CN103374260A - Superhydrophobic ink and application thereof to printing plate material for offset print - Google Patents
Superhydrophobic ink and application thereof to printing plate material for offset print Download PDFInfo
- Publication number
- CN103374260A CN103374260A CN201310329766XA CN201310329766A CN103374260A CN 103374260 A CN103374260 A CN 103374260A CN 201310329766X A CN201310329766X A CN 201310329766XA CN 201310329766 A CN201310329766 A CN 201310329766A CN 103374260 A CN103374260 A CN 103374260A
- Authority
- CN
- China
- Prior art keywords
- resin
- ink
- plate
- methyl
- hydrophobicity
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Printing Plates And Materials Therefor (AREA)
Abstract
The invention discloses a superhydrophobic ink and application thereof to a printing plate material for offset print. The superhydrophobic ink comprises 5-40 wt% of film forming resin, 0.01-5 wt% of a cross-linking agent, 0.01-5 wt% of an auxiliary agent, 0.01-5 wt% of a dye and the balance of a solvent. The invention employs a printing mode to output picture and text information formed by the superhydrophobic ink to a plate base with a nanometer structure; and after solidification treatment, the plate base can be directly used for printing on a machine by using an aqueous printing ink. The superhydrophobic ink prepared by the invention has good bonding function and excellent printing fluency. The print plate mode employed by the invention does not require operation away from light, or chemical treatment processes like development and fixing, so as to satisfy environmental protection requirements as well as save materials; the usage of aqueous printing ink for printing avoids fountain solution pollution caused by rear end printing.
Description
Technical field
The invention belongs to the direct plate making of ink-jet printing technical field, particularly a kind of super-hydrophobicity is printed plate-making ink and the application in the preparation of offset printing plate thereof.
Background technology
Direct plate making of ink-jet printing technology (Inkjet Computer To Plate) is to utilize ink-jet printer to make a plate to be sprayed on the image-text area of metallograph base or polymkeric substance version primary surface formation oleophylic with ink, the zone that does not spray ink is hydrophilic non-graphic zone, the plate-making technology that utilizes the contrast realization of hydrophilic and the oleophylic in image-text area and non-graphic zone to print.The direct plate making of ink-jet printing technology has been avoided the last handling processes such as exposure, development, the gained forme be printed on the machine rear resolving power and pressrun better.Avoided the dark room operation in the mode of traditional photosensitive lithographic, the chemical treating processes such as developing fixing, these treating processess are also brought larger environmental disruption in the waste that causes material.The discharging of the VOC of the solvent type ink that printing link is selected brings environmental issue equally.
The volatile matter of organic solvent is discharged in the atmosphere, can form the Greenhouse effect even more serious than effect of carbon dioxide, and can form oxide compound and photo-chemical smog, major polluting atmosphere environment under the irradiation of sunlight.The problems such as topsoil that solvent evaporates causes in the printing ink; Arbitrarily the sewage of discharging cleaning printing ink also can cause certain pollution to water quality; Contain the heavy metal elements such as lead, chromium, cadmium, mercury in some mineral dye, all have certain toxicity, can not be used for printing food product pack and toy for children etc.Contain p-diaminodiphenyl in the pigment dyestuff that has, wherein contain carcinogenic composition, should forbid to use.
The normal organic solvent that uses is in the solvent type ink: ethanol, Virahol, butanols, propyl alcohol, butanone, vinyl acetic monomer, N-BUTYL ACETATE, toluene, dimethylbenzene etc., and the residual smell of some or frowziness, toxic, high boiling solvent, particularly butanone is dense.Although can remove most organic solvents by drying, but because the granules of pigments in the printing ink is very thin, adsorptive power is very strong, the heat drying time is short, speed is fast, drying is often not thorough, the printed matter that particularly the inking area is large, the China ink layer is thicker, its residual solvent is more, if through compound more difficult dischargeing.And residual solvent also can move at leisure, permeate, and the packing content thing is polluted.During especially for food product pack, some toxic substance can be moved in the food, and harm people's health must cause concern.
In addition, printing personnel Long Term Contact organic solvent is worked in the environment that contains high density VOC, and healthy particularly neural system can be subject to great infringement.Water color ink can be avoided the generation of above-mentioned situation.Water color ink is widely used in gravure and flexo field now.But gravure and flexo plate-making somewhat expensive.It is imperative that water color ink is introduced lower-cost offset printing field.But the offset printing mode that the plate that utilizes ink-water balance prints can't be used existing water color ink at present.
Summary of the invention
For addressing the above problem, the invention provides a kind of direct plate making of ink-jet printing super-hydrophobicity ink and the application in the preparation of offset printing plate thereof, the graph text information that the mode of namely adopt printing forms the super-hydrophobicity ink of the present invention's preparation outputs on the version base that the surface has coarse structure, after solidification treatment, can directly use water-based printing ink to be printed on the machine.
Super-hydrophobicity for offset printing plate preparation of the present invention is printed the plate-making ink, is solvent composition by film-forming resin, the linking agent of 0.01-5wt%, the auxiliary agent of 0.01-5wt%, the dyestuff of 0.01-5wt%, the surplus of 5-40wt%.
The preferred 10-25wt% of the content of described film-forming resin specifically is selected from resol, polyvinyl chloride, polystyrene, polycarbonate, polyphenylene oxide, polysulfones, polymethylmethacrylate, vibrin, polymeric amide, Resins, epoxy, polyacrylic resin, polymethacrylate resin, the carboxylate of polyacrylic resin, the carboxylate of thermoset polyacrylic resin, the carboxylate of polymethacrylate resin, the carboxylate of thermoset polymethacrylate resin, polyimide resin, silicone resin, urethane, polyoxyethylene glycol, polypropylene glycol, polyvinyl alcohol, polyvinylpyrrolidone, polyvinyl formal, in the polyvinyl butyral acetal one or more.
Described linking agent is silicon fluoride class or silicone oil, the preferred 0.1-3wt% of content.
Described silicon fluoride class is selected from least a in 17 fluorine decyl Trimethoxy silanes, 17 fluorine decyl triethoxyl silanes, triethyl silicon fluoride, ten difluoro heptyl propyl trimethoxy silicanes, 4-methyl-(the basic ethyl of perfluor) propyl trimethoxy silicane, ten trifluoro octyl group Trimethoxy silanes, the ten difluoro heptyl propyl group methyl dimethoxysilanes; Described silicone oil is selected from Methyl Hydrogen Polysiloxane Fluid, methyl chloride phenyl silicone oil, MethylethoxylsiliconFluid Fluid, methyl trifluoro propyl silicone oil, methyl vinyl silicon oil, methyl hydroxy silicon oil, ethyl containing hydrogen silicone oil, hydroxyl hydrogen silicone oil, contains one or more in the nitrile silicone.
The preferred 0.01-2wt% of the content of described auxiliary agent specifically is selected from one or more in cationic fixing agent, defoamer, the antioxidant.
Described cationic fixing agent is one or more in polymine, polyvinylamine, the diallyl dimethyl ammoniumchloride; Described defoamer is organo-siloxane or polyethers; Described antioxidant is the ester of polyvalent alcohol.
Described dyestuff is selected from a kind of in matching stain, reactive dyestuffs or the basic dyestuff.
Described matching stain is a kind of among dyestuff acid blue 9, dyestuff acid blue 9 SF, the dyestuff acid yellow 23 SF; Described reactive dyestuffs are a kind of in black dyes SP series or the reactive black; Described basic dyestuff is alkaline gorgeous orchid or Victoria blue.
Described solvent is selected from one or more in lower alcohols, rudimentary ethers, polyalcohols, ester class, the lower paraffin hydrocarbons.
Described lower alcohol is the monohydroxy-alcohol of carbonatoms≤5.Described rudimentary ether is the ether of carbonatoms≤5.Described polyalcohols is the dibasic alcohol of carbonatoms≤5 or the trivalent alcohol of carbonatoms≤5.Described ester class is carboxylic acid esters.Described lower paraffin hydrocarbons is the straight-chain paraffin of 5≤carbonatoms≤10.
Described solvent specifically is selected from one or more in ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol mono-n-butyl ether, glycol dimethyl ether, propylene glycol monomethyl ether, dihydroxypropane single-ether, 1-Methoxy-2-propyl acetate, dioxane, butylacetate, ethyl acetate, the butyl formate.
An above-mentioned edition primary surface that uses when printing plate-making for the super-hydrophobicity printing plate-making ink of offset printing plate preparation has coarse structure.
The version base that above-mentioned surface has coarse structure is the version base through electrochemical treatment of Grains roughness parameter Ra value for 0.4-0.8 μ m, and the mass area ratio of the surface film oxide that obtains after the electrochemical treatment is at 2.5-4.0g/m
2
The version base that above-mentioned surface has coarse structure is that the surface has the version base that contains nanoparticle coating.
The described high molecular polymer of consisting of of nanoparticle coating: 5-40wt%, the nano level of 5-30wt% and/or the organic solvent of micron order oxide particle and surplus of containing.
Described high molecular polymer is selected from least a in the group that carboxylate, the carboxylate of thermoset polymethacrylate resin, polyvinyl formal, polyvinyl butyral acetal, Sudan Gum-arabic, polyoxyethylene glycol, polypropylene glycol, polyvinyl alcohol, the polyvinylpyrrolidone of front three resin, resol, Resins, epoxy, urethane, polyester, urea-formaldehyde resin, thermoset polyacrylic resin form.
Described front three resin is the multipolymer of methyl methacrylate, butyl methacrylate and methacrylic acid, and wherein the mass ratio of monomers methyl methacrylate, butyl methacrylate and methacrylic acid is 1:(1-10): (1-10).The preferred linear phenolic resin of described resol.Described Resins, epoxy is glycidyl ether based epoxy resin, glycidyl ester based epoxy resin, Racemic glycidol amine epoxy resin, line style aliphatic category Resins, epoxy or aliphatic category Resins, epoxy.Described urethane is the resin that isocyanate ester compound and hydroxy-containing compounds condensation obtain, described isocyanic ester is selected from tolylene diisocyanate, isophorone diisocyanate, PPDI, Methylcyclohexyl diisocyanate or 1, the 4-cyclohexyl diisocyanate, described hydroxy-containing compounds is selected from polyoxypropyleneglycol, polycarbonate diol, polyether triol, polytetrahydrofuran diol, polyether glycol, polyester glycol, polypropylene glycol, polyoxyethylene glycol or polyacrylate polyol.The carboxylate of described thermoset polyacrylic resin is the esterification reaction product of the monohydroxy-alcohol of polyacrylic resin and carbonatoms≤5.The carboxylate of described thermoset polymethacrylate resin is the esterification reaction product of the monohydroxy-alcohol of polymethacrylate resin and carbonatoms≤5.
The particle diameter of described nano level and/or micron order oxide particle specifically is selected from least a in the group that zinc oxide, aluminum oxide, titanium dioxide, silicon-dioxide, Cadmium oxide, cerium dioxide and zirconium white form between 5-3000nm.
Described organic solvent is selected from least a in the group that ester class, acetone, butanone, methyl alcohol, ethanol, 1-propyl alcohol, 2-propyl alcohol, 2-butanols, 2-methyl-2-propanol, carbonatoms form for 〉=5 the only methyl ether of alkane, toluene, ethylene glycol monomethyl ether, ethylene glycol monoemethyl ether, glycol dimethyl ether, propylene glycol, Propylene Glycol Dimethyl Ether, ether, N-Methyl pyrrolidone and tetrahydrofuran (THF).
Described ester class is selected from least a in the group that methyl acetate, ethyl formate, propyl formate, ethyl acetate and butylacetate form.Described carbonatoms is selected from least a in the group that normal heptane, normal hexane, Skellysolve A and hexanaphthene form for 〉=5 alkane.
Common offset printing plate can't use water color ink at present, and is because the composition of plate is not suitable for the water color ink printing, dirty on the easy deinking of printing process and justifying.The graph text information that the present invention adopts the mode of printing that the super-hydrophobicity ink of preparing is formed outputs on the version base with nanometer micrometer structure, after solidification treatment, the contrast in plate surface image areas and non-graphic district is increased, effectively avoid situation dirty on deinking and the justifying, can directly use water-based printing ink to be printed on the machine.The super-hydrophobicity ink of the present invention preparation has attachment function preferably and excellent printing fluency.The mode of the printing plate-making that the present invention adopts needn't lucifuge operate, and the chemical treating processes such as Nonvisualization, photographic fixing when satisfying environmental requirement, have been saved material; The printing of use water color ink, the pollution of having avoided the rear end to print the fountain solution that brings.
Embodiment
Embodiment 1
Super-hydrophobicity is printed the preparation of plate-making ink: the resol (reaching chemical industry company limited available from Benxi, Liaoning city Switzerland) of 5wt%, the 17 fluorine decyl Trimethoxy silanes of 0.01wt%, the polymine of 0.01wt%, the dyestuff acid blue 9 of 0.1wt% and the ethylene glycol monoemethyl ether of surplus are at room temperature mixed, after polymkeric substance dissolves fully, mixing solutions is filtered, make its particle diameter be lower than 300nm, namely get super-hydrophobicity and print the plate-making ink.
The mode of utilizing spray ink Printing with the super-hydrophobicity of above-mentioned preparation print the plate-making ink take the form of picture and text be printed on Grains roughness parameter Ra value as 0.5 μ m through electrochemical treatment and on the aluminium plate base behind the acetone rinsing, the mass area ratio of oxide film is at 3.0g/m
2Namely get the plate for offset printing after solidification treatment, the plate after the plate-making can directly use on the machine the water color ink printing.
Embodiment 2
Super-hydrophobicity is printed the preparation of plate-making ink: with the urethane (the Tianjin atropic is Fine Chemical Co., Ltd hereby) of 40wt%, the methyl vinyl silicon oil of 5wt%, the diallyl dimethyl ammoniumchloride of 1wt%, the containing hydrogen silicone oil of 2wt% (Shanghai open flat resin company limited), the Macrogol 200 monoleate of 2wt% (Shanghai Ao highland barley Industrial Co., Ltd.), the black dyes SP of 0.2wt% and the 1-Methoxy-2-propyl acetate of surplus at room temperature mix, after polymkeric substance dissolves fully, mixing solutions is filtered, make its particle diameter be lower than 200nm, namely get super-hydrophobicity and print the plate-making ink.
Contain the nanoparticle coating material preparation: the front three resin that will account for coating total amount 25wt% is (certainly synthetic, take the mass ratio of methyl methacrylate, butyl methacrylate and methacrylic acid as 1:1:5), the zinc oxide of 15wt% (particle diameter 200nm), and the ethyl acetate of surplus is mixed, stirring at room, remove impurity, obtain described coated material.
With not passing through the aluminium plate of electrolytic graining and anodic oxidation treatment, successively clean oven dry with acetone and water; Above-mentioned coated material is coated on the aluminium plate after the oven dry oven dry, the aluminium plate base that has certain roughness to obtain the surface with rolling method.
The mode of utilizing spray ink Printing is printed the plate-making ink with the super-hydrophobicity of above-mentioned preparation and is printed on the aluminium plate base of above-mentioned coating with the form of picture and text, namely get the plate for offset printing after solidification treatment, the plate after the plate-making can directly use on the machine the water color ink printing.
Embodiment 3
Super-hydrophobicity is printed the preparation of plate-making ink: with the resol (reaching chemical industry company limited available from Benxi, Liaoning city Switzerland) of 10wt%, the Resins, epoxy of 5wt% (be chemical industry company limited available from Guangzhou U.S.A), the Macrogol 2000 of 1wt%, the hydroxyl hydrogen silicone oil of 2wt%, the polyvinylamine of 0.02wt%, the active black dye SP of 0.2wt%, the ethylene glycol monoemethyl ether of 20wt% and the glycol dimethyl ether of surplus at room temperature mix, after polymkeric substance dissolves fully, mixing solutions is filtered, make its particle diameter be lower than 200nm, namely get super-hydrophobicity and print the plate-making ink.
Contain the nanoparticle coating material preparation: will account for the linear phenolic resin of coating total amount 40wt%, the aluminum oxide of 30wt% (particle diameter 5nm), and the mixing of the propylene glycol monomethyl ether of surplus, stirring at room is removed impurity, obtains described coated material.
With not passing through the aluminium plate of electrolytic graining and anodic oxidation treatment, successively clean oven dry with acetone and water; Above-mentioned coated material is coated on the aluminium plate after the oven dry oven dry, the aluminium plate base that has certain roughness to obtain the surface with rolling method.
The mode of utilizing spray ink Printing is printed the plate-making ink with the super-hydrophobicity of above-mentioned preparation and is printed on the aluminium plate base of above-mentioned coating with the form of picture and text, namely get the plate for offset printing after solidification treatment, the plate after the plate-making can directly use on the machine the water color ink printing.
Embodiment 4
Super-hydrophobicity is printed the preparation of plate-making ink: the polyvinyl butyral acetal (Beijing chemical reagents corporation) of 25wt%, the 17 fluorine decyl triethoxyl silanes of 0.01wt%, the methyl hydroxy silicon oil of 1wt%, the Macrogol 200 monoleate (Shanghai Ao highland barley Industrial Co., Ltd.) of 0.01wt%, the dyestuff acid yellow 23 SF of 0.1wt% and the propylene glycol monomethyl ether of surplus are at room temperature mixed, after polymkeric substance dissolves fully, mixing solutions is filtered, make its particle diameter be lower than 200nm, namely get super-hydrophobicity and print the plate-making ink.
Contain the nanoparticle coating material preparation: will account for the Resins, epoxy of coating total amount 20wt%, the titanium dioxide of 20wt% (particle diameter 300nm), and the mixing of the propyl formate of surplus, stirring at room is removed impurity, obtains described coated material.
With not passing through the aluminium plate of electrolytic graining and anodic oxidation treatment, successively clean oven dry with acetone and water; Above-mentioned coated material is coated on the aluminium plate after the oven dry oven dry, the aluminium plate base that has certain roughness to obtain the surface with rolling method.
The mode of utilizing spray ink Printing is printed the plate-making ink with the super-hydrophobicity of above-mentioned preparation and is printed on the aluminium plate base of above-mentioned coating with the form of picture and text, namely get the plate for offset printing after solidification treatment, the plate after the plate-making can directly use on the machine the water color ink printing.
Embodiment 5
Super-hydrophobicity is printed the preparation of plate-making ink: the polyimide (being purchased from Honghu City span novel material Science and Technology Ltd.) of 15wt%, the ten trifluoro octyl group Trimethoxy silanes of 0.01wt%, the methyl vinyl silicon oil of 0.01wt%, the dyestuff acid blue 9 SF of 0.03wt% and the hexanaphthene of surplus are at room temperature mixed, after polymkeric substance dissolves fully, mixing solutions is filtered, make its particle diameter be lower than 400nm, namely get super-hydrophobicity and print the plate-making ink.
Contain the nanoparticle coating material preparation: the resol that will account for coating total amount 10wt%, the front three resin of 5wt% is (certainly synthetic, take the mass ratio of methyl methacrylate, butyl methacrylate and methacrylic acid as 1:4:2), the zinc oxide (particle diameter 400nm) of the Resins, epoxy of 5wt% (be chemical industry company limited available from Guangzhou U.S.A), 15wt%, and the butylacetate of surplus mixes, stirring at room, remove impurity, obtain described coated material.
With not passing through the aluminium plate of electrolytic graining and anodic oxidation treatment, successively clean oven dry with acetone and water; Above-mentioned coated material is coated on the aluminium plate after the oven dry oven dry, the aluminium plate base that has certain roughness to obtain the surface with rolling method.
The mode of utilizing spray ink Printing is printed the plate-making ink with the super-hydrophobicity of above-mentioned preparation and is printed on the aluminium plate base of above-mentioned coating with the form of picture and text, namely get the plate for offset printing after solidification treatment, the plate after the plate-making can directly use on the machine the water color ink printing.
Embodiment 6
Super-hydrophobicity is printed the preparation of plate-making ink: with the polymeric amide of 30wt% (Tianjin, Beijing happy together safe Chemicals company limited), 1wt% contains nitrile silicone, the diallyl dimethyl ammoniumchloride of 0.02wt%, the containing hydrogen silicone oil of 0.03wt% (Shanghai open flat resin company limited), the Macrogol 200 monoleate of 1wt% (Shanghai Ao highland barley Industrial Co., Ltd.), the black dyes SP of 0.2wt% and the ethylene glycol monoethyl ether of surplus at room temperature mix, after polymkeric substance dissolves fully, mixing solutions is filtered, make its particle diameter be lower than 250nm, namely get super-hydrophobicity and print the plate-making ink.
Contain the nanoparticle coating material preparation: the front three resin that will account for coating total amount 15wt% is (certainly synthetic, take the mass ratio of methyl methacrylate, butyl methacrylate and methacrylic acid as 1:4:2), the silicon oxide of 10wt% (particle diameter 500nm), the ethanol of 5wt% and the n-butyl acetate of surplus mix, stirring at room, remove impurity, obtain described coated material.
With not passing through the aluminium plate of electrolytic graining and anodic oxidation treatment, successively clean oven dry with acetone and water; Above-mentioned coated material is coated on the aluminium plate after the oven dry oven dry, the aluminium plate base that has certain roughness to obtain the surface with rolling method.
The mode of utilizing spray ink Printing is printed the plate-making ink with the super-hydrophobicity of above-mentioned preparation and is printed on the aluminium plate base of above-mentioned coating with the form of picture and text, namely get the plate for offset printing after solidification treatment, the plate after the plate-making can directly use on the machine the water color ink printing.
The prepared plate of embodiment 1-6 is printed on the machine experiment and shows that its pressrun, resolving power can satisfy the requirement of domestic market, and the discharging of gained printed matter VOC free is conducive to the raising of environment protection and printing technology.
Claims (10)
1. a super-hydrophobicity that is used for the preparation of offset printing plate is printed the plate-making ink, it is characterized in that the linking agent of its film-forming resin by 5-40wt%, 0.01-5wt%, the auxiliary agent of 0.01-5wt%, the dyestuff of 0.01-5wt%, surplus are solvent composition.
2. the super-hydrophobicity for the preparation of offset printing plate according to claim 1 is printed the plate-making ink, it is characterized in that, the content of described film-forming resin is 10-25wt%, specifically is selected from resol, polyvinyl chloride, polystyrene, polycarbonate, polyphenylene oxide, polysulfones, polymethylmethacrylate, vibrin, polymeric amide, Resins, epoxy, polyacrylic resin, polymethacrylate resin, the carboxylate of polyacrylic resin, the carboxylate of thermoset polyacrylic resin, the carboxylate of polymethacrylate resin, the carboxylate of thermoset polymethacrylate resin, polyimide resin, silicone resin, urethane, polyoxyethylene glycol, polypropylene glycol, polyvinyl alcohol, polyvinylpyrrolidone, polyvinyl formal, in the polyvinyl butyral acetal one or more.
3. the super-hydrophobicity for the preparation of offset printing plate according to claim 1 is printed the plate-making ink, it is characterized in that described linking agent is silicon fluoride class or silicone oil, and content is 0.1-3wt%; Described silicon fluoride class is selected from least a in 17 fluorine decyl Trimethoxy silanes, 17 fluorine decyl triethoxyl silanes, triethyl silicon fluoride, ten difluoro heptyl propyl trimethoxy silicanes, 4-methyl-(the basic ethyl of perfluor) propyl trimethoxy silicane, ten trifluoro octyl group Trimethoxy silanes, the ten difluoro heptyl propyl group methyl dimethoxysilanes; Described silicone oil is selected from Methyl Hydrogen Polysiloxane Fluid, methyl chloride phenyl silicone oil, MethylethoxylsiliconFluid Fluid, methyl trifluoro propyl silicone oil, methyl vinyl silicon oil, methyl hydroxy silicon oil, ethyl containing hydrogen silicone oil, hydroxyl hydrogen silicone oil, contains one or more in the nitrile silicone.
4. the super-hydrophobicity for the preparation of offset printing plate according to claim 1 is printed the plate-making ink, it is characterized in that the content of described auxiliary agent is 0.01-2wt%, specifically is selected from one or more in cationic fixing agent, defoamer, the antioxidant; Described cationic fixing agent is one or more in polymine, polyvinylamine, the diallyl dimethyl ammoniumchloride; Described defoamer is organo-siloxane or polyethers; Described antioxidant is the ester of polyvalent alcohol.
5. the super-hydrophobicity for offset printing plate preparation according to claim 1 is printed the plate-making ink, it is characterized in that, described dyestuff is selected from a kind of in matching stain, reactive dyestuffs or the basic dyestuff; Described matching stain is a kind of among dyestuff acid blue 9, dyestuff acid blue 9 SF, the dyestuff acid yellow 23 SF; Described reactive dyestuffs are a kind of in black dyes SP series or the reactive black; Described basic dyestuff is alkaline gorgeous orchid or Victoria blue.
6. the super-hydrophobicity for the preparation of offset printing plate according to claim 1 is printed the plate-making ink, it is characterized in that described solvent is selected from one or more in lower alcohols, rudimentary ethers, polyalcohols, ester class, the lower paraffin hydrocarbons; Described lower alcohols is the monohydroxy-alcohol of carbonatoms≤5; Described rudimentary ethers is the ether of carbonatoms≤5; Described polyalcohols is the dibasic alcohol of carbonatoms≤5 or the trivalent alcohol of carbonatoms≤5; Described ester class is carboxylic acid esters; Described lower paraffin hydrocarbons is the straight-chain paraffin of 5≤carbonatoms≤10.
7. the super-hydrophobicity for the preparation of offset printing plate according to claim 1 is printed the plate-making ink, it is characterized in that described solvent specifically is selected from one or more in ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol mono-n-butyl ether, glycol dimethyl ether, propylene glycol monomethyl ether, dihydroxypropane single-ether, 1-Methoxy-2-propyl acetate, dioxane, butylacetate, ethyl acetate, the butyl formate.
8. arbitrary described super-hydrophobicity for the preparation of offset printing plate is printed the plate-making ink according to claim 1-7, it is characterized in that a described edition primary surface that uses for the super-hydrophobicity printing plate-making ink of offset printing plate preparation has coarse structure when printing plate-making.
9. the super-hydrophobicity for the preparation of offset printing plate according to claim 8 is printed the plate-making ink, it is characterized in that, the version base that described surface has coarse structure is the version base through electrochemical treatment of Grains roughness parameter Ra value for 0.4-0.8 μ m, and the mass area ratio of the surface film oxide that obtains after the electrochemical treatment is at 2.5-4.0g/m
2
10. the super-hydrophobicity for offset printing plate preparation according to claim 8 is printed the plate-making ink, it is characterized in that, the version base that described surface has a coarse structure contains the version base of nanoparticle coating for the surface has;
The described high molecular polymer of consisting of of nanoparticle coating: 5-40wt%, the nano level of 5-30wt% and/or the organic solvent of micron order oxide particle and surplus of containing;
Described high molecular polymer is selected from least a in the group that carboxylate, the carboxylate of thermoset polymethacrylate resin, polyvinyl formal, polyvinyl butyral acetal, Sudan Gum-arabic, polyoxyethylene glycol, polypropylene glycol, polyvinyl alcohol, the polyvinylpyrrolidone of front three resin, resol, Resins, epoxy, urethane, polyester, urea-formaldehyde resin, thermoset polyacrylic resin form;
Described front three resin is the multipolymer of methyl methacrylate, butyl methacrylate and methacrylic acid, and wherein the mass ratio of monomers methyl methacrylate, butyl methacrylate and methacrylic acid is 1:(1-10): (1-10); Described resol is linear phenolic resin; Described Resins, epoxy is glycidyl ether based epoxy resin, glycidyl ester based epoxy resin, Racemic glycidol amine epoxy resin, line style aliphatic category Resins, epoxy or aliphatic category Resins, epoxy; Described urethane is the resin that isocyanate ester compound and hydroxy-containing compounds condensation obtain, described isocyanic ester is selected from tolylene diisocyanate, isophorone diisocyanate, PPDI, Methylcyclohexyl diisocyanate or 1, the 4-cyclohexyl diisocyanate, described hydroxy-containing compounds is selected from polyoxypropyleneglycol, polycarbonate diol, polyether triol, polytetrahydrofuran diol, polyether glycol, polyester glycol, polypropylene glycol, polyoxyethylene glycol or polyacrylate polyol; The carboxylate of described thermoset polyacrylic resin is the esterification reaction product of the monohydroxy-alcohol of polyacrylic resin and carbonatoms≤5; The carboxylate of described thermoset polymethacrylate resin is the esterification reaction product of the monohydroxy-alcohol of polymethacrylate resin and carbonatoms≤5;
The particle diameter of described nano level and/or micron order oxide particle specifically is selected from least a in the group that zinc oxide, aluminum oxide, titanium dioxide, silicon-dioxide, Cadmium oxide, cerium dioxide and zirconium white form between 5-3000nm;
Described organic solvent is selected from least a in the group that ester class, acetone, butanone, methyl alcohol, ethanol, 1-propyl alcohol, 2-propyl alcohol, 2-butanols, 2-methyl-2-propanol, carbonatoms form for 〉=5 the only methyl ether of alkane, toluene, ethylene glycol monomethyl ether, ethylene glycol monoemethyl ether, glycol dimethyl ether, propylene glycol, Propylene Glycol Dimethyl Ether, ether, N-Methyl pyrrolidone and tetrahydrofuran (THF);
Described ester class is selected from least a in the group that methyl acetate, ethyl formate, propyl formate, ethyl acetate and butylacetate form; Described carbonatoms is selected from least a in the group that normal heptane, normal hexane, Skellysolve A and hexanaphthene form for 〉=5 alkane.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310329766.XA CN103374260B (en) | 2013-07-31 | 2013-07-31 | Superhydrophobic ink and application thereof to printing plate material for offset print |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310329766.XA CN103374260B (en) | 2013-07-31 | 2013-07-31 | Superhydrophobic ink and application thereof to printing plate material for offset print |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103374260A true CN103374260A (en) | 2013-10-30 |
| CN103374260B CN103374260B (en) | 2014-12-17 |
Family
ID=49460118
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310329766.XA Active CN103374260B (en) | 2013-07-31 | 2013-07-31 | Superhydrophobic ink and application thereof to printing plate material for offset print |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103374260B (en) |
Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103666094A (en) * | 2013-11-18 | 2014-03-26 | 蚌埠天光传感器有限公司 | Refractory printing ink and preparation method thereof |
| CN103790030A (en) * | 2013-12-30 | 2014-05-14 | 谢亚军 | Anhydrous printing environment-friendly ink and using method thereof |
| CN103937324A (en) * | 2014-03-21 | 2014-07-23 | 中国科学院化学研究所 | Free radical polymerization hydrophilic coating material and application of free radical polymerization hydrophilic coating material in preparation of printing plate material |
| CN104325802A (en) * | 2014-10-27 | 2015-02-04 | 中国科学院化学研究所 | Novel plate material using water-based printing ink |
| CN104513638A (en) * | 2015-01-22 | 2015-04-15 | 南安市荣兴专利技术转移中心有限公司 | Macromolecular new material environment-friendly adhesive |
| CN105862465A (en) * | 2016-05-04 | 2016-08-17 | 合肥聚合辐化技术有限公司 | Carboxylated-acrylonitrile-containing multi-compound imitated activity pigment printing binding agent and preparation method thereof |
| CN105862466A (en) * | 2016-05-04 | 2016-08-17 | 合肥聚合辐化技术有限公司 | Pigment printing bonding agent prepared with radiation method and preparing method thereof |
| CN106120375A (en) * | 2016-06-27 | 2016-11-16 | 苏州聚福环保科技有限公司 | A kind of environment-friendlytype type fabric printing and dyeing ink and preparation method thereof |
| CN106199899A (en) * | 2015-05-25 | 2016-12-07 | 超金光学有限公司 | Optical zooming method and module and application thereof |
| CN106274122A (en) * | 2015-06-02 | 2017-01-04 | 中国科学院化学研究所 | A kind of lithographic plate and its preparation method and application |
| CN107987712A (en) * | 2017-12-21 | 2018-05-04 | 珠海智星荟科技服务有限公司 | There is aqueous epoxy floor coating of anti-corrosive antibacterial and preparation method thereof |
| CN108192417A (en) * | 2017-12-06 | 2018-06-22 | 李正恩 | A kind of hydrophobic printed label |
| CN108329445A (en) * | 2017-01-20 | 2018-07-27 | 中国科学院化学研究所 | A kind of phenolic resin esterification benzene sulfonate and its synthetic method, printing hydrophilic version and application and galley |
| CN109021680A (en) * | 2018-07-28 | 2018-12-18 | 广东绿之彩印刷科技股份有限公司 | It is a kind of directly to export the ink and preparation method thereof on the film |
| CN109021685A (en) * | 2018-09-21 | 2018-12-18 | 楼乐超 | A kind of hydrophobicity fixation ink and its preparation process |
| CN109266094A (en) * | 2018-08-01 | 2019-01-25 | 广东和润新材料股份有限公司 | The preparation method of heat dissipation ink and the shielding case that radiates |
| CN110194913A (en) * | 2015-01-08 | 2019-09-03 | 佳能株式会社 | Image recording process, ink and liquid composition |
| CN112118802A (en) * | 2018-06-29 | 2020-12-22 | 3M创新有限公司 | Orthodontic articles prepared using polycarbonate diols and methods of making the same |
| US11225535B2 (en) | 2018-06-29 | 2022-01-18 | 3M Innovative Properties Company | Photopolymerizable compositions including a polyurethane methacrylate polymer prepared using a polycarbonate diol, articles, and methods |
| CN114059365A (en) * | 2021-12-23 | 2022-02-18 | 江苏德旺数码科技有限公司 | Dye composition for digital printing |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5218381A (en) * | 1992-04-28 | 1993-06-08 | Xerox Corporation | Hydrophobic coating for a front face of a printhead in an ink jet printer |
| CN101293441A (en) * | 2008-06-23 | 2008-10-29 | 石深泉 | Environment-friendly ink-jet CTP offset master and production method thereof |
| CN102757692A (en) * | 2011-06-10 | 2012-10-31 | 戴龙飞 | Thermosetting system white ink composition of LED flexible strip plate |
-
2013
- 2013-07-31 CN CN201310329766.XA patent/CN103374260B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5218381A (en) * | 1992-04-28 | 1993-06-08 | Xerox Corporation | Hydrophobic coating for a front face of a printhead in an ink jet printer |
| CN101293441A (en) * | 2008-06-23 | 2008-10-29 | 石深泉 | Environment-friendly ink-jet CTP offset master and production method thereof |
| CN102757692A (en) * | 2011-06-10 | 2012-10-31 | 戴龙飞 | Thermosetting system white ink composition of LED flexible strip plate |
Cited By (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103666094A (en) * | 2013-11-18 | 2014-03-26 | 蚌埠天光传感器有限公司 | Refractory printing ink and preparation method thereof |
| CN103666094B (en) * | 2013-11-18 | 2016-06-15 | 蚌埠天光传感器有限公司 | A kind of printing-ink and its preparation method |
| CN103790030A (en) * | 2013-12-30 | 2014-05-14 | 谢亚军 | Anhydrous printing environment-friendly ink and using method thereof |
| CN103937324A (en) * | 2014-03-21 | 2014-07-23 | 中国科学院化学研究所 | Free radical polymerization hydrophilic coating material and application of free radical polymerization hydrophilic coating material in preparation of printing plate material |
| CN104325802A (en) * | 2014-10-27 | 2015-02-04 | 中国科学院化学研究所 | Novel plate material using water-based printing ink |
| CN110194913A (en) * | 2015-01-08 | 2019-09-03 | 佳能株式会社 | Image recording process, ink and liquid composition |
| CN104513638A (en) * | 2015-01-22 | 2015-04-15 | 南安市荣兴专利技术转移中心有限公司 | Macromolecular new material environment-friendly adhesive |
| CN106199899A (en) * | 2015-05-25 | 2016-12-07 | 超金光学有限公司 | Optical zooming method and module and application thereof |
| CN106274122A (en) * | 2015-06-02 | 2017-01-04 | 中国科学院化学研究所 | A kind of lithographic plate and its preparation method and application |
| CN106274122B (en) * | 2015-06-02 | 2018-11-30 | 中国科学院化学研究所 | A kind of lithographic plate and its preparation method and application |
| CN105862466A (en) * | 2016-05-04 | 2016-08-17 | 合肥聚合辐化技术有限公司 | Pigment printing bonding agent prepared with radiation method and preparing method thereof |
| CN105862465A (en) * | 2016-05-04 | 2016-08-17 | 合肥聚合辐化技术有限公司 | Carboxylated-acrylonitrile-containing multi-compound imitated activity pigment printing binding agent and preparation method thereof |
| CN106120375A (en) * | 2016-06-27 | 2016-11-16 | 苏州聚福环保科技有限公司 | A kind of environment-friendlytype type fabric printing and dyeing ink and preparation method thereof |
| CN106120375B (en) * | 2016-06-27 | 2018-06-19 | 苏州聚福环保科技有限公司 | A kind of environment-friendlytype type fabric printing and dyeing ink and preparation method thereof |
| CN108329445A (en) * | 2017-01-20 | 2018-07-27 | 中国科学院化学研究所 | A kind of phenolic resin esterification benzene sulfonate and its synthetic method, printing hydrophilic version and application and galley |
| CN108329445B (en) * | 2017-01-20 | 2019-05-03 | 中国科学院化学研究所 | A kind of phenolic resin esterification benzene sulfonate and its synthetic method, printing hydrophilic version and application and galley |
| CN108192417A (en) * | 2017-12-06 | 2018-06-22 | 李正恩 | A kind of hydrophobic printed label |
| CN107987712B (en) * | 2017-12-21 | 2020-06-02 | 珠海智星荟科技服务有限公司 | Water-based epoxy floor coating with anticorrosion and antibacterial functions and preparation method thereof |
| CN107987712A (en) * | 2017-12-21 | 2018-05-04 | 珠海智星荟科技服务有限公司 | There is aqueous epoxy floor coating of anti-corrosive antibacterial and preparation method thereof |
| US11104758B2 (en) | 2018-06-29 | 2021-08-31 | 3M Innovative Properties Company | Orthodontic articles prepared using a polycarbonate diol, and methods of making same |
| CN112118802A (en) * | 2018-06-29 | 2020-12-22 | 3M创新有限公司 | Orthodontic articles prepared using polycarbonate diols and methods of making the same |
| CN112118802B (en) * | 2018-06-29 | 2021-12-07 | 3M创新有限公司 | Orthodontic articles prepared using polycarbonate diols and methods of making the same |
| US11225535B2 (en) | 2018-06-29 | 2022-01-18 | 3M Innovative Properties Company | Photopolymerizable compositions including a polyurethane methacrylate polymer prepared using a polycarbonate diol, articles, and methods |
| US11708428B2 (en) | 2018-06-29 | 2023-07-25 | 3M Innovative Properties Company | Photopolymerizable compositions including a polyurethane methacrylate polymer prepared using a polycarbonate diol, articles, and methods |
| CN109021680A (en) * | 2018-07-28 | 2018-12-18 | 广东绿之彩印刷科技股份有限公司 | It is a kind of directly to export the ink and preparation method thereof on the film |
| CN109266094A (en) * | 2018-08-01 | 2019-01-25 | 广东和润新材料股份有限公司 | The preparation method of heat dissipation ink and the shielding case that radiates |
| CN109266094B (en) * | 2018-08-01 | 2021-07-09 | 广东和润新材料股份有限公司 | Preparation method of heat dissipation ink and heat dissipation shielding case |
| CN109021685A (en) * | 2018-09-21 | 2018-12-18 | 楼乐超 | A kind of hydrophobicity fixation ink and its preparation process |
| CN114059365A (en) * | 2021-12-23 | 2022-02-18 | 江苏德旺数码科技有限公司 | Dye composition for digital printing |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103374260B (en) | 2014-12-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103374260B (en) | Superhydrophobic ink and application thereof to printing plate material for offset print | |
| CN103305078B (en) | A kind of hydrophobic material and the application in the preparation of offset printing plate thereof | |
| CN1955234B (en) | Photogravure ink equal to cut ink and its application | |
| Aydemir et al. | Environmental impact of printing inks and printing process | |
| CN1970657B (en) | Printing oil ink and production method of coating film using the oil ink | |
| TW201720881A (en) | Lithographic printing ink, varnish for lithographic inks, and method for producing printed matter using said ink | |
| JP5873555B2 (en) | Coating materials for aluminum substrates for inkjet computer to plate and their preparation and use | |
| CN101275041B (en) | Penetration inhibitor, solvent inkjet ink, and penetration inhibiting method | |
| CN106274122B (en) | A kind of lithographic plate and its preparation method and application | |
| CN102993823A (en) | Water-based ink used in inkjet printing direct-to-plate, and preparation method thereof | |
| CN102533068A (en) | Ultraviolet curing aluminized transferring coating and preparation method and application thereof | |
| CN101161735B (en) | Penetration inhibitor method | |
| EP1808466B1 (en) | Ink composition, inkjet recording method, printed material, process for producing lithographic printing plate, and lithographic printing plate | |
| CN108329446B (en) | Phenolic resin is esterified sulfonate and its synthetic method, printing hydrophilic version and application and galley | |
| CN103057294B (en) | Environmental-protecting type waterless offset plate | |
| CN104325802B (en) | Novel plate material using water-based printing ink | |
| CN110669378A (en) | Water-based ink composition and preparation method and application thereof | |
| WO2012163288A1 (en) | Ink for direct platemaking of nanometer material printing and method for preparing same | |
| JP2008138018A (en) | Oil-based pigment ink composition | |
| CN102161848B (en) | Heat shrinkage ink for direct plate making of inkjet printing as well as preparation method and application thereof | |
| CN108329409A (en) | Polyvinyl alcohol sulfonated ester and its synthetic method, printing hydrophilic version and application and galley | |
| JP4884932B2 (en) | Oil-based pigment ink composition for inkjet printer | |
| JP2006037020A (en) | Oil-based pigment ink composition for inkjet printer | |
| JP2008101099A (en) | Oily pigment ink composition | |
| JP2007090879A (en) | Recording method, reproducible recording paper, coloring ink, and reproducing method for the recording paper |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |