CN103666062B - A kind of ultraviolet curing embossed printing ink and preparation method thereof - Google Patents
A kind of ultraviolet curing embossed printing ink and preparation method thereof Download PDFInfo
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- CN103666062B CN103666062B CN201310601764.1A CN201310601764A CN103666062B CN 103666062 B CN103666062 B CN 103666062B CN 201310601764 A CN201310601764 A CN 201310601764A CN 103666062 B CN103666062 B CN 103666062B
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Abstract
The invention discloses a kind of ultraviolet curing embossed printing ink, it is characterized in that, be made up of the raw material of following weight part: pigment dyestuff 1-3,196 unsaturated polyester resin 10-12, acrylic resin 10-12, resol 13-16, glycerine 2-3, DMF 3-4, trifluoroacetylacetone europium 1-2, tetrahydrofuran (THF) 1-3, Mono-n-butyltin 1-2, triethylene tetramine 5-8,2-Hydroxy ethyl acrylate 6-9, tripropylene glycol diacrylate 12-15, tri (propylene glycol) diacrylate 12-15,184 light trigger 5-8, auxiliary agent 4-5; Auxiliary agent of the present invention improves the toughness of ink, makes distributes ink even, and maintains the stability of ink; Ink of the present invention once can be imprinted on gold and silver paperboard, PVC or mute film by screen painting mode, and it only needs one-step print just can form type effect lucuriant in design, packs for top grade.
Description
Technical field
The present invention relates to a kind of ink and preparation method thereof, particularly a kind of ultraviolet curing embossed printing ink and preparation method thereof.
Background technology
Ultraviolet curing embossed printing ink is a kind of screen printing ink, irradiation through the ultraviolet lamp of specific wavelength forms type effect lucuriant in design, this ink can be widely used in high-grade packaging aspect, can be formulated into the bright-coloured embossed printing ink of shades of colour according to customer requirement, its curing speed and sticking power are all excellent.Existing ultraviolet curing embossed printing ink all needs repeatedly to print and could form type effect, easily like this occurs register trouble expense material consuming time.
Summary of the invention
The object of this invention is to provide a kind of ultraviolet curing embossed printing ink and preparation method thereof.
In order to realize object of the present invention, the present invention is by following scheme implementation:
A kind of ultraviolet curing embossed printing ink, be made up of the raw material of following weight part: pigment dyestuff 1-3,196 unsaturated polyester resin 10-12, acrylic resin 10-12, resol 13-16, glycerine 2-3, DMF 3-4, trifluoroacetylacetone europium 1-2, tetrahydrofuran (THF) 1-3, Mono-n-butyltin 1-2, triethylene tetramine 5-8,2-Hydroxy ethyl acrylate 6-9, tripropylene glycol diacrylate 12-15, tri (propylene glycol) diacrylate 12-15,184 light trigger 5-8, auxiliary agent 4-5;
Described auxiliary agent is prepared from by the raw material of following weight part: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, silane resin acceptor kh-550 2-3, methacrylic acid-2-hydroxy methacrylate 2-3, neopentyl glycol 5-8, vinyl acetate 12-15, linking agent TAC2-3, oxidation inhibitor 10352-3, N hydroxymethyl acrylamide 1-2, Tenox PG 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 DEG C, and stirring reaction 30-40 minute, to obtain final product.
Ultraviolet curing embossed printing ink of the present invention, be made up of following concrete steps: first add pigment dyestuff, 196 unsaturated polyester resins, acrylic resin, resol, glycerine 2-3, N, dinethylformamide, trifluoroacetylacetone europium, tetrahydrofuran (THF), Mono-n-butyltin, triethylene tetramine stirring and evenly mixing, be heated to 80-90 DEG C, stir 25-35 minute; Then all the other remaining components except 184 light triggers are added, stirring reaction 3-5 hour; Finally be cooled to 60-70 DEG C, add 184 light triggers, stirring reaction 40-50 minute, after cooling, grinding obtains 20-40 μm of slurry, to obtain final product.
The invention has the beneficial effects as follows: auxiliary agent of the present invention improves the toughness of ink, make distributes ink even, and maintain the stability of ink; It once can be imprinted on gold and silver paperboard, PVC or mute film by screen painting mode by ink provided by the invention, and it only needs one-step print just can form type effect lucuriant in design, packs for top grade.
Specific embodiments
Below by specific examples, the present invention is described in detail.
A kind of ultraviolet curing embossed printing ink, be made up of the raw material of following weight part (kilogram): pigment dyestuff 1,196 unsaturated polyester resin 10, acrylic resin 10, resol 13, glycerine 2, DMF 3, trifluoroacetylacetone europium 1, tetrahydrofuran (THF) 1, Mono-n-butyltin 1, triethylene tetramine 5,2-Hydroxy ethyl acrylate 6, tripropylene glycol diacrylate 12, tri (propylene glycol) diacrylate 12,184 light trigger 5, auxiliary agent 4;
Described auxiliary agent is prepared from by the raw material of following weight part (kilogram): nano diatomite powder 0.2, nano mica powder 0.2, silane resin acceptor kh-550 2, methacrylic acid-2-hydroxy methacrylate 2, neopentyl glycol 5, vinyl acetate 12, linking agent TAC2, oxidation inhibitor 10352, N hydroxymethyl acrylamide 1, Tenox PG 2, coix seed oil 1; Its preparation method is by each mixing of materials, is heated to 60-70 DEG C, and stirring reaction 30-40 minute, to obtain final product.
Ultraviolet curing embossed printing ink of the present invention, be made up of following concrete steps: first add pigment dyestuff, 196 unsaturated polyester resins, acrylic resin, resol, glycerine 2-3, N, dinethylformamide, trifluoroacetylacetone europium, tetrahydrofuran (THF), Mono-n-butyltin, triethylene tetramine stirring and evenly mixing, be heated to 80-90 DEG C, stir 25-35 minute; Then all the other remaining components except 184 light triggers are added, stirring reaction 3-5 hour; Finally be cooled to 60-70 DEG C, add 184 light triggers, stirring reaction 40-50 minute, after cooling, grinding obtains 20-40 μm of slurry, to obtain final product.
The ink of gained, uses cross-hatching ox-hide tape stripping, draws compartment apart from 1mm, 100% attachment; Use the spirituous cotton balls of leaching, 300 grams of pressure wipings 50 times, are as good as shape; To be soaked in salad oil (normal temperature) 8 hours, to be as good as shape; Use and be soaked with the cotton balls of salt solution, 300 grams of pressure wipings 50 times, are as good as shape.
Claims (2)
1. a ultraviolet curing embossed printing ink, it is characterized in that, be prepared from by the raw material of following weight part: pigment dyestuff 1-3,196 unsaturated polyester resin 10-12, acrylic resin 10-12, resol 13-16, glycerine 2-3, DMF 3-4, trifluoroacetylacetone europium 1-2, tetrahydrofuran (THF) 1-3, Mono-n-butyltin 1-2, triethylene tetramine 5-8,2-Hydroxy ethyl acrylate 6-9, tripropylene glycol diacrylate 12-15, tri (propylene glycol) diacrylate 12-15,184 light trigger 5-8, auxiliary agent 4-5;
Described auxiliary agent is prepared from by the raw material of following weight part: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, silane resin acceptor kh-550 2-3, methacrylic acid-2-hydroxy methacrylate 2-3, neopentyl glycol 5-8, vinyl acetate 12-15, linking agent TAC2-3, oxidation inhibitor 10352-3, N hydroxymethyl acrylamide 1-2, Tenox PG 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 DEG C, and stirring reaction 30-40 minute, to obtain final product.
2. ultraviolet curing embossed printing ink according to claim 1, it is characterized in that, be made up of following concrete steps: first add pigment dyestuff, 196 unsaturated polyester resins, acrylic resin, resol, glycerine 2-3, N, dinethylformamide, trifluoroacetylacetone europium, tetrahydrofuran (THF), Mono-n-butyltin, triethylene tetramine stirring and evenly mixing, be heated to 80-90 DEG C, stir 25-35 minute; Then all the other remaining components except 184 light triggers are added, stirring reaction 3-5 hour; Finally be cooled to 60-70 DEG C, add 184 light triggers, stirring reaction 40-50 minute, after cooling, grinding obtains 20-40 μm of slurry, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201310601764.1A CN103666062B (en) | 2013-11-25 | 2013-11-25 | A kind of ultraviolet curing embossed printing ink and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310601764.1A CN103666062B (en) | 2013-11-25 | 2013-11-25 | A kind of ultraviolet curing embossed printing ink and preparation method thereof |
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| CN103666062A CN103666062A (en) | 2014-03-26 |
| CN103666062B true CN103666062B (en) | 2016-04-13 |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101275043A (en) * | 2007-03-28 | 2008-10-01 | 樊官保 | Environment-friendly water-soluble plate engraving ink |
| CN102300942A (en) * | 2009-01-29 | 2011-12-28 | 东海染工株式会社 | Marking ink |
| CN102643568A (en) * | 2011-02-17 | 2012-08-22 | 富士胶片株式会社 | Ink composition, ink set and image forming method |
| CN102827513A (en) * | 2012-09-04 | 2012-12-19 | 上海蓝沛新材料科技股份有限公司 | Photopolymerisable catalytic printing ink and application thereof |
| CN102876113A (en) * | 2011-07-14 | 2013-01-16 | 纪州技研工业株式会社 | Inkjet ink and printing methods |
| CN103342921A (en) * | 2013-07-29 | 2013-10-09 | 中国科学院化学研究所 | Ink with high hiding rate for ink-jet printing and application thereof to preparation of flexible plate |
-
2013
- 2013-11-25 CN CN201310601764.1A patent/CN103666062B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101275043A (en) * | 2007-03-28 | 2008-10-01 | 樊官保 | Environment-friendly water-soluble plate engraving ink |
| CN102300942A (en) * | 2009-01-29 | 2011-12-28 | 东海染工株式会社 | Marking ink |
| CN102643568A (en) * | 2011-02-17 | 2012-08-22 | 富士胶片株式会社 | Ink composition, ink set and image forming method |
| CN102876113A (en) * | 2011-07-14 | 2013-01-16 | 纪州技研工业株式会社 | Inkjet ink and printing methods |
| CN102827513A (en) * | 2012-09-04 | 2012-12-19 | 上海蓝沛新材料科技股份有限公司 | Photopolymerisable catalytic printing ink and application thereof |
| CN103342921A (en) * | 2013-07-29 | 2013-10-09 | 中国科学院化学研究所 | Ink with high hiding rate for ink-jet printing and application thereof to preparation of flexible plate |
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| CN103666062A (en) | 2014-03-26 |
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