CN106084998A - White waterproof ink - Google Patents
White waterproof ink Download PDFInfo
- Publication number
- CN106084998A CN106084998A CN201610650291.8A CN201610650291A CN106084998A CN 106084998 A CN106084998 A CN 106084998A CN 201610650291 A CN201610650291 A CN 201610650291A CN 106084998 A CN106084998 A CN 106084998A
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- CN
- China
- Prior art keywords
- parts
- agent
- white
- waterproof ink
- ink
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a kind of white waterproof ink, including silica gel, acrylic acid 2 hydroxy methacrylate, titanium dioxide pigment extender, trihydroxy methyl propane triacrylate, fatty acid monoglyceride, aluminium polychlorid, sodium silicate, ethyl acetoacetate, polysiloxanes, organosilicon polyacrylate, organic solvent, organic pigment, cross-linking agent, auxiliary agent, dispersant, defoamer, levelling agent and adhesive promoter.By the preparation of above-mentioned raw materials, the present invention can improve water resistance and the tinting strength, tinting power of ink.
Description
Technical field
The present invention relates to field of ink manufacture, particularly relate to a kind of white waterproof ink.
Background technology
Waterproof ink is a kind of planographic ink, and lithographic space of a whole page each several part lies substantially in a plane, at figure stricture of vagina
Oleophylic, hydrophilic at non-figure stricture of vagina, the principle utilizing profit to repel each other is printed, and offset printing is indirect printing in addition, it is desirable to have stronger
Tinting strength, tinting power could meet requirement.But, now very poor by the most solubization of raw material of waterproof ink, resistance to water is low, easily precipitates, shadow
Ring the water resistance of ink, and the marking that the ink made prints on leaflet is the thinnest, easily comes off.Therefore, improve existing
The part raw material of ink is current urgent problem to improve its quality parameter.
Summary of the invention
The technical problem that present invention mainly solves is to provide a kind of white waterproof ink, it is possible to increase the water resistance of ink
And tinting strength, tinting power.
For solving above-mentioned technical problem, the technical scheme that the present invention uses is: provide a kind of white waterproof ink, bag
Include following component: silica gel, 2-Hydroxy ethyl acrylate, titanium dioxide pigment extender, trihydroxy methyl propane triacrylate, list
Fatty acid glyceride, aluminium polychlorid, sodium silicate, ethyl acetoacetate, polysiloxanes, organosilicon polyacrylate, You Jirong
Agent, organic pigment, cross-linking agent, auxiliary agent, dispersant, defoamer, levelling agent and adhesive promoter.
Specifically, described raw material is based on following parts by weight:
Silica gel 8-20 part, 2-Hydroxy ethyl acrylate 30-50 part, titanium dioxide pigment extender 23-47 part, trihydroxy methyl propane
Triacrylate 53-78 part, fatty acid monoglyceride 45-60 part, aluminium polychlorid 25-36 part, sodium silicate 5-15 part, acetyl second
Acetoacetic ester 37-51 part, polysiloxanes 10-20 part, organosilicon polyacrylate 18-35 part, organic solvent 25-40 part, You Jiyan
Material 5-20 part, cross-linking agent 3-9 part, auxiliary agent 1-4 part, dispersant 2-5 part, defoamer 1-7 part, levelling agent 10-25 part and adhesive force
Reinforcing agent 2-6 part.
The present invention is to solve that the further technical scheme that its technical problem is used is:
It is preferred that a kind of conducting fluorescence ink, described raw material is based on following parts by weight:
16 parts of silica gel, 2-Hydroxy ethyl acrylate 40 parts, titanium dioxide pigment extender 35 parts, trihydroxy methyl propane three acrylic acid
Ester 63 parts, fatty acid monoglyceride 56 parts, aluminium polychlorid 30 parts, sodium silicate 10 parts, ethyl acetoacetate 45 parts, polysiloxanes
15 parts, organosilicon polyacrylate 25 parts, organic solvent 30 parts, organic pigment 15 parts, cross-linking agent 6 parts, auxiliary agent 3 parts, dispersant 4
Part, defoamer 3 parts, levelling agent 16 parts and adhesive promoter 4 parts.
Further, described silica gel is Kiselgel A.
Further, described 2-Hydroxy ethyl acrylate is by ethanol, methacrylic acid-2-hydroxy methacrylate and anhydrous
Ethanol, through heating, cool down, purifying, remixes developing agent and forms.
Further, described organosilicon polyacrylate be by styrene, fat alcohol polyethylene ether, Ammonium persulfate., third
Alkene nitrile, sodium lauryl sulphate, methyl methacrylate and Polyethylene Glycol composition.
Further, described auxiliary agent is by isobutene., Silane coupling agent KH550, compound mica, olive oil and benzene first
Acid composition.
Further, described organic solvent is styrene.
The invention has the beneficial effects as follows: the present invention is by silica gel, 2-Hydroxy ethyl acrylate, titanium dioxide pigment extender, three hydroxyls
Ylmethyl propane triacrylate, fatty acid monoglyceride, aluminium polychlorid, sodium silicate, ethyl acetoacetate, polysiloxanes,
Organosilicon polyacrylate, organic solvent, organic pigment, cross-linking agent, auxiliary agent, dispersant, defoamer, levelling agent and adhesive force increase
Strong agent composition.Wherein 2-Hydroxy ethyl acrylate and organosilicon polyacrylate can improve the water resistance of ink；Titanium white face
Material extender and adhesive promoter can improve the tinting strength, tinting power of ink.
Detailed description of the invention
Below in conjunction with specific embodiment, technical scheme is described in detail, so that advantages of the present invention and spy
Levy and can be easier to be readily appreciated by one skilled in the art, thus protection scope of the present invention is made apparent clear and definite defining.
Embodiment 1:
A kind of white waterproof ink, described raw material is based on following parts by weight:
15 parts of silica gel, 2-Hydroxy ethyl acrylate 32 parts, titanium dioxide pigment extender 40 parts, trihydroxy methyl propane three acrylic acid
Ester 55 parts, fatty acid monoglyceride 47 parts, aluminium polychlorid 29 parts, sodium silicate 9 parts, ethyl acetoacetate 40 parts, polysiloxanes
19 parts, organosilicon polyacrylate 26 parts, organic solvent 37 parts, organic pigment 9 parts, cross-linking agent 7 parts, auxiliary agent 4 parts, dispersant 3
Part, defoamer 6 parts, levelling agent 14 parts and adhesive promoter 3 parts.
Embodiment 2:
A kind of white waterproof ink, described raw material is based on following parts by weight:
17 parts of silica gel, 2-Hydroxy ethyl acrylate 45 parts, titanium dioxide pigment extender 32 parts, trihydroxy methyl propane three acrylic acid
Ester 62 parts, fatty acid monoglyceride 53 parts, aluminium polychlorid 27 parts, sodium silicate 11 parts, ethyl acetoacetate 39 parts, polysiloxanes
15 parts, organosilicon polyacrylate 20 parts, organic solvent 32 parts, organic pigment 19 parts, cross-linking agent 4 parts, auxiliary agent 2 parts, dispersant 2
Part, defoamer 5 parts, levelling agent 20 parts and adhesive promoter 2 parts.
Embodiment 3:
A kind of white waterproof ink, described raw material is based on following parts by weight:
10 parts of silica gel, 2-Hydroxy ethyl acrylate 47 parts, titanium dioxide pigment extender 28 parts, trihydroxy methyl propane three acrylic acid
Ester 60 parts, fatty acid monoglyceride 50 parts, aluminium polychlorid 31 parts, sodium silicate 14 parts, ethyl acetoacetate 47 parts, polysiloxanes
13 parts, organosilicon polyacrylate 33 parts, organic solvent 29 parts, organic pigment 13 parts, cross-linking agent 8 parts, auxiliary agent 1 part, dispersant 5
Part, defoamer 2 parts, levelling agent 18 parts and adhesive promoter 5 parts.
Embodiment 4:
A kind of white waterproof ink, described raw material is based on following parts by weight:
16 parts of silica gel, 2-Hydroxy ethyl acrylate 40 parts, titanium dioxide pigment extender 35 parts, trihydroxy methyl propane three acrylic acid
Ester 63 parts, fatty acid monoglyceride 56 parts, aluminium polychlorid 30 parts, sodium silicate 10 parts, ethyl acetoacetate 45 parts, polysiloxanes
15 parts, organosilicon polyacrylate 25 parts, organic solvent 30 parts, organic pigment 15 parts, cross-linking agent 6 parts, auxiliary agent 3 parts, dispersant 4
Part, defoamer 3 parts, levelling agent 16 parts and adhesive promoter 4 parts.
The preparation method of the white waterproof ink of above-described embodiment comprises the steps:
Step one: by aluminium polychlorid, sodium silicate, ethyl acetoacetate, polysiloxanes, organosilicon polyacrylic acid in agitator
Ester, organic solvent and organic pigment mix homogeneously, be heated to 70-80 DEG C, stirs 30-40 minute；
Step 2: continue to add silica gel, 2-Hydroxy ethyl acrylate, titanium dioxide pigment extender, trihydroxy methyl in agitator
Propane triacrylate and fatty acid monoglyceride, stir 2-3 hour, be cooled to 50-60 DEG C；
Step 3: add cross-linking agent, auxiliary agent, dispersant, defoamer, levelling agent and adhesive promoter, stir 1-2 hour, cold
Grind the most afterwards and obtain 20-30 μm, i.e. finished product.
The foregoing is only the preferred embodiments of the present invention, not thereby limit the scope of the claims of the present invention, every utilization
Equivalent structure or equivalence flow process that description of the invention content is made convert, or are directly or indirectly used in other relevant technology
Field, is the most in like manner included in the scope of patent protection of the present invention.
Claims (8)
1. a white waterproof ink, it is characterised in that include following components: silica gel, 2-Hydroxy ethyl acrylate, titanium white face
Material extender, trihydroxy methyl propane triacrylate, fatty acid monoglyceride, aluminium polychlorid, sodium silicate, acetoacetic acid second
Ester, polysiloxanes, organosilicon polyacrylate, organic solvent, organic pigment, cross-linking agent, auxiliary agent, dispersant, defoamer, levelling
Agent and adhesive promoter, above raw materials by weight portion meter: silica gel 8-20 part, 2-Hydroxy ethyl acrylate 30-50 part, titanium
White pigments extender 23-47 part, trihydroxy methyl propane triacrylate 53-78 part, fatty acid monoglyceride 45-60 part, poly-
Close aluminum chloride 25-36 part, sodium silicate 5-15 part, ethyl acetoacetate 37-51 part, polysiloxanes 10-20 part, organosilicon polypropylene
Acid esters 18-35 part, organic solvent 25-40 part, organic pigment 5-20 part, cross-linking agent 3-9 part, auxiliary agent 1-4 part, dispersant 2-5 part,
Defoamer 1-7 part, levelling agent 10-25 part and adhesive promoter 2-6 part.
White waterproof ink the most according to claim 1, it is characterised in that described raw material is based on following parts by weight: silica gel
16 parts, 2-Hydroxy ethyl acrylate 40 parts, titanium dioxide pigment extender 35 parts, trihydroxy methyl propane triacrylate 63 parts, single
Fatty acid glyceride 56 parts, aluminium polychlorid 30 parts, sodium silicate 10 parts, ethyl acetoacetate 45 parts, polysiloxanes 15 parts, organic
Silicon polyacrylate 25 parts, organic solvent 30 parts, organic pigment 15 parts, cross-linking agent 6 parts, auxiliary agent 3 parts, dispersant 4 parts, defoamer
3 parts, levelling agent 16 parts and adhesive promoter 4 parts.
White waterproof ink the most according to claim 1, it is characterised in that described silica gel is Kiselgel A.
White waterproof ink the most according to claim 1, it is characterised in that described 2-Hydroxy ethyl acrylate be by ethanol,
Methacrylic acid-2-hydroxy methacrylate and dehydrated alcohol, through heating, cool down, purifying, remix developing agent and form.
White waterproof ink the most according to claim 1, it is characterised in that described organosilicon polyacrylate is by benzene second
Alkene, fat alcohol polyethylene ether, Ammonium persulfate., acrylonitrile, sodium lauryl sulphate, methyl methacrylate and Polyethylene Glycol group
Become.
White waterproof ink the most according to claim 1, it is characterised in that described auxiliary agent is by isobutene., silane coupler
KH550, compound mica, olive oil and benzoic acid composition.
White waterproof ink the most according to claim 1, it is characterised in that described organic solvent is styrene.
White waterproof ink the most according to claim 1, it is characterised in that manufacture method comprises the following steps:
Step one: by aluminium polychlorid, sodium silicate, ethyl acetoacetate, polysiloxanes, organosilicon polyacrylic acid in agitator
Ester, organic solvent and organic pigment mix homogeneously, be heated to 70-80 DEG C, stirs 30-40 minute；
Step 2: continue to add silica gel, 2-Hydroxy ethyl acrylate, titanium dioxide pigment extender, trihydroxy methyl in agitator
Propane triacrylate and fatty acid monoglyceride, stir 2-3 hour, be cooled to 50-60 DEG C；
Step 3: add cross-linking agent, auxiliary agent, dispersant, defoamer, levelling agent and adhesive promoter, stir 1-2 hour, cold
Grind the most afterwards and obtain 20-30 μm, i.e. finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610650291.8A CN106084998A (en) | 2016-08-10 | 2016-08-10 | White waterproof ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610650291.8A CN106084998A (en) | 2016-08-10 | 2016-08-10 | White waterproof ink |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106084998A true CN106084998A (en) | 2016-11-09 |
Family
ID=57457227
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610650291.8A Pending CN106084998A (en) | 2016-08-10 | 2016-08-10 | White waterproof ink |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106084998A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113372758A (en) * | 2021-08-12 | 2021-09-10 | 北京康美特科技股份有限公司 | White organic silicon printing ink, reflecting layer, backlight substrate and backlight module |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103666064A (en) * | 2013-11-25 | 2014-03-26 | 铜陵方正塑业科技有限公司 | Ultraviolet light curing quick-dry waterproof ink and preparation method thereof |
| CN103666094A (en) * | 2013-11-18 | 2014-03-26 | 蚌埠天光传感器有限公司 | Refractory printing ink and preparation method thereof |
-
2016
- 2016-08-10 CN CN201610650291.8A patent/CN106084998A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103666094A (en) * | 2013-11-18 | 2014-03-26 | 蚌埠天光传感器有限公司 | Refractory printing ink and preparation method thereof |
| CN103666064A (en) * | 2013-11-25 | 2014-03-26 | 铜陵方正塑业科技有限公司 | Ultraviolet light curing quick-dry waterproof ink and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 禹茂章等: "《新编世界精细化学品手册》", 30 April 2000 * |
| 陈正伟等: "《印刷材料》", 31 March 2002, 印刷工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113372758A (en) * | 2021-08-12 | 2021-09-10 | 北京康美特科技股份有限公司 | White organic silicon printing ink, reflecting layer, backlight substrate and backlight module |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161109 |
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| RJ01 | Rejection of invention patent application after publication |