CN103666056A - Ultraviolet light curing antistatic ink and preparation method thereof - Google Patents
Ultraviolet light curing antistatic ink and preparation method thereof Download PDFInfo
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- CN103666056A CN103666056A CN201310601042.6A CN201310601042A CN103666056A CN 103666056 A CN103666056 A CN 103666056A CN 201310601042 A CN201310601042 A CN 201310601042A CN 103666056 A CN103666056 A CN 103666056A
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- 238000002360 preparation method Methods 0.000 title claims description 8
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000000463 material Substances 0.000 claims abstract description 8
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 claims abstract description 7
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 claims abstract description 7
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims abstract description 7
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920002239 polyacrylonitrile Polymers 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims abstract description 7
- NKFIBMOQAPEKNZ-UHFFFAOYSA-N 5-amino-1h-indole-2-carboxylic acid Chemical compound NC1=CC=C2NC(C(O)=O)=CC2=C1 NKFIBMOQAPEKNZ-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052582 BN Inorganic materials 0.000 claims abstract description 4
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 claims abstract description 4
- FQYUMYWMJTYZTK-UHFFFAOYSA-N Phenyl glycidyl ether Chemical compound C1OC1COC1=CC=CC=C1 FQYUMYWMJTYZTK-UHFFFAOYSA-N 0.000 claims abstract description 4
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 15
- 238000006243 chemical reaction Methods 0.000 claims description 10
- 239000012752 auxiliary agent Substances 0.000 claims description 7
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 6
- 239000000975 dye Substances 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 150000003014 phosphoric acid esters Chemical class 0.000 claims description 6
- 239000000049 pigment Substances 0.000 claims description 6
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 239000003112 inhibitor Substances 0.000 claims description 4
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 3
- GTELLNMUWNJXMQ-UHFFFAOYSA-N 2-ethyl-2-(hydroxymethyl)propane-1,3-diol;prop-2-enoic acid Chemical class OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.CCC(CO)(CO)CO GTELLNMUWNJXMQ-UHFFFAOYSA-N 0.000 claims description 3
- KDVYCTOWXSLNNI-UHFFFAOYSA-N 4-t-Butylbenzoic acid Chemical compound CC(C)(C)C1=CC=C(C(O)=O)C=C1 KDVYCTOWXSLNNI-UHFFFAOYSA-N 0.000 claims description 3
- 244000077995 Coix lacryma jobi Species 0.000 claims description 3
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 claims description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 239000010445 mica Substances 0.000 claims description 3
- 229910052618 mica group Inorganic materials 0.000 claims description 3
- HDZGCSFEDULWCS-UHFFFAOYSA-N monomethylhydrazine Chemical compound CNN HDZGCSFEDULWCS-UHFFFAOYSA-N 0.000 claims description 3
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims description 3
- 230000003647 oxidation Effects 0.000 claims description 3
- 238000007254 oxidation reaction Methods 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- 229910000077 silane Inorganic materials 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 3
- 230000003068 static effect Effects 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 4
- -1 metacrylic acid ester Chemical class 0.000 abstract description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- 239000002216 antistatic agent Substances 0.000 abstract 1
- 238000003754 machining Methods 0.000 abstract 1
- 239000004005 microsphere Substances 0.000 abstract 1
- BAVYZALUXZFZLV-UHFFFAOYSA-N mono-methylamine Natural products NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 abstract 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract 1
- 239000010452 phosphate Substances 0.000 abstract 1
- 230000000704 physical effect Effects 0.000 abstract 1
- 239000000976 ink Substances 0.000 description 23
- 240000001624 Espostoa lanata Species 0.000 description 2
- 235000009161 Espostoa lanata Nutrition 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 101000831616 Homo sapiens Protachykinin-1 Proteins 0.000 description 1
- 240000008415 Lactuca sativa Species 0.000 description 1
- 206010034972 Photosensitivity reaction Diseases 0.000 description 1
- 102100024304 Protachykinin-1 Human genes 0.000 description 1
- 239000011358 absorbing material Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 238000000016 photochemical curing Methods 0.000 description 1
- 230000036211 photosensitivity Effects 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 235000012045 salad Nutrition 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 238000002211 ultraviolet spectrum Methods 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses ultraviolet curing antistatic ink which is characterized by being prepared from the following raw materials in parts by weight: 1-3 parts of organic dye, 12-15 parts of methyl methacrylate, 3-4 parts of citric acid, 1-2 parts of polyacrylonitrile microsphere, 1-2 parts of glycidol butyl ether, 3-4 parts of triethylene glycol, 1-2 parts of polyving alcohol, 20-24 parts of trimethylolpropane triacrylate, 1-2 parts of phosphate, 4-6 parts of 184 photoinitiator, 1-2 parts of calcium naphthenate, 2-3 parts of phenyl glycidyl ether, 1-2 parts of m-amino methylamine, 1-2 parts of zirconium silicate, 1-2 parts of boron nitride and 4-5 parts of auxiliary. As a metacrylic acid ester antistatic agent is added into the formula, the static charges on the surface of a material can be well absorbed, the antistatic effect is achieved, the machining and treatment are simple and convenient, and the physical properties of a base material are not affected.
Description
Technical field
The present invention relates to a kind of ink and preparation method thereof, particularly a kind of ultraviolet photocurable anti-static printing ink and preparation method thereof.
Background technology
Ultraviolet light polymerization (UV) ink refers under uviolizing, utilizes the UV-light of different wave length and energy to make ink film forming and dry ink.Utilize different UV spectrum, can produce different-energy, the monomer polymerization in different ink vehicles is become to polymkeric substance, so the look film of UV ink has good machinery and chemical property.The major advantage of UV ink has: (1) is without solvent; (2) rate of drying is fast, and power consumption is few; (3) good luster, bright in luster; (4) water-fast, resistance to solvent, wear resisting property is good.In UV ink, light trigger is a kind of light activated compound that is subject to, and after absorb light is shone, is excited into free radical, and energy is transferred to photosensitivity molecule or photocrosslinking agent, makes UV China ink that photocuring reaction occur.The harm bringing in order to reduce static, at present, people conventionally adopt and in UV curable ink, add the leakage that color stuffing suppresses the generation of static charge and promotes static charge, thereby be lowered into a certain extent the surface resistivity of mould material, strengthen the antistatic property of filming, but, because reason and the color stuffing of class coating material self structure is generally small molecules, the antistatic effect that this method produces is not very good, how to develop the good and antistatic lasting anti static additive of a kind of antistatic effect, and for UV curable ink, it is the problem that all UV curable ink field worker faces.
Summary of the invention
The object of this invention is to provide a kind of ultraviolet photocurable anti-static printing ink and preparation method thereof.
In order to realize object of the present invention, the present invention passes through following scheme implementation:
A ultraviolet photocurable anti-static printing ink, is made by the raw material of following weight part: pigment dyestuff 1-3, methyl methacrylate 12-15, citric acid 3-4, polyacrylonitrile microballoon 1-2, Racemic glycidol butyl ether 1-2, triethylene glycol 3-4, polyvinyl alcohol 1-2, Viscoat 295 20-24, phosphoric acid ester 1-2,184 light trigger 4-6, calcium naphthenate 1-2, phenyl glycidyl ether 2-3, an amino methylamine 1-2, zirconium silicate 1-2, boron nitride 1-2, auxiliary agent 4-5;
Described auxiliary agent is prepared from by the raw material of following weight part: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, silane resin acceptor kh-550 2-3, tea-polyphenol 2-3, neopentyl glycol 5-7, p-tert-butyl benzoic acid 1-2, oxidation inhibitor 1035 1-2,2-butoxy-ethanol 3-4, linking agent TAC2-3, ethoxylated trimethylolpropane triacrylate 10-12, Tenox PG 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 ℃, and stirring reaction 30-40 minute, obtains.
Ultraviolet photocurable anti-static printing ink of the present invention, by following concrete steps, made: first add pigment dyestuff, methyl methacrylate, citric acid, polyacrylonitrile microballoon, Racemic glycidol butyl ether, triethylene glycol, polyvinyl alcohol, Viscoat 295, phosphoric acid ester stirring and evenly mixing, be heated to 80-90 ℃, stir 25-35 minute; Then add all the other remaining components except 184 light triggers, stirring reaction 3-5 hour; Finally be cooled to 60-70 ℃, add 184 light triggers, stirring reaction 40-50 minute, cooling after, grind and to obtain 20-40 μ m slurry, obtain.
The invention has the beneficial effects as follows: auxiliary agent of the present invention has improved the toughness of ink, make distributes ink even, and maintained the stability of ink; In the present invention formula, add methyl acrylic ester static inhibitor, the static charge on absorbing material surface preferably, thus play the effect of anti-electrostatic, and processing treatment is simple and convenient, and the physicochemical property of base material is unaffected.
Specific embodiments
Below by specific examples, the present invention is described in detail.
A ultraviolet photocurable anti-static printing ink, by following weight part (kilogram) raw material make: pigment dyestuff 1, methyl methacrylate 12, citric acid 3, polyacrylonitrile microballoon 1, Racemic glycidol butyl ether 1, triethylene glycol 3, polyvinyl alcohol 1, Viscoat 295 20, phosphoric acid ester 1,184 light triggers 4, calcium naphthenate 1, phenyl glycidyl ether 2, an amino methylamine 1, zirconium silicate 1, boron nitride 1, auxiliary agent 4;
Described auxiliary agent by following weight part (kilogram) raw material be prepared from: nano diatomite powder 0.2, nano mica powder 0.2, silane resin acceptor kh-550 2, tea-polyphenol 2, neopentyl glycol 5, p-tert-butyl benzoic acid 1, oxidation inhibitor 1,035 1,2-butoxy-ethanol 3, linking agent TAC2, ethoxylated trimethylolpropane triacrylate 10, Tenox PG 2, coix seed oil 1; Its preparation method is by each mixing of materials, is heated to 60-70 ℃, and stirring reaction 30-40 minute, obtains.
Ultraviolet photocurable anti-static printing ink of the present invention, by following concrete steps, made: first add pigment dyestuff, methyl methacrylate, citric acid, polyacrylonitrile microballoon, Racemic glycidol butyl ether, triethylene glycol, polyvinyl alcohol, Viscoat 295, phosphoric acid ester stirring and evenly mixing, be heated to 80-90 ℃, stir 25-35 minute; Then add all the other remaining components except 184 light triggers, stirring reaction 3-5 hour; Finally be cooled to 60-70 ℃, add 184 light triggers, stirring reaction 40-50 minute, cooling after, grind and to obtain 20-40 μ m slurry, obtain.
The ink of gained, is used cross-hatching ox-hide tape stripping, draws compartment apart from 1mm, and 100% adheres to; Spirituous cotton balls is soaked in use, and 300 grams of pressure wipings 50 times, are as good as shape; Be soaked in salad oil (normal temperature) 8 hours, be as good as shape; Use is soaked with the cotton balls of salt solution, and 300 grams of pressure wipings 50 times, are as good as shape.
Claims (2)
1. a ultraviolet photocurable anti-static printing ink, it is characterized in that, by the raw material of following weight part, made: pigment dyestuff 1-3, methyl methacrylate 12-15, citric acid 3-4, polyacrylonitrile microballoon 1-2, Racemic glycidol butyl ether 1-2, triethylene glycol 3-4, polyvinyl alcohol 1-2, Viscoat 295 20-24, phosphoric acid ester 1-2,184 light trigger 4-6, calcium naphthenate 1-2, phenyl glycidyl ether 2-3, an amino methylamine 1-2, zirconium silicate 1-2, boron nitride 1-2, auxiliary agent 4-5;
Described auxiliary agent is prepared from by the raw material of following weight part: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, silane resin acceptor kh-550 2-3, tea-polyphenol 2-3, neopentyl glycol 5-7, p-tert-butyl benzoic acid 1-2, oxidation inhibitor 1035 1-2,2-butoxy-ethanol 3-4, linking agent TAC2-3, ethoxylated trimethylolpropane triacrylate 10-12, Tenox PG 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 ℃, and stirring reaction 30-40 minute, obtains.
2. ultraviolet photocurable anti-static printing ink according to claim 1, it is characterized in that, by following concrete steps, made: first add pigment dyestuff, methyl methacrylate, citric acid, polyacrylonitrile microballoon, Racemic glycidol butyl ether, triethylene glycol, polyvinyl alcohol, Viscoat 295, phosphoric acid ester stirring and evenly mixing, be heated to 80-90 ℃, stir 25-35 minute; Then add all the other remaining components except 184 light triggers, stirring reaction 3-5 hour; Finally be cooled to 60-70 ℃, add 184 light triggers, stirring reaction 40-50 minute, cooling after, grind and to obtain 20-40 μ m slurry, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310601042.6A CN103666056A (en) | 2013-11-25 | 2013-11-25 | Ultraviolet light curing antistatic ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310601042.6A CN103666056A (en) | 2013-11-25 | 2013-11-25 | Ultraviolet light curing antistatic ink and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103666056A true CN103666056A (en) | 2014-03-26 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310601042.6A Pending CN103666056A (en) | 2013-11-25 | 2013-11-25 | Ultraviolet light curing antistatic ink and preparation method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN103666056A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107532028A (en) * | 2015-07-17 | 2018-01-02 | 惠普深蓝有限责任公司 | electrostatic ink composition |
| CN112654644A (en) * | 2018-09-10 | 2021-04-13 | Dic株式会社 | Active energy ray-curable composition and film using same |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1073464A (en) * | 1991-11-15 | 1993-06-23 | 曼弗雷德·R·屈恩勒 | Electrothermal printing ink containing monodisperse synthetic pigment particles and method and apparatus for electroprinting therewith |
| CN1552778A (en) * | 2003-06-06 | 2004-12-08 | 深圳市海川实业股份有限公司 | Ultraviolet photocurable anti-static printing ink |
| CN101870834A (en) * | 2010-06-18 | 2010-10-27 | 北京赛腾工业标识系统有限公司 | Code-spraying printing ink |
-
2013
- 2013-11-25 CN CN201310601042.6A patent/CN103666056A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1073464A (en) * | 1991-11-15 | 1993-06-23 | 曼弗雷德·R·屈恩勒 | Electrothermal printing ink containing monodisperse synthetic pigment particles and method and apparatus for electroprinting therewith |
| CN1552778A (en) * | 2003-06-06 | 2004-12-08 | 深圳市海川实业股份有限公司 | Ultraviolet photocurable anti-static printing ink |
| CN101870834A (en) * | 2010-06-18 | 2010-10-27 | 北京赛腾工业标识系统有限公司 | Code-spraying printing ink |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107532028A (en) * | 2015-07-17 | 2018-01-02 | 惠普深蓝有限责任公司 | electrostatic ink composition |
| CN107532028B (en) * | 2015-07-17 | 2021-02-12 | 惠普深蓝有限责任公司 | Electrostatic ink composition |
| CN112654644A (en) * | 2018-09-10 | 2021-04-13 | Dic株式会社 | Active energy ray-curable composition and film using same |
| CN112654644B (en) * | 2018-09-10 | 2023-02-28 | Dic株式会社 | Active energy ray curable composition and film using same |
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Application publication date: 20140326 |
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| RJ01 | Rejection of invention patent application after publication |