CN103666060A - UV-curing printing ink with high flexibility and preparation method thereof - Google Patents
UV-curing printing ink with high flexibility and preparation method thereof Download PDFInfo
- Publication number
- CN103666060A CN103666060A CN201310601293.4A CN201310601293A CN103666060A CN 103666060 A CN103666060 A CN 103666060A CN 201310601293 A CN201310601293 A CN 201310601293A CN 103666060 A CN103666060 A CN 103666060A
- Authority
- CN
- China
- Prior art keywords
- parts
- printing ink
- acetone
- hydroxy
- ink
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 238000007639 printing Methods 0.000 title abstract description 16
- 238000003848 UV Light-Curing Methods 0.000 title abstract 3
- IANQTJSKSUMEQM-UHFFFAOYSA-N 1-benzofuran Chemical compound C1=CC=C2OC=CC2=C1 IANQTJSKSUMEQM-UHFFFAOYSA-N 0.000 claims abstract description 8
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229940119545 isobornyl methacrylate Drugs 0.000 claims abstract description 7
- VLCAYQIMSMPEBW-UHFFFAOYSA-N methyl 3-hydroxy-2-methylidenebutanoate Chemical compound COC(=O)C(=C)C(C)O VLCAYQIMSMPEBW-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 4
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 4
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 claims abstract description 4
- IAXXETNIOYFMLW-COPLHBTASA-N [(1s,3s,4s)-4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl] 2-methylprop-2-enoate Chemical compound C1C[C@]2(C)[C@@H](OC(=O)C(=C)C)C[C@H]1C2(C)C IAXXETNIOYFMLW-COPLHBTASA-N 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 15
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 239000012752 auxiliary agent Substances 0.000 claims description 7
- YSVQGHIOJPVICX-UHFFFAOYSA-N 1-(1-hydroxycyclohexyl)-1-phenylpropan-2-one Chemical compound C1CCCCC1(O)C(C(=O)C)C1=CC=CC=C1 YSVQGHIOJPVICX-UHFFFAOYSA-N 0.000 claims description 6
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims description 6
- 239000000975 dye Substances 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 239000000049 pigment Substances 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 235000019198 oils Nutrition 0.000 claims description 4
- LJRSZGKUUZPHEB-UHFFFAOYSA-N 2-[2-(2-prop-2-enoyloxypropoxy)propoxy]propyl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COC(C)COC(=O)C=C LJRSZGKUUZPHEB-UHFFFAOYSA-N 0.000 claims description 3
- 244000077995 Coix lacryma jobi Species 0.000 claims description 3
- 241000628997 Flos Species 0.000 claims description 3
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 claims description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical compound C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 claims description 3
- 239000003112 inhibitor Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 239000010445 mica Substances 0.000 claims description 3
- 229910052618 mica group Inorganic materials 0.000 claims description 3
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims description 3
- 230000003647 oxidation Effects 0.000 claims description 3
- 238000007254 oxidation reaction Methods 0.000 claims description 3
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- 229910000077 silane Inorganic materials 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 3
- 239000012956 1-hydroxycyclohexylphenyl-ketone Substances 0.000 abstract 1
- 241000220317 Rosa Species 0.000 abstract 1
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- MQDJYUACMFCOFT-UHFFFAOYSA-N bis[2-(1-hydroxycyclohexyl)phenyl]methanone Chemical compound C=1C=CC=C(C(=O)C=2C(=CC=CC=2)C2(O)CCCCC2)C=1C1(O)CCCCC1 MQDJYUACMFCOFT-UHFFFAOYSA-N 0.000 abstract 1
- 230000002349 favourable effect Effects 0.000 abstract 1
- 239000012860 organic pigment Substances 0.000 abstract 1
- 239000000341 volatile oil Substances 0.000 abstract 1
- 240000001624 Espostoa lanata Species 0.000 description 2
- 235000009161 Espostoa lanata Nutrition 0.000 description 2
- 101000831616 Homo sapiens Protachykinin-1 Proteins 0.000 description 1
- 240000008415 Lactuca sativa Species 0.000 description 1
- 102100024304 Protachykinin-1 Human genes 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 235000012045 salad Nutrition 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
Abstract
The invention discloses a UV-curing printing ink with high flexibility and a preparation method thereof. The UV-curing printing ink is characterized by being prepared from the following raw materials in parts by weight: 1-3 parts of an organic pigment, 30-35 parts of urethane acrylate, 30-35 parts of hydroxyethyl methylacrylate, 14-18 parts of isobornyl methacrylate, 10-12 parts of 2-hydroxyl acrylic resin, 6-9 parts of 1-hydroxycyclohexyl phenyl ketone, 1-2 parts of rose essential oil, 4-5 parts of coumarone, 1-2 parts of an accelerator DM, 3-4 parts of octadecyl trimethyl ammonium chloride, and 4-5 parts of an assistant. The assistant improves the flexibility of printing ink, enables the printing ink to be uniformly dispersed, and maintains the stability of the printing ink. A favorable adhesive force of an overprint ink film is ensured while the flexibility of the cured film is improved, and the quality of the product is improved.
Description
Technical field
The present invention relates to a kind of ink and preparation method thereof, particularly UV curable ink of a kind of good toughness and preparation method thereof.
Background technology
At present, in screen printing process, ink film thickness after film-forming is compared the black bed thickness reality of other mode of printing, the ink film thickness of general single printing is 20～40 μ m, for guaranteeing that ink is in the lip-deep good adhesion of the product of undertaking the printing of, the ink total thickness of holding printing product surface double exposure should not surpass 100 μ m, and ink is on the product of undertaking the printing of general maximum overprintable 3 times.
Test is found, above to embody the product of undertaking the printing of of its unique printing effect for needing double exposure 3 times, if use existing ink to print, at ink printing after holding on printing product surface and solidifying, when extruding or crooked this are undertaken the printing of product, significantly ftractureing and come off in ink film surface conventionally appearance, affects quality product.
Summary of the invention
The object of this invention is to provide UV curable ink of a kind of good toughness and preparation method thereof.
In order to realize object of the present invention, the present invention passes through following scheme implementation:
A UV curable ink for good toughness, is made by the raw material of following weight part: pigment dyestuff 1-3, urethane acrylate 30-35, hydroxyethyl methylacrylate 30-35, isobornyl methacrylate 14-18,2-Hydroxylated acrylic resin 10-12,1-hydroxy-cyclohexyl phenyl-acetone 6-9, Flos Rosae Rugosae quintessence oil 1-2, coumarone 4-5, altax 1-2, octadecyl trimethyl ammonium chloride 3-4, auxiliary agent 4-5;
Described auxiliary agent is prepared from by the raw material of following weight part: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, silane resin acceptor kh-550 2-3, morpholine 1-2, neopentyl glycol 3-4, oxidation inhibitor 1035 1-2, linking agent TAC2-3, tri (propylene glycol) diacrylate 10-12,1-Methoxy-2-propyl acetate 5-10, Tenox PG 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 ℃, and stirring reaction 30-40 minute, obtains.
The UV curable ink of good toughness of the present invention, by following concrete steps, made: first add pigment dyestuff, urethane acrylate, hydroxyethyl methylacrylate, isobornyl methacrylate stirring and evenly mixing, be heated to 80-90 ℃, stir 25-35 minute; Then add all the other remaining components except 1-hydroxy-cyclohexyl phenyl-acetone, stirring reaction 3-5 hour; Finally be cooled to 60-70 ℃, add 1-hydroxy-cyclohexyl phenyl-acetone, stirring reaction 40-50 minute, cooling after, grind and to obtain 20-40 μ m slurry, obtain.
The invention has the beneficial effects as follows: auxiliary agent of the present invention has improved the toughness of ink, make distributes ink even, and maintained the stability of ink; The present invention is improving the flexible while of cured film, guarantees the good adhesion of double exposure ink film, has promoted quality product.
Specific embodiments
Below by specific examples, the present invention is described in detail.
A UV curable ink for good toughness, by following weight part (kilogram) raw material make: pigment dyestuff 1, urethane acrylate 30, hydroxyethyl methylacrylate 30, isobornyl methacrylate 14,2-Hydroxylated acrylic resin 10,1-hydroxy-cyclohexyl phenyl-acetone 6, Flos Rosae Rugosae quintessence oil 1, coumarone 4, altax 1, octadecyl trimethyl ammonium chloride 3, auxiliary agent 4;
Described auxiliary agent by following weight part (kilogram) raw material be prepared from: nano diatomite powder 0.2, nano mica powder 0.2, silane resin acceptor kh-550 2, morpholine 1, neopentyl glycol 3, oxidation inhibitor 1,035 1, linking agent TAC2, tri (propylene glycol) diacrylate 10,1-Methoxy-2-propyl acetate 5, Tenox PG 2, coix seed oil 1; Its preparation method is by each mixing of materials, is heated to 60-70 ℃, and stirring reaction 30-40 minute, obtains.
The UV curable ink of good toughness of the present invention, by following concrete steps, made: first add pigment dyestuff, urethane acrylate, hydroxyethyl methylacrylate, isobornyl methacrylate stirring and evenly mixing, be heated to 80-90 ℃, stir 25-35 minute; Then add all the other remaining components except 1-hydroxy-cyclohexyl phenyl-acetone, stirring reaction 3-5 hour; Finally be cooled to 60-70 ℃, add 1-hydroxy-cyclohexyl phenyl-acetone, stirring reaction 40-50 minute, cooling after, grind and to obtain 20-40 μ m slurry, obtain.
The ink of gained, is used cross-hatching ox-hide tape stripping, draws compartment apart from 1mm, and 100% adheres to; Spirituous cotton balls is soaked in use, and 300 grams of pressure wipings 50 times, are as good as shape; Be soaked in salad oil (normal temperature) 8 hours, be as good as shape; Use is soaked with the cotton balls of salt solution, and 300 grams of pressure wipings 50 times, are as good as shape.
Claims (2)
1. the UV curable ink of a good toughness, it is characterized in that, by the raw material of following weight part, made: pigment dyestuff 1-3, urethane acrylate 30-35, hydroxyethyl methylacrylate 30-35, isobornyl methacrylate 14-18,2-Hydroxylated acrylic resin 10-12,1-hydroxy-cyclohexyl phenyl-acetone 6-9, Flos Rosae Rugosae quintessence oil 1-2, coumarone 4-5, altax 1-2, octadecyl trimethyl ammonium chloride 3-4, auxiliary agent 4-5;
Described auxiliary agent is prepared from by the raw material of following weight part: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, silane resin acceptor kh-550 2-3, morpholine 1-2, neopentyl glycol 3-4, oxidation inhibitor 1035 1-2, linking agent TAC2-3, tri (propylene glycol) diacrylate 10-12,1-Methoxy-2-propyl acetate 5-10, Tenox PG 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 ℃, and stirring reaction 30-40 minute, obtains.
2. the UV curable ink of good toughness according to claim 1, it is characterized in that, by following concrete steps, made: first add pigment dyestuff, urethane acrylate, hydroxyethyl methylacrylate, isobornyl methacrylate stirring and evenly mixing, be heated to 80-90 ℃, stir 25-35 minute; Then add all the other remaining components except 1-hydroxy-cyclohexyl phenyl-acetone, stirring reaction 3-5 hour; Finally be cooled to 60-70 ℃, add 1-hydroxy-cyclohexyl phenyl-acetone, stirring reaction 40-50 minute, cooling after, grind and to obtain 20-40 μ m slurry, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310601293.4A CN103666060B (en) | 2013-11-25 | 2013-11-25 | UV curable ink of a kind of good toughness and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310601293.4A CN103666060B (en) | 2013-11-25 | 2013-11-25 | UV curable ink of a kind of good toughness and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103666060A true CN103666060A (en) | 2014-03-26 |
| CN103666060B CN103666060B (en) | 2016-04-13 |
Family
ID=50304866
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310601293.4A Active CN103666060B (en) | 2013-11-25 | 2013-11-25 | UV curable ink of a kind of good toughness and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103666060B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103992239A (en) * | 2014-05-12 | 2014-08-20 | 洞头县恒立印刷材料有限公司 | A synthetic method of ultraviolet-curable amino methacrylate |
| CN111621197A (en) * | 2020-05-27 | 2020-09-04 | 江苏云合新材料科技有限公司 | Preparation method of water-based ink |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101659809A (en) * | 2009-01-14 | 2010-03-03 | 佛山市顺德区德美油墨化工有限公司 | Water-based UV black ink with super-high solid content and preparation method thereof |
| CN101824152A (en) * | 2010-04-13 | 2010-09-08 | 深圳职业技术学院 | Preparation method and application of resin having double curing groups |
| CN101962430A (en) * | 2010-08-27 | 2011-02-02 | 苏州嘉祥树脂有限公司 | Method for producing ultraviolet curable amino acrylate resin |
| CN102099427A (en) * | 2008-05-14 | 2011-06-15 | 玛莱宝两合公司 | Radiation-curable printing ink or printing lake |
| CN102977684A (en) * | 2012-12-07 | 2013-03-20 | 武汉大学 | Water-soluble (Ultra Violet) curing ink and preparation method thereof |
-
2013
- 2013-11-25 CN CN201310601293.4A patent/CN103666060B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102099427A (en) * | 2008-05-14 | 2011-06-15 | 玛莱宝两合公司 | Radiation-curable printing ink or printing lake |
| CN101659809A (en) * | 2009-01-14 | 2010-03-03 | 佛山市顺德区德美油墨化工有限公司 | Water-based UV black ink with super-high solid content and preparation method thereof |
| CN101824152A (en) * | 2010-04-13 | 2010-09-08 | 深圳职业技术学院 | Preparation method and application of resin having double curing groups |
| CN101962430A (en) * | 2010-08-27 | 2011-02-02 | 苏州嘉祥树脂有限公司 | Method for producing ultraviolet curable amino acrylate resin |
| CN102977684A (en) * | 2012-12-07 | 2013-03-20 | 武汉大学 | Water-soluble (Ultra Violet) curing ink and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103992239A (en) * | 2014-05-12 | 2014-08-20 | 洞头县恒立印刷材料有限公司 | A synthetic method of ultraviolet-curable amino methacrylate |
| CN111621197A (en) * | 2020-05-27 | 2020-09-04 | 江苏云合新材料科技有限公司 | Preparation method of water-based ink |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103666060B (en) | 2016-04-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103666032B (en) | A kind of ultraviolet light polymerization packaging ink and preparation method thereof | |
| CN103666060A (en) | UV-curing printing ink with high flexibility and preparation method thereof | |
| CN103666071A (en) | Light-curable printing ink used for silk screen printing and preparation method thereof | |
| CN103666043A (en) | UV printing ink having quick solidification effect and good adhesive attraction | |
| CN103666065A (en) | Ultraviolet-curable printing ink for surface printing and preparation method of ultraviolet-curable printing ink | |
| CN103666072B (en) | A kind of UV curable ink for electronic component mark and preparation method thereof | |
| CN103666079B (en) | A kind of silk screen printing UV curable ink and preparation method thereof | |
| CN103666046B (en) | A kind of novel ultraviolet light cured offset printing ink and preparation method thereof | |
| CN103666058A (en) | UV curing offset printing ink and preparation method thereof | |
| CN103666034B (en) | UV cured printing ink of the little good luster of a kind of viscosity and preparation method thereof | |
| CN103666055A (en) | Photo-cured and environment-friendly screen printing ink and preparation method thereof | |
| CN103666059A (en) | Ultraviolet-curing printing ink and preparation method thereof | |
| CN103666045A (en) | UV solidified printing ink with small particle size and low adhesive force, and preparation method of UV solidified printing ink | |
| CN103666070B (en) | UV curable ink of a kind of good toughness and preparation method thereof | |
| CN103666054A (en) | UV-curable printing ink used for processing organic glass and preparation method thereof | |
| CN103666062B (en) | A kind of ultraviolet curing embossed printing ink and preparation method thereof | |
| CN103666050B (en) | A kind of gloss silk-screen UV curing inks and preparation method thereof | |
| CN103666113B (en) | A kind of UV solidifies jetted ink and preparation method thereof | |
| CN103666064A (en) | Ultraviolet light curing quick-dry waterproof ink and preparation method thereof | |
| CN103666041B (en) | A kind of UV curable ink and preparation method thereof | |
| CN103666037B (en) | A kind of high-performance ultraviolet cured ink and preparation method thereof | |
| CN103666049B (en) | A kind of UV optic-solidified adhesive printing ink and preparation method thereof | |
| CN103666067A (en) | Flexible UV curing offset printing ink and preparation method | |
| CN103666047B (en) | A kind of ultraviolet cured offset printing ink and preparation method thereof | |
| CN103666103B (en) | A kind of spraying type ultraviolet cured ink and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20231211 Address after: No. 16, Nishan Road, Xianhua Street, Pujiang County, Jinhua City, Zhejiang Province, 322200 Patentee after: Pujiang Dazhong Printing Materials Co.,Ltd. Address before: 244000 No. 3201, Cuihu Fourth Road, Tongling Economic Development Zone, Anhui Province Patentee before: TONGLING FOUNDER PLASTICS TECHNOLOGY Co.,Ltd. |