CN103666041A - Ultraviolet light curing ink and preparation method thereof - Google Patents
Ultraviolet light curing ink and preparation method thereof Download PDFInfo
- Publication number
- CN103666041A CN103666041A CN201310600481.5A CN201310600481A CN103666041A CN 103666041 A CN103666041 A CN 103666041A CN 201310600481 A CN201310600481 A CN 201310600481A CN 103666041 A CN103666041 A CN 103666041A
- Authority
- CN
- China
- Prior art keywords
- parts
- ink
- minute
- light trigger
- add
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000002360 preparation method Methods 0.000 title claims description 8
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims abstract description 21
- 235000019832 sodium triphosphate Nutrition 0.000 claims abstract description 13
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 7
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 7
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims abstract description 7
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims abstract description 7
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- DOOTYTYQINUNNV-UHFFFAOYSA-N Triethyl citrate Chemical compound CCOC(=O)CC(O)(C(=O)OCC)CC(=O)OCC DOOTYTYQINUNNV-UHFFFAOYSA-N 0.000 claims abstract description 4
- 235000010489 acacia gum Nutrition 0.000 claims abstract description 4
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000001069 triethyl citrate Substances 0.000 claims abstract description 4
- VMYFZRTXGLUXMZ-UHFFFAOYSA-N triethyl citrate Natural products CCOC(=O)C(O)(C(=O)OCC)C(=O)OCC VMYFZRTXGLUXMZ-UHFFFAOYSA-N 0.000 claims abstract description 4
- 235000013769 triethyl citrate Nutrition 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 15
- 238000006243 chemical reaction Methods 0.000 claims description 10
- 239000012752 auxiliary agent Substances 0.000 claims description 7
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims description 6
- 101710194948 Protein phosphatase PhpP Proteins 0.000 claims description 6
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 6
- 239000003112 inhibitor Substances 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 230000003647 oxidation Effects 0.000 claims description 6
- 238000007254 oxidation reaction Methods 0.000 claims description 6
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 claims description 6
- 239000000049 pigment Substances 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 239000011347 resin Substances 0.000 claims description 6
- 229920005989 resin Polymers 0.000 claims description 6
- 229910000077 silane Inorganic materials 0.000 claims description 6
- 229910052708 sodium Inorganic materials 0.000 claims description 6
- 239000011734 sodium Substances 0.000 claims description 6
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 claims description 3
- LJRSZGKUUZPHEB-UHFFFAOYSA-N 2-[2-(2-prop-2-enoyloxypropoxy)propoxy]propyl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COC(C)COC(=O)C=C LJRSZGKUUZPHEB-UHFFFAOYSA-N 0.000 claims description 3
- 244000215068 Acacia senegal Species 0.000 claims description 3
- 244000077995 Coix lacryma jobi Species 0.000 claims description 3
- 229920000084 Gum arabic Polymers 0.000 claims description 3
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- SSOONFBDIYMPEU-UHFFFAOYSA-N [3-hydroxy-2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propyl] prop-2-enoate Chemical compound OCC(CO)(CO)COCC(CO)(CO)COC(=O)C=C SSOONFBDIYMPEU-UHFFFAOYSA-N 0.000 claims description 3
- 239000000205 acacia gum Substances 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 239000010445 mica Substances 0.000 claims description 3
- 229910052618 mica group Inorganic materials 0.000 claims description 3
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims description 3
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 3
- 238000001723 curing Methods 0.000 abstract description 3
- 238000000016 photochemical curing Methods 0.000 abstract description 3
- 238000005265 energy consumption Methods 0.000 abstract description 2
- QNODIIQQMGDSEF-UHFFFAOYSA-N (1-hydroxycyclohexyl)-phenylmethanone Chemical compound C=1C=CC=CC=1C(=O)C1(O)CCCCC1 QNODIIQQMGDSEF-UHFFFAOYSA-N 0.000 abstract 1
- 239000006087 Silane Coupling Agent Substances 0.000 abstract 1
- MPIAGWXWVAHQBB-UHFFFAOYSA-N [3-prop-2-enoyloxy-2-[[3-prop-2-enoyloxy-2,2-bis(prop-2-enoyloxymethyl)propoxy]methyl]-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(COC(=O)C=C)(COC(=O)C=C)COCC(COC(=O)C=C)(COC(=O)C=C)COC(=O)C=C MPIAGWXWVAHQBB-UHFFFAOYSA-N 0.000 abstract 1
- 239000001785 acacia senegal l. willd gum Substances 0.000 abstract 1
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 230000003078 antioxidant effect Effects 0.000 abstract 1
- XPGAWFIWCWKDDL-UHFFFAOYSA-N propan-1-olate;zirconium(4+) Chemical compound [Zr+4].CCC[O-].CCC[O-].CCC[O-].CCC[O-] XPGAWFIWCWKDDL-UHFFFAOYSA-N 0.000 abstract 1
- 239000000976 ink Substances 0.000 description 25
- 239000000126 substance Substances 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 240000001624 Espostoa lanata Species 0.000 description 2
- 235000009161 Espostoa lanata Nutrition 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000012634 fragment Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 101000831616 Homo sapiens Protachykinin-1 Proteins 0.000 description 1
- 240000008415 Lactuca sativa Species 0.000 description 1
- 206010034972 Photosensitivity reaction Diseases 0.000 description 1
- 102100024304 Protachykinin-1 Human genes 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 230000005283 ground state Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- -1 ion free radical Chemical class 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 230000036211 photosensitivity Effects 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 235000012045 salad Nutrition 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000002211 ultraviolet spectrum Methods 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses ultraviolet curing ink which is characterized by being prepared from the following raw materials in parts by weight: 4-5 parts of dye, 40-45 parts of UV (Ultraviolet) pure acrylic resin, 10-15 parts of trimethylolpropane triacrylate, 5-8 parts of ethyl acetate, 12-15 parts of methyl methacrylate, 3-4 parts of zirconium n-propoxide, 5-6 parts of sodium tripolyphosphate, 1-2 parts of nickel nitrate, 1-2 parts of Arabic gum, 3-4 parts of butyl acrylate, 6-9 parts of dipentaerythritol hexaacrylate, 2-3 parts of antioxidant 1035, 3-4 parts of triethyl citrate, 1-2 parts of accelerant M, 2-3 parts of silane coupling agent KH-550, 4-5 parts of auxiliary and 6-12 parts of photoinitiator 184. The auxiliary disclosed by the invention improves the toughness of the ink, the ink can be uniformly dispersed, and the stability of the ink is maintained; the ultraviolet curing ink disclosed by the invention is short in photo-curing time, does not need to be heated, saves the energy consumption, and is free of pollution on atmosphere and excellent in comprehensive property.
Description
Technical field
The present invention relates to a kind of ink and preparation method thereof, particularly a kind of UV curable ink and preparation method thereof.
Background technology
Ultraviolet light polymerization (UV) ink refers under uviolizing, utilizes the UV-light of different wave length and energy to make ink film forming and dry ink.The curing mechanism of UV curable ink is, the light trigger in system directly or indirectly absorbs after ultraviolet luminous energy, from ground state transition to excited singlet, alters and jump to excited triplet state between being; After excited singlet or triplet state experience unit molecule or bimolecular chemical action, the biologically active fragment that generation can trigger monomer polymerization, these fragments can be free radical, positively charged ion, negatively charged ion or ion free radical.Utilize different UV spectrum, can produce different-energy, the monomer polymerization in different ink vehicles is become to polymkeric substance, so the look film of UV ink has good machinery and chemical property.The major advantage of UV ink has: (1) is without solvent; (2) rate of drying is fast, and power consumption is few; (3) good luster, bright in luster; (4) water-fast, resistance to solvent, wear resisting property is good.In UV ink, light trigger is a kind of light activated compound that is subject to, and after absorb light is shone, is excited into free radical, and energy is transferred to photosensitivity molecule or photocrosslinking agent, makes UV China ink that photocuring reaction occur.UV China ink has become a kind of more ripe ink technology at present, and its pollutant emission is almost nil.Except not containing solvent, UV China ink is also just like being difficult for scumming, and site is clear, the bright-coloured light of mass colour, the advantage such as chemical resistance is excellent, low-consuming.
Summary of the invention
The object of this invention is to provide a kind of UV curable ink and preparation method thereof.
In order to realize object of the present invention, the present invention passes through following scheme implementation:
A UV curable ink, is made by the raw material of following weight part: pigment 4-5, UV pure acrylic resin 40-45, Viscoat 295 10-15, ethyl acetate 5-8, methyl methacrylate 12-15, zirconium-n-propylate 3-4, tripoly phosphate sodium STPP 5-6, nickelous nitrate 1-2, gum arabic 1-2, butyl acrylate 3-4, dipentaerythritol acrylate 6-9, oxidation inhibitor 1035 2-3, triethyl citrate 3-4, captax 1-2, silane resin acceptor kh-550 2-3, auxiliary agent 4-5, light trigger 184 6-12;
Described auxiliary agent is prepared from by the raw material of following weight part: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, silane resin acceptor kh-550 2-3, morpholine 1-2, neopentyl glycol 3-4, oxidation inhibitor 1035 1-2, linking agent TAC2-3, tri (propylene glycol) diacrylate 10-12,1-Methoxy-2-propyl acetate 5-10, Tenox PG 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 ℃, and stirring reaction 30-40 minute, obtains.
UV curable ink of the present invention, by following concrete steps, made:
First add pigment, UV pure acrylic resin, Viscoat 295, ethyl acetate, methyl methacrylate, zirconium-n-propylate, tripoly phosphate sodium STPP stirring and evenly mixing, be heated to 80-90 ℃, stir 25-35 minute; Then add all the other remaining components except light trigger 184, stirring reaction 3-5 hour; Finally be cooled to 60-70 ℃, add light trigger 184, stirring reaction 40-50 minute, cooling after, grind and to obtain 20-40 μ m slurry, obtain.
Beneficial effect of the present invention: auxiliary agent of the present invention has improved the toughness of ink, makes distributes ink even, and has maintained the stability of ink; The UV curable ink photocuring time of the present invention is short, does not need heating, and save energy consumption is pollution-free to atmosphere, high comprehensive performance.
Specific embodiments
Below by specific examples, the present invention is described in detail.
A UV curable ink, by following weight part (kilogram) raw material make: pigment 4, UV pure acrylic resin 40, Viscoat 295 10, ethyl acetate 5, methyl methacrylate 12, zirconium-n-propylate 3, tripoly phosphate sodium STPP 5, nickelous nitrate 1, gum arabic 1, butyl acrylate 3, dipentaerythritol acrylate 6, oxidation inhibitor 1,035 2, triethyl citrate 3, captax 1, silane resin acceptor kh-550 2, auxiliary agent 4, light trigger 184 6;
Described auxiliary agent by following weight part (kilogram) raw material be prepared from: nano diatomite powder 0.2, nano mica powder 0.2, silane resin acceptor kh-550 2, morpholine 1, neopentyl glycol 3, oxidation inhibitor 1,035 1, linking agent TAC2, tri (propylene glycol) diacrylate 10,1-Methoxy-2-propyl acetate 5, Tenox PG 2, coix seed oil 1; Its preparation method is by each mixing of materials, is heated to 60-70 ℃, and stirring reaction 30-40 minute, obtains.
UV curable ink of the present invention, by following concrete steps, made:
First add pigment, UV pure acrylic resin, Viscoat 295, ethyl acetate, methyl methacrylate, zirconium-n-propylate, tripoly phosphate sodium STPP stirring and evenly mixing, be heated to 80-90 ℃, stir 25-35 minute; Then add all the other remaining components except light trigger 184, stirring reaction 3-5 hour; Finally be cooled to 60-70 ℃, add light trigger 184, stirring reaction 40-50 minute, cooling after, grind and to obtain 20-40 μ m slurry, obtain.
The ink of gained, is used cross-hatching ox-hide tape stripping, draws compartment apart from 1mm, and 100% adheres to; Spirituous cotton balls is soaked in use, and 300 grams of pressure wipings 50 times, are as good as shape; Be soaked in salad oil (normal temperature) 8 hours, be as good as shape; Use is soaked with the cotton balls of salt solution, and 300 grams of pressure wipings 50 times, are as good as shape.
Claims (2)
1. a UV curable ink, it is characterized in that, by the raw material of following weight part, made: pigment 4-5, UV pure acrylic resin 40-45, Viscoat 295 10-15, ethyl acetate 5-8, methyl methacrylate 12-15, zirconium-n-propylate 3-4, tripoly phosphate sodium STPP 5-6, nickelous nitrate 1-2, gum arabic 1-2, butyl acrylate 3-4, dipentaerythritol acrylate 6-9, oxidation inhibitor 1035 2-3, triethyl citrate 3-4, captax 1-2, silane resin acceptor kh-550 2-3, auxiliary agent 4-5, light trigger 184 6-12;
Described auxiliary agent is prepared from by the raw material of following weight part: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, silane resin acceptor kh-550 2-3, morpholine 1-2, neopentyl glycol 3-4, oxidation inhibitor 1035 1-2, linking agent TAC2-3, tri (propylene glycol) diacrylate 10-12,1-Methoxy-2-propyl acetate 5-10, Tenox PG 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 ℃, and stirring reaction 30-40 minute, obtains.
2. UV curable ink according to claim 1, is characterized in that, by following concrete steps, is made:
First add pigment, UV pure acrylic resin, Viscoat 295, ethyl acetate, methyl methacrylate, zirconium-n-propylate, tripoly phosphate sodium STPP stirring and evenly mixing, be heated to 80-90 ℃, stir 25-35 minute; Then add all the other remaining components except light trigger 184, stirring reaction 3-5 hour; Finally be cooled to 60-70 ℃, add light trigger 184, stirring reaction 40-50 minute, cooling after, grind and to obtain 20-40 μ m slurry, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310600481.5A CN103666041B (en) | 2013-11-25 | 2013-11-25 | A kind of UV curable ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310600481.5A CN103666041B (en) | 2013-11-25 | 2013-11-25 | A kind of UV curable ink and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103666041A true CN103666041A (en) | 2014-03-26 |
| CN103666041B CN103666041B (en) | 2016-05-04 |
Family
ID=50304847
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310600481.5A Active CN103666041B (en) | 2013-11-25 | 2013-11-25 | A kind of UV curable ink and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103666041B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103923526A (en) * | 2014-04-30 | 2014-07-16 | 苏州安洁科技股份有限公司 | Semitransparent grey environment-friendly ink |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1073464A (en) * | 1991-11-15 | 1993-06-23 | 曼弗雷德·R·屈恩勒 | Electrothermal printing ink containing monodisperse synthetic pigment particles and method and apparatus for electroprinting therewith |
| CN1552778A (en) * | 2003-06-06 | 2004-12-08 | 深圳市海川实业股份有限公司 | Ultraviolet photocurable anti-static printing ink |
| CN101870834A (en) * | 2010-06-18 | 2010-10-27 | 北京赛腾工业标识系统有限公司 | Code-spraying printing ink |
-
2013
- 2013-11-25 CN CN201310600481.5A patent/CN103666041B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1073464A (en) * | 1991-11-15 | 1993-06-23 | 曼弗雷德·R·屈恩勒 | Electrothermal printing ink containing monodisperse synthetic pigment particles and method and apparatus for electroprinting therewith |
| CN1552778A (en) * | 2003-06-06 | 2004-12-08 | 深圳市海川实业股份有限公司 | Ultraviolet photocurable anti-static printing ink |
| CN101870834A (en) * | 2010-06-18 | 2010-10-27 | 北京赛腾工业标识系统有限公司 | Code-spraying printing ink |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103923526A (en) * | 2014-04-30 | 2014-07-16 | 苏州安洁科技股份有限公司 | Semitransparent grey environment-friendly ink |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103666041B (en) | 2016-05-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103666064B (en) | A kind of ultraviolet light polymerization quick-dry waterproof ink and preparation method thereof | |
| CN103666043B (en) | UV ink that a kind of quick solidifying sticking power is good and preparation method thereof | |
| CN103666032B (en) | A kind of ultraviolet light polymerization packaging ink and preparation method thereof | |
| CN103666058A (en) | UV curing offset printing ink and preparation method thereof | |
| CN103666053B (en) | A kind of UV curing transfer ink and preparation method thereof | |
| CN103666041A (en) | Ultraviolet light curing ink and preparation method thereof | |
| CN103666069A (en) | Ultraviolet light cured printing ink with good adhesive attraction and toughness and preparation method thereof | |
| CN103666045B (en) | UV curing inks of the little strong adhesion of a kind of granularity and preparation method thereof | |
| CN107129714A (en) | A kind of preparation method of soybean oil acrylate type UV-cured resin | |
| CN103666065B (en) | A kind of UV curable ink for surface printing and preparation method thereof | |
| CN103666044A (en) | Environment-friendly UV-curable printing ink and preparation method thereof | |
| CN103666056A (en) | Ultraviolet light curing antistatic ink and preparation method thereof | |
| CN107400407B (en) | Environment-friendly energy-saving LED (light-emitting diode) photocuring ink and application thereof | |
| CN103666103B (en) | A kind of spraying type ultraviolet cured ink and preparation method thereof | |
| CN103666059A (en) | Ultraviolet-curing printing ink and preparation method thereof | |
| CN103666068B (en) | A kind of energy-conserving and environment-protective UV curing inks and preparation method thereof | |
| CN103666060A (en) | UV-curing printing ink with high flexibility and preparation method thereof | |
| CN103666015A (en) | Light-curable printing ink taking LED as light source and preparation method of light-curable printing ink | |
| CN103666055A (en) | Photo-cured and environment-friendly screen printing ink and preparation method thereof | |
| CN103666040B (en) | UV curable ink of a kind of good luster that flowed and preparation method thereof | |
| CN103666050B (en) | A kind of gloss silk-screen UV curing inks and preparation method thereof | |
| CN103666026A (en) | UV (Ultraviolet) curing ink with excellent comprehensive property and preparation method thereof | |
| CN103666067A (en) | Flexible UV curing offset printing ink and preparation method | |
| CN103666074A (en) | Safe and environmental-friendly ultraviolet curing ink and preparation method thereof | |
| CN103666078B (en) | A kind of inkjet printer UV curable ink and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20230323 Address after: No. 259, Mount Taishan Road, National Economic and Technological Development Zone, Hebi, Henan 458030 Patentee after: HEBI RUITELONG BIOMASS MATERIALS TECHNOLOGY Co.,Ltd. Address before: 244000 No. 3201, Cuihu Fourth Road, Tongling Economic Development Zone, Anhui Province Patentee before: TONGLING FOUNDER PLASTICS TECHNOLOGY Co.,Ltd. |