CN103666094A - Refractory printing ink and preparation method thereof - Google Patents
Refractory printing ink and preparation method thereof Download PDFInfo
- Publication number
- CN103666094A CN103666094A CN201310574961.9A CN201310574961A CN103666094A CN 103666094 A CN103666094 A CN 103666094A CN 201310574961 A CN201310574961 A CN 201310574961A CN 103666094 A CN103666094 A CN 103666094A
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- parts
- ink
- ethanol
- preparation
- butyl ester
- Prior art date
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- Granted
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- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 238000007639 printing Methods 0.000 title abstract description 6
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims abstract description 21
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 14
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims abstract description 8
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims abstract description 7
- GTELLNMUWNJXMQ-UHFFFAOYSA-N 2-ethyl-2-(hydroxymethyl)propane-1,3-diol;prop-2-enoic acid Chemical class OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.CCC(CO)(CO)CO GTELLNMUWNJXMQ-UHFFFAOYSA-N 0.000 claims abstract description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 7
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 7
- 229910000416 bismuth oxide Inorganic materials 0.000 claims abstract description 7
- 229910052810 boron oxide Inorganic materials 0.000 claims abstract description 7
- TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 claims abstract description 7
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- 239000011787 zinc oxide Substances 0.000 claims abstract description 7
- 230000003647 oxidation Effects 0.000 claims abstract description 4
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- 239000012752 auxiliary agent Substances 0.000 claims description 7
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 claims description 6
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 239000003153 chemical reaction reagent Substances 0.000 claims description 6
- 230000008878 coupling Effects 0.000 claims description 6
- 238000010168 coupling process Methods 0.000 claims description 6
- 238000005859 coupling reaction Methods 0.000 claims description 6
- 238000005502 peroxidation Methods 0.000 claims description 6
- WBHHMMIMDMUBKC-QJWNTBNXSA-N ricinoleic acid Chemical compound CCCCCC[C@@H](O)C\C=C/CCCCCCCC(O)=O WBHHMMIMDMUBKC-QJWNTBNXSA-N 0.000 claims description 6
- 229960003656 ricinoleic acid Drugs 0.000 claims description 6
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 claims description 6
- 229910000077 silane Inorganic materials 0.000 claims description 6
- 229910052710 silicon Inorganic materials 0.000 claims description 6
- 239000010703 silicon Substances 0.000 claims description 6
- VXHFNALHLRWIIU-UHFFFAOYSA-N tert-butyl 2,2-dimethylpropanoate Chemical compound CC(C)(C)OC(=O)C(C)(C)C VXHFNALHLRWIIU-UHFFFAOYSA-N 0.000 claims description 6
- OSBSFAARYOCBHB-UHFFFAOYSA-N tetrapropylammonium Chemical compound CCC[N+](CCC)(CCC)CCC OSBSFAARYOCBHB-UHFFFAOYSA-N 0.000 claims description 6
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 238000009826 distribution Methods 0.000 claims description 3
- 239000000975 dye Substances 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 239000003112 inhibitor Substances 0.000 claims description 3
- 239000000049 pigment Substances 0.000 claims description 3
- 239000000244 polyoxyethylene sorbitan monooleate Substances 0.000 claims description 3
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 3
- 229920000053 polysorbate 80 Polymers 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 4
- 230000001681 protective effect Effects 0.000 abstract description 2
- 230000002349 favourable effect Effects 0.000 abstract 4
- NDWUBGAGUCISDV-UHFFFAOYSA-N 4-hydroxybutyl prop-2-enoate Chemical compound OCCCCOC(=O)C=C NDWUBGAGUCISDV-UHFFFAOYSA-N 0.000 abstract 1
- 238000005299 abrasion Methods 0.000 abstract 1
- 238000009776 industrial production Methods 0.000 abstract 1
- 239000012860 organic pigment Substances 0.000 abstract 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 abstract 1
- ZNVWLZGTXSHPMH-UHFFFAOYSA-N tert-butyl 3-hydroperoxy-2,2-dimethylpropanoate Chemical compound CC(C)(C)OC(=O)C(C)(C)COO ZNVWLZGTXSHPMH-UHFFFAOYSA-N 0.000 abstract 1
- -1 tetrapropylammonium tetrafluoroborate Chemical compound 0.000 abstract 1
- 238000001035 drying Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000002844 melting Methods 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- POCFBDFTJMJWLG-UHFFFAOYSA-N dihydrosinapic acid methyl ester Natural products COC(=O)CCC1=CC(OC)=C(O)C(OC)=C1 POCFBDFTJMJWLG-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention relates to a refractory printing ink which is prepared from the following raw materials in parts by weight: 3-4 parts of bismuth oxide, 2-3 parts of boron oxide, 3-4 parts of zinc oxide, 4-6 parts of silica sol, 5-8 parts of ethyl acetate, 1-2 parts of tetrapropylammonium tetrafluoroborate, 3-4 parts of 2-butoxy-ethanol, 6-8 parts of isopropanol, 10-12 parts of ethoxylated trimethylolpropane triacrylate, 12-14 parts of 4-hydroxybutyl acrylate, 6-9 parts of polyethyleneglycol acrylate, 1-2 parts of tert-butyl peroxylpivalate, 3-4 parts of organic pigment and 4-5 parts of assistant. The ink has the advantages of favorable glossiness, bright color, high fastness, favorable water resistance, favorable refractoriness, favorable abrasion resistance and the like; and the preparation method of the ink is simple and quick in the preparation process and is suitable for industrial production. The assistant can form a protective film on the ink surface to isolate air, prevent water and other molecules in air from corroding the surfaces of the ink and sprayed objects and resist oxidation, so that the color can be bright permanently, and the smoothness is enhanced.
Description
Technical field
The invention belongs to printing ink paint field, relate in particular to a kind of refractoriness printing-ink and preparation method thereof.
Background technology
The color of ink (form and aspect), body bone (rheological property such as rare thick, degree of mobilization) and drying property are three most important performances of ink.Their kind is a lot, and physical properties is also different, and what have is very thick, very sticky; And have quite rare.What have makes low-melting ink vehicle with vegetables oil; Somely with resin and solvent or water etc., make low-melting ink vehicle.These are to be all that the type of stock, printing process, printing plate and drying means etc. decide according to the object of printing.
The rate of drying of ink, thixotropy, skeleton property have tremendous influence to production efficiency, quality product, and the composition of ink has impact to human body, how to study as far as possible little to harm, production efficiency is high, environmental friendliness, ink that cost is low have profound significance.
Summary of the invention
The object of the present invention is to provide a kind of refractoriness printing-ink and preparation method thereof, this ink is water-fast, refractory, wear-resisting.
Technical scheme of the present invention is as follows:
A refractoriness printing-ink, is characterized in that being made by the raw material of following weight part: bismuth oxide 3-4, boron oxide 2-3, zinc oxide 3-4, silicon sol 4-6, ethyl acetate 5-8, tetrapropyl ammonium borofluoride 1-2,2-butoxy-ethanol 3-4, Virahol 6-8, ethoxylated trimethylolpropane triacrylate 10-12, vinylformic acid-4-hydroxyl butyl ester 12-14, polyethylene glycol acrylate 6-9, peroxidation trimethylacetic acid tert-butyl ester 1-2, pigment dyestuff 3-4, auxiliary agent 4-5;
Described auxiliary agent is made by the raw material of following weight part: Silane coupling reagent KH-570 2-3, Viscoat 295 3-4,2-n-octyl-4-isothiazoline-3-ketone 1-2,2-amino-2-methyl-1-propyl alcohol 1-2, polyoxyethylene sorbitan monooleate 2-3, ricinolic acid 1-2, oxidation inhibitor 1035 1-2, linking agent TAC1-2, ethanol 20-24; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 60-70 ℃, stirs after 20-30 minute, then adds other remaining component, is warming up to 80-85 ℃, stirs 30-40 minutes, obtains.
The preparation method of described refractoriness printing-ink, it is characterized in that comprising the following steps: by bismuth oxide, boron oxide, zinc oxide, silicon sol, ethyl acetate, tetrapropyl ammonium borofluoride, 2-butoxy-ethanol, Virahol, ethoxylated trimethylolpropane triacrylate mixes, under 1000-1400 rev/min of stirring, add the peroxidation trimethylacetic acid tert-butyl ester, speed with 5-8 ℃/minute is heated to 70-90 ℃, add vinylformic acid-4-hydroxyl butyl ester, polyethylene glycol acrylate, continue stirring reaction 30-40 minute, add other remaining components, continue stirring reaction 1.5-2 hour, grinding distribution becomes the slurry of 20-40 μ m, obtain.
Beneficial effect of the present invention
Ink of the present invention has that glossiness is good, bright in luster, firmness is high, has the advantages such as good water-fast, refractory, wear resisting property; The preparation method of ink, preparation process is simple and direct, is suitable for suitability for industrialized production.Auxiliary agent of the present invention can form protective membrane in ink pellet surface, isolated air, and the surface that prevents water and other molecules corrosion ink and spraying object in atmosphere, anti-oxidant, make color bright-coloured lastingly, and improve slickness, wear resistance, extend working time.
Embodiment
A refractoriness printing-ink, by following weight part (kilogram) raw material make: bismuth oxide 3.5, boron oxide 2.5, zinc oxide 3.5, silicon sol 5, ethyl acetate 6, tetrapropyl ammonium borofluoride 1.5,2-butoxy-ethanol 3.5, Virahol 7, ethoxylated trimethylolpropane triacrylate 11, vinylformic acid-4-hydroxyl butyl ester 13, polyethylene glycol acrylate 8, the peroxidation trimethylacetic acid tert-butyl ester 1.5, pigment dyestuff 3.5, auxiliary agent 4.5;
Described auxiliary agent by following weight part (kilogram) raw material make: Silane coupling reagent KH-570 2.5, Viscoat 295 3.5,2-n-octyl-4-isothiazoline-3-ketone 1.5,2-amino-2-methyl-1-propyl alcohol 1.5, polyoxyethylene sorbitan monooleate 2.5, ricinolic acid 1.5, oxidation inhibitor 1,035 1.5, linking agent TAC1.5, ethanol 22; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 65 ℃, stirs after 26 minutes, then adds other remaining component, is warming up to 83 ℃, stirs 34 minutes, obtains.
The preparation method of described refractoriness printing-ink, comprise the following steps: by bismuth oxide, boron oxide, zinc oxide, silicon sol, ethyl acetate, tetrapropyl ammonium borofluoride, 2-butoxy-ethanol, Virahol, ethoxylated trimethylolpropane triacrylate mixes, under 1200 revs/min of stirrings, add the peroxidation trimethylacetic acid tert-butyl ester, with the speed of 7 ℃/minute, be heated to 80 ℃, add vinylformic acid-4-hydroxyl butyl ester, polyethylene glycol acrylate, continue stirring reaction 35 minutes, add other remaining components, continue stirring reaction 1.8 hours, grinding distribution becomes the slurry of 30 μ m, obtain.
Ink quality homogeneous of the present invention, tinting strength, adhere firmly degree, viscosity, first dryness and other performances have reached the requirement of QB/T2024-94 standard.
Claims (2)
1. a refractoriness printing-ink, is characterized in that being made by the raw material of following weight part: bismuth oxide 3-4, boron oxide 2-3, zinc oxide 3-4, silicon sol 4-6, ethyl acetate 5-8, tetrapropyl ammonium borofluoride 1-2,2-butoxy-ethanol 3-4, Virahol 6-8, ethoxylated trimethylolpropane triacrylate 10-12, vinylformic acid-4-hydroxyl butyl ester 12-14, polyethylene glycol acrylate 6-9, peroxidation trimethylacetic acid tert-butyl ester 1-2, pigment dyestuff 3-4, auxiliary agent 4-5;
Described auxiliary agent is made by the raw material of following weight part: Silane coupling reagent KH-570 2-3, Viscoat 295 3-4,2-n-octyl-4-isothiazoline-3-ketone 1-2,2-amino-2-methyl-1-propyl alcohol 1-2, polyoxyethylene sorbitan monooleate 2-3, ricinolic acid 1-2, oxidation inhibitor 1035 1-2, linking agent TAC1-2, ethanol 20-24; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 60-70 ℃, stirs after 20-30 minute, then adds other remaining component, is warming up to 80-85 ℃, stirs 30-40 minutes, obtains.
2. the preparation method of refractoriness printing-ink according to claim 1, it is characterized in that comprising the following steps: by bismuth oxide, boron oxide, zinc oxide, silicon sol, ethyl acetate, tetrapropyl ammonium borofluoride, 2-butoxy-ethanol, Virahol, ethoxylated trimethylolpropane triacrylate mixes, under 1000-1400 rev/min of stirring, add the peroxidation trimethylacetic acid tert-butyl ester, speed with 5-8 ℃/minute is heated to 70-90 ℃, add vinylformic acid-4-hydroxyl butyl ester, polyethylene glycol acrylate, continue stirring reaction 30-40 minute, add other remaining components, continue stirring reaction 1.5-2 hour, grinding distribution becomes the slurry of 20-40 μ m, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310574961.9A CN103666094B (en) | 2013-11-18 | 2013-11-18 | A kind of printing-ink and its preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310574961.9A CN103666094B (en) | 2013-11-18 | 2013-11-18 | A kind of printing-ink and its preparation method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103666094A true CN103666094A (en) | 2014-03-26 |
| CN103666094B CN103666094B (en) | 2016-06-15 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310574961.9A Expired - Fee Related CN103666094B (en) | 2013-11-18 | 2013-11-18 | A kind of printing-ink and its preparation method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103666094B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104194471A (en) * | 2014-07-28 | 2014-12-10 | 蚌埠首创滤清器有限公司 | Printing ink prepared by modifying waste powdered ink |
| CN106084998A (en) * | 2016-08-10 | 2016-11-09 | 苏州中亚油墨有限公司 | White waterproof ink |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60248711A (en) * | 1984-05-25 | 1985-12-09 | Ricoh Co Ltd | Non-aqueous resin dispersion |
| CN102627028A (en) * | 2012-03-29 | 2012-08-08 | 中国科学院化学研究所 | Method for preparing high-resolution pattern based on self-infiltration-removal of ink droplet |
| CN103374260A (en) * | 2013-07-31 | 2013-10-30 | 中国科学院化学研究所 | Superhydrophobic ink and application thereof to printing plate material for offset print |
-
2013
- 2013-11-18 CN CN201310574961.9A patent/CN103666094B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60248711A (en) * | 1984-05-25 | 1985-12-09 | Ricoh Co Ltd | Non-aqueous resin dispersion |
| CN102627028A (en) * | 2012-03-29 | 2012-08-08 | 中国科学院化学研究所 | Method for preparing high-resolution pattern based on self-infiltration-removal of ink droplet |
| CN103374260A (en) * | 2013-07-31 | 2013-10-30 | 中国科学院化学研究所 | Superhydrophobic ink and application thereof to printing plate material for offset print |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104194471A (en) * | 2014-07-28 | 2014-12-10 | 蚌埠首创滤清器有限公司 | Printing ink prepared by modifying waste powdered ink |
| CN104194471B (en) * | 2014-07-28 | 2016-06-15 | 蚌埠首创滤清器有限公司 | A kind of printing-ink being modifiied preparation by wasted ink powder |
| CN106084998A (en) * | 2016-08-10 | 2016-11-09 | 苏州中亚油墨有限公司 | White waterproof ink |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103666094B (en) | 2016-06-15 |
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Granted publication date: 20160615 Termination date: 20181118 |