CN103666064A - Ultraviolet light curing quick-dry waterproof ink and preparation method thereof - Google Patents
Ultraviolet light curing quick-dry waterproof ink and preparation method thereof Download PDFInfo
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- CN103666064A CN103666064A CN201310602008.0A CN201310602008A CN103666064A CN 103666064 A CN103666064 A CN 103666064A CN 201310602008 A CN201310602008 A CN 201310602008A CN 103666064 A CN103666064 A CN 103666064A
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Abstract
The invention discloses ultraviolet curing quick-dry waterproof ink which is characterized by being prepared from the following raw materials in parts by weight: 1-3 parts of organic dye, 5-9 parts of glycerol, 3-4 parts of aluminum sulfate, 1-2 parts of sodium metasilicate, 20-25 parts of metacrylic acid ester, 10-14 parts of ethyl acetate, 3-4 parts of mercaptopolysiloxane, 45-50 parts of polyester acrylate, 5-8 parts of 1-hydroxy-cyclohexyl phenyl ketone, 10-12 parts of trimethylolpropane triacrylate, 6-9 parts of crylic acid-2-hydroxy ethyl ester, 3-4 parts of triphenyl phosphate, 1-2 parts of cross-linking agent TAIC and 4-5 parts of auxiliary. The auxiliary disclosed by the invention improves the toughness of the ink, the ink can be uniformly dispersed, and the stability of the ink is maintained; the ink disclosed by the invention has good adhesion properties, is not easy to crack and drop off, is good in waterproof property, rapid in curing speed, and energy-saving and environment-friendly.
Description
Technical field
The present invention relates to a kind of ink and preparation method thereof, particularly a kind of ultraviolet light polymerization rapid-curing cutback waterproof ink and preparation method thereof.
Background technology
Ultraviolet light polymerization (UV) ink refers under uviolizing, utilizes the UV-light of different wave length and energy to make ink film forming and dry ink.Utilize different UV spectrum, can produce different-energy, the monomer polymerization in different ink vehicles is become to polymkeric substance, so the look film of UV ink has good machinery and chemical property.The major advantage of UV ink has: (1) is without solvent; (2) rate of drying is fast, and power consumption is few; (3) good luster, bright in luster; (4) water-fast, resistance to solvent, wear resisting property is good.In UV ink, light trigger is a kind of light activated compound that is subject to, and after absorb light is shone, is excited into free radical, and energy is transferred to photosensitivity molecule or photocrosslinking agent, makes UV China ink that photocuring reaction occur.UV China ink has become a kind of more ripe ink technology at present, and its pollutant emission is almost nil.Except not containing solvent, UV China ink is also just like being difficult for scumming, and site is clear, the bright-coloured light of mass colour, the advantage such as chemical resistance is excellent, low-consuming.
Summary of the invention
The object of this invention is to provide a kind of ultraviolet light polymerization rapid-curing cutback waterproof ink and preparation method thereof.
In order to realize object of the present invention, the present invention passes through following scheme implementation:
A ultraviolet light polymerization rapid-curing cutback waterproof ink, is made by the raw material of following weight part: pigment dyestuff 1-3, glycerol 5-9, Tai-Ace S 150 3-4, flower bulb alkali 1-2, methacrylic ester 20-25, ethyl acetate 10-14, sulfydryl polysiloxane 3-4, polyester acrylate 45-50,1-hydroxyl-ring base in the sixth of the twelve Earthly Branches phenyl ketone 5-8, Viscoat 295 10-12, vinylformic acid-2-hydroxy methacrylate 6-9, triphenyl phosphite 3-4, linking agent TAIC 1-2, auxiliary agent 4-5;
Described auxiliary agent is prepared from by the raw material of following weight part: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, double pentaerythritol methacrylate 10-12, neopentyl glycol 5-7, p-tert-butyl benzoic acid 1-2, linking agent TAC2-3, polyisobutene 2-3, silane coupling agent KH560 1-2, Tenox PG 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 ℃, and stirring reaction 30-40 minute, obtains.
Ultraviolet light polymerization rapid-curing cutback waterproof ink of the present invention, by following concrete steps, made: first add pigment dyestuff, glycerol, Tai-Ace S 150, flower bulb alkali, methacrylic ester, ethyl acetate, sulfydryl polysiloxane, polyester acrylate stirring and evenly mixing, be heated to 80-90 ℃, stir 25-35 minute; Then add all the other remaining components except 1-hydroxyl-ring base in the sixth of the twelve Earthly Branches phenyl ketone, stirring reaction 3-5 hour; Finally be cooled to 60-70 ℃, add 1-hydroxyl-ring base in the sixth of the twelve Earthly Branches phenyl ketone, stirring reaction 40-50 minute, cooling after, grind and to obtain 20-40 μ m slurry, obtain.
The invention has the beneficial effects as follows: auxiliary agent of the present invention has improved the toughness of ink, make distributes ink even, and maintained the stability of ink; Ink of the present invention has good sticking power, not easy to crack, comes off, and water resistance is good, and curing speed is fast, energy-conserving and environment-protective.
Specific embodiments
Below by specific examples, the present invention is described in detail.
A ultraviolet light polymerization rapid-curing cutback waterproof ink, by following weight part (kilogram) raw material make: pigment dyestuff 1, glycerol 5, Tai-Ace S 150 3, flower bulb alkali 1, methacrylic ester 20, ethyl acetate 10, sulfydryl polysiloxane 3, polyester acrylate 45,1-hydroxyl-ring base in the sixth of the twelve Earthly Branches phenyl ketone 5, Viscoat 295 10, vinylformic acid-2-hydroxy methacrylate 6, triphenyl phosphite 3, linking agent TAIC 1, auxiliary agent 4;
Described auxiliary agent by following weight part (kilogram) raw material be prepared from: nano diatomite powder 0.2, nano mica powder 0.2, double pentaerythritol methacrylate 10, neopentyl glycol 5, p-tert-butyl benzoic acid 1, linking agent TAC2, polyisobutene 2, silane coupling agent KH560 1, Tenox PG 2, coix seed oil 1; Its preparation method is by each mixing of materials, is heated to 60-70 ℃, and stirring reaction 30-40 minute, obtains.
Ultraviolet light polymerization rapid-curing cutback waterproof ink of the present invention, by following concrete steps, made: first add pigment dyestuff, glycerol, Tai-Ace S 150, flower bulb alkali, methacrylic ester, ethyl acetate, sulfydryl polysiloxane, polyester acrylate stirring and evenly mixing, be heated to 80-90 ℃, stir 25-35 minute; Then add all the other remaining components except 1-hydroxyl-ring base in the sixth of the twelve Earthly Branches phenyl ketone, stirring reaction 3-5 hour; Finally be cooled to 60-70 ℃, add 1-hydroxyl-ring base in the sixth of the twelve Earthly Branches phenyl ketone, stirring reaction 40-50 minute, cooling after, grind and to obtain 20-40 μ m slurry, obtain.
The ink of gained, is used cross-hatching ox-hide tape stripping, draws compartment apart from 1mm, and 100% adheres to; Spirituous cotton balls is soaked in use, and 300 grams of pressure wipings 50 times, are as good as shape; Be soaked in salad oil (normal temperature) 8 hours, be as good as shape; Use is soaked with the cotton balls of salt solution, and 300 grams of pressure wipings 50 times, are as good as shape.
Claims (2)
1. a ultraviolet light polymerization rapid-curing cutback waterproof ink, it is characterized in that, by the raw material of following weight part, made: pigment dyestuff 1-3, glycerol 5-9, Tai-Ace S 150 3-4, flower bulb alkali 1-2, methacrylic ester 20-25, ethyl acetate 10-14, sulfydryl polysiloxane 3-4, polyester acrylate 45-50,1-hydroxyl-ring base in the sixth of the twelve Earthly Branches phenyl ketone 5-8, Viscoat 295 10-12, vinylformic acid-2-hydroxy methacrylate 6-9, triphenyl phosphite 3-4, linking agent TAIC 1-2, auxiliary agent 4-5;
Described auxiliary agent is prepared from by the raw material of following weight part: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, double pentaerythritol methacrylate 10-12, neopentyl glycol 5-7, p-tert-butyl benzoic acid 1-2, linking agent TAC2-3, polyisobutene 2-3, silane coupling agent KH560 1-2, Tenox PG 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 ℃, and stirring reaction 30-40 minute, obtains.
2. ultraviolet light polymerization rapid-curing cutback waterproof ink according to claim 1, it is characterized in that, by following concrete steps, made: first add pigment dyestuff, glycerol, Tai-Ace S 150, flower bulb alkali, methacrylic ester, ethyl acetate, sulfydryl polysiloxane, polyester acrylate stirring and evenly mixing, be heated to 80-90 ℃, stir 25-35 minute; Then add all the other remaining components except 1-hydroxyl-ring base in the sixth of the twelve Earthly Branches phenyl ketone, stirring reaction 3-5 hour; Finally be cooled to 60-70 ℃, add 1-hydroxyl-ring base in the sixth of the twelve Earthly Branches phenyl ketone, stirring reaction 40-50 minute, cooling after, grind and to obtain 20-40 μ m slurry, obtain.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310602008.0A CN103666064B (en) | 2013-11-25 | 2013-11-25 | A kind of ultraviolet light polymerization quick-dry waterproof ink and preparation method thereof |
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| CN201310602008.0A CN103666064B (en) | 2013-11-25 | 2013-11-25 | A kind of ultraviolet light polymerization quick-dry waterproof ink and preparation method thereof |
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| CN103666064A true CN103666064A (en) | 2014-03-26 |
| CN103666064B CN103666064B (en) | 2016-03-23 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106084998A (en) * | 2016-08-10 | 2016-11-09 | 苏州中亚油墨有限公司 | White waterproof ink |
| CN111607098A (en) * | 2020-05-22 | 2020-09-01 | 东莞德芳油墨科技有限公司 | Multi-component UV-LED photocuring screen printing ink for glass substrate and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1970656A (en) * | 2006-11-23 | 2007-05-30 | 北京印刷学院 | Thermoforming plastic printing ink adopting ultraviolet-infra red drying technology |
| CN103342921A (en) * | 2013-07-29 | 2013-10-09 | 中国科学院化学研究所 | Ink with high hiding rate for ink-jet printing and application thereof to preparation of flexible plate |
-
2013
- 2013-11-25 CN CN201310602008.0A patent/CN103666064B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1970656A (en) * | 2006-11-23 | 2007-05-30 | 北京印刷学院 | Thermoforming plastic printing ink adopting ultraviolet-infra red drying technology |
| CN103342921A (en) * | 2013-07-29 | 2013-10-09 | 中国科学院化学研究所 | Ink with high hiding rate for ink-jet printing and application thereof to preparation of flexible plate |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106084998A (en) * | 2016-08-10 | 2016-11-09 | 苏州中亚油墨有限公司 | White waterproof ink |
| CN111607098A (en) * | 2020-05-22 | 2020-09-01 | 东莞德芳油墨科技有限公司 | Multi-component UV-LED photocuring screen printing ink for glass substrate and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN103666064B (en) | 2016-03-23 |
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