CN103666064A - Ultraviolet light curing quick-dry waterproof ink and preparation method thereof - Google Patents
Ultraviolet light curing quick-dry waterproof ink and preparation method thereof Download PDFInfo
- Publication number
- CN103666064A CN103666064A CN201310602008.0A CN201310602008A CN103666064A CN 103666064 A CN103666064 A CN 103666064A CN 201310602008 A CN201310602008 A CN 201310602008A CN 103666064 A CN103666064 A CN 103666064A
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- China
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- ink
- ultraviolet light
- phenyl ketone
- hydroxyl
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- Granted
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- 238000002360 preparation method Methods 0.000 title claims description 8
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims abstract description 21
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 21
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 7
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims abstract description 7
- -1 metacrylic acid ester Chemical class 0.000 claims abstract description 7
- 229920000728 polyester Polymers 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 claims abstract description 4
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 15
- 238000006116 polymerization reaction Methods 0.000 claims description 11
- 238000006243 chemical reaction Methods 0.000 claims description 10
- 239000002585 base Substances 0.000 claims description 9
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 9
- 239000012752 auxiliary agent Substances 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 claims description 6
- 239000003513 alkali Substances 0.000 claims description 6
- 239000000975 dye Substances 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 239000000049 pigment Substances 0.000 claims description 6
- 229920001296 polysiloxane Polymers 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 claims description 6
- KDVYCTOWXSLNNI-UHFFFAOYSA-N 4-t-Butylbenzoic acid Chemical compound CC(C)(C)C1=CC=C(C(O)=O)C=C1 KDVYCTOWXSLNNI-UHFFFAOYSA-N 0.000 claims description 3
- 244000077995 Coix lacryma jobi Species 0.000 claims description 3
- 229920002367 Polyisobutene Polymers 0.000 claims description 3
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 claims description 3
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- APZPSKFMSWZPKL-UHFFFAOYSA-N [3-hydroxy-2,2-bis(hydroxymethyl)propyl] 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(CO)(CO)CO APZPSKFMSWZPKL-UHFFFAOYSA-N 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 239000010445 mica Substances 0.000 claims description 3
- 229910052618 mica group Inorganic materials 0.000 claims description 3
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 3
- 239000012956 1-hydroxycyclohexylphenyl-ketone Substances 0.000 abstract 1
- 239000004115 Sodium Silicate Substances 0.000 abstract 1
- MQDJYUACMFCOFT-UHFFFAOYSA-N bis[2-(1-hydroxycyclohexyl)phenyl]methanone Chemical compound C=1C=CC=C(C(=O)C=2C(=CC=CC=2)C2(O)CCCCC2)C=1C1(O)CCCCC1 MQDJYUACMFCOFT-UHFFFAOYSA-N 0.000 abstract 1
- 239000003431 cross linking reagent Substances 0.000 abstract 1
- 235000019795 sodium metasilicate Nutrition 0.000 abstract 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052911 sodium silicate Inorganic materials 0.000 abstract 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 abstract 1
- 239000000976 ink Substances 0.000 description 24
- 238000001723 curing Methods 0.000 description 8
- 239000002904 solvent Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 240000001624 Espostoa lanata Species 0.000 description 2
- 235000009161 Espostoa lanata Nutrition 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- 101000831616 Homo sapiens Protachykinin-1 Proteins 0.000 description 1
- 240000008415 Lactuca sativa Species 0.000 description 1
- 206010034972 Photosensitivity reaction Diseases 0.000 description 1
- 102100024304 Protachykinin-1 Human genes 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 238000000016 photochemical curing Methods 0.000 description 1
- 230000036211 photosensitivity Effects 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 235000012045 salad Nutrition 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 238000002211 ultraviolet spectrum Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses ultraviolet curing quick-dry waterproof ink which is characterized by being prepared from the following raw materials in parts by weight: 1-3 parts of organic dye, 5-9 parts of glycerol, 3-4 parts of aluminum sulfate, 1-2 parts of sodium metasilicate, 20-25 parts of metacrylic acid ester, 10-14 parts of ethyl acetate, 3-4 parts of mercaptopolysiloxane, 45-50 parts of polyester acrylate, 5-8 parts of 1-hydroxy-cyclohexyl phenyl ketone, 10-12 parts of trimethylolpropane triacrylate, 6-9 parts of crylic acid-2-hydroxy ethyl ester, 3-4 parts of triphenyl phosphate, 1-2 parts of cross-linking agent TAIC and 4-5 parts of auxiliary. The auxiliary disclosed by the invention improves the toughness of the ink, the ink can be uniformly dispersed, and the stability of the ink is maintained; the ink disclosed by the invention has good adhesion properties, is not easy to crack and drop off, is good in waterproof property, rapid in curing speed, and energy-saving and environment-friendly.
Description
Technical field
The present invention relates to a kind of ink and preparation method thereof, particularly a kind of ultraviolet light polymerization rapid-curing cutback waterproof ink and preparation method thereof.
Background technology
Ultraviolet light polymerization (UV) ink refers under uviolizing, utilizes the UV-light of different wave length and energy to make ink film forming and dry ink.Utilize different UV spectrum, can produce different-energy, the monomer polymerization in different ink vehicles is become to polymkeric substance, so the look film of UV ink has good machinery and chemical property.The major advantage of UV ink has: (1) is without solvent; (2) rate of drying is fast, and power consumption is few; (3) good luster, bright in luster; (4) water-fast, resistance to solvent, wear resisting property is good.In UV ink, light trigger is a kind of light activated compound that is subject to, and after absorb light is shone, is excited into free radical, and energy is transferred to photosensitivity molecule or photocrosslinking agent, makes UV China ink that photocuring reaction occur.UV China ink has become a kind of more ripe ink technology at present, and its pollutant emission is almost nil.Except not containing solvent, UV China ink is also just like being difficult for scumming, and site is clear, the bright-coloured light of mass colour, the advantage such as chemical resistance is excellent, low-consuming.
Summary of the invention
The object of this invention is to provide a kind of ultraviolet light polymerization rapid-curing cutback waterproof ink and preparation method thereof.
In order to realize object of the present invention, the present invention passes through following scheme implementation:
A ultraviolet light polymerization rapid-curing cutback waterproof ink, is made by the raw material of following weight part: pigment dyestuff 1-3, glycerol 5-9, Tai-Ace S 150 3-4, flower bulb alkali 1-2, methacrylic ester 20-25, ethyl acetate 10-14, sulfydryl polysiloxane 3-4, polyester acrylate 45-50,1-hydroxyl-ring base in the sixth of the twelve Earthly Branches phenyl ketone 5-8, Viscoat 295 10-12, vinylformic acid-2-hydroxy methacrylate 6-9, triphenyl phosphite 3-4, linking agent TAIC 1-2, auxiliary agent 4-5;
Described auxiliary agent is prepared from by the raw material of following weight part: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, double pentaerythritol methacrylate 10-12, neopentyl glycol 5-7, p-tert-butyl benzoic acid 1-2, linking agent TAC2-3, polyisobutene 2-3, silane coupling agent KH560 1-2, Tenox PG 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 ℃, and stirring reaction 30-40 minute, obtains.
Ultraviolet light polymerization rapid-curing cutback waterproof ink of the present invention, by following concrete steps, made: first add pigment dyestuff, glycerol, Tai-Ace S 150, flower bulb alkali, methacrylic ester, ethyl acetate, sulfydryl polysiloxane, polyester acrylate stirring and evenly mixing, be heated to 80-90 ℃, stir 25-35 minute; Then add all the other remaining components except 1-hydroxyl-ring base in the sixth of the twelve Earthly Branches phenyl ketone, stirring reaction 3-5 hour; Finally be cooled to 60-70 ℃, add 1-hydroxyl-ring base in the sixth of the twelve Earthly Branches phenyl ketone, stirring reaction 40-50 minute, cooling after, grind and to obtain 20-40 μ m slurry, obtain.
The invention has the beneficial effects as follows: auxiliary agent of the present invention has improved the toughness of ink, make distributes ink even, and maintained the stability of ink; Ink of the present invention has good sticking power, not easy to crack, comes off, and water resistance is good, and curing speed is fast, energy-conserving and environment-protective.
Specific embodiments
Below by specific examples, the present invention is described in detail.
A ultraviolet light polymerization rapid-curing cutback waterproof ink, by following weight part (kilogram) raw material make: pigment dyestuff 1, glycerol 5, Tai-Ace S 150 3, flower bulb alkali 1, methacrylic ester 20, ethyl acetate 10, sulfydryl polysiloxane 3, polyester acrylate 45,1-hydroxyl-ring base in the sixth of the twelve Earthly Branches phenyl ketone 5, Viscoat 295 10, vinylformic acid-2-hydroxy methacrylate 6, triphenyl phosphite 3, linking agent TAIC 1, auxiliary agent 4;
Described auxiliary agent by following weight part (kilogram) raw material be prepared from: nano diatomite powder 0.2, nano mica powder 0.2, double pentaerythritol methacrylate 10, neopentyl glycol 5, p-tert-butyl benzoic acid 1, linking agent TAC2, polyisobutene 2, silane coupling agent KH560 1, Tenox PG 2, coix seed oil 1; Its preparation method is by each mixing of materials, is heated to 60-70 ℃, and stirring reaction 30-40 minute, obtains.
Ultraviolet light polymerization rapid-curing cutback waterproof ink of the present invention, by following concrete steps, made: first add pigment dyestuff, glycerol, Tai-Ace S 150, flower bulb alkali, methacrylic ester, ethyl acetate, sulfydryl polysiloxane, polyester acrylate stirring and evenly mixing, be heated to 80-90 ℃, stir 25-35 minute; Then add all the other remaining components except 1-hydroxyl-ring base in the sixth of the twelve Earthly Branches phenyl ketone, stirring reaction 3-5 hour; Finally be cooled to 60-70 ℃, add 1-hydroxyl-ring base in the sixth of the twelve Earthly Branches phenyl ketone, stirring reaction 40-50 minute, cooling after, grind and to obtain 20-40 μ m slurry, obtain.
The ink of gained, is used cross-hatching ox-hide tape stripping, draws compartment apart from 1mm, and 100% adheres to; Spirituous cotton balls is soaked in use, and 300 grams of pressure wipings 50 times, are as good as shape; Be soaked in salad oil (normal temperature) 8 hours, be as good as shape; Use is soaked with the cotton balls of salt solution, and 300 grams of pressure wipings 50 times, are as good as shape.
Claims (2)
1. a ultraviolet light polymerization rapid-curing cutback waterproof ink, it is characterized in that, by the raw material of following weight part, made: pigment dyestuff 1-3, glycerol 5-9, Tai-Ace S 150 3-4, flower bulb alkali 1-2, methacrylic ester 20-25, ethyl acetate 10-14, sulfydryl polysiloxane 3-4, polyester acrylate 45-50,1-hydroxyl-ring base in the sixth of the twelve Earthly Branches phenyl ketone 5-8, Viscoat 295 10-12, vinylformic acid-2-hydroxy methacrylate 6-9, triphenyl phosphite 3-4, linking agent TAIC 1-2, auxiliary agent 4-5;
Described auxiliary agent is prepared from by the raw material of following weight part: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, double pentaerythritol methacrylate 10-12, neopentyl glycol 5-7, p-tert-butyl benzoic acid 1-2, linking agent TAC2-3, polyisobutene 2-3, silane coupling agent KH560 1-2, Tenox PG 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 ℃, and stirring reaction 30-40 minute, obtains.
2. ultraviolet light polymerization rapid-curing cutback waterproof ink according to claim 1, it is characterized in that, by following concrete steps, made: first add pigment dyestuff, glycerol, Tai-Ace S 150, flower bulb alkali, methacrylic ester, ethyl acetate, sulfydryl polysiloxane, polyester acrylate stirring and evenly mixing, be heated to 80-90 ℃, stir 25-35 minute; Then add all the other remaining components except 1-hydroxyl-ring base in the sixth of the twelve Earthly Branches phenyl ketone, stirring reaction 3-5 hour; Finally be cooled to 60-70 ℃, add 1-hydroxyl-ring base in the sixth of the twelve Earthly Branches phenyl ketone, stirring reaction 40-50 minute, cooling after, grind and to obtain 20-40 μ m slurry, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310602008.0A CN103666064B (en) | 2013-11-25 | 2013-11-25 | A kind of ultraviolet light polymerization quick-dry waterproof ink and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310602008.0A CN103666064B (en) | 2013-11-25 | 2013-11-25 | A kind of ultraviolet light polymerization quick-dry waterproof ink and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103666064A true CN103666064A (en) | 2014-03-26 |
| CN103666064B CN103666064B (en) | 2016-03-23 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201310602008.0A Active CN103666064B (en) | 2013-11-25 | 2013-11-25 | A kind of ultraviolet light polymerization quick-dry waterproof ink and preparation method thereof |
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| CN (1) | CN103666064B (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106084998A (en) * | 2016-08-10 | 2016-11-09 | 苏州中亚油墨有限公司 | White waterproof ink |
| EP3502150A4 (en) * | 2016-08-22 | 2020-01-22 | Osaka Soda Co., Ltd. | LIGHT-CURABLE RESIN COMPOSITION, INK AND COATING MATERIAL |
| CN111607098A (en) * | 2020-05-22 | 2020-09-01 | 东莞德芳油墨科技有限公司 | Multi-component UV-LED photocuring screen printing ink for glass substrate and preparation method thereof |
| US20220112377A1 (en) * | 2019-02-18 | 2022-04-14 | 3M Innovative Properties Company | Radiation-Curable Composition Containing Mercapto-Functional Polyorganosiloxanes for Additive-Manufacturing Technology |
| CN119931408A (en) * | 2024-12-17 | 2025-05-06 | 江门市健鼎包装有限公司 | A kind of UV waterproof ink and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1970656A (en) * | 2006-11-23 | 2007-05-30 | 北京印刷学院 | Thermoforming plastic printing ink adopting ultraviolet-infra red drying technology |
| CN103342921A (en) * | 2013-07-29 | 2013-10-09 | 中国科学院化学研究所 | Ink with high hiding rate for ink-jet printing and application thereof to preparation of flexible plate |
-
2013
- 2013-11-25 CN CN201310602008.0A patent/CN103666064B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1970656A (en) * | 2006-11-23 | 2007-05-30 | 北京印刷学院 | Thermoforming plastic printing ink adopting ultraviolet-infra red drying technology |
| CN103342921A (en) * | 2013-07-29 | 2013-10-09 | 中国科学院化学研究所 | Ink with high hiding rate for ink-jet printing and application thereof to preparation of flexible plate |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106084998A (en) * | 2016-08-10 | 2016-11-09 | 苏州中亚油墨有限公司 | White waterproof ink |
| EP3502150A4 (en) * | 2016-08-22 | 2020-01-22 | Osaka Soda Co., Ltd. | LIGHT-CURABLE RESIN COMPOSITION, INK AND COATING MATERIAL |
| US20220112377A1 (en) * | 2019-02-18 | 2022-04-14 | 3M Innovative Properties Company | Radiation-Curable Composition Containing Mercapto-Functional Polyorganosiloxanes for Additive-Manufacturing Technology |
| US12071544B2 (en) * | 2019-02-18 | 2024-08-27 | Solventum Intellectual Properties Company | Radiation-curable composition containing mercapto-functional polyorganosiloxanes for additive-manufacturing technology |
| CN111607098A (en) * | 2020-05-22 | 2020-09-01 | 东莞德芳油墨科技有限公司 | Multi-component UV-LED photocuring screen printing ink for glass substrate and preparation method thereof |
| CN119931408A (en) * | 2024-12-17 | 2025-05-06 | 江门市健鼎包装有限公司 | A kind of UV waterproof ink and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103666064B (en) | 2016-03-23 |
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