniform, mixing speed is reduced, mallear stria agent and defoamer are being added under stirring at low speed, up to component A；Again by water
Property epoxy hardener is uniformly mixed with deionized water, up to B component；By component A and B component it is finally 3 in proportion：1 mixing
Uniformly, up to water-base epoxy hammer paint.
In order to further understand the performance of product of the present invention, the water-base epoxy of the invention to being prepared in embodiment 1-4
Hammer paint and common hammer paint performance test, specific measurement effect are as follows：
By the performance detection of the water-base epoxy hammer paint that upper table prepares embodiment 1-4 and common hammer paint, can see
Go out, the water-base epoxy hammer paint for preparing of the present invention surface drying time, hardness of paint film, paint film toughness, impact strength, corrosion resistance with
And pot-life etc. is superior to common hammer paint.And decorative pattern to be reached can be seen that by the proportioning of different A, B component
A, B component are just pressed 4 by the effect moderate, three-dimensional sense is strong and gloss is high：1 prepares, and to reach that decorative pattern is big, three-dimensional sense is strong and light
The higher effect in pool, just presses 3 by A, B component：1 prepares.
In addition, compared with the existing technology, water-base epoxy hammer paint prepared by the present invention has the advantages that easy for construction, is not required to
Make priming paint, directly can bottom surface it is general, anti-corrosive properties are much better than existing acrylic acid or polyurethanes hammer paint, and antiseptic property is it
More than 10 times, and hardness height, good chemical resistance, paint film are three-dimensional beautiful.The product is without nuisances such as heavy metal, triphens
Matter, it is environmentally protective, harmless, belong to environmentally friendly machine, industrial applications have good prospects.
The present invention is water-based hammer artistic coating, be mainly used in all kinds of mechanical machines, instrument and meter, hardware device, with
And woodwork etc., good decoration and protection effect can be played, especially to chemical-resistant and corrosion resistance requirement
Higher engineering machinery, antitheft door, electromechanical instrument etc..
The foregoing description of the disclosed embodiments, enables professional and technical personnel in the field to realize or use the present invention.
A variety of modifications to these embodiments will be apparent for those skilled in the art, as defined herein
General Principle can be realized in other embodiments without departing from the spirit or scope of the present invention.Therefore, it is of the invention
The embodiments shown herein is not intended to be limited to, and is to fit to and the principles and novel features disclosed herein phase one
The most wide scope caused.
Claims (9)
1. a kind of water-base epoxy hammer paint, it is characterised in that include the raw material of following parts by weight：
Component A is：50-60 parts of aqueous epoxy resins, 20-32 parts of deionized water, 3-5 parts of cosolvent, wetting aid 0.3-0.8
Part, 5-8 parts of mallear stria agent, 0.3-0.8 parts of thixotropic agent, 1-2 parts of thickener, 0.8-1.5 parts of dispersant, 3-5 parts of silver powder, mill base 0.8-
1.5 parts, 0.3-0.8 parts of defoamer；
B component is：65-75 parts of aqueous epoxy curing agent, 25-35 parts of deionized water.
2. a kind of water-base epoxy hammer paint according to claim 1, it is characterised in that include the original of following parts by weight
Material：
Component A is：53-57 parts of aqueous epoxy resins, 25-28 parts of deionized water, 3.5-4.5 parts of cosolvent, wetting aid 0.4-
0.7 part, 5.5-7.5 parts of mallear stria agent, 0.4-0.7 parts of thixotropic agent, 1.2-1.8 parts of thickener, 1-1.3 parts of dispersant, silver powder 3.5-
4.5 parts, 1-1.2 parts of mill base, 0.4-0.6 parts of defoamer；
B component is：67-72 parts of aqueous epoxy curing agent, 28-32 parts of deionized water.
3. a kind of water-base epoxy hammer paint according to claim 1, it is characterised in that include the original of following parts by weight
Material：
Component A is：55 parts of aqueous epoxy resins, 27 parts of deionized water, 4 parts of cosolvent, 0.5 part of wetting aid, 6 parts of mallear stria agent,
0.5 part of thixotropic agent, 1.5 parts of thickener, 1 part of dispersant, 4 parts of silver powder, 1 part of mill base, 0.5 part of defoamer；
B component is：70 parts of aqueous epoxy curing agent, 30 parts of deionized water.
4. according to a kind of water-base epoxy hammer paint of claim 1-3 any one of them, it is characterised in that the water-base epoxy tree
Fat is resin SWT703A.
5. according to a kind of water-base epoxy hammer paint of claim 1-3 any one of them, it is characterised in that the cosolvent includes
Butyl glycol ether and alcohol ester, its ratio be 3：2.
6. according to a kind of water-base epoxy hammer paint of claim 1-3 any one of them, it is characterised in that the wetting aid is
One or more in Tego4000, Tego4100, Tego270；The mallear stria agent is mallear stria agent 68；The thixotropic agent is
BENTONE DE；The thickener is RHEOLATE299, the one or more in RM-8W, Borchi Gel0620.
7. according to a kind of water-base epoxy hammer paint of claim 1-3 any one of them, it is characterised in that the dispersant is
One or more in BYK190, BYK194；The silver powder is non-leafing aluminum paste 967；The mill base is aqueous color paste；It is described
Defoamer is the one or more in BYK024, BYK028, BYK020, Tego825, Tego810；The aqueous epoxy curing agent
For Aradur3986.
8. a kind of preparation method of water-base epoxy hammer paint, it is characterised in that include the following steps：
(1) each raw material is weighed by a kind of water-base epoxy hammer paint of claim 1 to 7 any one of them；
(2) aqueous epoxy resins weighed in step (1) are added in paint mixing cylinder, sequentially add dispersant, wetting helps
Agent and deionized water, then high-speed stirred, adds cosolvent under high-speed stirred state and thixotropic agent, high speed dispersion is opened, then
The color needed for mill base is modulated, adds thickener and silver powder, to be mixed uniform, reduces mixing speed, is adding under stirring at low speed
Enter mallear stria agent and defoamer, up to component A；
(3) aqueous epoxy curing agent that step (1) has weighed is uniformly mixed with deionized water, up to B component；
(4) component A prepared in step (2) is uniformly mixed with the B component prepared in step (3), up to water-base epoxy
Hammer paint.
A kind of 9. preparation method of water-base epoxy hammer paint according to claim 8, it is characterised in that the component A with
The ratio of the B component is 4：1 or 3：1.
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| CN201711215634.9A CN107955494A (en) | 2017-11-28 | 2017-11-28 | A kind of water-base epoxy hammer paint and preparation method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108795236A (en) * | 2018-06-15 | 2018-11-13 | 河北晨阳工贸集团有限公司 | A kind of superpower anti-corrosion function aqueous double-component epoxy orange-peel paint and preparation method thereof convenient for application |
| CN108948959A (en) * | 2018-06-29 | 2018-12-07 | 西北永新涂料有限公司 | A kind of two-component epoxy water aluminum powder paint of salt spray resistance and preparation method thereof |
| CN109207026A (en) * | 2018-07-10 | 2019-01-15 | 河北晨阳工贸集团有限公司 | A kind of lathe single-component water-based orange-peel paint and preparation method thereof |
| CN109337515A (en) * | 2018-10-08 | 2019-02-15 | 辽宁大学 | A kind of high-strength waterborne polyurethane modified epoxy orange-peel paint and its preparation method and application |
| CN109679448A (en) * | 2018-11-30 | 2019-04-26 | 成都展辰涂料有限公司 | A kind of woodenware aqueous Brilliant white paint and preparation method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108795236A (en) * | 2018-06-15 | 2018-11-13 | 河北晨阳工贸集团有限公司 | A kind of superpower anti-corrosion function aqueous double-component epoxy orange-peel paint and preparation method thereof convenient for application |
| CN108948959A (en) * | 2018-06-29 | 2018-12-07 | 西北永新涂料有限公司 | A kind of two-component epoxy water aluminum powder paint of salt spray resistance and preparation method thereof |
| CN108948959B (en) * | 2018-06-29 | 2020-08-25 | 西北永新涂料有限公司 | Salt-fog-resistant two-component epoxy water-based silver paint and preparation method thereof |
| CN109207026A (en) * | 2018-07-10 | 2019-01-15 | 河北晨阳工贸集团有限公司 | A kind of lathe single-component water-based orange-peel paint and preparation method thereof |
| CN109337515A (en) * | 2018-10-08 | 2019-02-15 | 辽宁大学 | A kind of high-strength waterborne polyurethane modified epoxy orange-peel paint and its preparation method and application |
| CN109679448A (en) * | 2018-11-30 | 2019-04-26 | 成都展辰涂料有限公司 | A kind of woodenware aqueous Brilliant white paint and preparation method thereof |
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